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A facile, green synthesis of carbon quantum dots from Polyalthia longifolia and its application for the selective detection of cadmium
Carbon quantum dots (CQDs) has received world-wide recognition for their outstanding physicochemical properties that have the ability to substitute the semiconductor quantum dots. Herein, we have developed a strategy to determine the presence of Cd2+ using CQDs as a fluorescence probe. The CQDs were synthesized from the leaves of Polyalthia longifolia (a natural source) through a one-step hydrothermal method. The CQDs obtained from Polyalthia longifolia (p-CQDs) was characterized using XRD, TEM, FTIR, Raman Spectroscopy, XPS Studies, UVVisible spectroscopy and PL Spectroscopy. The p-CQDs displayed bright red fluorescence under the UV light, with good water solubility, and appreciable photostability and a quantum yield of 22%. The p-CQDs had a quasi-spherical morphology with an average particle size of 3.33 nm. The p-CQDs showed high selectivity and sensitivity for the detection of Cd2+ with a low limit of detection of 2.4 nM and a wide linear range of 7.3 nM12 ?M. The PL intensity of the p-CQDs showed a quenching effect in presence of Cd2+ and the mechanism of quenching was validated via fluorescence lifetime decay studies. We have also studied the effectiveness of the fluorescent probe developed for Cd2+ sensing in real samples of ground water and industrial effluents. 2022 Elsevier Ltd -
A facile, green synthesis of carbon quantum dots from Polyalthia longifolia and its application for the selective detection of cadmium /
Dyes and Pigments, Vol.210, ISSN No: 0143-7208.
Carbon quantum dots (CQDs) has received world-wide recognition for their outstanding physicochemical properties that have the ability to substitute the semiconductor quantum dots. Herein, we have developed a strategy to determine the presence of Cd<sup>2+</sup> using CQDs as a fluorescence probe. The CQDs were synthesized from the leaves of <em>Polyalthia longifolia</em> (a natural source) through a one-step hydrothermal method. The CQDs obtained from <em>Polyalthia longifolia</em> (p-CQDs) was characterized using XRD, TEM, FTIR, Raman Spectroscopy, XPS Studies, UV–Visible spectroscopy and PL Spectroscopy. The p-CQDs displayed bright red fluorescence under the UV light, with good water solubility, and appreciable photostability and a quantum yield of 22%. The p-CQDs had a quasi-spherical morphology with an average particle size of 3.33 nm. -
A FAMILY OF CONGRUENCES FOR (2, ?)?REGULAR BIPARTITIONS
The congruence of certain restricted partition functions known as regular bipartition is discussed in this paper. We particularly investigate the (2, ?)-regular bipartitions of n, denoted by B2,? (n), and establish certain congruences for B2,? (n) when ? ? 3. We derive infinite families of congruences modulo 4 for the (2, 3)-regular bipartition. We also obtain a generalisation of the regular bipartition for modulo p and p2. Indian Mathematical Society, 2022. -
A Family of Mexican Hat Wavelet Stieltjes Transform for Unbounded Non-decreasing Functions
In the present article, we examine the characteristics of the Mexican hat wavelet Stieltjes transform (MHWST) for a specific set of functions belonging to one of the sub-class of bounded variation functions. The subset comprises functions that are unbounded and non-decreasing. Further, a unified approach is applied to establish a uniqueness theorem and subsequently derive a representation theorem for the MHWST. The Author(s), under exclusive licence to The National Academy of Sciences, India 2024. -
A First Report of Docosahexaenoic Acid-Clocked Polymer Enveloped Gold Nanoparticles: A Way to Precision Breast Cancer and Triple Negative Breast Cancer Therapy and Its Apoptosis Induction
Functionalized gold nanoparticles (GNPs) are extensively utilized in various disciplines due to their excellent bioactivity, biocompatibility, and extended drug half-life, influenced by the ligands and size that are changed on surfaces. In this study, we successfully fabricated GNPs coated with ligands containing docosahexaenoic acid (DHA) and polyethylene glycol (PEG) clocked by a carboxyl group. These nanoparticles are referred to as MPA@GNPs-PEG-DHA. The cytotoxicity results demonstrate that MPA@GNPs-PEG-DHA exhibits superior cell selectivity, explicitly inhibiting the proliferation of breast cancerous cells than noncancerous cell lines. Apoptosis is involved in the reduction of cell proliferation by MPA@GNPs-PEG-DHA, as demonstrated clearly through many assays measuring apoptotic index, including AO/EB staining, DAPI, annexin V-FITC staining, mitochondrial membrane potential (MMP), and reactive oxygen species (ROS) measurement. The efficacy of MPA@GNPs-PEG-DHA in inducing apoptosis was demonstrated by its inhibition of mitochondrial dysfunction by ROS. MPA@GNPs-PEG-DHA has the potential to improve the induction of apoptosis in breast cancerous cells. 2024 Wiley Periodicals LLC. -
