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Priority based prediction mechanism for ranking providers in federated cloud architecture
Cloud computing is a growing and excellent technology, as exponentially increasing the interest among users to utilize cloud applications; they need to depend on any one of the particular service provider. Now a days number of service providers also rapidly increasing in wide range, this leads ambiguity and distrust among the users. In this paper, enhanced broker based federated cloud architecture is proposed to resolve the selection of service provider issue using grading techniques and results proved that better performance improvement than single service provider selection. This broker architecture also addresses to selects the appropriate service provider automatically in the federated cloud architecture for the users submitted requests by previous experience with help of Bayesian network model. The former one implemented through concept of grade system. It is constructed for categorizing the providers based on the level of available resources. Grade and grade values distributed by applying the grade distribution algorithm for distinguishes the components. Total grade values computed for every service provider and sorted using quick sort algorithm to grade the cloud service providers. Priority based feedback decision tree technique added with this for separates similar grade cloud service provider in the selected list. Second Bayesian network model also used to rank the cloud service providers according to the previous performance of the providers with customers. Probability of satisfied customers feedback calculated for individual Service Measurements Index of Cloud Service Providers. 2018, Springer Science+Business Media, LLC, part of Springer Nature. -
Utilization of CO2 for Electrocarboxylation of Benzophenone Using MXene-Based Electrodes: A Sustainable Approach
The significant rise in atmospheric carbon dioxide (CO2) levels has prompted the need to develop efficient methods for CO2 conversion and fixation methods. Electrocarboxylation reaction is a highly efficient and sustainable method for activating and utilizing CO2, yielding essential carboxylic acids and their analogues, which are important intermediates in the pharmaceutical and fuel industries. This research demonstrates the efficiency of 2D Ti3C2Tx and Ta2CTx MXene-modified carbon fiber paper electrodes (Ti3C2Tx/CFP and Ta2CTx/CFP) for CO2 fixation with benzophenone in a tetrabutylammonium bromide/acetonitrile (TBABr/CH3CN) medium, yielding benzilic acid. Ti3C2Tx/CFP exhibited superior electrocatalytic activity with a lower reduction potential for benzophenone at ?1.0 V and achieved a 72% yield of benzilic acid at an optimum current density of 50 mA cm-2. In comparison, Ta2CTx/CFP exhibited a cathodic peak at ?1.08 V, producing a 66% yield at 70 mA cm-2. The electron paramagnetic resonance spectrum substantiates the generation of reactive radical intermediates during the reaction. Ti3C2Tx/CFP showed robust structural stability with ?88% Faradaic efficiency and a turnover frequency of 1.90444 10-5 s-1, indicating its potential for CO2 fixation. 2024 American Chemical Society. -
A facile, green synthesis of carbon quantum dots from Polyalthia longifolia and its application for the selective detection of cadmium
Carbon quantum dots (CQDs) has received world-wide recognition for their outstanding physicochemical properties that have the ability to substitute the semiconductor quantum dots. Herein, we have developed a strategy to determine the presence of Cd2+ using CQDs as a fluorescence probe. The CQDs were synthesized from the leaves of Polyalthia longifolia (a natural source) through a one-step hydrothermal method. The CQDs obtained from Polyalthia longifolia (p-CQDs) was characterized using XRD, TEM, FTIR, Raman Spectroscopy, XPS Studies, UVVisible spectroscopy and PL Spectroscopy. The p-CQDs displayed bright red fluorescence under the UV light, with good water solubility, and appreciable photostability and a quantum yield of 22%. The p-CQDs had a quasi-spherical morphology with an average particle size of 3.33 nm. The p-CQDs showed high selectivity and sensitivity for the detection of Cd2+ with a low limit of detection of 2.4 nM and a wide linear range of 7.3 nM12 ?M. The PL intensity of the p-CQDs showed a quenching effect in presence of Cd2+ and the mechanism of quenching was validated via fluorescence lifetime decay studies. We have also studied the effectiveness of the fluorescent probe developed for Cd2+ sensing in real samples of ground water and industrial effluents. 2022 Elsevier Ltd -
Bounds related to product variants of graphs
Operations in graph theory have a significant influence in the theoretical and application aspect of the domain. Topological indices serve as a crucial component in chemical graph theory linked with some molecular structure. Recently, the study on the new graph product variants is initiated. In the article, the computation of some bounds for atom-bond connectivity index, inverse sum indeg index, geometric-arithmetic index and sombor index of graph operations notably the corona join product, subdivision vertex join product and the subdivision vertex-edge join is carried out. Palestine Polytechnic University-PPU 2023. -
