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Development of Green Synthesized Novel Carbon Dots from Ruta Graveolens L. for Fluorescent and Intracellular Sensing of Mercury Ions in Pico-molar (pm) Concentration
Green nanotechnology, which uses carbon nanomaterials for environmental remediation, is the pioneer among the prevailing approaches for the production and characterization. In the present study, highly fluorescent carbon dots (CDs) from Ruta Graveolens (ARH-CD) is developed, and its efficacy as a fluorescent sensor and biomarker is investigated. They act as a fluorescence sensor for Hg2+ over an extensive concentration range of 1 picomolar (pm) to 1 molar (m), with a detection limit as low as 26.75 pm. The studies reveal ARH-CD as an effective biomarker for intracellular toxicity analysis and a fluorescent probe for multi-colored (blue, green, and red) imaging of HEK293 cell lines. After 24 h of incubation, it is found that the ARH material reveals noticeable biocompatibility and visible fluorescence, with a viability of 98.88% at 5 gmL?1 and over 78.33% even at a concentration of 100 gmL?1. The IC50 value for the MTT assay for cell viability results is calculated to be 224.56 4.67 g, which further confirms the appreciable biocompatibility of the ARH-CD. The obtained samples are effective in being inspected for the intracellular detection of Hg2+ and serve as a possible candidate for cell imaging. 2024 Wiley-VCH GmbH. -
Conflict and Coexistence of Human Rights: An Exploratory Study with Reference to Intellectual Property Rights
Human rights and Intellectual Property Rights (IPRs) have developed independently. Human rights are inalienable rights associated with human dignity while IPRs are the rights with the goal of promoting innovations and the interests of select communities to further economic and technological growth. The economic and personal interests of the individual have received prime attention under the international intellectual property law. Economic growth is given priority over human rights in the international criteria for IPRs in global trade. Whereas, it has a significant impact on the implementation of human rights for both individuals and communities, including the rights to adequate food, health, environment, and education. IPRs are gravely at odds with human rights, even though a connection between the two rights can be found in General Comment No. 17 on Article 15(1)(c) of the International Covenant on Economic, Social, and Cultural Rights (ICESCR) and Article 27 of the Universal Declaration of Human Rights (UDHR). According to the UDHR, intellectual property is a human right in and of itself, but its enforcement often infringes other human rights. In light of the above perspective, the authors explore the interrelationship between IPRs and human rights and also analyze the evolving IPRs, in different fields of its application, causing adversarial impacts on several other human rights. The Author(s), under exclusive licence to Springer Nature Switzerland AG 2025. -
Investor's behaviour to COVID-19 vaccination campaign; An event study and panel data analysis in the southeast asian region
This study examines how the COVID-19 immunization campaign has influenced the stock market responses in the WHO Southeast Asian Region. The effects of the immunization campaign on the WHO Southeast Asian countries were different, and the study used event study techniques and panel-data regression models to investigate the impact of the WHO South-East Asian capital market. Some countries like India, Sri Lanka, and South Korea had positive markets that responded to the news, while others did not. The findings of this study suggest that investors make fair assessments and respond to events and announcements, but they tend to have a more visible reaction to negative incidents than to positive news/events. However, after 51 days, the WHO South East region as a whole had internalized the encouraging news. The study has a few limitations, such as a small dataset and period, only a few variables and models, and so on. Future studies could include a few additional countries and periods to produce more significant results. Originality/value- This study contributes to the existing knowledge about the impact of drugs and vaccinations on stock markets. It is the first study to investigate how the WHO Southeast Asian Region's COVID-19 immunization program affects the stock market reaction. The study used keywords such as Immunization campaign, abnormal returns, Cumulative average abnormal returns, Event Study, and WHO Southeast Asian Region. 2025 Universidad Nacional Autonoma de Mexico. All rights reserved. -
A happy mother raises a happy child: insights from employed mothers in Bengali families in Kolkata
The present study explores the complexities of motherhood in Bengali middle-class families, where mothers are traditionally viewed as primary caregivers. Despite societal shifts and increased female workforce participation, mothers still face pressure to prioritize intensive mothering. Through qualitative analysis, the research explores how employed mothers balance work and childcare responsibilities, shedding light on their agency and empowerment within patriarchal structures. Findings reveal a nuanced landscape where mothers navigate societal expectations while striving for autonomy. Support systems, changing socio-economic dynamics, and technological advancements contribute to reshaping maternal roles. Mothers, though not uniformly identifying as feminists, challenge traditional norms, embracing an egalitarian approach to mothering. The study underscores the resilience of mothers in negotiating patriarchal constraints, highlighting their capacity to foster empowerment for themselves and their children within familial and societal contexts. This qualitative study conducted in-depth interviews with 37 employed mothers representing diverse professions and roles. 2025 Informa UK Limited, trading as Taylor & Francis Group. -