A formative measurement model and development of quality of work-life scale based on two-factor theory: evidence from Indian private industries
Purpose: This study examines the quality of work-life (QoWL) as a formative construct and validates the scale in an Indian context. Taking a cue from the two-factor (Herzberg) theory, the study developed and validated a formative assessment model of QoWL in the current scenario. Design/methodology/approach: Cross-sectional data and a self-administered questionnaire were used to analyze the QoWL scale based on a sample of 841 respondents from IT/ITES, BFSI, CPG and manufacturing sectors. Indicators/items of QoWL were considered a first-order reflective construct, and factors of QoWL were considered second-order formative construct in the study. Embedded two-stage approach was used to assess the antecedent construct in the model in which QoWL was measured with seven formative indicators in stage one, and all the constructs of the QoWL are measured with a single item (Global_QWL, i.e. the essence of all constructs) in stage two. Findings: The study found QoWL as a formative construct with seven significant dimensions; namely, hygiene factors included fairness in compensation (FC), job security (JS), interpersonal relationship (IR), health and wellbeing (HWB), where motivational factors had rewards and career growth (RG), work-life balance (WLB) and learning and development (LD). The study also indicated the strong association of a single item (global_QWL) with all constructs of QoWL. The study findings conceptualize a QoWL as a formative construct within the mentioned sector and can be generalized and extended to other sectors of the economy as well. Research limitations/implications: Future researchers can take guidance to deal with the formative construct in the development and validation of scale in various topics in the field of HRM. Future researchers can extend the study across cities and different sectors. Practical implications: In this VUCA world, employees have to be constantly on their toes to ensure their organization remains relevant. In this context, the least organization can do for their employees is to offer a conducive environment and favorable QoWL. This study aims to assist the key decision-makers in applying the QoWL index as a formative construct and aiding them in improving the quality of their decisions. Social implications: Researcher believes that applying the QoWL index as a formative construct can aid decision-makers in improving the quality of their decisions by equipping them with relevant inputs and knowledge. Government can focus on the employees' welfare and introduce the current motivational and hygiene factors in the area of quality of life of the Indians. Originality/value: Formative assessment measurement of QoWL model was validated with the two-factor theory to understand the work environment of India in the private sector across different sectors. The unique finding of the study was a single item (global_QWL) to conclude the QoWL index as a formative construct by redundancy analysis. 2022, Emerald Publishing Limited. -
A Fractional Atmospheric Circulation System under the Influence of a Sliding Mode Controller
The earths surface is heated by the large-scale movement of air known as atmospheric circulation, which works in conjunction with ocean circulation. More than (Formula presented.) variables are involved in the complexity of the weather system. In this work, we analyze the dynamical behavior and chaos control of an atmospheric circulation model known as the Hadley circulation model, in the frame of Caputo and CaputoFabrizio fractional derivatives. The fundamental novelty of this paper is the application of the Caputo derivative with equal dimensionality to models that includes memory. A sliding mode controller (SMC) is developed to control chaos in this fractional-order atmospheric circulation system with uncertain dynamics. The proposed controller is applied to both commensurate and non-commensurate fractional-order systems. To demonstrate the intricacy of the models, we plot some graphs of various fractional orders with appropriate parameter values. We have observed the influence of thermal forcing on the dynamics of the system. The outcome of the analytical exercises is validated using numerical simulations. 2022 by the authors. -
A Framework for Integrating the Distributed Hash Table (DHT) with an Enhanced Blooms Filter in MANET
