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NAVIGATING FOR PEACE IN THE CONUNDRUMS OF RELIGION AND LAW
It is a critical question whether unrestricted freedom of religion is detrimental to the development of peace. Recently the religious dictate of wearing a hijab has come in conflict with the prescription of uniforms at educational institutions. This led to large-scale violence and unrest in society. It raised concerns about the scope of the right to freedom of expression, protection of religious expression, the overarching requirement of a need for public order, and reasonable accommodation of diversity in society. This research explores these issues in the context of educational institutions by critically analysing the laws and operative principles and the role of law and religion in promoting social cohesion and integrity. It addresses the counterarguments of reasonable accommodation and argues that the concept of reasonable accommodation fails to address deep-rooted structural inequalities, and in an education setup prescription of uniforms is justified as it portrays higher values of equality, development, and peace. 2022 Journal of Dharma: Dharmaram Journal of Religions and Philosophies (DVK, Bangalore),. -
Endurance and Evolution: Exploring Levels of Resilience Among Indian Breast Cancer Survivors
Resilience for Indian women with breast cancer involves maintaining positivity and adaptability amid the complex challenges affecting their physical, emotional, and social well-being. However, research focused on resilience amongst this population in Indian settings is limited. Therefore, the aim of the study is to explore the experience of levels, patterns, and processes of resilience in Indian women living with breast cancer. A qualitative phenomenological approach was used to study resilience. Thirty-three participants from two hospitals underwent semistructured interviews, including survivors, women in cancer therapy, and family members. Data collected via audio recordings were analyzed using reflective thematic analysis techniques. The finding describes four themes of experience of resilience in women living with breast cancer. (a) Cancer diagnosis is a life-changing experience. Breast cancer diagnosis and therapy cause existential crisis, psychological distress, and social stigma. (b) Restoring healthy perception in an adverse event. Navigating challenges and achieving a balance between internal and external factors. (c) Types of supportthe pathway to resilience. Enhanced their resilience through internal support including attributes, past experiences, sociodemographic factors, and brain fitness. External support includes family, friends, religious or spiritual advisors, medical care, role models, other cancer survivors, and comfortable environments. (d) Learning and growing from the experience. Gained a better perspective on life, ultimately resulting in a new normal and finding meaning in the experience. Data show breast cancer survivors experience dynamic resilience, highlighting the need for culturally tailored interventions and supportive avenues within cancer care by healthcare providers and policymakers. The Author(s) 2024. -
Determinants of Quality of Life in Women with Breast Cancer: A Systematic Review
The morbidity and mortality rates associated with breast cancer are a major public health concern globally. The resulting impairment in the patients quality of life (QOL) affects their health, symptoms, and well-being in physical, social, psychological, environmental, and sexual functioning. The aim of this study was to systematically review the literature addressing the determinants of QOL in breast cancer patients. A search of 6 electronic medical databases was undertaken. Employing a rigorous systematic protocol, eligible articles were analyzed and a total of 22 studies that met all eligibility criteria were included in the systematic review. The total sample size was 7,041 women ranging from 30 to 66 years. The determinants of QOL were found to cluster into 10 areas. These include the degree of pain, type and stage of cancer treatment, medical health, cognitive and behavioural factors, emotional health, physical activity and appearance, social factors, age and menopausal status, education and employment status, and ethnicity and religion. The types of breast cancer treatment and psychological parameters were the most common determinants of QOL in breast cancer patients. These insights can help formulate proactive interventions that can be used by patients, caregivers, and healthcare professionals to build protective capacities and alleviate challenges to ensure superior quality of life in women with breast cancer. 2022,Journal of International Women''s Studies. All Rights Reserved. -
Interventions for the improvement of social skills in autism spectrum disorder in India: A systematic review
