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                <text>Jose J., Department of Chemistry, Christ University, Bengaluru, 560029, India; Binish C.J., Department of Chemistry, Christ University, Bengaluru, 560029, India; Johns J., Department of Physics, Rajarajeswari College of Engineering, Mysore Road, Bengaluru, 560074, India; Harisha G., Department of Physics, SJC Institute of Technology, Karnataka, Chickballapur, 562101, India; Murugendrappa M.V., Department of Physics, BMS College of Engineering, Bangalore, 560019, India; Chundattu S.J., Department of Sciences and Humanities, Christ University, Bengaluru, 560074, India; Vijayasankar V.A., Department of Chemistry, Christ University, Bengaluru, 560029, India</text>
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                <text>Arecanut organic residue (AR) incorporated polyvinyl alcohol (PVA)-chitosan (CH) films were successfully synthesized using the solvent casting method, aiming to enhance structural rigidity and dielectric performance. The novelty of this work lies in utilizing AR, a sustainable agricultural byproduct, as a natural functional additive to enhance the dielectric and thermal stability of PVAchitosan blends. This eco-friendly approach introduces a biogenic interfacial modifier that improves polymer compatibility and performance without relying on synthetic fillers or chemical cross-linkers. FTIR spectra revealed the existence of cross-linking between PVA, chitosan and AR. Thermogravimetric analysis revealed that AR-PVA-CH films exhibited enhanced thermal stability compared to pure PVA, chitosan and PVA-CH blend. The dielectric constant, dielectric loss, DC conductivity, polarization and permittivity of pure PVA, pure chitosan, PVA-CH and AR-PVA-CH films were analysed in the frequency range from 100Hz to 100kHz. The optimized formulation (AR-C4) exhibited a maximum dielectric constant of 224.31 at 1kHz, significantly higher than that of the pristine PVACH blend. The improvement in thermal stability has also been emphasized by indicating the increase in the T?? value from 279.66C for PVACH to 358.37C for AR-C4. Furthermore, the enhancement in AC conductivity from 1.23 10?10 S/m for the PVACH blend to 5.93 108 S/m for AR-C5 has been mentioned, demonstrating the synergistic influence of arecanut residue on charge transport and interfacial polarization. This research showcases that AR-induced structural changes in PVA-chitosan films lead to a notable improvement in their dielectric properties, making them promising candidates for advanced dielectric and thermal applications.  The Polymer Society, Taipei 2025.</text>
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                <text>Arecanut organic residue-enhanced polymer films: An efficient catalyst for amidation reactions</text>
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                <text>Jose J., Department of Chemistry, CHRIST University, Bengaluru, 560029, India; C J B., Department of Chemistry, CHRIST University, Bengaluru, 560029, India, Centre for Renewable Energy and Environmental Sustainability, CHRIST University, Bengaluru, 560029, India; Johns J., Department of Physics, Rajarajeswari College of Engineering, Mysore Road, Bengaluru, 560074, India; Chundattu S.J., Department of Sciences and Humanities, CHRIST University, Bengaluru, 560074, India; A V V., Department of Chemistry, CHRIST University, Bengaluru, 560029, India, Centre for Renewable Energy and Environmental Sustainability, CHRIST University, Bengaluru, 560029, India</text>
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                <text>This research introduces an innovative approach to repurpose agricultural by-products as catalysts in chemical synthesis, addressing waste disposal challenges. Composite films were developed using arecanut organic residue, an underexploited by-product, blended with polyvinyl alcohol (PVA) and chitosan. The films were synthesized through solvent casting and thermal curing, with experimental parameters systematically optimized. Physicochemical characterization confirmed successful integration of components and revealed structural properties. The catalytic efficiency of the films was evaluated in amide synthesis, a key reaction in pharmaceuticals. A blend of 1.5 g PVA, 0.3 g chitosan, and 1 mL arecanut residue achieved a 95 % yield in ester-amine reactions, attributed to synergistic interactions between the polymer matrix and reactive sites. The films exhibited excellent reusability, maintaining catalytic efficiency over three cycles. This study highlights the potential of arecanut residue-based composites as sustainable, efficient catalysts for industrially relevant transformations.  2025 Korean Physical Society</text>
