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New Horizons in the Synthesis, Properties, and Applications of MXene Quantum Dots
The progress of MXenes, a 2D layered structural material since its discovery in 2011 recently arouses a great deal of attention due to their plethora of applications in a diverse range of fields. Their excellent properties in terms of surface chemistry, optical activity, electrical conductivity, presence of abundant active catalytic sites, tunable band gap structure, ease of surface functionalization, and good biocompatibility make them an ideal candidate. The authors aim to guide the readers through various aspects such as their unique properties, synthesis techniques, and the recent advancements associated with MXene quantum dots (QDs). Herein, this review serves as a one-stop point for prospective researchers to gain a better understanding of the application of MXene QDs in various fields including electrochemical detection, biomedical applications, and energy conversion and storage applications. 2023 The Authors. Advanced Materials Interfaces published by Wiley-VCH GmbH. -
A facile, green synthesis of carbon quantum dots from Polyalthia longifolia and its application for the selective detection of cadmium
Carbon quantum dots (CQDs) has received world-wide recognition for their outstanding physicochemical properties that have the ability to substitute the semiconductor quantum dots. Herein, we have developed a strategy to determine the presence of Cd2+ using CQDs as a fluorescence probe. The CQDs were synthesized from the leaves of Polyalthia longifolia (a natural source) through a one-step hydrothermal method. The CQDs obtained from Polyalthia longifolia (p-CQDs) was characterized using XRD, TEM, FTIR, Raman Spectroscopy, XPS Studies, UVVisible spectroscopy and PL Spectroscopy. The p-CQDs displayed bright red fluorescence under the UV light, with good water solubility, and appreciable photostability and a quantum yield of 22%. The p-CQDs had a quasi-spherical morphology with an average particle size of 3.33 nm. The p-CQDs showed high selectivity and sensitivity for the detection of Cd2+ with a low limit of detection of 2.4 nM and a wide linear range of 7.3 nM12 ?M. The PL intensity of the p-CQDs showed a quenching effect in presence of Cd2+ and the mechanism of quenching was validated via fluorescence lifetime decay studies. We have also studied the effectiveness of the fluorescent probe developed for Cd2+ sensing in real samples of ground water and industrial effluents. 2022 Elsevier Ltd -
Utilization of CO2 for Electrocarboxylation of Benzophenone Using MXene-Based Electrodes: A Sustainable Approach
The significant rise in atmospheric carbon dioxide (CO2) levels has prompted the need to develop efficient methods for CO2 conversion and fixation methods. Electrocarboxylation reaction is a highly efficient and sustainable method for activating and utilizing CO2, yielding essential carboxylic acids and their analogues, which are important intermediates in the pharmaceutical and fuel industries. This research demonstrates the efficiency of 2D Ti3C2Tx and Ta2CTx MXene-modified carbon fiber paper electrodes (Ti3C2Tx/CFP and Ta2CTx/CFP) for CO2 fixation with benzophenone in a tetrabutylammonium bromide/acetonitrile (TBABr/CH3CN) medium, yielding benzilic acid. Ti3C2Tx/CFP exhibited superior electrocatalytic activity with a lower reduction potential for benzophenone at ?1.0 V and achieved a 72% yield of benzilic acid at an optimum current density of 50 mA cm-2. In comparison, Ta2CTx/CFP exhibited a cathodic peak at ?1.08 V, producing a 66% yield at 70 mA cm-2. The electron paramagnetic resonance spectrum substantiates the generation of reactive radical intermediates during the reaction. Ti3C2Tx/CFP showed robust structural stability with ?88% Faradaic efficiency and a turnover frequency of 1.90444 10-5 s-1, indicating its potential for CO2 fixation. 2024 American Chemical Society. -
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Priority based prediction mechanism for ranking providers in federated cloud architecture
Cloud computing is a growing and excellent technology, as exponentially increasing the interest among users to utilize cloud applications; they need to depend on any one of the particular service provider. Now a days number of service providers also rapidly increasing in wide range, this leads ambiguity and distrust among the users. In this paper, enhanced broker based federated cloud architecture is proposed to resolve the selection of service provider issue using grading techniques and results proved that better performance improvement than single service provider selection. This broker architecture also addresses to selects the appropriate service provider automatically in the federated cloud architecture for the users submitted requests by previous experience with help of Bayesian network model. The former one implemented through concept of grade system. It is constructed for categorizing the providers based on the level of available resources. Grade and grade values distributed by applying the grade distribution algorithm for distinguishes the components. Total grade values computed for every service provider and sorted using quick sort algorithm to grade the cloud service providers. Priority based feedback decision tree technique added with this for separates similar grade cloud service provider in the selected list. Second Bayesian network model also used to rank the cloud service providers according to the previous performance of the providers with customers. Probability of satisfied customers feedback calculated for individual Service Measurements Index of Cloud Service Providers. 2018, Springer Science+Business Media, LLC, part of Springer Nature. -
