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Sustainable Spending in Destinations : Factors Discouraging Tourists
Purpose: This study investigated the factors influencing tourists sustainable spending behavior in tourism destinations aimed to provide insights for policymakers and businesses to promote sustainability. The research objectives included identifying key factors affecting sustainable spending, assessing their impact, and examining their implications. Methodology: A quantitative approach utilizing confirmatory factor analysis (CFA) was employed to analyze data collected from tourists visiting destinations. Findings: The major findings revealed six significant factors: Perceived costs, availability, awareness, convenience, hedonism & benefits, and culture, elucidating the complex interplay shaping sustainable spending behavior. Theoretical Implications: The importance of perceptions, awareness, and cultural norms in understanding tourists spending decisions has been found to be value added to the literature. A comprehensive measurement technique has been produced in the literature. Practical Implications: This study offered insights for marketers to address perceived cost concerns, enhance availability, and promote awareness of sustainable options. Policymakers could use these findings to formulate targeted policies and incentives to encourage sustainable spending. This research also contributed to advancing the understanding of sustainable tourism spending and provided actionable insights to promote sustainability in line with the United Nations Sustainable Development Goals (UNSDGs). 2024, Associated Management Consultants Pvt. Ltd.. All rights reserved. -
Sustainable tourism development in the backwaters of South Kerala, India: The local government perspective
Improper waste management continues to be a major challenge in the backwater destinations of South Kerala, India and the local government has been identified as a key player having a strong influence on sustainable tourism development initiatives in the destination. The study examines the major obstacles encountered while implementing sustainable tourism development practices in the backwater destinations of South Kerala, India. Qualitative data collected with the support of semi-structured interviews with top government officials of the Tourism Industry is used for the study. The findings from the study show that improper waste management affects sustainable tourism development in the backwater destinations, and that community involvement and community support are pre-requisites for implementing solid waste management practices in the backwater destinations of the state. The study also enlightens the roles of various stakeholders in waste management so as to develop a strong perspective of sustainable tourism development in the region. 2020 Editura Universitatii din Oradea. All rights reserved. -
SUSTAINABLE TOURISM PRACTICES: A PERCEPTION of BACKWATER TOURISM DESTINATIONS in SOUTH KERALA, INDIA
The Tourism Industry in South Kerala focuses more on Houseboat Tourism and Backwater Tourism. The unique, natural features set this destination apart from nearby places, as backwater destinations are rich in numerous natural resources. The sustainable development of these resources will highly enhance the livelihood of the communities in the backwater regions. They will be able to attract tourists seeking unique backwater experiences. Therefore, this article intends to comprehend the stakeholders' perceptions on Sustainable Tourism Development in the backwater destinations of South Kerala in India. A total of 277 respondents participated in the research and the study adopted a quantitative research design, while considering the influence of various factors on the Economic, Social and Environmental Sustainability. The data gathered from the study illustrated that the perception of stakeholders about Sustainable Tourism Development varied across different groups. Hence, all the stakeholders in the Tourism Industry need to work together, as this coordination will help to strengthen future development plans, in order to minimize the negative impacts of tourism in the backwater destinations of South Kerala. The study has also identified key turning points that will help to reshape the Sustainable Development of backwater tourism destinations of South Kerala. 2021 Editura Universitatii din Oradea. All rights reserved. -
SVD-CLAHE boosting and balanced loss function for Covid-19 detection from an imbalanced Chest X-Ray dataset