MANET, a self-organizing, infrastructure-less, wireless network is a fast-growing technology in day-to-day life. There is a rapid growth in the area of mobile computing due to the extent of economical and huge availability of wireless devices which leads to the extensive analysis of the mobile ad-hoc network. It consists of the collection of wireless dynamic nodes. Due to this dynamic nature, the routing of packets in the MANET is a complex one. The integration of distributed hash table (DHT) in MANET is performed to enhance the overlay of routing. The node status updating in the centralized hash table creates the storage overhead. The bloom filter is a data structure that is a space-effective randomized one but it allows the false-positive rates. However, this can be able to compensate for the issue of storage overhead in DHT (Distributed hash table). Hence, to overcome the storage overhead occurring in DHT, and reduce the false positives, the Bloom's filter is integrated with the DHT initially. Furthermore, the link stability is measured by the distance among mobile nodes. The optimal node selection should be done for the transmission of packets which is the lacking factor. If it fails to select the optimal path then the removal of malicious nodes may lead to the unwanted entry of nodes into the other clustering groups. Therefore, to solve this problem, the bloom's filter is modified for enhancing the link stability. The novelty of this proposed work is the integration of Bloom's filter with the Distributed Hash Table which provides good security on transmission data by removing false-positive errors and storage overhead 2022,International Journal of Advanced Computer Science and Applications.All Rights Reserved -
A framework for national-level prevention initiatives in Indian schools: A risk reduction approach
India's mental health policies predominantly prioritize treatment and rehabilitation. While acknowledging the significance of youth well-being, the initiatives undertaken are fragmented, lacking comprehensive data on reach and utilization. Mounting evidence supports the preventability of mental illnesses, highlighting the cost-effectiveness of prevention initiatives, particularly within school-based programs. This paper aims to delineate a preventive framework centered on schools, employing the six-step OrigAMI (Origins of Adult Mental Illnesses) model. This model targets modifiable risk factors to stop the development of mental illnesses. Each step of this model is dissected and examined within the context of the school environment, elucidating the unique and influential role that educational institutions can undertake in preventive initiatives in India. In the initial step, the paper identifies modifiable risk factors in children and adolescents that can be addressed within the school environment. The second and third steps involve pinpointing the target demographic and utilizing data from comprehensive reviews of mental health initiatives. The fourth and fifth steps delineate the workforce structure, advocating for task shifting to non-specialists, engaging school stakeholders and parents, and establishing a systematic workforce framework. The final step delves into policy implications, exploring the potential to reduce the prevalence of mental illness by focusing on risk factors with a high Population Attributable Fraction. This section also contrasts the proposed approach in terms of expenditure against the current budget allocations. The paper culminates with a recommendation to integrate these preventive programs into existing healthcare policies, positioning schools as central to these prevention efforts. The integration of prevention programs into healthcare policies aims to reduce prevalence rates and alleviate the burden on the healthcare system. 2024 Elsevier GmbH -
A framework for natural resource management with geospatial machine learning: a case study of the 2021 Almora forest fires
Background: Wildfires have a substantial impact on air quality and ecosystems by releasing greenhouse gases (GHGs), trace gases, and aerosols into the atmosphere. These wildfires produce both light-absorbing and merely scattering aerosols that can act as cloud condensation nuclei, altering cloud reflectivity, cloud lifetime, and precipitation frequency. Uttarakhand province in India experiences frequent wildfires that affect its protected ecosystems. Thus, a natural resource management system is needed in this region to assess the impact of wildfire hazards on land and atmosphere. We conducted an analysis of a severe fire event that occurred between January and April 2021 in the Kumaun region of Uttarakhand, by utilizing open-source geospatial data. Near-real-time satellite observations of pre- and post-fire conditions within the study area were used to detect changes in land and atmosphere. Supervised machine learning algorithm was also implemented to estimate burned above ground biomass (AGB) to monitor biomass stock. Results: The study found that 21.75% of the total burned area burned with moderate to high severity, resulting in a decreased Soil Adjusted Vegetation Index value (> 0.3), a reduced Normalized Differential Moisture Index value (> 0.4), and a lowered Normalized Differential Vegetation Index (> 0.5). The AGB estimate demonstrated a significant simple determination (r2 = 0.001702) and probability (P < 2.2 10?16), along with a positive correlation (r ? 