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Eco-Conscious Silver Nanoparticles via Quassia indica: Characterization and Multifaceted Applications
This research work explores the green synthesis of silver nanoparticles using Quassia indica (QI-Ag NPs), a natural plant extract, as a stabilizing and reducing agent. The synthesized QI-Ag NPs were characterized using various analytical techniques, including UV-Visible spectroscopy, X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDX), Transmission Electron Microscopy (HR-TEM) and Selected Area Electron Diffraction (SAED). The UV-Visible analysis revealed a characteristic peak at 430 nm, indicating the successful formation of AgNPs. XRD analysis unveiled the crystalline nature of the nanoparticles, with four distinctive peaks corresponding to the silver crystallographic planes. SEM and EDX provided insights into the morphology and chemical composition of the QI-AgNPs. Moreover, TEM and SAED elucidated the structural attributes and crystallinity of the nanoparticles. The Ag NPs exhibited a spherical structure and crystalline nature, as supported by both SAED and XRD findings. The zeta potential of QI-Ag NPs exhibited a value of-24.2 mV. The synthesized QI-Ag NPs were evaluated for their photocatalytic potential, demonstrating a remarkable 97% degradation of Crystal Violet dye. Furthermore, comprehensive studies encompassing antioxidant, antimicrobial and cytotoxicity assessments were conducted, showcasing the multifaceted applications of these nanoparticles. This research underscores the promising potential of Q. indica-mediated silver nanoparticles as environmentally benign and versatile nanomaterials. 2024 World Scientific Publishing Company. -
ANALYSIS, ASSESSMENT, AND MANAGEMENT OF ENVIRONMENTAL AIR POLLUTION USING ENVIRONMENTAL ENGINEERING IN DEVELOPING COUNTRIES
Recent studies underscore the value of contemporary technology and gas emissions mitigation while overlooking the necessity of optimal fuel in Developing Countries (DC). DC's historical economic expansion has significantly depended on fossil fuels, resulting in severe environmental air pollution (EAP) challenges. The separation of economic progress from pollution has been the central emphasis in advancing environmental civilization in emerging countries. This study presents an analysis, assessment, and management of EAP using environmental engineering (EE) in DC. This work has examined the evolution of EAP regulations in DC, emphasizing a strategic shift from emission regulation to Air Quality Management (AQM). The regulation of Sulfur dioxide (SO2) emissions addressed the worsening of acid rain in DC. Since 2015, regulatory measures across several sources and industries have aimed to decrease the total amount of Fine Particulate Matter (FPM2.5), signifying a shift towards an AQM-focused policy. Escalating ozone (O3) pollution necessitates integrated management measures for O3 and FPM2.5, focusing on their intricate photochemical reactions. Significant enhancement of AQM in DC, as a crucial metric for the efficacy of sustainable economic development, necessitates the profound carbon reduction of the DC's energy infrastructure and the establishment of more integrated strategies to tackle EAP and climate change in DC concurrently. 2024, Rotherham Academic Press Ltd. All rights reserved. -
Tuning the electronic dimensionality and bandgap in Cs2AgBiX6 (X = Br, Cl) for photovoltaic applications: a DFT-1/2 study of cation disorder
Nontoxic, stable, and experimentally realized lead-free halide double perovskites, Cs2AgBiX6 (X = Br, Cl), attracted much attention for solar cell applications. However, their reduced electronic dimensionality and indirect (wide) bandgap, limiting solar energy absorption efficiency, are not mostly suitable. To address such issues, we employ the computationally efficient DFT-1/2 + SOC method to study the electronic structure of cation-ordered and cation-disordered materials comparatively. Our study explores the impact of cation disorder in tuning the electronic dimensionality, demonstrating how the disorder effect reduces bandgaps, increases solar energy absorption, enhances band dispersion, and decreases carrier effective masses for better photovoltaic performance. We observe an evolution of the electronic dimensionality in the disordered systems, influencing the carrier effective masses and absorption properties. Fractional (and non-integer) electronic dimensionality appears to be an essential concept in understanding the optoelectronic properties. The direct bandgap, high absorption in the desired energy range, and mostly lower effective masses of the disordered systems make them suitable for solar cell applications. 2024 The Royal Society of Chemistry. -
Evaluating the effect of different ligands on the supercapacitance and hydrogen evolution reaction studies of Zn-Co MOF