Covid-19 disease has had a disastrous effect on the health of the global population, for the last two years. Automatic early detection of Covid-19 disease from Chest X-Ray (CXR) images is a very crucial step for human survival against Covid-19. In this paper, we propose a novel data-augmentation technique, called SVD-CLAHE Boosting and a novel loss function Balanced Weighted Categorical Cross Entropy (BWCCE), in order to detect Covid 19 disease efficiently from a highly class-imbalanced Chest X-Ray image dataset. Our proposed SVD-CLAHE Boosting method is comprised of both oversampling and under-sampling methods. First, a novel Singular Value Decomposition (SVD) based contrast enhancement and Contrast Limited Adaptive Histogram Equalization (CLAHE) methods are employed for oversampling the data in minor classes. Simultaneously, a Random Under Sampling (RUS) method is incorporated in major classes, so that the number of images per class will be more balanced. Thereafter, Balanced Weighted Categorical Cross Entropy (BWCCE) loss function is proposed in order to further reduce small class imbalance after SVD-CLAHE Boosting. Experimental results reveal that ResNet-50 model on the augmented dataset (by SVD-CLAHE Boosting), along with BWCCE loss function, achieved 95% F1 score, 94% accuracy, 95% recall, 96% precision and 96% AUC, which is far better than the results by other conventional Convolutional Neural Network (CNN) models like InceptionV3, DenseNet-121, Xception etc. as well as other existing models like Covid-Lite and Covid-Net. Hence, our proposed framework outperforms other existing methods for Covid-19 detection. Furthermore, the same experiment is conducted on VGG-19 model in order to check the validity of our proposed framework. Both ResNet-50 and VGG-19 model are pre-trained on the ImageNet dataset. We publicly shared our proposed augmented dataset on Kaggle website (https://www.kaggle.com/tr1gg3rtrash/balanced-augmented-covid-cxr-dataset), so that any research community can widely utilize this dataset. Our code is available on GitHub website online (https://github.com/MrinalTyagi/SVD-CLAHE-and-BWCCE). 2022 Elsevier Ltd -
SVM Ensemble Model for Investment Prediction
International Journal of IT, Engineering and Applied Sciences Research, Vol-1 (2), pp. 19-23. ISSN-2319-4413 -
Switchable surface activity of Bi2Al4O9 nano particles: A contemporary approach in heterocyclic synthesis
Ferroelectric catalysis is emerging as an efficient chemical transformation strategy, especially in the field of clean energy production, wastewater treatment and degradation of pollutants. The core of ferroelectric catalysis is the dynamically switchable electrical polarization on their surface. It enables them to switch their surface activity, more precisely due to binding strength with the substrate. Even though a plethora of reports are available, the introduction of ferroelectric catalytic surfaces for the generation of heterocyclic compounds is a novel aspect. Here, we introduce ferroelectric Bismuthaluminate nanoparticles as catalysts for generating derivatives of azalactone, tetrahydro-benzopyran and pyranopyrazole with improved catalytic efficiency. This can be achieved by switching the direction of polarization of the catalyst which indeed alters the surface electronic states and stimulates the reaction followed by the excellent yield. Here the switchable property is due to the thermally induced polarization of water. Graphical Abstract: [Figure not available: see fulltext.]. 2023, The Author(s), under exclusive licence to Springer Nature B.V. -
SWITCHING INTENTION AND SWITCHING BEHAVIOR OF ADULTS IN THE NON-LIFE INSURANCE SECTOR: MEDIATING ROLE OF BRAND LOVE
In this digital era, customers in the insurance sector always look for better insurance products and services at an affordable price. When customers are unsure about service, they switch over to a better service provider. This behavior is more relevant to non-life insurance. However, the switching behavior of customers is hampered by certain switchover barriers such as brand consciousness, brand pride, brand loyalty, etc. This study focuses on exploring switching intentions and switching behaviors of adults in India keeping brand love as a mediator. A structured questionnaire was employed to collect the primary data from adults having non-life insurance products to analyze switching intentions and switching behaviors. The collected data were analyzed employing SPSS software and Hayes Process Model and appropriate statistical tools. The study results show that the switching intentions of adults vary based on their age, annual income, and education. Mean scores reveal that the lesser the age, the higher the intention to switch over. Further, based on annual income, adults who earn up to Rs 2 lakhs annually have more switching-over intentions (Mean score: 3.9719) followed by adults who earn Rs more than 2 lakhs to 5 lakhs annually (Mean score: 3.7590). Mean scores of education levels regarding switching intentions are higher among more educated adults and less among those who are qualified up to the school level. Arun Kumar N., Girish S., Suresha B., Mahesh E., 2023. -