0.24) with vegetation and soil indices. The algorithm predicted that 17.56 tonnes of biomass per hectare burned in the Kumaun forests. This fire incident resulted in increased emissions of carbon dioxide (CO2; ~ 0.8 10?4kgcarbonh?1), methane (CH4; ~ 200 10?9mol fraction in dry air), carbon monoxide (CO; 2000 1015moleculescm?2 total column), and formaldehyde (HCHO; 3500 1013moleculescm?2 total column), along with increased aerosol optical thickness (varying from 0.2 to 0.5). Conclusions: We believe that our proposed operational framework for managing natural resources and assessing the impact of natural hazards can be used to efficiently monitor near-real-time forest-fire-caused changes in land and atmosphere. This method makes use of openly accessible geospatial data that can be employed for several objectives, including monitoring carbon stocks, greenhouse gas emissions, criterion air pollution, and radiative forcing of the climate, among many others. Our proposed framework will assist policymakers and the scientific community in mitigating climate change problems and in developing adaptation policies. The Author(s) 2024. -
A Fusion Based Approach for Blood Vessel Segmentation from Fundus Images by Separating Brighter Optic Disc
Abstract: In ophthalmology, blood vessel segmentation from fundus images plays a significant role in automated retinal disease screening systems. Several research papers on blood vessel segmentation suggest enhancing fundus images before segmentation significantly to improve performance. The brightness of the optic disc region in a fundus image negatively influences the enhancement of relatively darker vessel pixels. Segregation of brighter optic disc from fundus images before its enhancement is the fundamental idea behind developing the proposed framework. Initially, the optic disc is extracted from the input fundus image to form two images, one containing optical disc and the other, fundus image without optical disk. In the second stage, both the images are enhanced independently, followed by blood vessel segmentation. Finally, the segmented blood vessels from the images are fused to obtain a single image. Experiments conducted with fundus images from DRIVE, STARE, and CHASE_DB1 databases show improvement in the identification of blood vessel pixels. 2021, Pleiades Publishing, Ltd. -
A fuzzy approach to project team selection
Project team selection is a complex process in software engineering. The study uses a multiple criteria decision making (MCDM) approach for the selection of a project team under fuzzy environment. In this paper a FRI, FSS approaches are developed to the selection of project team. 2019, International Journal of Scientific and Technology Research. All rights reserved. -
A generalized software reliability prediction model for module based software incorporating testing effort with cost model
As software innovation has advanced, it has been noted that the testing effort function (TEF) is one of the key factors influencing the improvement of software reliability. This paper presents a simplified model which incorporates the testing effort for the reliability growth of a software. A closed form solution has been derived for the reliability of the software. This study examines the impact of testing efforts on a software reliability model based on NHPP. The sensitivity analysis has been made available to investigate how the created model's system parameters affect the cost function, mean value function, and softwares reliability. The parameters of the model have been estimated using the non-linear least square estimation (MLE) method in MATLAB software. Additionally, a warranty cost model is constructed to assess the optimal release policy for the software. The general form of the reliability expression involves elliptic integrals, which can be computed easily through a software like Mathematica. We have derived analytical solutions for reliability pertaining to several particular cases. Optimal release time for the software product has been calculated for some particular cost-sets. Goodness of fit curves have been plotted to compare the proposed model with some well-known existing SRGMs. Numerical illustrations are provided to bolster the analytical outcomes. The Author(s), under exclusive licence to Society for Reliability and Safety (SRESA) 2024. -
A generic cyber immune framework for anomaly detection using artificial immune systems
Intrusion detection systems play a significant role in computer security. Artificial immune systems are the prime contender in developing an anomaly-based intrusion detection system due to their simplicity. The fundamental goal of this paper is to create a generic framework for an artificial immune system which is fast and accurate in detecting anomalies using artificial immune system concepts. Natural killer cells in the immune system and their quick response to foreign pathogens inspired the adaptation of those cells into an artificial immune system based framework. A natural killer cell-based framework is proposed to improve the accuracy and speed of anomaly detection. The structure of the proposed framework includes major histocompatibility complex class 1 representation, affinity calculation, cell generation, and cell proliferation. This framework addresses the overlapping and hole problem while creating natural killer cells to increase the system's performance. The negative selection algorithm and the positive selection algorithm generate the cells that enhance the anomaly detection technique and give high precision. The parameter response time introduced in this paper is crucial for an intrusion system to be used in real-time. 2022 Elsevier B.V. -
