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Surface tempering of poly-(3 thiophene acetic acid) coated carbon fiber paper electrode with spine-like cobalt inorganic phosphate: An efficacious electrochemical metol sensor /
Surfaces and Interfaces, Vol.35, ISSN No: 2468-0230.
N-methyl-p-aminophenol sulfate (metol) is a photographic developing agent that has a toxic effect on humans and aquatic life. A cost-effective and sensitive electrochemical sensor was developed by electrodepositing Co-Pi over poly-(3 thiophene acetic acid) coated carbon fiber paper electrode (Co-Pi/PTAA/CFP) for the determination of metol (ML). Surface modification of Co-Pi facilitates superior electrocatalytic performance by offering more active sites and faster electron transport kinetics. The Physico-chemical characterization of the fabricated electrode was carried out by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) Field emission scanning electron microscopy (FESEM) with energy-dispersive X-ray spectroscopy (EDS), Optical profilometer, Fourier transform infrared spectroscopy (FTIR), and electroanalytical techniques. -
A road map on nanostructured surface tuning strategies of carbon fiber paper electrode: Enhanced electrocatalytic applications /
Journal of Science: Advanced Materials and Devices, Vol.7, Issue 3, ISSN No: 2468-2179.
Impressive characteristics of carbon fiber paper (CFP) electrodes propound greater demand in electrochemical applications. CFP has a network structure composed of interwoven carbon fibers (CFs). The macroporous structure, chemical inertness, high conductivity, low cost, corrosion resistance, good electrical properties, mechanical strength, and self-standing capabilities have led to the large-scale acceptance of CFP. This review appraises the current progress of CFP based electrodes for electrocatalytic applications in the field of electrochemical sensors, electrochemical capacitors, batteries, electro Fenton oxidation, electrooxidation of alcohols, water splitting, hydrogen evolution reaction (HER), and oxygen evolution reaction (OER) together with the different fabrication strategies on the CFP substrate in an organized manner. -
Lora-WAN Powered by Renewable Energy, and Its Operation with Siri / Google Assistant
LoRa WAN is a newly emerged game changing communication technology for sending small data packets of size 50 bytes or less, wirelessly over an area of up to 10 Km without the need of an internet connection. LoRa WAN has its own frequency band and the band is different for every country. This technology is now starring to boost WSN technology better than ever before. This paper aims to, power up a LoRa Enabled Device or a LoRa Gateway by using a reliable dual mode non-conventional energy resource for storage and utilization, find peak performances altering the data rate that can be achieved in a LoRa WAN Communication (using Indoor RAK Gateway), make use data compression techniques, data packet encoding/decoding, Coding Apple Shortcuts, setting up Siri and Google Assistant for voice control and future scope. 2020, Asian Research Association. All rights reserved. -
Efficient hydrogen evolution reaction performance of Ni substituted WS2 nanoflakes
We have investigated the structural, optical and electrocatalytic hydrogen evolution reaction (HER) performance of pristine, Co and Ni substituted WS2 nanoflakes synthesised by facile hydrothermal method. The XRD pattern confirms the formation of hexagonal WS2 for both pristine and substituted WS2 nanoflakes. The FESEM images validate the flake-like structure for both pristine and substituted WS2. In addition, we have also analysed the Raman and UV-Vis absorbance spectra of the samples. The electrocatalytic studies reveal that the nickel-substituted WS2 (Ni-WS2) nanoflakes show superior hydrogen evolution (HER) performance compared to cobalt-substituted WS2 (Co-WS2) nanoflakes. Hence, we have varied the Ni concentration and investigated the dependence of Ni content on the electrocatalytic performance. It is found that the electrocatalytic performance of the Ni-WS2 nanoflakes increases with an increase in Ni content owing to the modified edge structures. Thus, our studies suggest Ni substitution in WS2 nanostructures can boost electrocatalytic HER performance. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024. -
EDGE INCIDENT 2-EDGE COLORING SUM OF GRAPHS
The edge incident 2-edge coloring number, ?ein2(G), of a graph G is the highest coloring number used in an edge coloring of a graph G such that the edges incident to an edge e = uv in G is colored with at most two distinct colors. The edge incident 2-edge coloring sum of a graph G, denoted as (Formula presented.), is the greatest sum among all the edge incident 2-edge coloring of graph G which receives maximum ?ein2(G) colors. The main objective of this paper is to study the edge incident 2-edge coloring sum of graphs and find the exact values of this parameter for some known graphs. I??k University, Department of Mathematics, 2025; all rights reserved. -