Bounds of Sombor Index for F-Sum Operation
Graph operations have a major impact in the aspects of theory and empirical literature of the domain. For relating the molecular topology to any real chemical attribute, the conversion of the relevant details embedded into chemical structure to some numeric value becomes so vital which ultimately paves the way for the emergence of topological indices. Topological descriptor acts as an effective graph invariant in chemical graph theory associated with certain molecular structure. Recently, the study on the sombor index is initiated by I.Gutman [16]. In the article, we utilise combinatorial inequalities, including the general sum-connectivity index, the first general zagreb index and few other indices in their formulations, for the determination of bounds for sombor index for the F-sum operation of connected graphs. Palestine Polytechnic University-PPU 2023. -
QSPR Analysis of Polycyclic Aromatic Hydrocarbons
Topological indices serve as a crucial component in chemical graph theory linked with some molecular structure. The First and Second Zagreb Indices are one among the earliest and extensively explored molecular descriptors. The study on equitable zagreb indices have been initiated earlier by Akram Alqesmah, Anwar Alwardi and R. Rangarajan based on the equitable degree of the vertices. In this paper, we introduce the first and second equitable and non-equitable zagreb polynomials and compute the exact values of the respective equitable and non-equitable zagreb indices for polycyclic aromatic hydrocarbons. We have also utilised certain formulations for the determination of the corresponding relative equitable and non-equitable zagreb indices of the chemical graph. Further, QSPR analysis is carried out for the topological indices with regard to the physico-chemical properties of the polycyclic hydrocarbon molecules. 2022, Books and Journals Private Ltd.. All rights reserved. -
ON THE INDICES OF CERTAIN GRAPH PRODUCTS
Molecular descriptors are numerical graph invariants that are used to study the chemical structure of molecules. In this paper, we determine the upper bound of the Sombor index based on four operations involving the subdivision graph, semi-total point graph, semi-total line graph, and total graph related to the lexicographic and tensor product. The exact expressions of the first reformulated Zagreb index and the second hyper-Zagreb index of the tensor product are formulated on the basis of the four significant graphs. Further, the descriptors for certain standard graphs are obtained and the graphical comparison for the first reformulated Zagreb index has also been illustrated to understand the result better. 2025 University of Isfahan -
ON SECOND HYPER-ZAGREB INDEX OF CORONA PRODUCTS RELATED TO R-GRAPHS
The cognitive and evidential features of the graph discipline are significantly influenced by the implementation of graph operations. Molecular descriptor acts as a fundamental network invariant relevant to a particular molecular structure in the framework of chemical graph theory. The semi-total point graph features the edges of subdivision graph as well as the edges of the original graph. In this paper, we explore combinatorial inequalities associated with the edges, vertices and its corresponding neighborhood notions along with the inclusion of other molecular descriptors in the computations for the determination of exact expressions of second hyper-Zagreb index for certain corona products involving the semi-total point graph. 2023 Academic Publications -
QSPR ANALYSIS OF CERTAIN ANTI-HIV DRUGS
A broad spectrum of advanced medications appears yearly following the accelerated evolution of the chemical and pharmaceutical industry. In this paper, various degree-based and neighborhood degree sum-based topological indices of some anti-HIV drugs are explored applying the M-polynomial and NM-polynomial formulations. Moreover, QSPR analysis is carried out for the topological indices with regard to the physico-chemical properties of the anti-HIV drugs. The activity of nucleoside and non-nucleoside reverse transcriptase inhibitors is implemented as in drug configuration to manifest the significance of topological indices in the medicinal world. The procured outcomes affirm that topological indices being stud- ied reflect effective correlation in accordance to physical and chemical properties of the anti-HIV drugs and consequently can assist in development of advanced and promising pharmaceutical for HIV medication. 2022, RAMANUJAN SOCIETY OF MATHEMATICS AND MATHEMATICAL SCIENCES. All rights reserved. -
Bounds on Sombor index of graph operations
Operations in graph theory have a significant influence in the theoretical and application aspect of the domain. Topological indices serve as a crucial component in chemical graph theory linked with some molecular structure. Recently, Gutman initiated the study on the Sombor index. In this paper, the computation of some bounds for Sombor index of graph operation notably join, cartesian product, corona product, lexicographic product, tensor product and strong product is carried out. The computation has been utilized to determine the upper bounds of the index for the specified graph operations for some standard graphs like the path and cycle graphs. 2025 World Scientific Publishing Company. -
