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                <text>Faculty Publications</text>
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              <text>Jacob, Evin; Varghese, Anitha</text>
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              <text>Electrosynthesized Metal/Polymer Hybrid: Unlocking Selective Formate Production via CO2Electroreduction</text>
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              <text>01-01-2025</text>
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              <text>ACS Sustainable Resource Management;Volume;2;Issue;8;pp.1437-1448</text>
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              <text>&lt;a href="https://doi.org/10.1021/acssusresmgt.5c00204" target="_blank" rel="noreferrer noopener"&gt;https://doi.org/10.1021/acssusresmgt.5c00204&lt;/a&gt; &lt;br /&gt;&lt;br /&gt;&lt;a href="https://www.scopus.com/pages/publications/105021883578?origin=resultslist" target="_blank" rel="noreferrer noopener"&gt;https://www.scopus.com/pages/publications/105021883578?origin=resultslist&lt;/a&gt;</text>
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              <text>Jacob E., Department of Chemistry, Christ University, Karnataka, Bangalore, 560029, India; Varghese A., Centre for Renewable Energy and Environmental Sustainability, Christ University, Karnataka, Bangalore, 560029, India</text>
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              <text>Carbon dioxide reduction via electrochemical means offers a sustainable pathway to mitigate CO2emissions and synthesize value-added chemicals. Here, we report the synthesis and performance of a metal/polymer-carbon paper (CuxOy/PoPD/CFP) electrode prepared via a simple two-step in situ electrodeposition method for the electrochemical CO2reduction reaction (CO2ER). Unlike most reported catalysts that yield multiple liquid products and complicate downstream separation processes, CuxOy/PoPD/CFP selectively produces formate as the sole liquid product across all of the test potentials. The amine-rich and porous PoPD matrix synergistically enhanced CO2capture, provided a conductive scaffold for efficient electron transfer, and facilitated intimate interfacial contact with copper oxides, enabling improved catalytic performance. The catalyst demonstrated an onset potential of ??0.27 V (vs RHE) and achieved a faradaic efficiency of 72.6% for formate with a current density of 6.70 mA/cm2at ?0.80 V (vs RHE). Studies showcased an electrochemically active surface area (ECSA) of 16.625 cm2and a roughness factor of 8.31. The long-duration electrolysis experiment demonstrated stable performance for an extended period, maintaining continuous electrolysis for up to 9.5 h without significant fluctuations or degradation in activity.  2025 American Chemical Society</text>
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              <text>carbon fiber paper electrode; CO&lt;sub&gt;2&lt;/sub&gt;electroreduction reaction; electrodeposition; metalpolymer hybrid</text>
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              <text>American Chemical Society</text>
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              <text>ISSN: 28371445;</text>
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              <text>Restricted Access; Hardcopy may be available in the library</text>
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              <text>online</text>
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