Metal-Organic Frameworks (MOFs) have recently attracted a lot of interest because of their potential uses in energy storage and catalysis. In this study, we investigate the impact of various ligands on the electrochemical performance of Zn-Co MOFs for both energy storage and hydrogen evolution reaction (HER) studies. Specifically, Zn-Co MOFs are synthesized using different ligands, and their structural and electrochemical properties are characterized by a range of analytical techniques. 2,5-dihydroxybenzoic acid (DBA) and benzene-1,2,4,5-tetracarboxylic acid (BTC) are employed due to their distinct structural features and potential effects on MOF performance. Subsequently, electrochemical studies are conducted to assess the supercapattery performance and HER activity of these MOFs. The specific capacitance and overpotential value at 10 mA/cm2 of Zn-Co/DBA MOF is observed to be 1775.3 F/g and 186 mV, whereas that of Zn-Co/BTC MOF is found to be 136.6 F/g and 279 mV. The MOF synthesis using DBA as a ligand is more effective for energy-related applications. This study aims to report a multifunctional MOF composite for energy and environmental applications with better efficiency than other reported systems. Our findings provide insights into how the choice of ligand influences the structural properties and electrochemical behavior of Zn-Co MOFs, shedding light on the potential of these MOFs as versatile materials for energy storage and HER applications. 2024 Elsevier B.V. -
Na+ doped CuO: A new paradigm electrode material for high performance supercapacitors
This study investigates the influence of sodium doping on the properties of cupric oxide (CuO) thin films synthesized via spray pyrolysis. Comprehensive characterization was conducted using X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDAX), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FESEM), Raman spectroscopy, Hall effect measurements, and electrochemical studies. All films exhibited p-type conductivity, with an optical band gap variation from 1.53 to 1.73 eV. XRD analysis confirmed the dominance of monoclinic CuO, with minor phases of Cu2O and Cu4O3. EDAX and XPS verified the incorporation of Cu, O, and Na elements. FESEM revealed a densely packed morphology with uniform particle distribution and rough surfaces in the electrically optimized film. The Raman spectra of doped samples showed increased intensity and sharpness, attributed to Na + ion-induced polarizability enhancement. Hall effect measurements indicated a tenfold decrease in carrier concentration and a more than tenfold increase in mobility upon sodium doping. Films doped with 4 at.% sodium exhibited the lowest resistivity. Additionally, Na doping enhanced the electrochemical performance of CuO. These findings demonstrate that sodium doping significantly enhances the electrical, optical and electrochemical properties of CuO thin films, making them suitable for applications in optoelectronic devices and supercapacitors. 2024 Elsevier Ltd and Techna Group S.r.l. -
Deciphering the properties of UV upturn galaxies in the Virgo cluster
The UV upturn refers to the increase in UV flux at wavelengths shorter than 3000 observed in quiescent early-type galaxies (ETGs), which still remains a puzzle. In this study, we aim to identify ETGs showing the UV upturn phenomenon within the Virgo galaxy cluster. We utilized a colourcolour diagram to identify all potential possible UV upturn galaxies. The spectral energy distributions (SED) of these galaxies were then analysed using the CIGALE software; we confirmed the presence of UV upturn in galaxies within the Virgo cluster. We found that the SED fitting method is the best tool to visualize and confirm the UV upturn phenomenon in ETGs. Our findings reveal that the population distributions regarding stellar mass and star formation rate properties are similar between UV upturn and red sequence galaxies. We suggest that the UV contribution originates from old stellar populations and can be modelled effectively without a burst model. Moreover, by estimating the temperature of the stellar population responsible for the UV emission, we determined it to be 13 000 K to 18 000 K. These temperature estimates support the notion that the UV upturn likely arises from the contribution of low mass evolved stellar populations (extreme horizontal branch stars). Furthermore, the Mg2 index, a metallicity indicator, in the confirmed upturn galaxies shows higher strength and follows a similar trend to previous studies. This study sheds light on the nature of UV upturn galaxies within the Virgo cluster and provides evidence that low-mass evolved stellar populations are the possible mechanisms driving the UV upturn phenomenon. 2024 The Author(s). -
Magnetic field and light dependant supercapacitor behaviours of Mn3O4-rGO hybrid nanocomposites