Bounds on Sombor Index for Corona Products on R-Graphs
Operations in the theory of graphs has a substantial influence in the analytical and factual dimensions of the domain. In the realm of chemical graph theory, topological descriptor serves as a comprehensive graph invariant linked with a specific molecular structure. The study on the Sombor index is initiated recently by Ivan Gutman. The triangle parallel graph comprises of the edges of subdivision graph along with the edges of the original graph. In this paper, we make use of combinatorial inequalities related with the vertices, edges and the neighborhood concepts as well as the other topological descriptors in the computations for the determination of bounds of Sombor index for certain corona products involving the triangle parallel graph. 2024 Azarbaijan Shahid Madani University. -
Extremal reformulated forgotten index of trees, unicyclic and bicyclic graphs
The reformulated forgotten index (RF) is the edge version of the ordinary forgotten index. We describe graph transformations, by means of which RF increases or decreases. Using these transformations, the trees, unicyclic, and bicyclic graphs extremal w.r.t. RF are characterized. 2024, University of Nis. All rights reserved. -
ON TRANSFORMED GRAPHS
The network systems and graphical analysis through the study of structural characteristics is a vast field of growing importance in research. Topological indices have a significant and crucial role in the study of structureproperty relationships. In this paper, we examine constructional transformed networks constructed by unique vertex-edge incidence and mutual adjacency associations. Expressions for the first and second hyper Zagreb indices and co-indices of these transformed networks and their complements are obtained. 2023, RAMANUJAN SOCIETY OF MATHEMATICS AND MATHEMATICAL SCIENCES. All rights reserved. -
Using Behavioural Economics to Analyse and Enhance Contraception Usage Decisions
Existent literature helped narrow down variables influencing modern contraceptive adoption (usage), a behaviour carrying enormous positive externality. Using finite population sample size formula and probability proportional to size method of sample selection, primary data was collected from participants using inclusion and exclusion criterions. Binary logistic regression model was used to predict probability of occurrence of dependent variable usage of modern method of contraception being treated at a dichotomous outcome level. Predictor variables after confirming association by cross tabulation were introduced stepwise to build model subject to elimination of those variables adding insignificantly to the overall predictability of the model. Variables such as gender, education level, spousal influence, extended family influence, financial well-being and contraceptive information were found to significantly predict the probability of occurrence of the dependent variable. Except for financial well-being with three sub-categories, other independent variables were treated at dichotomous level. Income level was found to be an important predictor although found statistically insignificant. Non-contributory factors such as age, occupation and years of marriage were dropped. Post-model construction, borrowing nudges from behavioural economics (BE) domain, strategies to nurture the significant context specific influencing variables, were articulated. BE was particularly preferred for its openness to the paradigm of non-rational behavioural choices. 2022 SAGE Publications. -
Should we judge phcs by only iphs guidelines or probe further?
Background: Indian Public Health Standards (IPHS) evaluates supply side compliance of Primary Health Centers (PHCs). Patient Satisfaction (PS) on the other hand, assesses the demand side. Objective: Examining the supply side compliance and relating it to PS in the domain of Reproductive Health (RH). Methods: Using multistage stratified sampling, six rural and three urban PHCs in sub-districts, Ramanagara and Channapatna, in District Ramanagara, state of Karnataka, India, were chosen. Information collected using IPHS proforma for PHCs was compared with PS questionnaire (PSQ 18) data, collected from 398 patients visiting these facilities. Results: Using descriptive and inferential analysis, sub-optimal compliance levels in ease of access, physical & human infrastructure, patient data and usage of untied funds was found. Existing behavioral compliance was found to be optimal. These findings were in alignment with PS findings. Conclusion: Results call for PHC capacity building, incentivization and a crucial need to look into PS side, before passing judgement about performance standard. 2020, Indian Association of Preventive and Social Medicine. All rights reserved. -
Are muslims incurring higher out-of-pocket expenditures than hindus in reproductive healthcare at sub-district levels in Karnataka?