A genome wide association study of fast beta EEG in families of European ancestry
Background Differences in fast beta (2028Hz) electroencephalogram (EEG) oscillatory activity distinguish some individuals with psychiatric and substance use disorders, suggesting that it may be a useful endophenotype for studying the genetics of disorders characterized by neural hyper-excitability. Despite the high heritability estimates provided by twin and family studies, there have been relatively few genetic studies of beta EEG, and to date only one genetic association finding has replicated (i.e., GABRA2). Method In a sample of 1564 individuals from 117 families of European Ancestry (EA) drawn from the Collaborative Study on the Genetics of Alcoholism (COGA), we performed a Genome-Wide Association Study (GWAS) on resting-state fronto-central fast beta EEG power, adjusting regression models for family relatedness, age, sex, and ancestry. To further characterize genetic findings, we examined the functional and behavioral significance of GWAS findings. Results Three intronic variants located within DSE (dermatan sulfate epimerase) on 6q22 were associated with fast beta EEG at a genome wide significant level (p<5נ10?8). The most significant SNP was rs2252790 (p<2.6נ10?8; MAF=0.36; ?=0.135). rs2252790 is an eQTL for ROS1 expressed most robustly in the temporal cortex (p=1.2נ10?6) and for DSE/TSPYL4 expressed most robustly in the hippocampus (p=7.3נ10?4; ?=0.29). Previous studies have indicated that DSE is involved in a network of genes integral to membrane organization; gene-based tests indicated that several variants within this network (i.e., DSE, ZEB2, RND3, MCTP1, and CTBP2) were also associated with beta EEG (empirical p<0.05), and of these genes, ZEB2 and CTBP2 were associated with DSM-V Alcohol Use Disorder (AUD; empirical p<0.05). Discussion In this sample of EA families enriched for AUDs, fast beta EEG is associated with variants within DSE on 6q22; the most significant SNP influences the mRNA expression of DSE and ROS1 in hippocampus and temporal cortex, brain regions important for beta EEG activity. Gene-based tests suggest evidence of association with related genes, ZEB2, RND3, MCTP1, CTBP2, and beta EEG. Converging data from GWAS, gene expression, and gene-networks presented in this study provide support for the role of genetic variants within DSE and related genes in neural hyperexcitability, and has highlighted two potential candidate genes for AUD and/or related neurological conditions: ZEB2 and CTBP2. However, results must be replicated in large, independent samples. 2016 Elsevier B.V. -
A global perspective on psychologists' and their organizations' response to a world crisis; [Una perspectiva global sobre la respuesta de los psicogos y sus organizaciones a una crisis mundial]
Around the world, individual psychologists have stepped up to deliver essential services to address the social and emotional sequelae of the COVID-19 pandemic. Many psychological organizations have also responded to this public health crisis, though their efforts may be less widely recognized. Psychological organizations engaged in preventive and mitigation efforts targeted, among others, the general public, local communities, and high-risk groups such as health care providers. They disseminated mental health information to the general public, trained laypersons to provide psychological first aid, and used research to design and evaluate public health responses to the pandemic. In some countries, psychological organizations contributed to the design and implementation of public health policies and practices. The nature of these involvements changed throughout the pandemic and evolved from reactive to proactive, from local to international. Several qualities appear key to the value, impact, and success of these efforts. These include organizational agility and adaptability, the ability to overcome their political inertia and manage conflict, recognizing the need to address cultural differences, and allocating limited resources to high-risk and resource-depleted constituencies where it was needed most. 2021, Sociedad Interamericana de Psicologia. All rights reserved. -
A happy mother raises a happy child: insights from employed mothers in Bengali families in Kolkata