Recently, hybrid nanostructures have been very promising candidates for energy generation and storage applications in nanotechnology. Here, Manganese Oxide (Mn3O4) decorated reduced graphene oxide (rGO) nanosheets hybrid composite was synthesised in chemical methods. The hybrid nanocomposite shows supercapacitance performance under a magnetic field and light irradiation. The magnetoelectrochemistry behaviour of the material was studied by varying external magnetic fields and the charge storage behaviours depending on the magnetic field. Additionally, the charge storage behaviour also changes under visible light irradiation. Interestingly, 82% enhancement is obtained under visible light. Therefore the present work gives a new pathway to understand the charge storage behaviour under light and magnetic fields. Qatar University and Springer Nature Switzerland AG 2024. -
Environmental degradation in geopolitical risk and uncertainty contexts for India: A comparison of ecological footprint, CO2 emissions, and load capacity factor
This study assesses the role of geopolitical risk and uncertainty in the degradation of the environment by forming the functions for ecological footprint, CO2 emissions, and load capacity factor for the period 19902019 in India. Besides, the specified function endogenizes economic growth, renewable energy consumption, and natural resource rent as the additional covariates. The use of the autoregressive distributed lag model (ARDL) confirms the long-run relationship between study variables. Further, the dynamic simulations of the autoregressive distributed lag model (DYNARDL) outcomes show that geopolitical risk improves the quality of the environment by reducing the ecological footprint and CO2 emissions. However, it degrades the environment by reducing the load capacity factor. Furthermore, the uncertainty improves the environmental quality by reducing the CO2 emissions and ecological footprint, but the reduced load capacity factor due to uncertainty implies the degradation of environmental quality in India. Given these findings, the study proposes different environmental conservation policies. 2023 Elsevier Ltd -
Detection of high-frequency pulsation in WR135: Investigation of stellar wind dynamics
We report the detection of high-frequency pulsations in WR 135 from short-cadence (10 minute) optical photometric and spectroscopic time series surveys. The harmonics up to the sixth order are detected from the integrated photometric flux variations, while the comparatively weaker eighth harmonic is detected from the strengths of the emission lines. We investigate the driving source of the stratified winds of WR 135 using the radiative transfer modeling code, CMFGEN, and find the physical conditions that can explain the propagation of such pulsations. From our study, we find that the optically thick subsonic layers of the atmosphere are close to the Eddington limit and are launched by the Fe opacity. The outer optically thin supersonic winds (Tross = 0.1 0.01) are launched by the He II and C IV opacities. The stratified winds above the sonic point undergo velocity perturbation that can lead to clumps. In the optically thin supersonic winds, dense clumps of smaller size (fVFF = 0.27 0.3, where fVFF is the volume filling factor) pulsate with higher-order harmonics. The larger clumps (fVFF = 0.2) oscillate with lower-order harmonics of the pulsation and affect the overall wind variability. 2024. The Author(s). -
Pure and suggestive impulse buying in mobile shopping app: shopping pattern of young consumers
Purpose: This study differentiates pure impulse buying behaviour from suggestive impulse buying behaviour in using mobile shopping applications (apps). This study aims to assess the moderating effects of instant discount and cashback promotional offers along with the mediating effects of impulse buying intention (IBI) and user satisfaction (US), using the app stimuli (performance expectancy, effort expectancy, layout, atmosphere, privacy and security). Design/methodology/approach: The study was done in three stages: analysis of variance, followed by structural equation modelling (SEM) and paired t-tests. Findings: The results showed that instant discounts and cashback offers are different from each other for the mediating variable IBI. The SEM results for pure impulse buying showed that, except for layout, the remaining variables have a positive relationship with IBI. For suggestive impulse buying, effort expectancy and layout were significantly related to both the mediating variables. Finally, pure and suggestive impulse buying behaviour showed significant differences. Originality/value: Previous studies have looked into impulse buying in its generic sense and not through the types of impulse buying they were measuring. As impulse buying behaviour is a predominant theme for discussion today, marketing professionals and researchers must comprehend the impact of app stimuli in the context of select types of impulse buying behaviour. 2024, Emerald Publishing Limited. -