Background and Objective: This study was undertaken to evaluate level of differences found in Out-of-pocket expenditures (OOPE) among Hindus and Muslims, OOPE being a sub-component while constructing reproductive health account (RHA) matrices for Ramanagara district, Karnataka. Method: Adopting multistage stratified sampling method, individual level data was collected using survey tools, catering to six dimensions of RH functions, taken from WHO Guide to produce RH Sub-Account. 517 Hindu and Muslim men and women meeting inclusion criteria of reproductive age (15-49) incurring RH expenditures in last one year were included followed later by only 382 uninsured individuals for hypothesis testing. Results: Muslims showing almost double OOPE in RH necessitated hypothesis testing of significant difference in OOPE, equating groups, post exclusion of insured individuals. Statistically significant difference was revealed in RH expenditures using Mann-Whitney U test. Interpretations and conclusions: Vicious cycle of disparity in education levels, lower income levels, negligible health coverage, strenuous work conditions, poor living standards, repeated RH contingencies leading to massive borrowing financed OOPE in RH continues. 2019, Indian Journal of Public Health Research and Development. All rights reserved. -
COVID-19: Trend analysis for market arrival of green gram in India
The unprecedented crisis hovering over the world due to Covid-19 pandemic has structurally impacted every sector of the world economy. This paper attempts to study the impact of ongoing pandemic in the agricultural sector specific to pulses in India. This paper finds that there is a significantly negative impact of Covid-19 on the pulses market. The market arrival of pulses has declined in the recent period while market demand for pulses has increased, therefore, there exists a supply side shortage for pulses in the domestic economy of India. This paper suggests that Government of India (Agriculture Department) urgently needs to deal with this shortage in supply of domestic pulses in "mandis" (agricultural markets). In this paper market arrival for pulses particularly green gram (Moong whole) has been forecasted for the next few months in Indian Agricultural Markets with the forecasting techniques such as Auto Regressive Integrated Moving Average (ARIMA) model and Artificial Neural Network (ANN) technique for pre and during pandemic period by using the arrival data in agriculture markets of India from Agmarknet. The results of this study using ARIMA models and ANNs have been compared to obtain the final conclusions with higher visibility in forecasting performance, which shows that there will be a sharp decline in market arrival with an average arrival of 494 quintals per day which can be maximized up to 623 quintals per day by stimulating the modal price at maximum possible point. Therefore, the urgent need of upscaling the technical efficiency of the farmers in different agro-climatic zones is needed to meet the domestic demand with domestic supply. 2020 DAV College. All rights reserved. -
Sustainable approach to life in water: Science and ethics of the oceans
Oceans have always remained a mystery to humankind. We owe the oceans the very air we breathe. Oceans are storehouses of nutrient rich food that can alleviate the hunger of many generations to come, offer rich minerals and medicines to cure many diseases, regulate the temperature of our planet, stabilize weather patterns, and provide livelihood for many in the fishing and tourism industry. But sadly they are overexploited and polluted to the core. The very fact that these mighty oceans have started showing the ill effects of anthropogenic activities itself is testimony to the tremendous greed of humanity. Among all the mighty oceans, the Arctic ocean is the most sensitive and vulnerable to these changes as it holds a pivotal position in maintaining life on Earth by different mechanisms. The Sustainable Development Goal (SDG) 14 of the United Nations underlines the urgent need to conserve marine resources and give equal rights to people in all countries to enjoy these resources. The current review is an attempt to highlight the enormous number of ways in which oceans have helped humankind, the serious threats the oceans are facing now, and how best we can have a sustainable approach to halt the total crashing of our great ocean systems. 2021 Journal of Dharma: Dharmaram Journal of Religions and Philosophies (DVK, Bangalore). -
An ancestral genomic locus in Mycobacterium tuberculosis clinical isolates from India hints the genetic link with Mycobacterium canettii
Background: Tuberculosis remains a worldwide public health emergency. To better understand M. tuberculosis and to identify genomic variations characteristic to the Indian clinical isolates by a low-cost method, a genomic subtractive hybridization between M. tuberculosis H37Rv and a clinical isolate from South India was performed. Results: This revealed a novel 0.4-kb subtractive fragment which was used as a handle to pull out a 4.5-kb genomic region characteristic to the clinical isolate and was absent in H37Rv. On further studies, this 4.5-kb region was found to be present in 91% of the M. tuberculosis clinical isolates screened from Kerala, a state in South India. Interestingly, this novel region has 99% identity (with 100% query coverage) with genomic regions of M. canettii. Discussion: The present study hypothesizes that this locus was present in the recent common environmental ancestor of mycobacteria, retained to the maximum extent in M. canettii and ancestral isolates of M. tuberculosis, and later deleted in other modern lineages of M. tuberculosis. Thus, this region may serve as one of the links between the pathogenic mycobacteria and the environmental species. We also propose that the Indian isolates of M. tuberculosis might be closely related to the putative progenitor M. prototuberculosis with respect to this locus. More studies on other genomic loci from different strains of M. tuberculosis are required to establish more links in this direction. 2020, Springer Nature Switzerland AG. -
Multidrug Resistant Bacteria: The Fatal Menace in Healthcare
Mapana Journal of Sciences, Vol-11 (1), pp. 31-47. ISSN-0975-3303