Liquid gold: assessing groundwater quality at the historic Kolar gold fields, Karnataka, India
To assess ecological sustainability and resilience, it is necessary to periodically examine various ecological properties in areas with high pollution and contaminant risks. Kolar Gold Fields (KGF) in Kolar, Karnataka, showcases one of India's most contaminated zones because of the extensive gold mining and its lingering effects. In KGF, the quality of groundwater has been severely reduced as there exist extensive mining tailings, locally referred to as cyanide dumps, which have been neglected for several preceding years without proper disposal strategies. The current approach focuses on the water pollution caused by heavy metal deposits in the KGF region. Groundwater samples were sampled from Oorgam, an abandoned region in KGF, and subsequently filtered for water quality examinations. The investigation documented concentrations of several metals, including cadmium (0.068 0.0024 ppm), lead (0.288 0.0016 ppm), nickel (0.058 0.0047 ppm), and chromium (0.23 0.0235 ppm) and have met the standard specifications in accordance with World Health Organization (WHO). Prominent pH disparity was documented amongst the experimental samples, with a detectable pH drop in the aqua-purified water in comparison to the positive control. The test results imply that the water samples collected from KGF remain unpotable for consumption or irrigation due to the persistence of high levels of heavy metal concentration. This study underscores the urgent requirement for a remedial approach to ensure water safety for drinking and irrigation in the area. 2025 Brawijaya University. All rights reserved. -
Deterministic, Stochastic, and Deep Learning Approaches to Understand the Economic Fluctuations in India
In the present work, a new mathematical framework is proposed for studying the interrelation among population growth rate, GDP, inflation rate, and unemployment rate within deterministic and stochastic frameworks. The values of the parameters of the proposed model are estimated using real data from India. The local and global uniqueness of solutions is established for the stochastic model. The deterministic model is solved by using the Adams-Bashforth-Moulton predictor-corrector method, and Milstein's method is used for solving the stochastic model. Numerical simulations correlated quite strongly with observed data, while projections for the 20242030 period indicate that controlled population growth bodes well for the outlook of the economy for India, supporting economic prosperity alongside reduced inflation and better employment conditions. The findings presented in this work are correlational; therefore, to find the possible cause for this phenomenon, further research is required with detailed datasets. Comparing our model's GDP predictions with that obtained using a long short-term memory recurrent neural network model returned very high values of predictive accuracy, thus reinforcing the strength and reliability of our framework. 2025 John Wiley & Sons Ltd. -
The total upper domatic number of a graph
Let G = (V, E) be a graph with no isolated vertices. For two disjoint subsets A and B of V , if every vertex in B is adjacent to at least one vertex in A, then the set A is said to dominate set B. A partition ? = {V1, V2, . . ., Vk} of the vertex set V is a total upper domatic partition of G if Vi dominates Vj or Vj dominates Vi or both, for any Vi, Vj ? ? and G[Vi], 1 ? i ? k, has no isolated vertices. The total upper domatic number Dt(G) of G is the maximum order of a total upper domatic partition of G. In this paper, we initiate a study on the concept of total upper domatic number and determine the bounds of Dt(G) and exact values of the same for some classes of graphs. World Scientific Publishing Company. -
Nitrogen-Oxygen Co-Functionalized Waste Cassava Peel-Derived Carbon Dots for White Led
White light emitting diodes (WLEDs)are most sought after, with the broad spectra ranging from cool to warm white light being skillfully utilized to create various modes of lighting effects. The fabrication of WLEDs is generally sophisticated, involving either multiple components emitting in different regions or single-component phosphors with complex elemental compositions. In the present work, WLEDs utilizing solvent-tuned carbon dots derived from waste cassava peel are reported through a facile one-step microwave-assisted solvothermal method. The carbon dots show evident UV absorption and correspondingly emit broad visible light spectra when dispersed in a dimethylformamide (DMF)-polyvinyl alcohol (PVA)blend, making themselves suitable white lightemitting down conversion materials. The successful transformation of a 400nm UV LED into a WLED with a general colour rendering index (CRI) of 83 and colour correlation temperature (CCT) of 4426 K gives a promising future outlook toward developing eco and economic-friendly WLEDs. 2025 Wiley-VCH GmbH. -