Background: The increasing prevalence of Autism Spectrum Disorders (ASD) in India is in a gaping contrast with the existing interventions in India. Though several interventions have proved their efficiency in foreign countries, such studies within India are scarce. Aims: This review attempts to systematically examine the different intervention practices that include improvement of social skills in ASD that is practiced in India as revealed through published literature on the same. Methods: Studies published from 2000 to 2020 were selected for the study. Evidence is presented for nine treatment categories: Behavior-based interventions, Developmental Interventions, TEACHH approach, Parent-mediated Interventions, speech-based Interventions, electronics-based interventions, augmentative and alternative communication, play-based interventions and Yoga-based interventions. These studies were drawn from databases Ebsco, Proquest, PubMed, MEDLINE, science direct and Google Scholar. Though a definitive conclusion cannot be drawn without a meta-analysis, the available evidence is gathered and evaluated in the present review. Results: The review has proved to be a reliable summary of the interventions that include improvement of social skills in ASD that is practiced in India. Conclusions: Parent-mediated interventions may be more appropriate for the resource-poor settings of India, when developmental interventions may be more appropriate for the resourcerich settings of India. The scarcity of published literature on the topic in India is also a significant factor that highlighted itself through the research. 2021, Indian Association for Child and Adolescent Mental Health. All rights reserved. -
Spoofing Face Detection Using Novel Edge-Net Autoencoder for Security
Recent security applications in mobile technologies and computer systems use face recognition for high-end security. Despite numerous security tech-niques, face recognition is considered a high-security control. Developers fuse and carry out face identification as an access authority into these applications. Still, face identification authentication is sensitive to attacks with a 2-D photo image or captured video to access the system as an authorized user. In the existing spoofing detection algorithm, there was some loss in the recreation of images. This research proposes an unobtrusive technique to detect face spoofing attacks that apply a single frame of the sequenced set of frames to overcome the above-said problems. This research offers a novel Edge-Net autoencoder to select convoluted and dominant features of the input diffused structure. First, this pro-posedmethodistestedwiththeCross-ethnicityFaceAnti-spoofing (CASIA), Fetal alcohol spectrum disorders (FASD) dataset. This database has three models of attacks: distorted photographs in printed form, photographs with removed eyes portion, and video attacks. The images are taken with three different quality cameras: low, average, and high-quality real and spoofed images. An extensive experimental study was performed with CASIA-FASD, 3 Diagnostic Machine Aid-Digital (DMAD) dataset that proved higher results when compared to existing algorithms. 2023, Tech Science Press. All rights reserved. -
The computational model of nanofluid considering heat transfer and entropy generation across a curved and flat surface
The entropy generation analysis for the nanofluid flowing over a stretching/shrinking curved region is performed in the existence of the cross-diffusion effect. The surface is also subjected to second-order velocity slip under the effect of mixed convection. The Joule heating that contributes significantly to the heat transfer properties of nanofluid is incorporated along with the heat source/sink. Furthermore, the flow is assumed to be governed by an exterior magnetic field that aids in gaining control over the flow speed. With these frameworks, the mathematical model that describes the flow with such characteristics and assumptions is framed using partial differential equations (PDEs). The bvp4c solver is used to numerically solve the system of non-linear ordinary differential equations (ODEs) that are created from these equations. The solutions of obtained through this technique are verified with the available articles and the comparison is tabulated. Meanwhile, the interpretation of the results of this study is delivered through graphs. The findings showed that the Bejan number was decreased by increasing Brinkman number values whereas it enhanced the entropy generation. Also, as the curvature parameter goes higher, the speed of the nanofluid flow diminishes. Furthermore, the increase in the Soret and Dufour effects have enhanced the thermal conduction and the mass transfer of the nanofluid. 2023, The Author(s). -
Machine Learning-Enabled NIR Spectroscopy. Part 3: Hyperparameter by Design (HyD) Based ANN-MLP Optimization, Model Generalizability, and Model Transferability