The present study explores the complexities of motherhood in Bengali middle-class families, where mothers are traditionally viewed as primary caregivers. Despite societal shifts and increased female workforce participation, mothers still face pressure to prioritize intensive mothering. Through qualitative analysis, the research explores how employed mothers balance work and childcare responsibilities, shedding light on their agency and empowerment within patriarchal structures. Findings reveal a nuanced landscape where mothers navigate societal expectations while striving for autonomy. Support systems, changing socio-economic dynamics, and technological advancements contribute to reshaping maternal roles. Mothers, though not uniformly identifying as feminists, challenge traditional norms, embracing an egalitarian approach to mothering. The study underscores the resilience of mothers in negotiating patriarchal constraints, highlighting their capacity to foster empowerment for themselves and their children within familial and societal contexts. This qualitative study conducted in-depth interviews with 37 employed mothers representing diverse professions and roles. 2025 Informa UK Limited, trading as Taylor & Francis Group. -
A high-efficiency poly-input boost DCDC converter for energy storage and electric vehicle applications
This research paper introduces an avant-garde poly-input DCDC converter (PIDC) meticulously engineered for cutting-edge energy storage and electric vehicle (EV) applications. The pioneering converter synergizes two primary power sourcessolar energy and fuel cellswith an auxiliary backup source, an energy storage device battery (ESDB). The PIDC showcases a remarkable enhancement in conversion efficiency, achieving up to 96% compared to the conventional 8590% efficiency of traditional converters. This substantial improvement is attained through an advanced control strategy, rigorously validated via MATLAB/Simulink simulations and real-time experimentation on a 100 W test bench model. Simulation results reveal that the PIDC sustains stable operation and superior efficiency across diverse load conditions, with a peak efficiency of 96% when the ESDB is disengaged and an efficiency spectrum of 9195% during battery charging and discharging phases. Additionally, the integration of solar power curtails dependence on fuel cells by up to 40%, thereby augmenting overall system efficiency and sustainability. The PIDCs adaptability and enhanced performance render it highly suitable for a wide array of applications, including poly-input DCDC conversion, energy storage management, and EV power systems. This innovative paradigm in power conversion and management is poised to significantly elevate the efficiency and reliability of energy storage and utilization in contemporary electric vehicles and renewable energy infrastructures. The Author(s) 2024. -
A homotopy-based computational scheme for two-dimensional fractional cable equation
In this paper, we examine the time-dependent two-dimensional cable equation of fractional order in terms of the Caputo fractional derivative. This cable equation plays a vital role in diverse areas of electrophysiology and modeling neuronal dynamics. This paper conveys a precise semi-analytical method called the q-homotopy analysis transform method to solve the fractional cable equation. The proposed method is based on the conjunction of the q-homotopy analysis method and Laplace transform. We explained the uniqueness of the solution produced by the suggested method with the help of Banach's fixed-point theory. The results obtained through the considered method are in the form of a series solution, and they converge rapidly. The obtained outcomes were in good agreement with the exact solution and are discussed through the 3D plots and graphs that express the physical representation of the considered equation. It shows that the proposed technique used here is reliable, well-organized and effective in analyzing the considered non-homogeneous fractional differential equations arising in various branches of science and engineering. 2024 World Scientific Publishing Company. -
A Hybrid AES with a Chaotic Map-Based Biometric Authentication Framework for IoT and Industry 4.0
The Internet of Things (IoT) is being applied in multiple domains, including smart homes and energy management. This work aims to tighten security in IoTs using fingerprint authentications and avoid unauthorized access to systems for safeguarding user privacy. Captured fingerprints can jeopardize the security and privacy of personal information. To solve privacy- and security-related problems in IoT-based environments, Biometric Authentication Frameworks (BAFs) are proposed to enable authentications in IoTs coupled with fingerprint authentications on edge consumer devices and to ensure biometric security in transmissions and databases. The Honeywell Advanced Encryption Security-Cryptography Measure (HAES-CM) scheme combined with Hybrid Advanced Encryption Standards with Chaotic Map Encryptions is proposed. BAFs enable private and secure communications between Industry 4.0s edge devices and IoT. This works suggested schemes evaluations with other encryption methods reveal that the suggested HAES-CM encryption strategy outperforms others in terms of processing speeds. 2023 by the authors.