An efficient reconfigurable band tuning filter design for channelizer in transponder satellite system
For improved performance in a variety of applications, the transponder in satellite systems must be very flexible. The channelizer-dependent transponder system significantly boosts the operation of a satellite system. When channelizing wideband input signals, a digital filter bank is typically used to extract several small sub-bands. In this research, a reconfigurable band tuning (RBT) design for the channelizer in the satellite transponder system is designed and implemented. Cosine modulation, exponential modulation and IFIR filter are the techniques behind the RBT design. The RBT design facilitates the generation of many channels enabling channelization with non-uniform narrow transition width. A number of examples are presented to illustrate how well the RBT design performs. Findings indicate that there are fewer filter coefficients in the RBT design than there are in the current approaches Effective implementation of a properly designed RBT design lowers power consumption and simplifies the hardware. 2024 The Franklin Institute -
Flow of nanofluid past a stretching cylinder subject to Thompson and Troian slip in the presence of gyrotactic microorganisms
Incorporating the Thompson and Troian slip condition, this work studies the bioconvective flow of a nanofluid past a vertically stretching cylinder. The Thompson and Troian slip deals with the molecular scale interactions at the solidfluid interface, which plays a pivotal role in the fluid flow analysis. This study helps in understanding the behaviours of fluid flow in the presence of non-linear slip past a vertically stretching cylinder. The corresponding partial differential equations (PDEs) for momentum, energy, concentration of nanoparticles, and concentration of microbes are developed using Buongiornos model. A suitable similarity transformation is then applied to these PDEs, converting them into a set of ordinary differential equations (ODEs). The RungeKuttaFehlberg (RKF-45) method is utilized to calculate the numerical solution of the resulting ODE problem. The results demonstrate that the interaction of slip conditions, viscous dissipation, heat source, and bioconvection causes complex flow patterns and heat transfer characteristics. These observations are extremely relevant for applications including better oil recovery procedures, biomedical engineering, and microfluidic devices where exact control over nanofluid behaviour is necessary. Some of the major observations of the study include the enhancement of the temperature in the nanofluid for higher Eckert numbers, control of fluid flow through an external magnetic field, and Peclet number significantly decreased the motile density in the nanofluid. The Author(s), under exclusive licence to Springer Nature Switzerland AG 2024. -
Silenced, Scarred & Shattered: Unmasking the Wounds of Child Sexual Abuse in Select American Memoirs
The research brings to light the marginalized voices of three American women who have written about their sexual abuse in their respective memoirs Roxane Gay, Hunger: A Memoir of my Body (2017), Nikki Dubose, Washed Away: From Darkness to Light (2016) and Neesha Arter Controlled: The worst Night of my Life and its Aftermath (2015). Using these memoirs as primary data and using thematic analysis the study identified three themes which were further classified into different subthemes. Firstly, the research discovered the challenges faced by the survivors in expressing and communicating about sexual abuse due to fear and shame, the survivors do not come forward because of threats, because of rape stereotypes that permeate the society and the fear of what parents and others might think. Secondly, the research explores the various impact of trauma that is caused by sexual abuse which include shame, guilt and self blame, unworthy self, uncontrollable rage, disruption of safety and trust, isolating themselves from everyone, hostility towards body, destructive behaviours which include eating disorder from Anorexia Nervosa to Binge eating disorder, it also includes self harm and substance abuse. Thirdly, the research focuses on the recovery aspect on how the survivors learn to live with the wounds caused by sexual abuse. It focuses on how the survivors came in terms with the abuse, the conflicting feelings of forgiveness and revenge and how they sought redemption through writing their journey. 2025 Sciedu Press. All rights reserved. -
Climate predictors in Indian summer monsoon forecasting: a novel De-correlated RVFL ensemble strategy