Data variations, library changes, and poorly tuned hyperparameters can cause failures in data-driven modelling. In such scenarios, model drift, a gradual shift in model performance, can lead to inaccurate predictions. Monitoring and mitigating drift are vital to maintain model effectiveness. USFDA and ICH regulate pharmaceutical variation with scientific risk-based approaches. In this study, the hyperparameter optimization for the Artificial Neural Network Multilayer Perceptron (ANN-MLP) was investigated using open-source data. The design of experiments (DoE) approach in combination with target drift prediction and statistical process control (SPC) was employed to achieve this objective. First, pre-screening and optimization DoEs were conducted on lab-scale data, serving as internal validation data, to identify the design space and control space. The regression performance metrics were carefully monitored to ensure the right set of hyperparameters was selected, optimizing the modelling time and storage requirements. Before extending the analysis to external validation data, a drift analysis on the target variable was performed. This aimed to determine if the external data fell within the studied range or required retraining of the model. Although a drift was observed, the external data remained well within the range of the internal validation data. Subsequently, trend analysis and process monitoring for the mean absolute error of the active content were conducted. The combined use of DoE, drift analysis, and SPC enabled trend analysis, ensuring that both current and external validation data met acceptance criteria. Out-of-specification and process control limits were determined, providing valuable insights into the models performance and overall reliability. This comprehensive approach allowed for robust hyperparameter optimization and effective management of model lifecycle, crucial in achieving accurate and dependable predictions in various real-world applications. Graphical Abstract: [Figure not available: see fulltext.]. 2023, The Author(s). -
Machine LearningEnabled NIR Spectroscopy. Part 2: Workflow for Selecting a Subset of Samples from Publicly Accessible Data
Abstract: An increasingly large dataset of pharmaceuticsdisciplines is frequently challenging to comprehend. Since machine learning needs high-quality data sets, the open-source dataset can be a place to start. This work presents a systematic method to choose representative subsamples from the existing research, along with an extensive set of quality measures and a visualization strategy. The preceding article (Muthudoss et al. in AAPS PharmSciTech 23, 2022) describes a workflow for leveraging near infrared (NIR) spectroscopy to obtain reliable and robustdata on pharmaceutical samples. This study describes the systematic and structured procedure for selecting subsamples from the historical data. We offer a wide range of in-depth quality measures, diagnostic tools, and visualization techniques. A real-world, well-researched NIR dataset was employed to demonstrate this approach. This open-source tablet dataset (http://www.models.life.ku.dk/Tablets) consists of different doses in milligrams, different shapes, and sizes of dosage forms, slots in tablets, three different manufacturing scales (lab, pilot, production), coating differences (coated vs uncoated), etc. This sample is appropriate; that is, the model was developed on one scale (in this research, the lab scale), and it can be great to investigate how well the top models are transferable when tested on new data like pilot-scale or production (full) scale. A literature review indicated that the PLS regression models outperform artificial neural network-multilayer perceptron (ANN-MLP). This work demonstrates the selection of appropriate hyperparameters and their impact on ANN-MLP model performance. The hyperparameter tuning approaches and performance with available references are discussed for the data under investigation. Model extension from lab-scale to pilot-scale/production scale is demonstrated. Highlights: We present a comprehensive quality metrics and visualization strategy in selecting subsamples from the existing studies A comprehensive assessment and workflow are demonstrated using historical real-world near-infrared (NIR) data sets Selection of appropriate hyperparameters and their impact on artificial neural network-multilayer perceptron (ANN-MLP) model performance The choice of hyperparameter tuning approaches and performance with available references are discussed for the data under investigation Model extension from lab-scale to pilot-scale successfully demonstrated Graphical Abstract: [Figure not available: see fulltext.]. 2023, The Author(s). -
DDoS Intrusions Detection in Low Power SD-IoT Devices Leveraging Effective Machine Learning