Symmetric supercapacitor based on Co3O4 nanoparticles with an improved specific capacitance and energy density
Metal oxides have garnered significant research interest as highly effective electrode materials for supercapacitors. In this study, we synthesized Co3O4, an electrode material for supercapacitors, utilizing an in-situ hydrothermal method with varying pH levels in the precursor solution. The obtained samples underwent through structural, optical, surface morphological, electrical, and electrochemical analyses, affirming their exceptional suitability for supercapacitor applications. The influence of pH fluctuations in the synthesis process, on the specific capacitance values were analyzed. The X-ray diffraction pattern and Raman spectrum confirmed the normal cubic spinel structure of Co3O4 nanoparticles. The X-ray photoelectron spectrum revealed the chemical bond states of Co3O4. The optical bandgap have been investigated from the Tauc plot. The surface area and morphology were determined through Brunauer Emmett and Teller method and field emission scanning electron microscope images. A high specific capacitance of 1195.05 Fg?1 at a current density of 1.5 Ag?1 was obtained in the three-electrode study for the sample synthesized at a pH of 10. A symmetric supercapacitor (SSC) device was fabricated to facilitate practical analysis. The symmetric supercapacitor device demonstrated a notably elevated specific capacitance of 870.6 Fg?1 at an operational current density of 5 Ag?1, concurrently achieving an enhanced energy density of 77.3 W h/kg and superior power density of 1997.7 W/kg. These performance metrics surpassed those of prior studies in the field. Furthermore, the SSC device exhibited an excellent cyclic stability of 88 % after undergoing 970 charge/discharge cycles. As a result, Co3O4 emerges as a promising and efficient electrode material for applications in supercapacitors. 2024 Elsevier Ltd -
Symmetric Supercapacitors based on Reduced Graphene Oxide/Multi-walled Carbon Nanotubes/Cobalt Oxide Ternary Composites
Ternary nanocomposites of reduced graphene oxide/multi-walled carbon nanotubes/cobalt oxide nanoparticles (rGO/MWCNT/Co3O4) were synthesized employing a facile hydrolysis method with subsequent heat treatment. The good electrical conductivity and remarkable carrier mobility of rGO and MWCNTs make them a suitable matrix for hybrid supercapacitors, and their composites with metal oxides exhibit enhanced electrochemical properties due to the advantages of the synergistic contribution and the integration of different dimensionalities. The binary counterparts of Co3O4 with GO or MWCNTs were also produced using the same technique to gain additional insight into the characteristics of the individual components. The structural and morphological properties of the composites were analyzed using various analytical techniques. The electrochemical behaviors of the prepared composites were investigated using cyclic voltammetry (CV), galvanostatic chargedischarge (GCD), and electrochemical impedance spectroscopy (EIS) in 1 M H2SO4. A platinum electrode modified with the rGO/MWCNT/Co3O4 composite displayed a remarkable specific capacitance of 922 F g?1 at a current density of 1 A g?1 composite with a negligible capacitance drop after 2000 cycles. The symmetric supercapacitor fabricated using the rGO/MWCNT/Co3O4 composite showed an energy density of 32.2 Wh Kg?1 at 1 A g?1, and the corresponding power density was 2000 W Kg?1. The supercapacitor fabricated using the composite displayed 83% capacitance retention after 2000 cycles at 3 A g?1 composite. 2023 Taylor & Francis Group, LLC. -
Synchronous learning and asynchronous learning during COVID-19 pandemic: a case study in India