Excessive rainfall and droughts harshly impact India's social and economic growth. Though several statistical methods have been used in literature to predict Indian monsoons, uncertainties cannot be ruled out. The accuracy prediction of ISMR (Indian Summer Monsoon Rainfall) is scientifically demanding. From this perspective, it is essential to explore exploiting machine learning techniques. In this paper, a novel De-correlated Regularized Random Vector Functional Link Neural Network Ensemble (DRRNE) prediction approach was proposed using Climate Predictors such as Southern Oscillation Index (SOI), Sea Surface Temperature Anomaly (SST), El-Ni Southern Oscillation (ENSO), and Dipole Mode Index (DMI) to predict ISMR. The proposed work has also investigated the predictability of climate above predictors using the DRRNE approach to predict ISMR. In addition to the predictors above, the data for an 8-year training window time series for June to September is combined and analyzed for four predictors (ENSO, DMI, SOI, and SST) to derive another predictor, ENSO-DMI-SOI-SST (EDSS). It is found that the combination of these four predictors- the EDSS- produces better accuracy than using any of the individual predictors in this study. Among the individual predictors (ENSO, DMI, SOI, and SST), the DMI predictor has shown the best predictability for ISMR prediction. Thus, the suggestedstudy concludes that the DRRNE technique with negative correlation learning may be a suitable tool for predicting the ISMR using the combined outcome of the four climate predictorsas mentioned above. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2025. -
Mental health professionals insights on developing and implementing a Mental Health Awareness and Destigmatisation program (MHAD) for adolescents
This study examined mental health professionals insights on developing and implementing a Mental Health Awareness and Destigmatisation (MHAD) program for adolescents aged 1418 years in Bangalore. Qualitative Interviews with 17 professionals revealed three main themes: 1. Awareness and Destigmatisation Programs: A Boon 2. Key Ingredients: Program Content and Delivery Style 3. Shaping Program Success: Key Drivers and Challenges. Professionals recommend interactive programs that promote open discussions and educate them on symptom recognition, online behavior, and healthy relationships. They identified key enablers and challenges, emphasizing the programs ability to empower adolescents, parents, and educators to create a supportive, stigma-free environment. 2024 Taylor & Francis Group, LLC. -
A taxation perspective on how domestic double taxation on corporate taxes affects Indian commerce
This paper examines the impact of domestic double taxation on corporate taxation in India after the abolition of the dividend distribution tax (DDT) and the introduction of the new tax rates and rules in 2020. Domestic double taxation occurs when the same income is taxed twice by the same jurisdiction, such as at the corporate and shareholder level. Using data from the Income Tax Department and the Reserve Bank of India, this paper estimates the effective tax rate on corporate income and dividends in India under the current tax system. It compares it with the previous tax system and the international standards. It also analyses the effect of domestic double taxation on corporate financial decisions, such as the dividend payout ratio, the retained earnings, the debt-equity ratio, and the investment rate. It evaluates the effect of domestic double taxation on corporate tax revenue, tax incidence, and tax efficiency. The authors identify that, between 2019 and 2023, corporate income tax revenue in India increased alongside nominal GDP growth, with a notable positive correlation coefficient between the two variables. The empirical analysis technique involves gathering and analyzing quantitative data to assess the real impact of new tax reforms and reduced corporate tax rates. Finally, this study proposes policy recommendations to mitigate the adverse effects of domestic double taxation and improve India's corporate taxation system and GDP. This paper contributes to the literature by providing updated and comprehensive empirical evidence on domestic double taxation and corporate taxation in India and by offering some insights and suggestions for the policymakers, the tax authorities, the corporate sector, and the academic community. 2025 Malque Publishing. All rights reserved. -
Innovative Leadership and Sustainable Development: Exploring Resource-Efficient Strategies Among Indian Managers
Global sustainability challenges demand innovative leadership approaches, particularly in resource-constrained environments where traditional models may fall short. The current study aimed to explore the need for adaptive, resource-efficient leadership by examining key traits such as empathy, inclusivity, adaptability, and intuitive decision-making that allows managers to balance immediate organizational demands with long-term sustainability goals. A Qualitative-Interpretative Phenomenological Approach was adopted. A total of 28 senior Indian managers were interviewed to understand traits aligned with stakeholder theory and the resource-based view, positioning them as strategic assets for achieving sustainable competitive advantage. Findings revealed that culturally resonant practices of frugality and resilience support social innovation and organizational resilience, contributing to broader sustainable development objectives. Further, it advances sustainable leadership literature by showcasing how resource efficiency and contextual adaptability can foster impactful, sustainable practices, particularly within emerging economies. 2024 ERP Environment and John Wiley & Sons Ltd. -
Twins in diversity: Understanding circumstellar disc evolution in the twin clusters of W5 complex