Security and privacy are significant concerns in software-defined networking (SDN)-applied Internet of Things (IoT) environments, due to the proliferation of connected devices and the potential for cyberattacks. Hence, robust security mechanisms need to be developed, including authentication, encryption, and distributed denial of service (DDoS) attack detection, tailored to the constraints of low-power IoT devices. Selecting a suitable tiny machine learning (TinyML) algorithm for low-power IoT devices for DDoS attack detection involves considering various factors such as computational complexity, robustness in dealing with heterogeneous data, accuracy, and the specific constraints of the target IoT device. In this paper, we present a two-fold approach for the optimal TinyML algorithm selection leveraging the hybrid analytical network process (HANP). First, we make a comparative analysis (qualitative) of the machine learning algorithm in the context of suitability for TinyML in the domain of SD-IoT devices and generate the weights of suitability for TinyML applications in SD-IoT. Then we evaluate the performance of the machine learning algorithms and validate the results of the model to demonstrate the effectiveness of the proposed method. Finally, we see the effect of dimensionality reduction with respect to features and how it affects the precision, recall, accuracy, and F1 score. The results demonstrate the effectiveness of the scheme. 1975-2011 IEEE. -
Wireless Network Security Using Load Balanced Mobile Sink Technique
Real-time applications based on Wireless Sensor Network (WSN) technologies are quickly increasing due to intelligent surroundings. Among the most significant resources in the WSN are battery power and security. Clustering stra-tegies improve the power factor and secure the WSN environment. It takes more electricity to forward data in a WSN. Though numerous clustering methods have been developed to provide energy consumption, there is indeed a risk of unequal load balancing, resulting in a decrease in the networks lifetime due to network inequalities and less security. These possibilities arise due to the cluster heads limited life span. These cluster heads (CH) are in charge of all activities and control intra-cluster and inter-cluster interactions. The proposed method uses Lifetime centric load balancing mechanisms (LCLBM) and Cluster-based energy optimization using a mobile sink algorithm (CEOMS). LCLBM emphasizes the selection of CH, system architectures, and optimal distribution of CH. In addition, the LCLBM was added with an assistant cluster head (ACH) for load balancing. Power consumption, communications latency, the frequency of failing nodes, high security, and one-way delay are essential variables to consider while evaluating LCLBM. CEOMS will choose a cluster leader based on the influence of the fol-lowing parameters on the energy balance of WSNs. According to simulated find-ings, the suggested LCLBM-CEOMS method increases cluster head selection self-adaptability, improves the networks lifetime, decreases data latency, and bal-ances network capacity. 2023, Tech Science Press. All rights reserved. -
Next-Generation Connectivity in A Heterogenous Railway World
Global System for Mobile communication - Railway (GSM-R) is widely used for operational communications between train and signaler. However, there is a need to define a successor that addresses: obsolescence, radio spectrum demand and the enabling of a range of emerging digital applications such as radio-based signaling and Automatic Train Control (ATC). Therefore, the International Union of Railways (UIC) started the initiative to develop the Future Railway Mobile Communication System (FRMCS). This article describes an Adaptable Communication System (ACS) that is being developed jointly by industry and railway operators as a possible successor covering all types of railways and all aspects of the FRMCS. A pragmatic approach is suggested that considers diverse railway settings and makes use of various radio access technologies. Countries, geographical regions and infrastructure managers differ concerning available radio technologies, but use of a suitable ACS could pave the way towards innovation in the railway sector. For this adaptive concept we discuss several network models and enhancements including satellite communications (SatCom), Software-Defined Networking (SDN) integration and antenna systems that support multiple bearers in one. For SatCom a software defined radio (SDR) prototype using random access is presented that is able to fulfill the requirements of ETCS. We found that SDN can be used for dynamically changing the access technology for critical and non-critical railway use cases. Furthermore, we present an antenna prototype that can be used for 5G, GSM, WLAN and LTE in parallel which saves limited mounting surface on the train. 1979-2012 IEEE. -
Integrated hybrid membrane system for enhanced water treatment and desalination for environmental preservation