Purpose: This research aims to study the students' perspectives on synchronous and asynchronous learning during the COVID-19 Pandemic. Both synchronous and asynchronous learning approaches used in online education have positive and negative outcomes. Hence, the aim is to study online education's positive and negative consequences, reflecting sync and async approaches. This research followed a mixed research approach. The key stakeholders of this research are the Indian educational institutions and students. Design/methodology/approach: This research collected data from the students undergoing synchronous and asynchronous learning amidst the COVID-19 Pandemic. The data were collected (N=655) from various students taking online classes during the pandemic. A questionnaire survey was distributed to the students through online platforms to collect the data. In this research, the authors have collected data using simple random sampling, and the same has been used for data analysis using SPSS version 26. The collected data were exposed to a factor analysis using a principal component analysis technique to reduce the vast dimensions. Findings: The study findings show that synchronous learning is sometimes stressful, placing more responsibility on students mainly because of the increased screen time. At the same time, asynchronous learning allows the students to self-explore and research the topics assigned to them. Students also felt that asynchronous activities create a burden because of many written assignments to be submitted within a short period. Overall, the COVID-19 pandemic has been challenging for the students and the teachers. However, teachers have helped students to learn through digital platforms. The majority of the respondents opined that technological disruptions and death in the family circle had been significant reasons for not concentrating during online classes. However, the combination of synchronous and asynchronous learning has led to a balanced education. Practical implications: Higher education has undergone multiple transformations in a short period (from March 2020, 2021 and beyond). Educational institutions underwent a rapid transition in remote teaching and learning in the initial stages. As time progressed, educational institutions did course navigation where they relooked into their course plans, syllabus and brought a structural change to match the pandemic requirements. Meanwhile, educational institutions slowly equipped themselves with infrastructure facilities to bring academic integrity. At present, educational institutions are ready to face the new normality without disrupting services to society. Social implications: Educational institutions create intellectual capital, which is important for the development of the economy. In the light of COVID-19, there are new methods and approaches newly introduced or old methods and approaches, which are reimplemented, and these approaches always work for the benefit of the student community. Originality/value: The authors collected data during the COVID-19 pandemic; it helped capture the students' experience about synchronous and asynchronous learning. Students and faculty members are newly exposed to synchronous and asynchronous learning, and hence, it is essential to determine the outcome that will help many stakeholders. 2022, Cassandra Jane Fernandez, Rachana Ramesh and Anand Shankar Raja Manivannan. -
Synergetic effects of cross-linking and incorporation of Fe-Al bimetallic combination on the properties of polyvinyl alcohol novel films
Polyvinyl alcohol films incorporated with Fe-Al bimetallic combination novel films were synthesized by sol-gel method in the presence of glutaraldehyde (GA). The results of FTIR spectra confirmed the cross-linking between PVA and GA, resulted in the formation of rigid molecular chains. The comparison of thermograms of pure PVA and Fe-Al PVA films cured with GA indicated the enhanced thermal stability of the cured films. The electrical properties of the pure PVA films and bimetallic PVA films cured with GA were studied in the frequency range 100 Hz to 100 kHz. The current study explains the effect of GA and incorporation of Fe-Al bimetallic combination towards the structural modification and dielectric properties like dielectric constant, dielectric loss, ac conductivity, polarization, and permittivity of the cured PVA films. The variation of the storage modulus of cured PVA films as a function of temperature has also been studied. 2023, Qatar University and Springer Nature Switzerland AG. -
Synergistic advancements in energy storage: g-C3N4/NiFe2O4/PANI composite with augmented electrochemical capabilities
This study examines the electrochemical behaviour of a hybrid composite material of graphitic carbon nitride/Nickel ferrite/Polyaniline (g-C3N4/NiFe2O4/PANI) synthesized by hydrothermal method, coupled with in-situ polymerisation. The ensuing g-C3N4/NiFe2O4/PANI composite demonstrates superior characteristics for energy storage applications. Through a comprehensive analysis, we elucidate the combined effects of the distinct components, revealing improved electrochemical properties. The composite exhibits improved galvanostatic charge/discharge exhibiting a specific capacitance of 770 Fg?1 at 1 Ag?1 current density. This research underscores the perspective of the g-C3N4/NiFe2O4/PANI composite as a promising candidate for advanced energy storage systems. 2024 Elsevier Ltd -