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                <text>The specific atoms or group of atoms that can attach to the other organic or inorganic compounds due to the strong affinity is called as the anchoring group. The electrons from these organic and inorganic compounds are potent to travel through the anchor group. This leads to specific features with the change in the arrangement of atoms in the entire molecule/system. Hence, the redox reaction properties, molecular chain length and the extent of conjugation of the resultant anchored product vary. Depending upon the binding nature, anchoring groups can be divided into monodentate, bidentate, and multidentate. Among these, multidentate anchoring groups are more significant since it can bind either partially to the molecules or withthe whole surface. Though many multidentate anchoring groups like fullerene, carbon nanotubes, polymers, calixarenes, and graphene are presented in the literature, graphene oxide anchored organic and inorganic compounds are important because of its amazing contributions to the material science and design. The high thermal and electrical conductivity, large surface area, mechanical strength, and availability of more mobile electrons make graphene as the suitable anchor group for diverse applications in the field of adsorption of polluted gases, catalyst for the organic conversions, medicinal chemistry, electrochemical sensing, and energy storage devices. Therefore, Graphene oxide (GO) is one of the good choices to develop supercapacitance systems and electrochemical sensing materials. Heteroatom doping, conducting polymer, metal complexes, and metal oxides anchored graphene oxide are more significant because they change the electroactive properties significantly. Considering these, we studied the photophysical and electrochemical properties of chromium complex anchored GO synthesised by silane and diazonium coupling. The results exhibited that both silane functionalized GO and azo dye enable an electronic interaction due to the recombination of sp2 and sp3 states and electron-hole pairs which have extensive importance in developing optoelectronic devices. </text>
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                <text>The specific atoms or group of atoms that can attach to the other organic or inorganic newlinecompounds due to the strong affinity is called as the anchoring group. The electrons newlinefrom these organic and inorganic compounds are potent to travel through the anchor newlinegroup. This leads to specific features with the change in the arrangement of atoms in newlinethe entire molecule/system. Hence, the redox reaction properties, molecular chain newlinelength and the extent of conjugation of the resultant anchored product vary. Depending upon the binding nature, anchoring groups can be divided into monodentate, bidentate, and multidentate. Among these, multidentate anchoring groups are more significant since it can bind either partially to the molecules or with the whole surface. Though many multidentate anchoring groups like fullerene, carbon nanotubes, polymers, calixarenes, and graphene are presented in the literature, newlinegraphene oxide anchored organic and inorganic compounds are important because of its amazing contributions to the material science and design. The high thermal and electrical conductivity, large surface area, mechanical strength, and availability of more mobile electrons make graphene as the suitable anchor group for diverse applications in the field of adsorption of polluted gases, catalyst for the organic conversions, medicinal chemistry, electrochemical sensing, and energy storage devices. Therefore, Graphene oxide (GO) is one of the good choices to develop supercapacitance systems and electrochemical sensing materials. Heteroatom doping, conducting polymer, metal complexes, and metal oxides anchored graphene oxide are more significant because they change the electroactive properties significantly. Considering these, we studied the photophysical and electrochemical properties of chromium complex anchored GO synthesised by silane and diazonium coupling.</text>
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                <text>Jose J., Department of Chemistry, Christ University, Hosur Road, Bengaluru, 560029, India; Mathew A.J., Department of Chemistry, Christ University, Hosur Road, Bengaluru, 560029, India; Gabriel E., Department of Chemistry, Christ University, Hosur Road, Bengaluru, 560029, India; James A., Department of Chemistry, Christ University, Hosur Road, Bengaluru, 560029, India; Vinod T.P., Department of Chemistry, Christ University, Hosur Road, Bengaluru, 560029, India, Centre for Renewable Energy and Environmental Sustainability, Christ University, Bengaluru, 560029, India</text>