A homotopy-based computational scheme for two-dimensional fractional cable equation
In this paper, we examine the time-dependent two-dimensional cable equation of fractional order in terms of the Caputo fractional derivative. This cable equation plays a vital role in diverse areas of electrophysiology and modeling neuronal dynamics. This paper conveys a precise semi-analytical method called the q-homotopy analysis transform method to solve the fractional cable equation. The proposed method is based on the conjunction of the q-homotopy analysis method and Laplace transform. We explained the uniqueness of the solution produced by the suggested method with the help of Banach's fixed-point theory. The results obtained through the considered method are in the form of a series solution, and they converge rapidly. The obtained outcomes were in good agreement with the exact solution and are discussed through the 3D plots and graphs that express the physical representation of the considered equation. It shows that the proposed technique used here is reliable, well-organized and effective in analyzing the considered non-homogeneous fractional differential equations arising in various branches of science and engineering. 2024 World Scientific Publishing Company. -
Phytofabricated bimetallic synthesis of silver-copper nanoparticles using Aerva lanata extract to evaluate their potential cytotoxic and antimicrobial activities
In this study, we demonstrate the green synthesis of bimetallic silver-copper nanoparticles (AgCu NPs) using Aerva lanata plant extract. These NPs possess diverse biological properties, including in vitro antioxidant, antibiofilm, and cytotoxic activities. The synthesis involves the reduction of silver nitrate and copper oxide salts mediated by the plant extract, resulting in the formation of crystalline AgCu NPs with a face-centered cubic structure. Characterization techniques confirm the presence of functional groups from the plant extract, acting as stabilizing and reducing agents. The synthesized NPs exhibit uniform-sized spherical morphology ranging from 7 to 12nm. They demonstrate significant antibacterial activity against Staphylococcus aureus and Pseudomonas aeruginosa, inhibiting extracellular polysaccharide secretion in a dose-dependent manner. The AgCu NPs also exhibit potent cytotoxic activity against cancerous HeLa cell lines, with an inhibitory concentration (IC50) of 17.63gmL?1. Additionally, they demonstrate strong antioxidant potential, including reducing capability and H2O2 radical scavenging activity, particularly at high concentrations (240gmL?1). Overall, these results emphasize the potential of A. lanata plant metabolite-driven NPs as effective agents against infectious diseases and cancer. 2024, The Author(s). -
Chitosan stabilized platinum nanoparticles: Synthesis, characterization and cytotoxic impacts on human breast cancer cells
Platinum nanoparticles are widely studied as a nanomedicine against many of the solid tumours. Due to their promising physicochemical properties, chitosan-stabilized platinum nanoparticles may exhibit exceptional cytotoxic effects on cancer cells. This article describes the synthesis and characterization of chitosan-stabilized platinum nanoparticles (Ch-Pt NPs) through a wet chemical method and in vitro studies of their anticancer effect on human breast cancer cells (MCF-7 cell line). Different analytical methods confirmed the formation of chitosan-stabilized platinum nanoparticles. The structural and surface morphological analyses were done using XRD, FTIR, TEM, FESEM, etc. Elemental analysis was done using XPS and EDX. The hydrodynamic diameter and zeta potential were determined using DLS and zeta analyzer. These platinum nanoparticles have a spherical shape and FCC structure with an average particle size of 3.4 nm and an average hydrodynamic diameter of 248 nm. The characteristic FTIR peaks of chitosan in the sample confirmed the capping of chitosan on the surface of the Pt NPs. The surface charge estimation using a zeta potential analyzer showed ?23.8 mV, elucidating the stability and dispersity of the as-synthesized Pt NPs. The in vitro cytotoxicity study using MTT assay revealed a non-toxic behaviour on normal L929 cell lines and a severe anti-proliferative activity on a human breast cancer (MCF-7) cell line with an IC50 value of 35.60 ?g/ml after 24 h of incubation. This result indicates a better anticancer therapeutic application against human breast cancer cells for the as-synthesized chitosan-stabilized platinum nanoparticles. 2024 Elsevier B.V. -
Development of classical swine fever virus E2-protein based indirect ELISA for detection of antibodies against the virus in pigs