Synergistic Co-grafting of multiwalled carbon nanotubes using SO3H and choline chloride-urea in fabricating uniform thin films with enhanced visible light transparency and reduced sheet resistance
New materials and innovative modification methods are indispensable to advance the energy field. The present work reports the fabrication of transparent conducting electrodes using Multiwalled carbon nanotube (MWCNT) that have been modified with sulfonic acid (SO3H) and a combination of Choline Chloride-Urea/Sulfonic acid (DES/SO3H). A comprehensive investigation was conducted to ascertain the impact of employing DES and SO3H in achieving consistent and long-lasting dispersions of multiwalled carbon nanotubes in different solvents and the most favourable condition was achieved when employing n-heptanol. The films were fabricated on glass substrate by using the spray pyrolysis technique. The stability of the system following the modification was unequivocally confirmed by SEM analysis, while the electronic structure was assessed qualitatively by EDX analysis. Optical profilometry analysis revealed that the film thickness fell within the range of 350385 nm. The co-grafted film demonstrated an optical transparency of approximately 84.96%, modestly exceeding that of the singly grafted film, which was determined to be 70.14% in the visible region. The sheet resistance of DES/S-MWCNT and S-MWCNTs was calculated to be approximately 3.33k?/Sq and 5.02k?/Sq, respectively. The calculated charge transfer resistance (RCT) for the co-grafted and singly grafted MWCNT systems was 0.185? and 0.190?, respectively. These values align closely with the corresponding sheet resistance values obtained. The electrochemical investigations also showed an increased specific capacity for DES/S-MWCNT, approximately 896.2C/g, whereas the calculated value for the S-MWCNT system was 826.8C/g. 2024 Elsevier B.V. -
Synergistic Effect of Chemical and Physical Treatments on Azolla pinnata for Cadmium Ions Removal from Synthetic Wastewater Systems
Azolla pinnata, an aquatic fern has been utilized as an effective biofiltering and ad-sorbent agent to complement many convention-al treatment methods for the removal of environmental pollutants. This study is designed to develop an effective regime to treat metal pollutants of industrial and urban waste discharge using a novel strategy involving Azolla pinnata. In the present study, cell surface modification by physical treatments that include heating (muffle furnace), and mechanical waves (ultrasonication) and chemical treatments as sulphuric acid and ethanol were employed to enhance the adsorption of metal pollutants. Factors such as biosorbent dose, contact time, initial metal ion concentration, temperature, and solution pH were optimised in batch mode. The point of zero charge of the adsorbent was determined to be at 5.85 pH. The results of surface morphology, elemental analysis, crystallinity, recorded through SEM, FTIR and XRD confirmed the ad-sorptive properties in both modified and unmod-ified biomass. The intensity peaks linked to O-H, C-H, C-N, N-H and C=O stretching bands was intense in the treated A. pinnata groups indicat-ing the induction of the active groups. Out of the two chemical pre-treatments, the batch ad-sorption experiment with ethanol found to che-late Cd+2 metal ions to a higher extent (94.36%) in contrast to the results obtained from H2SO4 treated biomass. Whereas, the physical treat-ments exhibited the strong adsorption (83.28 and 96.920.55%) for ultrasonicated and muf-fle furnace pre-treated biomass respectively for the dosage of 0.25g. The adsorption efficiency of physically modified sorbent revealed the cent percent removal of Cd+2 ions from the aqueous phase with the dosage of 1.0g in 15min of con-tact time which is due to the incorporation of new binding sites. Moreover, these results proved that the highest rate of cadmium adsorption onto A. pinnata is in result of the modifications caused onto surface structure, porosity and the addition of functional groups on the surface of the treated biomass. 2024, Curr. Trends Biotechnol. Pharm. All rights reserved. -
Synergistic effect of metals and cross linkers on surface modification of iron aluminum oxyhydroxide-PVA polymer films for enhanced catalytic activity in transesterification reaction