Zone based relative density feature extraction algorithm for unconstrained handwritten numeral recognition
The recognition of handwritten characters and numerals has been a challenging problem among the researchers for few decades. This paper proposes a relative density feature extraction algorithm for recognizing unconstrained single connected handwritten numerals independent of the languages. The proposed method consists of four phases, namely, image enhancement (dilation), representation (zone based), feature extraction (relative density) and recognition (minimum distance classifier). The handwritten numerals must be enhanced with dilation, in order to connect the broken digits. After enhancement, the dilated binary images can be represented as a mid-point aspect ratio class interval values. There can be M * N zones and subsequently there would be 2M*N relational density exist using mid-point aspect ratio class interval values. In order to minimize the number of features, a subset of W relative densities has been extracted from the binary image since the relative density is too large to be handled efficiently. The minimum distance classifier technique has been used to recognize the given numerals. The proposed algorithm would be an alternative to recognize the handwritten numerals for recognizing unconstrained single connected handwritten numerals. The method sounds promising with a recognition rate of 92.8567%. 2005 - 2014 JATIT & LLS. All rights reserved. -
Microbial Polyhydroxyalkanoates (PHAs): A Review on Biosynthesis, Properties, Fermentation Strategies and Its Prospective Applications for Sustainable Future
Exponential increase in the use and disposal of synthetic plastics has raised an alarming concern related to their adverse effect on the environment due to their recalcitrant nature and non biodegradability. Nevertheless, the depletion in the petrochemical sources made it imperative to search for other sustainable alternatives to synthetic plastics. This triggered the attention on biodegradable plastics produced from plants, animals and microbial sources that have excellent material properties like their synthetic counterparts. Polyhydroxyalkanoates (PHAs) are ineluctably promising microbial polyesters that have the competence to supersede traditional oil-based synthetic polymers which causes major disposal issues worldwide. The compostable nature, biocompatibility, thermostability, and resilience of these bio-based polymers make them an acceptable replacement in the global market. Their versatile material properties made them a propitious candidate in packaging, biomedicine, tissue engineering, biofuel production, nanocomposite formation, and other industrial applications. Despite their potential advantages, the commercialization of PHA is hindered majorly due to the high cost associated with their production and extraction. This review work majorly focuses on the production, extraction, applications and fermentation strategies for enhancing PHA production. The review also addresses the production of PHA from extremophiles, challenges associated with PHA production and sustainable substrates for PHA production using various agroindustrial wastes. 2022, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature. -
Viologen appended Schiff base polymer and its symmetrical supercapacitor device performance
A new hyperbranched viologen containing Schiff base polymer (VSBP) is synthesized by condensing TRIPOD and VDA. The polymer is characterized using spectroscopic techniques (FT-IR & 13C NMR) and microscopic (SEM) analyses. The VSBP modified NF electrode renders an effectual electrochemical performance with maximum specific capacitance of 256 F/g at 0.5 A/g. From cyclic stability measurement, 87% capacitance retention is retained at 10 A/g and 95% achieved at 0.5 A/g after 3000 GCD cycles in a three-electrode system. Assembling of VSBP modified NF electrode as a symmetrical supercapacitor device exhibits a high energy density value of 17.02 Wh/kg with a power density of 816 W/kg and acceptable capacitance retention is achieved 90.6% at 1 A/g current density after 5000 cycles. 2023 Elsevier Ltd -
Pseudocapacitive electrode performance of zinc oxide decorated reduced graphene oxide/poly(1,8-diaminonaphthalene) composite
Development of Reduced graphene oxide/Zinc oxide/poly(1,8-diaminonaphthalene) (rGO/ZnO/PDAN) composite and its supercapacitor performance has been evaluated. Functional, crystal and morphological structures along with the thermal stability of the polymer-impregnated composite were studied using analyses such as FTIR, powder XRD, Raman, SEM and TGA techniques. The SEM images showcased the random decoration of irregularly shaped ZnO in between the wrinkled rGO sheets and the PDAN. The defective structure of the hybrid composite contributes capacitive features through electron transfer kinetics. The specific capacitance value for the rGO/ZnO/PDAN composite modified NF electrode in 3 M KOH was found to be 239 F/g at the current density of 0.5 A/g. The capacitance retained is 92 % after 5000 cycles at 5 A/g current density. A solid-state symmetrical supercapacitor device based on a novel rGO/ZnO/PDAN composite was successfully developed, which exhibits the specific capacity (40 at 0.6 A/g), energy density (12.66 Wh/kg) and power density (993 W/kg). The synergistic combination of surface-active nitrogen heteroatoms, extended conjugation and ZnO particles decorated over rGO sheets of rGO/ZnO/PDAN ternary hybrid composite displayed significant structural stability and electrochemical pseudocapacitive performances. 2023 Elsevier Ltd -