Classical swine fever (CSF) is an economically important and highly contagious disease of pigs caused by CSF virus, genus Pestivirus. Serological diagnosis of the disease is highly valuable for surveillance and thereby containment of spread of the disease. In this study, we have demonstrated the development of CSFV envelope glycoprotein E2-based indirect ELISA (E2-iELISA) for the detection of CSFV specific antibodies. The full-length E2 protein was expressed in E. coli and the purified protein was used as a coating antigen in indirect ELISA for detecting CSFV specific antibodies in pigs. A panel of 506 pig sera samples was used to validate the ELISA and the results were highly comparable to the results obtained with the commercial antibody detection kit (PrioCHECK CSFV Ab kit). The in-house E2-iELISA demonstrated high diagnostic sensitivity (95.4%) and specificity (95.5%), highlighting its potential application for sero-surveillance or monitoring of the disease in the swine population. The Author(s), under exclusive licence to Springer Nature B.V. 2024. -
Unveiling the Indian REIT narrative-qualitative insights intoretail investors perspectives
Purpose: The present study delves into the causes of relatively lower retail participation in the Indian REIT market. Specifically, it investigates investors' attitudes and perceptions towards REITs as a unique asset class. This paper provides a comprehensive understanding of the perception and factors influencing Indian retail investors' reluctance to participate in the REIT market. Design/methodology/approach: Qualitative research was conducted through semi-structured interviews to gather insights from non-investors in REITs. The data were transcribed and analyzed using content analysis techniques. Finally, coding techniques were used to identify broad study themes. Findings: According to the study results, many retail investors are unfamiliar with REITs. Even among those knowledgeable about REITs and with a favorable view, it is not commonly seen as a feasible investment option due to its early stage, unattractive returns and limited number of REITs. Practical implications: Developed countries have established REIT markets, while it is still in its infancy in developing countries such as India. Financial advisors, fund houses and the media should focus on educating investors to increase awareness. Originality/value: The study is the first qualitative investigation into the perception of retail investors to understand the reasons for lower retail engagement in the Indian REIT market. 2024, Emerald Publishing Limited. -
Electrochemical investigations of chitosan/ZrO2-Bi2O3 composite for advanced energy and environmental applications
Energy needs are on the rise, and the need for effective corrosion resistance measures are also vital to meet the requirements prevailing in society. A multifunctional Chitosan/ZrO2-Bi2O3 composite is synthesized, keeping electrochemical analysis of energy and environmental applications in mind. Various physicochemical methods confirm the impact of integrating ZrO2-Bi2O3 into chitosan, resulting in improved efficacy across applications. The electrocatalytic supercapacitance, hydrogen evolution reaction, and corrosion inhibition studies are carried out to evaluate the efficiency of the synthesized composite. The composite shows a specific capacitance of 636.5 F/g, ensuring the effective utility for supercapacitance applications. The lower overpotential of 135.2 mV is shown by the composite in the electrocatalytic hydrogen evolution reaction. The synthesized composite also shows 96.2 % efficacy in corrosion inhibition studies. The studies conducted demonstrate the increased effectiveness of chitosan when combined with bimetal oxide. The chitosan composite is therefore a competent catalyst for energy and environmental applications. 2024 Elsevier Ltd -
Zinc oxide/tin oxide nanoflower-based asymmetric supercapacitors for enhanced energy storage devices
Research on energy storage devices has focused on improving asymmetric supercapacitors (ASCs) by utilizing two different electrode materials. In this work, we have successfully prepared a unique material, ZnO/SnO2 nanoflower, via the hydrothermal method. Graphene oxide (GO) was synthesized by applying the modified Hummers' technique. The ZnO/SnO2 nanoflower was deposited on a polypyrrole (PPY) nanotube/graphene oxide composite (ZS/GP) in two steps: in situ chemical polymerization, followed by a hydrothermal method. Electrochemical properties of the prepared material nanocomposite were analyzed by applying cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) and electrochemical impedance spectroscopy (EIS) techniques. An asymmetric supercapacitor (ASC) was constructed using ZS/GP nanocomposite as the positive electrode and Caesalpinia pod-based carbonaceous material as the negative electrode material, and its performance was