Iron-incorporated aluminum oxyhydroxide polyvinyl alcohol films (Fe-Al-PVA) were synthesized using the solgel method. The influence of cross-linking agents on the aluminum oxyhydroxide films was investigated by incorporating glutaraldehyde into the synthesized films. Various characterization techniques were employed to understand the physico-chemical properties that affect the catalytic and adsorptive behavior of the self-supported films. The liquid phase transesterification of terpenes was used to test the catalytic activity of the films for the synthesis of industrially important terpene esters. The products were analyzed using GC, GCMS, and NMR techniques, and optimization studies were carried out under different experimental conditions. The reaction scope was expanded to a wider range of organic compounds, and a possible reaction mechanism was proposed. This study demonstrates the design and modification of efficient bimetallic polymer film catalyst for organic transformations. 2023 Wiley Periodicals LLC. -
Synergistic effects of CuO/TiO2-chitosan-farnesol nanocomposites: Synthesis, characterization, antimicrobial, and anticancer activities on melanoma cells SK-MEL-3
The current investigation focuses on synthesizing copper oxide (CuO)-titanium oxide (TiO2)-chitosan-farnesol nanocomposites with potential antibacterial, antifungal, and anticancer properties against Melanoma cells (melanoma cells [SK-MEL-3]). The nanocomposites were synthesized using the standard acetic acid method and subsequently characterized using an X-ray diffractometer, scanning electron microscope, transmission electron microscopy, and Fourier transform infrared spectroscopy. The results from the antibacterial tests against Streptococcus pneumoniae and Stapylococcus aureus demonstrated significant antibacterial efficacy. Additionally, the antifungal studies using Candida albicans through the agar diffusion method displayed a considerable antifungal effect. For evaluating the anticancer activity, various assays such as MTT assay, acridine orange/ethidium bromide dual staining assay, reactive oxygen species (ROS) generation assay, and mitochondrial membrane potential (MMP) analysis were conducted on SK-MEL-3 cells. The nanocomposites exhibited the ability to induce ROS generation, decrease MMP levels, and trigger apoptosis in SK-MEL-3 cells. Collectively, the findings demonstrated a distinct pattern for the synthesized bimetallic nanocomposites. Furthermore, these nanocomposites also displayed significant (p < 0.05) antibacterial, antifungal, and anticancer effects when tested on the SK-MEL-3 cell line. 2023 Wiley-VCH GmbH. -
Synergistic effects of graphene oxide grafted chitosan & decorated MnO2 nanorods composite materials application in efficient removal of toxic industrial dyes
In this study, we designed a heterogeneous graphene oxide (GO) grafted on chitosan decorated with MnO2 nanorods (?-MnO2NRs/GO-Chit) composite materials and its ability to remove the cationic and anionic toxic dyes from wastewaters were analysed. The synthesised materials presented an effective stabilization of active MnO2 nanorods (NRs) on the GO-Chit surface. The synthesised materials were detailed characterised by several spectroscopic and microscopic techniques such as, FT-IR, P-XRD, SEM, TEM, Raman, TGA, XPS, BET, CO2-TPD and UVVisible analysis. In addition, ?-MnO2NRs/GO-Chit material is successfully applied in removal of industrial ionic dyes such as amido black 10B (AB) and methylene blue (MB), respectively. The dye adsorption experiments confirmed that the GO-Chit/?-MnO2 NRs material exhibited remarkably high adsorption capacity in efficient removal of cationic dye methylene blue (MB) and anionic dye amido black 10B (AB). The maximum MB dye removal (97%) process completed in 24 min at C0 = 30 mgL?1, but in the case of AB the maximum dye removal (80%) process was reached in 700 min. Over GO-Chit/?-MnO2 NRs hybrid material, a maximum theoretical monolayer adsorption (qmax values is 328.9 mg g?1) of MB was calculated from the Langmuir isotherm equation. In case MB, a faster adsorption and 2.18 times maximum adsorption capacity was achieved than that of AB10 dye. The enhanced adsorption over ?-MnO2NRs/GO-Chit is due to the increased surface functionalities (i.e., oxygen-containing groups), high basicity and strong electrostatic forces between MnO2 nanorods and GO-Chit. Furthermore, ?-MnO2NRs/GO-Chit hybrid material displayed good stability after 10 successive adsorption tests. 2022 Elsevier Ltd -
Synergistic fabrication, characterization, and prospective optoelectronic applications of DES grafted activated charcoal dispersed PVA films