Edge incident 2-edge coloring of graphs
The edge incident 2-edge coloring of a graph G is an edge coloring of the graph G such that not more than two colors are assigned to the edges incident to an edge e = uv in G. In other words, for every edge e in G, the edge e and all the edges that are incident to the edge e is in at most two different color classes. The edge incident 2-edge coloring number ?n2(G) is the maximum number of colors in any edge incident 2-edge coloring of G. The main objective of this paper is to study the edge incident 2-edge coloring concept and apply the same to some graph classes. Besides finding the exact values of these parameters, we also obtain some bounds. World Scientific Publishing Company. -
Vertex neighborhood restricted edge achromatic sums of graphs
The vertex induced 2-edge coloring number ?vi2?(G) of a graph G is the highest number of colors that can occur in an edge coloring of a graph G such that not more than two colors can be used to color the edges in the induced subgraph (N[v]) generated by the closed neighborhood N[v] of a vertex v in V (G). The vertex induced 2-edge coloring sum of a graph G denoted as vi2?(G), is the greatest sum among all the vertex induced 2-edge coloring of a graph G which concedes ?vi2?(G) colors. The vertex incident 2-edge coloring number of a graph G is the highest number of colors required to color the edges of a graph G such that not more than two colors can be ceded to the edges incident at the vertex v of G. The vertex incident 2-edge coloring sum of a graph G denoted as vi2?(G), is the maximum sum among all the vertex incident 2-edge coloring of graph G which receives maximum ?vin2?(G) colors. In this paper, we initiate a study on the vertex induced 2-edge coloring sum and vertex incident 2-edge coloring sum concepts and apply the same to some graph classes. Besides finding the exact values of these parameters, we also obtain some bounds and a few comparative results. 2023 World Scientific Publishing Company. -
VERTEX INDUCED k-EDGE COLORING AND VERTEX INCIDENT k-EDGE COLORING OF GRAPHS
Let k ? 2 be a natural number. Then the vertex induced k-edge coloring number ? vik(G) of a simple connected graph G = (V,E) is the highest number of colors needed to color the edges of a graph G such that the edges of the subgraph induced by the closed neighborhood N[v] of the vertex v ? V (G) receives not more than k colors. The vertex incident k-edge coloring number ? vink(G) of a simple connected graph G = (V,E) is the highest number of colors required to color the edges of a graph G such that the edges incident to a vertex v in graph G receives not more than k colors. In this paper, we initiate the study on ? vik(G) and ? vink(G). We also determine the exact values of ? vik(G) and ? vink(G) for k = 2 for some special graphs. 2023 Yarmouk University. All rights reserved. -
VERTEX INDUCED 2-EDGE COLORING AND VERTEX INCIDENT 2-EDGE COLORING OF SOME GRAPH PRODUCTS
Let G = (V, E) be a simple connected graph with vertex set V and edge set E. The vertex induced 2-edge coloring number ?vi2? (G) is the maximum number of colors used in coloring the edges of a graph G such that for each vertex v ? V, at most two edges in the induced subgraph ?N[v]?, generated by the closed neighborhood N[v], receive different colors. The vertex incident 2-edge coloring number ?vin2? (G) of graph G is the maximum number of colors required to color the edges of G such that at most two edges incident to a vertex v in G receive different colors. In this paper, the vertex induced 2-edge coloring number and vertex incident 2-edge coloring number of some graph products such as Cartesian product and strong product are discussed. The ?vi2?(G) and??vin2(G) number in the rooted product of a general connected graphs with some graph classes are also discussed in this paper. Palestine Polytechnic University-PPU 2022. -
Influence of pulse reverse current parameters on electrodeposition of copper-graphene nanocomposite coating
This work focuses on the influence of pulse reverse current parameters such as duty cycle and frequency on the microstructure and properties of graphene reinforced copper nanocomposite (Cu-Gr) coating. Graphene nanosheets were prepared by a liquid phase exfoliation technique and characterized using FE-SEM and Raman spectroscopy. Cu-Gr nanocomposite coating on stainless steel was prepared by pulse reverse electrodeposition method. The influence of pulse reverse current parameters such as duty cycle and frequency on the coating structure and texture was analyzed. By reducing the duty cycle and increasing frequency, a high amount of graphene co-deposition was achieved. A duty cycle of 40%, frequency of 1000 Hz and stirring speed of 500 rpm produced