Studies on design and simulation of di-methyl ether plant of 160 TPD capacity
Energy is needed to run almost everything we see around us, from cars to the electricity power generation plants and everything else. Fossil fuels produce harmful products on combustion. One such eco-friendly alternative is Di-Methyl Ether also known as DME. In this study, a DME plant of capacity 160 tons per day was designed. Methanol dehydration process has been adapted as the process of production. The purity of DME from this plant is 99.5% by weight. Distillation column T-202 and heat exchanger E-208 were designed in detail. The detail design results showed that T-202 needed 6 stages for separation and a column diameter of 1.28m, while the simulation results showed 7 stages and column diameter as 1.285m for the same separation process. Furthermore, E-208 is of type 1-2 shell & tube heat exchanger with 307 tubes and tube length of 5.5m, however the Aspen EDR simulation results were also in close agreement with 304 tubes and 5m length for the same heat exchanger. This paper presents the results of simulation results of the simulation of these equipment's and full plant done using Aspen plus V8.8 software and Aspen EDR. 2023 Author(s). -
Experimental scrutinization on production of biogas from vegetable and animal waste
Anaerobic fermentation is a highly promising technology for converting biomass waste into methane, which may directly be used as an energy source. The objective of this research was to investigate production rate of biogas from camel dung, chicken dropping and vegetable waste. Attempts have been made in this study to optimize various parameters in order to determine the most favorable conditions for maximum biogas production from three different types of wastes such as camel dung (CAD), chicken droppings (CHD) and vegetable waste (VW). The amount of biogas produced from the wastes is compared as: VW >CHD>CAD. The results showed that biogas produced from VW is 720 ml in 32 days as compared to CHD and CAD which are 600 ml in 36 days and 80 ml in 40 days respectively. The effect of the pH and temperature on the amount of biogas produced was also studied. The experiments were conducted in temperatures ranging from 36 C to 44 C. 2023 Author(s). -
Smartbag safety guaranteed /
Patent Number: 202241013759, Applicant: Kavipriya K.
Coronary artery disease is becoming one of the most common heart diseases recently because of the unhealthy lifestyle from past few decades. The coronary artery supplies the oxygenated blood and nutrient to the heart muscle. If the artery is blocked or narrowed by the stenosis deposit on the wall of the artery it led to coronary artery disease. If the block is high it will lead to heart attack or stroke. Doctors do an Angiogram test to diagnosis the stenosis. -
A mini review on recent advancements in inclined solar still
Water shortage is a global problem, and the demand for fresh water is growing at an ever-increasing rate. The only method to meet the demand for water is via water filtration. Water purification may be done in a variety of methods, including cleaning saltwater or holding rainfall and then releasing it into the environment. There are still several kinds of solar still are available, which may be utilized to improve the amount of water that is generated. The inclined solar still (ISS) is a particularly successful option because it has a large outer water surface to supplement the normal potable water production, as well as because it has a shallow depth of water to increase the overall efficacy of the inclined solar still. Increasing the water's surface area has been the subject of much investigation. As a result of this study, an evaluation was conducted on the present state of various ISS designs in order to make advanced adjustments and research to increase the productivity of the ISS in order to meet the rising need for potable water. According to this analysis, active ISS and hybrid ISS are shown to be the most successful ISS methods. 2022 The Author(s) -
DeFi's transformative influence on the global financial landscape
The rise of decentralized finance (DeFi) has fundamentally reshaped the financial industry, challenging traditional banking systems and opening up a world of possibilities in global finance. This chapter explores the multifaceted impact of DeFi on the global economic landscape, addressing critical themes through a series of subtitles. DeFi is disrupting traditional banking models by offering alternative financial services directly on blockchain networks, such as lending, borrowing, and trading. One of the remarkable achievements of DeFi is its ability to provide financial services to previously underserved and unbanked populations. Tokenization is a crucial aspect of DeFi, enabling the representation of real-world assets as digital tokens on the blockchain. DeFi offers numerous advantages but poses security challenges, including smart contract vulnerabilities and hacks. This chapter provides an overview of the major themes and implications of DeFi's influence on finance, highlighting its opportunities and challenges. 2024, IGI Global. All rights reserved. -
Leveraging Employee Data to Optimize Overall Performance: Using Workforce Analytics