investigated. As a result, the fabricated ASCs were found to have an excellent specific capacitance of 165.88 F g?1 at 1.4 V, with an energy density of 5.12 W h kg?1 and a power density of 2672 W kg?1. The prepared nanocomposite material for the ASC showed a cycle stability of 17k cycles at a current density of 5 A g?1. This study revealed that the electrode material ZS/GP nanocomposite is highly suitable for supercapacitor applications. The ASC device's extended cycle life experiments for 17k cycles produced a coulombic efficiency of 97% and a capacitance retention of 73%, demonstrating the promising potential of the electrode materials for greener as well as efficient energy storage applications while converting abundant bio waste into effective energy. 2024 The Royal Society of Chemistry. -
Metaheuristic Machine Learning Algorithms for Liver Disease Prediction
In machine learning, optimizing solutions is critical for improving performance. This study explores the use of metaheuristic algorithms to enhance key processes such as hyperparameter tuning, feature selection, and model optimization. Specifically, we integrate the Artificial Bee Colony (ABC) algorithm with Random Forest and Decision Tree models to improve the accuracy and efficiency of disease prediction. Machine learning has the potential to uncover complex patterns in medical data, offering transformative capabilities in disease diagnosis. However, selecting the optimal algorithm for model optimization presents a significant challenge. In this work, we employ Random Forest, Decision Tree models, and the ABC algorithmbased on the foraging behaviours of honeybeesto predict liver disease using a dataset from Indian medical records. Our experiments demonstrate that the Random Forest model achieves an accuracy of 85.12%, the Decision Tree model 76.89%, and the ABC algorithm 80.45%. These findings underscore the promise of metaheuristic approaches in machine learning, with the ABC algorithm proving to be a valuable tool in improving predictive accuracy. In conclusion, the integration of machine learning models with metaheuristic techniques, such as the ABC algorithm, represents a significant advancement in disease prediction, driving progress in data-driven healthcare. 2024, Iquz Galaxy Publisher. All rights reserved. -
Synthesis of ZnO and NiO nano ceramics composite high-performance supercapacitor and its catalytic capabilities
NiO and ZnO mixed nanocomposites were manufactured using the solution combustion process. As-prepared samples were analyzed using XRD. The XRD shows an average crystallite size of 3540 nm. The elemental composition determined by EDS indicates a nearly equal proportion of Ni and Zn, with an atomic ratio of Ni/Zn = 0.96. The specific capacitances of NiO is 295.5 Fg-1, ZnO is 117.3 Fg-1 and ZnO/NiO nanocomposites is 561.75 Fg-1 which are more than NiO and ZnO alone. This study shows that constructing binary oxide nanocomposites is an approach for developing high-performance supercapacitor electrode materials. Experimental observations on catalytic activity revealed that NiO/ZnO increased catalytic activity. Furthermore, adding NiO to ZnO in the composite increased the overall amount of oxygen vacancies in the samples. Our research lays the door for a simple, inexpensive, nontoxic, and quick technique to synthesize binary transition metal oxide-based electrode materials for high-performance supercapacitors. 2024 Elsevier Ltd and Techna Group S.r.l. -
Engineering the functionality of porous organic polymers (POPs) for metal/cocatalyst-free CO2 fixation at atmospheric conditions
Carbon dioxide (CO2) utilization as C1 feedstock under metal/co-catalyst-free conditions facilitates the development of eco-friendly routes for mitigating atmospheric CO2 concentration and producing value-added compounds. In this regard, herein, we designed a bifunctional porous organic polymer (POP-1) by incorporating acidic (-CONH) and CO2-philic (-NH/N) sites by judicious choice of organic precursors. Indeed, POP-1 exhibits high heat of interaction for CO2 (40.2 kJ/mol) and excellent catalytic performance for transforming carbon dioxide to cyclic carbonates, a high-value commodity chemical with high selectivity and yield under metal/cocatalyst/solvent-free atmospheric pressure conditions. Interestingly, an analogous polymer (POP-2) that lacks basic (-NH/N) sites showed lower CO2 interaction energy (31.6 kJ/mol) and catalytic activity than that of POP-1. The theoretical studies further supported the superior catalytic activity of POP-1 in the absence of Lewis acidic metal and cocatalyst. Notably, POP-1 showed excellent reusability with retention of catalytic performance for multiple cycles of usage. Overall, this work presents a novel approach to metal/cocatalyst/solvent-free utilization of CO2 under eco-friendly atmospheric pressure conditions. 2024 Elsevier Ltd