Cu-Gr coatings with maximum graphene codeposition. XRD analysis showed that the change in duty cycle and pulse frequency influenced the crystal structure, preferred orientation, and crystallite size of the deposit. A high pulse frequency improved the compactness of the composite coating, while longer pulse off-time and application of reverse pulse resulted in highly oriented (220) texture of pure Cu and Cu-Gr nanocomposite coatings. Due to graphene co-deposition, the copper grains became more refined, and hence the microhardness of the composite coating showed a tremendous increase compared to pure Cu coating. The Tafel polarization and electrochemical impedance studies revealed that pulse reverse electrodeposited Cu-Gr coating has higher corrosion resistance than pure Cu coating due to strong (220) texture and barrier effect of graphene. 2021 The Authors -
Basic human values of Indian management professionals: a demographic profile
This study tries to check the degree of basic human values among management professionals in India with considerable cultural and linguistic differences and how it varies across the different demographic influences. We have checked the impact of demographic variables like gender, age, education, type of organisation, place of residence, and work experience on basic human values. Hypotheses testing were conducted using MANOVA. It was inferred that the perception regarding the degree of basic human values differs among different management professionals based on their age, gender, education, type of organisation, and place of residence. Surprisingly, the work experience of the person does not have a significant influence on basic human values. Consequently, we imply that the demographics of an individual carve their basic human values. The findings and inferences of the proposed study will be of great importance to policymakers and recruiting managers to fetch the right candidate. Copyright 2023 Inderscience Enterprises Ltd. -
Suicidal behavior prediction using data mining techniques
Background: Suicide is one of the most serious public health problem that has affected many people. After being recognized as a public health priority by the WHO (World Health Organization) various studies have been going out for its prevention. It is one of a serious health problem and it is preventable and can be controlled by proper interventions and study in the field. The objective of the study is to create a prediction model for individuals who are at higher risk of suicide by studying the different predictors of suicide such as depression, anxiety, hopelessness, stress etc. by using data mining techniques for the prediction. Study Design: Systematic review and predictive analysis for suicidal behavior. Methods: The research applies data mining process to analyze the data and on the basis of analysis create the model to predict suicidal behaviors present in the individual. Prediction is done on the basis of analysis of risk factors which are Depression, anxiety, hopelessness, stress, or substance misuse which is calculated by using various psychological measures such as Beck hopelessness scale,suicidal ideation subscale,hospital anxiety and depression scale.Various data mining algorithms for classification are compared for the purpose of prediction. Results: Six different data mining classification algorithms which are namely Classification Via Regression, Logistic Regression. Random Forest, Decision Table, SMO are compared and Classification Via Regression was found to the highest accuracy in prediction. Conclusions: Data required for the development of such a model requires continuous monitoring and needs to be updated on a periodic basis to increase the accuracy of prediction. IAEME Publication. -
Gender Issues and Related Social Stigma Affecting Patients with a Disorder of Sex Development in India
Children with disorders of sex development (DSD) manifest at birth with malformed genitalia or later with atypical pubertal development. Those born with malformed genitalia are often diagnosed at birth. However, in resource-poor countries like India, where not all births are supervised by healthcare workers, some of these children remain undiagnosed until puberty or even later. The aim of this study was to assess the gender issues and psychosocial problems of children with DSD. Participants included 205 children with DSD (103 with 46,XX DSD and 102 with 46,XY DSD). Both the children with DSD and their parents underwent semistructured interviews by a clinical psychologist. The birth of a child with DSD was perceived as a major medical and social problem by parents from all socioeconomic strata. Mothers were distressed as many believed the DSD condition was transmitted through the mother. Children who were not diagnosed and treated during infancy or early childhood experienced considerable social discrimination not only from relatives and friends but also from medical and paramedical staff in hospitals. Several patients had been operated during infancy without an etiological diagnosis and without provision of adequate information to the parents. Some children had problems related to complications of surgery. Most teenage patients with 5?