This study investigates the synthesis, analysis, and utility of films comprising deep eutectic solvent (DES) grafted activated charcoal (AC) within a polyvinyl alcohol (PVA) matrix for optoelectronic device applications. The fabrication process involves the dispersion of DES functionalization AC into the PVA solution, followed by casting onto substrates with controlled drying. Comprehensive characterization encompassing X-ray diffraction (XRD), scanning electron microscopy (SEM), UVvis spectroscopy, Fourier-transform infrared spectroscopy (FTIR), and impedance spectroscopy which discerns the films microstructure, morphology, conductance, band-gap, and optical traits. The DES grafted AC infusion with variable concentration has significantly influenced optical absorbance and reduced the band gap indicating efficient charge mobility. Furthermore, the impedance analysis has revealed the electrical conduction of the film to be 1.8 10?6 ??1 m?1. In summary, the dispersion of DES modified AC in the PVA matrix have converted the insulating PVA to a semiconducting polymeric film with reduced band-gap and increased absorption, which present a propitious avenue for wide array of optoelectronic devices, such as thin film transistors, photovoltaics, LEDs, photodetectors, and many such applications. 2024 The Authors. Polymers for Advanced Technologies published by John Wiley & Sons Ltd. -
Synergistic g-c3n4/v2o5/pani composite for electrochemical energy storage
This work illustrates the synthesis of a ternary hybrid composite (g-C3N4/V2O5/PANI) from graphitic carbon nitride, vanadium pentoxide, and Polyaniline via hydrothermal method followed by in-situ polymerization. Morphological analysis confirms the integration of vanadium pentoxide (V2O5) and polyaniline (PANI) within the interlayer spaces of graphitic materials. The resultant hybrid composite structure facilitates rapid diffusion and ion movement at the electrode-electrolyte interface. Additionally, incorporating V2O5 within a polymer matrix alongside graphitic material generates diverse electrical profiles, enhancing electrochemical performance. The electrochemical characteristics of g-C3N4/V2O5/PANI composites were examined by Cyclic voltammetry (CV), Galvanostatic charge-discharge (GCD), and Electrochemical impedance spectroscopy (EIS). The GCD analysis shows that the g-C3N4/V2O5/PANI composite exhibits a specific capacitance of 880 Fg?1 at a current density of 1 Ag?1, retaining 78 % of its initial capacitance after executing 2000 cycles at 3 Ag?1. Furthermore, a symmetric supercapacitor was constructed using g-C3N4/V2O5/PANI composite material as the electrode, showing a capacitance of 246 Fg?1 when measured at an input current density of 1 Ag?1. This study demonstrates g-C3N4/V2O5/PANI is a potential electrode material for supercapacitor application. 2024 -
Synergizing Neutrosophy and Randomized Blocks Design: Development and Analytical Insights
The design of the experiment is a strategy for effectively examining the relationship between input design parameters and process output and developing a greater understanding. A randomized block design is an experimental design that has two primary factors and is widely used in agriculture, environment, biological, animal, and food sciences, where experimental material is heterogeneous and precise. In a randomised block design, one or more observations may lose their true significance due to an accident, poor handling, pest infestations in agricultural trials, or other factors. It is prudent to treat this value as missing and estimate it. In todays practical situations, uncertainty and inaccuracies are inevitable in most research areas. It is important to handle such data, which can lead to inaccurate and unreliable results. Neutrosophy is the branch of philosophy that provides an efficient method to study impreciseness among the data. Some of the common sources of Neutrosophy in randomised block design are incorrect blocking factor selection, measurement error, subjective factors, and natural variability. It is paramount to handle the Neutrosophy in a randomised block design; otherwise, it may lead to various problems, like a high risk of false positives. In this paper, the Neutrosophic Randomised Block Design (NRBD) is introduced to tackle data impreciseness. The study also, outlines a methodology for estimating missing observations in NRBD and presents its analysis. Additionally, the study compares the efficiency of NRBD to that of the Neutrosophic Completely Randomised Design (NCRD). 2024, American Scientific Publishing Group (ASPG). All rights reserved.