Technology advancements in desalination, water treatment, and energy efficiency are crucial to preserving our planet. It is critical to find solutions for the future that save natural resources and lessen environmental damage because the freshwater shortage is getting worse, and energy demand is increasing. They face various obstacles, even though their breakthroughs are extremely important. Lot of energy can be utilized for the traditional desalination techniques, as it negatively impacts the environment. Then, the process of the existing Water Treatment (WT) are expensive and ineffective. An Integrated Hybrid Membrane System for Enhanced WT (IHMS-EWT) is a unique technique for WT and desalination was suggested in this study. The integration of many membrane procedures like nanofiltration, reverse and forward osmosis, and membrane distillation, and these will helps in facilitating the best WT and desalination methods. Due to the incorporating Renewable Energy (RE), the IHMS-EWT also demonstrates the (SWMS) Sustainable Water Management System, as it enhances the EE and thereby reducing the environmental impact. The great potential in the wide range of applications was offered by the IHMS-EWT technique. Providing the decentralized WT solutions in the remote areas, this unique approach has the ability to reduce the fresh water scarcity in the coastal areas based on the demands of the municipal, industrial and agricultural demands. The environmental sustainability throughout the lenghthy operations was ensured by the support of IHMS-EWT. It also helps in providing resilience in the crisis situations. The cost-effective evaluations, operating parameter optimization, and performance prediction of the method was enabled by employing the computational modelling. Through simulatimg different contexts, the effective configurations and operational techniques are focussed on the study for enhancing the IHMS-EWT technology.The model shift in the SWM, the IHMS-EWT technique addresses the main problems and brings one step for more secure environment. Comparing to other existing methods, Improving the water purification by 98.2 %, 94.2 % efficiency rate, the EC prediction rate of 96.2 %, the cost-effectiveness rate by 82.4 % and the performance rate by 96.7 % by the suggested IHMS-EWT model and it was demonstrated by the outcomes of the experiment. 2024 The Authors -
End-to-End Encryption in Resource-Constrained IoT Device
Internet of Things (IoT) technologies will interconnect with a wide range of network devices, regardless of their local network and resource capacities. Ensuring the security, communication, and privacy protection of end-users is a major concern in IoT development. Secure communication is a significant requirement for various applications, especially when communication devices have limited resources. The emergence of IoT also necessitates the use of low-power devices that interconnect with each other for essential processing. These devices are expected to handle large amounts of monitoring and control data while having limited capabilities and resources. The algorithm used for secure encryption should protect vulnerable devices. Conventional encryption methods such as RSA or AES are computationally expensive and require large amounts of memory, which can adversely affect device performance. Simplistic encryption techniques are easily compromised. To address these challenges, an effective and secure lightweight cryptographic process is proposed for computer devices. This process utilizes a symmetrical encryption key block, incorporating a custom proxy network (SP) and a modified Feistel architecture. Security analysis and performance evaluation results demonstrate that the proposed protocol is secure and energy-efficient. The symmetric key encryption scheme is based on sequences in the Feistel cipher, with multiple rounds and sub-keys generated using principles derived from genetic algorithms. This proposed algorithm minimizes processing cycles while providing sufficient security. 2013 IEEE. -
Novel HGDBO: A Hybrid Genetic and Dung Beetle Optimization Algorithm for Microarray Gene Selection and Efficient Cancer Classification; [Nuevo HGDBO: Un Algoritmo Hrido de Optimizaci Genica y de Escarabajos Peloteros para la Selecci de Genes en Microrrays y la Clasificaci Eficiente del Ccer]
Introduction: ovarian cancer ranked as the seventh most common cancer and the eighth leading cause of cancer-related mortality among women globally. Early detection was crucial for improving survival rates, emphasizing the need for better screening techniques and increased awareness. Microarray gene data, containing numerous genes across multiple samples, presented both opportunities and challenges in understanding gene functions and disease pathways. This research focused on reducing feature selection time in large gene expression datasets by applying a hybrid bio-inspired method, HGDBO. The goal was to enhance classification accuracy by optimizing gene subsets for improved gene expression analysis. Method: the study introduced a novel hybrid feature selection method called HGDBO, which combined the Dung Beetle Optimization (DBO) algorithm with the Genetic Algorithm (GA) to improve microarray data analysis. The HGDBO method leveraged the exploratory strengths of DBO and the exploitative capabilities of GA to identify relevant genes for disease classification. Experiments conducted on multiple microarray datasets showed that the hybrid approach offered superior classification performance, stability, and computational efficiency compared to traditional methods. Ovarian cancer classification was performed using Nae Bayes (NB) and Random Forest (RF) algorithms. Results and Discussion: the Random Forest model outperformed the Nae Bayes model across all metrics, achieving higher accuracy (0,96 vs. 0,91), precision (0,95 vs. 0,91), recall (0,97 vs. 0,90), F1 score (0,95 vs. 0,91), and specificity (0,97 vs. 0,86). Conclusions: these results demonstrated the effectiveness of the HGDBO method and the Random Forest classifier in improving the analysis and classification of ovarian cancer using microarray gene data. 2024; Los autores. -