-reductase-2 deficiency reared as females presented with gender dysphoria, while children with androgen insensitivity (except for one) or with gonadal dysgenesis developed a gender identity concordant with their gender of rearing. Parents of children with DSD preferred a male gender assignment for their children (if that was possible) because of the social advantages of growing up male in a patriarchal society. 2016, Springer Science+Business Media New York. -
The Cartesian product of wheel graph and path graph is antimagic
Suppose each edge of a simple connected undirected graph is given a unique number from the numbers 1, 2, . . ., q, where q is the number of edges of that graph. Then each vertex is labelled with sum of the labels of the edges incident to it. If no two vertices have the same label, then the graph is called an antimagic graph. We prove that the Cartesian product of wheel graph and path graph is antimagic. 2023 Azarbaijan Shahid Madani University. -
The times of jeopardising free speech
Press freedom is at stake in India, which holds a dismal rank of 159 among 180 countries in the Press Freedom Index 2024. While dissent and democracy ideally go hand in hand, a glance at the present situation in India suggests that these terms are perceived as antonyms in practice. The state is exerting its repressive power over dissenters, particularly targeting media outlets that do not align with the states interests. The media has a great responsibility and obligation to the citizens to bring out real stories with diligence and truthfulness. In India, the depiction of socioeconomic and political realities is mostly done at utmost risk and with an air of uneasiness. The truth remains elusive to the majority of the public, as they receive information from a restrained source constantly under government surveillance. This article aims to analyse the current situation of media and democracy in India with reference to freedom of speech and expression. The writing is an outcome of analysing the past and present sociopolitical contexts in India concerning the concept of free speech. The Author(s) 2024. -
Student-managed investment funds (SMIFs) in India: the perspectives of student fund managers
Purpose: This paper aims to explore how the student fund managers perceive the benefits of being part of the fund. Furthermore, this paper examines the country-specific challenges of setting up and managing a student-managed investment fund (SMIF) in India. Design/methodology/approach: Qualitative content analysis technique is used to identify, compare and retrieve critical themes about the present state of SMIF clubs in India. The data collection method involved structured, in-depth online interviews with ten student fund managers from various higher educational institutions in India. Findings: Some of the studys key findings indicate that the existence of SMIFs as part of learning facilitates group decision-making and peer learning. Additionally, this study brings to light specific issues related to registration, incorporating real-world practices and integrating SMIF into the academic curriculum. Social implications: The outcomes of this study shall be of use to students and the teaching fraternity across Indian colleges and universities who aspire to set up SMIFs as part of experiential learning. This study will also help existing SMIF clubs in India understand how their counterparts work and can consequently improvise their organizational structure and functioning. Originality/value: To the best of the authors knowledge, this is the first interview-based evaluation of the present structure of SMIFs structured as clubs in India. 2022, Emerald Publishing Limited. -
The unseen dilemma of AI in mental healthcare
[No abstract available] -
Efficient discrimination by MIRU-VNTRs of Mycobacterium tuberculosis clinical isolates belonging to the predominant SIT11/EAI3-IND ancestral genotypic lineage in Kerala, India
The present study evaluated the ability of MIRU-VNTRs to discriminate Mycobacterium tuberculosis (MTB) clinical isolates belonging to the SIT11/EAI3-IND ancestral genotypic lineage, which is highly prevalent in Kerala, India. Starting from 168 MTB clinical isolates, spoligotyping (discriminatory index of 0.9113) differentiated the strains into 68 distinct patterns, the biggest cluster being SIT11/48 SIT11 ( n= 48). The present study shows that 12-loci MIRUs and 3 ETRs allowed an efficient discrimination of these isolates (discriminatory indexes of 0.7819 and 0.5523, respectively). 2013 Asian-African Society for Mycobacteriology.