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                <text>This study reports the synthesis of fluorescent nanocellulose from Plectranthus barbatus and its effective use as a fluorescent probe for the detection of Pb(ii) ions in aqueous solutions. Nanocellulose, a nanoscale derivative of cellulose, is used in a variety of applications, such as sensing, food packaging, and biomedical applications, owing to its characteristic properties. In sensing applications, it is mostly used as a support or substrate for the sensing probe. Nanocellulose shows intrinsic fluorescence, which can be harnessed for sensing applications. This underexplored research domain holds significant potential for developing sustainable and cost-effective sensing materials. We synthesized nanocellulose from Plectranthus barbatus (PBNC) and employed it as a fluorescent probe for the detection of Pb(ii). To the best of our knowledge, this is the first report demonstrating the potential of fluorescent nanocellulose for metal ion detection. The properties of fluorescent nanocellulose, PBNC, were studied using Fourier Transform Infrared (FTIR) spectroscopy, X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM), and Photoluminescence (PL) spectroscopy. The fluorescence intensity of the nanocellulose was remarkably quenched in the presence of Pb(ii) ions selectively. The detection limit (LOD) of Pb(ii) using PBNC was found to be 2.7 nM. PBNC is a novel autofluorescent material that functions as an efficient nanosensor for the detection of Pb(ii) ions, and its applications can be extended to bio-imaging and sensing in biological, chemical, and environmental samples. This journal is  The Royal Society of Chemistry, 2026.</text>
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                <text>Jose J., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bengaluru, India; P. S. A., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bengaluru, India; Vinod T.P., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bengaluru, India</text>
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                <text>Polyurethane (PU) is composed of polyisocyanate and polyol units joined through urethane linkages. The isocyanate and polyol units constitute different domains in PU, which are, in turn, responsible for its properties such as softness, flexibility, and hardness. Shielding of electromagnetic (EM) radiation is generally attained by reflecting EM waves from the surface, absorbing the signals, or by multiple internal reflections. Pristine PU is not an efficient electromagnetic interference (EMI) shielding material because of its nonconducting nature. But the EMI shielding can be improved by incorporating conducting polymers into the PU-based nanocomposite. Significant factors that influence the shielding effect of PU nanocomposites are the thickness and conductivity of the film. Features that predominantly influence the EMI shielding performance of nanocomposites are identified as the nanofillers used, the dispersion state, and the interaction between the filler and the polymer. This book chapter attempts to explain the EMI shielding of PU nanocomposites, synthesis of PU-based EMI shielding materials, different nanofillers used along with PU nanocomposites, and their efficiency in EMI shielding.  2026 Elsevier Ltd. All rights reserved.</text>
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                <text>Midrib of coconut (Cocos nucifera) is a natural source of cellulose, which is renewable and biodegradable. The use of natural cellulose for practical applications exemplifies a sustainable reuse of agricultural waste. This work presents the preparation of nanocellulose from coconut midrib using optimized pretreatment and acid hydrolysis processes. The resulting nanocellulose was characterized through various analyses to confirm the morphology and composition. Nanocellulose thus synthesized was used for preparing cellulose nanopaper. In order to improve the water resistance of the cellulose nanopaper, we used a simple approach of functionalization by impregnating it with chitosan (CS), followed by in situ polymerization of polypyrrole (PPy) in the matrix. The functionalized cellulose nanopaper shows good electrical conductivity and an electromagnetic interference (EMI) shielding effectiveness of 21.92 dB at 10 GHz, which makes it a potential material for EMI shielding applications. In addition, the functionalized cellulose nanopaper exhibits bacterial reductions of 93.47% and 82.79% towards Staphylococcus aureus and Escherichia coli, respectively. This work provides a facile and efficient method for the synthesis of nanocellulose from coconut midrib and a useful approach to functionalize cellulose nanopaper. Cellulose nanopapers thus prepared were demonstrated to have applications in EMI shielding and antibacterial coating.  2025 The Royal Society of Chemistry.</text>
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