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                <text>Detection of explosive picric acid via ESIPT-inhibited fluorescent chemosensor: theoretical insights, vapour phase detection and flexible indicator design</text>
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                <text>S P., Department of Chemistry, Christ University, Hosur Road, Karnataka, Bangalore, 560029, India, Centre for Renewable Energy and Environmental Sustainability, Christ University, Karnataka, 560029, India; Semwal K., Department of Chemistry, Christ University, Hosur Road, Karnataka, Bangalore, 560029, India, Centre for Renewable Energy and Environmental Sustainability, Christ University, Karnataka, 560029, India; S V., Department of Chemistry, Christ University, Hosur Road, Karnataka, Bangalore, 560029, India, Centre for Renewable Energy and Environmental Sustainability, Christ University, Karnataka, 560029, India; Salian R.D., Department of Physics and Electronics, Christ University, Bangalore, 560029, India; Kumbhakar P., Department of Physics and Electronics, Christ University, Bangalore, 560029, India; Das A.K., Department of Chemistry, Christ University, Hosur Road, Karnataka, Bangalore, 560029, India, Centre for Renewable Energy and Environmental Sustainability, Christ University, Karnataka, 560029, India</text>
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                <text>A fluorescent probe, (E)-2-((benzo[d]thiazol-2-ylimino)methyl)-5-(diethylamino)phenol (BMP), was designed and synthesized using 4-(diethylamino)-2-hydroxybenzaldehyde and benzothiazole-2-amine, and subsequently characterized for its selective turn-off response toward picric acid (PA). Upon the gradual addition of PA, significant changes in the absorption and fluorescence spectra were observed, marked by strong fluorescence quenching even in the presence of competing nitroaromatic compounds. BMP exhibited two absorption signals at 350 nm and 433 nm with a prominent emission band at 488 nm, attributed to excited-state intramolecular proton transfer (ESIPT), accompanied by a large Stokes shift of 138 nm. The interaction between PA and the hydroxyl group of BMP effectively suppressed the ESIPT process, leading to the observed spectral variations. The binding interactions were further confirmed through NMR spectroscopy and density functional theory (DFT) calculations. The ligand BMP has been utilized as a selective chemosensor for PA with a 2-fold reduction in fluorescence intensity and 19-fold increment in absorption intensity, showing a binding affinity of 2 104 M?1 and strong quenching efficiency toward picric acid, with a SternVolmer constant (Ksv) of 14.059 M?1 with a limit of detection (LOD) of 4.87 ?M. For practical implementation, BMP was successfully employed in a dipstick-based detection format for vapor-phase sensing. Moreover, BMP-embedded polymer films demonstrated excellent potential as solid-state fluorescent sensors, exhibiting visible fluorescence quenching upon exposure to PA. Their rapid, time-dependent emission response under UV light allows for convenient, on-site detection using devices such as smartphones, making them highly promising for real-world applications in explosives detection and environmental monitoring. This journal is  The Royal Society of Chemistry, 2025</text>
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The achievement of an organization's goals is impossible without effective human resource management. The research focuses on the human resource practices of retail organisations, which have an impact on both employee and organizational performance. The primary goal of this paper is to investigate the human resource management practices used in India's organised retail sector. A questionnaire is used to collect the most important data.</text>
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                <text>The exponential growth of the capital market witnessed in recent years had resulted in a near complete breakdown of the paper based transaction system. The amount of capital raised has shot up, the number of issues had increased substantially, trading volumes on the stock exchanges had grown several fold and the markets had become institutionalised with the entry of Foreign Institutional Investors (FIIs) and private mutual funds. As a result, there had been an increase in paper work causing a gridlock at every stage. This delays the clearance and settlement of trades, registration of securities and increases back office paper work for intermediaries. The outdated systems had increased settlement risks and have rendered the implementation of a Delivery versus Payment (DP) system impossible. The systemic risks face further threat by theft, forgery, bad delivery, issue of fake share certificates and loss of certificates. This had eroded investor confidence.</text>
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