Consistent employee performance is necessary for timely achievement and business success. Many key performance indicators influence an employees organizational performance, such as employee satisfaction, employee work environment, relationship with managers and coworkers, work-life balance, and many more. It becomes critical to regularly understand how these factors are connected to employee performance. One such method that is commonly used in companies is workforce analytics. It is a process that uses data-based intelligence for improving and enhancing management decisions in hiring and constructing compensations in alignment with employee performance. This also helps the management make data-based decisions and predictions, which helps in cost reductions and increases the overall profit. This chapter aims to analyze and report the workforce-related data and visualize the performance of 1,470 employees using published IBM human resources (HR) data made available at https://s3-euw1-ap-pe-df-pch-content-public-p.s3.eu-west-1.amazonaws.com/9781003357070/bb25a486-c036-4524-ab00-446f8eda3fd1/content/www.Kaggle.com xmlns:xlink=https://www.w3.org/1999/xlink>Kaggle.com. The chapter considers the following factors - job involvement, job satisfaction, performance rating, relationship satisfaction, environmental satisfaction, employee tenure, work-life balance, and income level - for data analysis and visualization of employee performance. The chapter aims to adopt descriptive, diagnostic, and predictive analysis using various software like Python, the Konstanz Information Miner (KNIME), and Orange. The visualization will be made using Tableau, Power BI, and Google Data Studio. Thus, the chapter gives a comprehensive insight into the meaning and importance of workforce analytics, different technologies used in workforce analytics, workforce analytics trends and tools, challenges of workforce analytics, and the process of implementation of workforce analytics. 2024 selection and editorial matter, Alex Khang, Sita Rani, Rashmi Gujrati, Hayri Uygun, and Shashi Kant Gupta; individual chapters, the contributors. -
The Interplay Between Artificial Intelligence and Operations Management
Artificial intelligence incorporated into machines utilizes capacities to work and replaces people. Knowledge is the method of assembling empowered machines that can mirror human tasks as unique. With digitalization, organizations are remodifying their enterprises and making new business possibilities. Because of AI innovation, organizations change their dynamic cycles and systems and everyday tasks to accomplish the upper hand. An impressive development in the utilization of AI for activities, the board, is fully intent on observing answers for issues that are expanding in intricacy and scale. With the turn of growth and advancement of data innovation, competitiveness has become increasingly more in-depth worldwide. The AI has its own explanations behind examining and settling the sorts of issues that prompted a critical measure of exploration along with the conventional operational research discipline. Many organizations have estimated the fate of operations management. This paper lines with a descriptive research study highlighting the importance of process operations. This paper gives insights about AI technology into operations management and suggests selecting process technology and deploying AI into operations management. 2023 American Institute of Physics Inc.. All rights reserved. -
Android controlled robot with image transfer /
International Journals of Advanced Multidisciplinary Research, Vol.2, Issue 3, pp.70-74, ISSN No: 2393-8870. -
Strength and leaching characteristics of red mud (bauxite residue) as a geomaterial in synergy with fly ash and gypsum
Red mud (Bauxite residue) comprises microscopic particles and other chemical constituents that pose a major threat to the environment. The most common solution to resolve issues related to any solid waste is its reuse in construction. This paper delves into the possibility of using red mud as a geomaterial in synergy with fly ash and gypsum. In this regard upon finding the geotechnical properties of virgin red mud, it is strengthened with fly ash by replacing 10, 20, and 30% of red mud by its dry weight and to these combinations gypsum was added by 0.5% and 1% and prepared various combinations. The impact of these material additions on the characteristics of red mud were investigated using the Unconfined compressive strength and California bearing ratio values and their environmental compatibility was further studied by conducting the leaching characteristics using Toxicity Characteristics Leaching Procudure (TCLP) method. The findings of the tests indicated that fly ash and gypsum significantly enhanced the strength qualities of red mud as compared to unstabilized red mud. The stabilization helps red mud to attain a minimum strength required to use as a subgrade material. Furthermore, leaching investigations performed on stabilised samples have revealed that the vast majority of leaching heavy metals are within the WHO's authorised threshold for toxicity. 2022 -
Potential use of waste foundry sand with lateritic clayey soil in the construction of pavement sub-bases
The current study investigates the potential for use of waste foundry sand (WFS) in highway sub-base construction. Lateritic clayey soil (LCS) and waste foundry sand were combined in different proportions to examine its potential to use as construction material in sub bases. In this research, geotechnical investigation was conducted that is particle size distribution, specific gravity, Atterberg limits, OMC, density, un-soaked and soaked CBR were conducted to evaluate the properties and validity of WFS upon stabilizing with the LCS for usage in construction of sub bases. The study shows that WFS can be effectively used in highway sub-base construction upon stabilizing with the lateritic clayey soils. 2019 SERSC.