Energy management of hybrid microgrids A comparative study with hydroplus and methanol based fuel cells
Energy management is essential for the efficient operation of microgrids with reduced energy costs and minimized emissions. Energy management of PV/battery/fuel cell/diesel generator-based microgrid to minimize the operations cost considering battery degradation and emissions for a fully functional microgrid existing in the campus of Sultan Qaboos University, Oman, is presented in this work. A microgrid with a state-of-the-art hydroplus fuel cell without the necessity for hydrogen storage is presented in this study with experimentally obtained parameters. Also, a comparison of operations cost with microgrids using two different technologies of PEM fuel cells, one with hydroplus fuel cell and the second with the methanol fuel cell which requires provision for hydrogen storage is performed with three different cases; the scheduled, grid-tied, and islanded with different scenarios under grid-tied mode. The analysis proved that using a hydroplus fuel cell instead of a methanol fuel cell with hydrogen storage reduces the cost of the daily operation by 6.9% in the scheduled mode and 18.2% in the islanded mode. In the grid-tied mode three different grid limits, 20 kW, 15 kW, and 10 kW are considered. The analysis showed no reduction, 1.3% and 5.9% reduction in the operations cost respectively. The results obtained are highly promising to be applied in microgrids where conventional fuel cells are currently employed. The new technology of fuel cells introduced in this study, possesses the advantages of near zero emissions and reduced operations costs besides avoiding the perilousness of hydrogen storage. 2024 Hydrogen Energy Publications LLC -
Development of Biocompatible Barium peroxide/Pluronic F127/L-ornithine Composite for Enriched Antimicrobial, Antioxidant and Anticancer Potential: An in vitro Study
Osteosarcoma (MG-63) is a type of bone cancer affects mostly adolescents and young adults. Disease-causing microorganisms like Bacillus subtilis, Staphylococcus aureus, Escherichia coli, Klebsiella pneumoniae and Candida albicans pose serious illness in humans. There is a need to develop multifunctional composite to combat cancer and other most common disease caused by disease causing microorganisms. In this context, BaO2 and pluronic F127, L-Ornithine coated BaO2 (BaO2-PF127-LO) composite have been prepared and characterized by XRD, FTIR, UV-Vis, SEM, HRTEM, EDAX, and XPS analytical techniques. BaO2 and BaO2-PF127-LO were orthorhombic crystalline structure and the crystallite size was found as 32nm for BaO2 and 26nm for modified BaO2 PL studies revealed the green emission observed at 506nm for BaO2-PF127-LO composite which is absent in the case of bare BaO2. Antimicrobial activity of BaO2 and BaO2-PF127-LO was investigated. MTT assay was performed to determine the anticancer potential while the DPPH free radical scavenging assay was carried out to determine the antioxidant potential. The experiment study revealed that the BaO2-PF127-LO exhibited enhanced antimicrobial, antioxidant, and anticancer activity and low toxicity when compared to pristine BaO2. The experimental results revealed that the BaO2-PF127-LO composite holds promising potential for biomedical applications. The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. -
Optimized green synthesis of ZnO nanoparticles: evaluation of structural, morphological, vibrational and optical properties
In this study, leaf extracts of Aloe vera (AV), Azadirachta indica (AI), and Amaranthus dubius (AD) were used to synthesize zinc oxide nanoparticles utilizing a simple green synthesis process. The structural, optical, band energy, size, surface area, and shape of as-prepared nanoparticles were studied using analytical techniques. The hexagonal phase was revealed by XRD studies for all three samples: AV-ZnO, AI-ZnO, and AD-ZnO, with crystallite sizes of 35.8nm, 30.83nm, and 33.1nm, respectively. The UVVisible spectra of AV-ZnO, AI-ZnO, and AD-ZnO exhibit the characteristic absorption in the range of 200 to 450nm, and the band gap energy was found to be 3.10eV, 3.12eV, and 3.07eV, respectively. FESEM and TEM studies revealed that the ZnO NPs are rod-shaped with a roughly spherical appearance. EDAX analysis confirmed the presence of zinc and oxygen and indicates that the formed product is a pure phase of ZnO NPs. Increased antibacterial activity was noted for AV-ZnO, AI-ZnO, and AD-ZnO against gram-negative (Klebsiella pneumonia, Shigella dysenteriae), gram positive (Staphylococcus aureus, and Bacillus) bacterial strain. 2022, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature. -
Structural modification of electrophilic group substituted phenyldiazenyl derivatives for antitubercular application
In the present work, four electrophilic group substitute phenyldiazenyl derivatives were synthesized using an electrophilic substitution reaction. The physicochemical analysis was carried out using FT-IR, 1H NMR, and HR-MS data. The photophysical studies were carried out using theoretical methods. Density functional theory was employed to illustrate the electronic and optical characteristics of the synthesized compounds. The HOMO-LUMO energies were theoretically computed in different solvents using Gaussian 09W software and results are compared with the experimental values. The molecule PT4 shows highest bandgap of 4.497eV. Further, the global chemical reactivity descriptors were used to determined nature of chemical reactivity. The anti-tubercular activity was evaluated using invitro and molecular docking techniques and results reveal that barbituric acid coupled with phenyldiazenyl displayed excellent anti-tubercular activity compared with the standard Gentamycin. 2024 Indian Chemical Society -
Theory of planned behavior in predicting the construction of eco-friendly houses
Purpose: The present study aimed to explore the applicability of theory of planned behavior in construction of eco-friendly houses. Design/methodology/approach: Study utilized cross-sectional correlational research design, collected data from 269 adult house owners of Kerala, India, with the help of a self-report measures namely, attitude towards eco-friendly house construction, subjective norm, perceived behavioral control, behavioral intention to build eco-friendly houses, check list of eco-friendly house and socio-demographic data sheet. Descriptive statistics, Karl Pearson product moment correlation, confirmatory factor analysis and mediation analysis with the help of AMOS were used to describe the distribution of study variables and to test the research hypotheses and proposed model. Findings: Study revealed that behavioral intention to build eco-friendly house was the immediate and strongest predictor of actual behavior of constructing an eco-friendly house. Behavioral intention mediated the relationship of attitudinal variables, normative variables and control variables with the behavior of constructing eco-friendly houses. Research limitations/implications: The results vouched the applicability of theory of planned behavior as a comprehensive model in explaining the behavior of eco-friendly house construction. Practical implications: Results of the study iterates the utility of attitudinal, normative and control factors in enhancing the choice of constructing eco-friendly houses. The results can be applied to develop a marketing tool to enhance the behavior of choosing or constructing eco-friendly houses in the population. Originality/value: Role of conventional concrete construction in climate crisis is unquestioned, and adopting eco-friendly architecture is a potential solution to the impending doom of climate crisis. Behavioral changes play a significant role in the success of global actions to curb the climate crisis. Present study discusses the role of psychological variables in constructing eco-friendly houses. 2022, Emerald Publishing Limited. -
A multi-scale and rotation-invariant phase pattern (MRIPP) and a stack of restricted Boltzmann machine (RBM) with preprocessing for facial expression classification
In facial expression recognition applications, the classification accuracy decreases because of the blur, illumination and localization problems in images. Therefore, a robust emotion recognition technique is needed. In this work, a Multi-scale and Rotation-Invariant Phase Pattern (MRIPP) is proposed. The MRIPP extracts the features from facial images, and the extracted patterns are blur-insensitive, rotation-invariant and robust. The performance of classification algorithms like Fisher faces, Support Vector Machine (SVM), Extreme Learning Machine (ELM), Convolutional Neural Network (CNN) and Deep Neural Network (DNN) are analyzed. In order to reduce the time for classification, an OPTICS-based pre-processing of the features is proposed that creates a non-redundant and compressed training set to classify the test set. Ten-fold cross validation is used in experimental analysis and the performance metric classification accuracy is used. The proposed approach has been evaluated with six datasets Japanese Female Facial Expression (JAFFE), Cohn Kanade (CK +), Multi- media Understanding Group (MUG), Static Facial Expressions in the Wild (SFEW), Oulu-Chinese Academy of Science, Institute of Automation (Oulu-CASIA) and ManMachine Interaction (MMI) datasets to meet a classification accuracy of 98.2%, 97.5%, 95.6%, 35.5%, 87.7% and 82.4% for seven class emotion detection using a stack of Restricted Boltzmann Machines(RBM), which is high when compared to other latest methods. 2020, Springer-Verlag GmbH Germany, part of Springer Nature.