Young star-forming regions in massive environments are ideal test beds to study the influence of surroundings on the evolution of discs around low-mass stars. We explore two distant young clusters, IC 1848-East and West located in the massive W5 complex. These clusters are unique due to their similar (distance, age and extinction) yet distinct (stellar density and far-ultraviolet radiation fields) physical properties. We use deep multiband photometry in optical, near-infrared and mid-infrared wavelengths complete down to the substellar limit in at least five bands. We trace the spectral energy distribution of the sources to identify the young pre-main sequence members in the region and derive their physical parameters. The disc fraction for the East and West clusters down to 0.1?M was found to be 2 per?cent (N = 184, N = 492) and 1 per?cent (N = 173, N = 814), respectively. While no spatial variation in the disc fraction is observed, these values are lower than those in other nearby young clusters. Investigating the cause of this decrease, we find a correlation with the intense feedback from massive stars throughout the cluster area. We also identified the disc sources undergoing accretion and observed the mass accretion rates to exhibit a positive linear relationship with the stellar host mass and an inverse relationship with stellar age. Our findings suggest that the environment significantly influences the dissipation of discs in both clusters. These distant clusters, characterized by their unique attributes, can serve as templates for future studies in outer galaxy regions, offering insights into the influence of feedback mechanisms on star and planetary formation. 2024 The Author(s). Published by Oxford University Press on behalf of Royal Astronomical Society. -
A generalized software reliability prediction model for module based software incorporating testing effort with cost model
As software innovation has advanced, it has been noted that the testing effort function (TEF) is one of the key factors influencing the improvement of software reliability. This paper presents a simplified model which incorporates the testing effort for the reliability growth of a software. A closed form solution has been derived for the reliability of the software. This study examines the impact of testing efforts on a software reliability model based on NHPP. The sensitivity analysis has been made available to investigate how the created model's system parameters affect the cost function, mean value function, and softwares reliability. The parameters of the model have been estimated using the non-linear least square estimation (MLE) method in MATLAB software. Additionally, a warranty cost model is constructed to assess the optimal release policy for the software. The general form of the reliability expression involves elliptic integrals, which can be computed easily through a software like Mathematica. We have derived analytical solutions for reliability pertaining to several particular cases. Optimal release time for the software product has been calculated for some particular cost-sets. Goodness of fit curves have been plotted to compare the proposed model with some well-known existing SRGMs. Numerical illustrations are provided to bolster the analytical outcomes. The Author(s), under exclusive licence to Society for Reliability and Safety (SRESA) 2024. -
Non-inverse signed graph of a group
Let G be a group with binary operation *. The non-inverse graph (in short, i*-graph) of G, denoted by ?, is a simple graph with vertex set consisting of elements of G and two vertices x, y ? ? are adjacent if x and y are not inverses of each other. That is, x ? y if and only if x * y ?= iG ?= y*x, where iG is the identity element of G. In this paper, we extend the study of i*-graphs to signed graphs by defining i*-signed graphs. We characterize the graphs for which the i*-signed graphs and negated i*-signed graphs are balanced, sign-compatible, consistent and k-clusterable. We also obtain the frustration index of the i*-signed graph. Further, we characterize the homogeneous non-inverse signed graphs and study the properties like net-regularity and switching equivalence. Amreen J., Naduvath S., 2024. -
Telehealth Services for an Adolescent with Duchenne Muscular Dystrophy (DMD) During the COVID-19 Pandemic
The neuropalliative approach in a hospital setting for neuromuscular disorders is essentially multidisciplinary in focus and involves co-ordinated interventions. This case report describes an intensive case management approach through telehealth services provided from a hospital context in South India for psychosocial interventions for an adolescent with Duchenne Muscular Dystrophy. Case management interventions during the COVID-19 pandemic were provided through sixteen sessions over the telephone, focusing on need assessment, service plan development, implementation, co-ordination, and monitoring. Major strategies were crisis management, supportive psychotherapy, and cognitive-behavioural strategies. Adaptations made to meet the challenges of the COVID-19 pandemic using telehealth facilities can be incorporated into routine clinical practice in low-resource settings. IMPLICATIONS Telehealth, which emerged as a viable option for providing effective psychosocial care during the COVID 19 pandemic, could be adopted to complement routine clinical care in low-resource settings. 2024 Australian Association of Social Workers. -
DECODING INTENTIONS TO PURCHASE ORGANIC FOOD PRODUCTS IN AN EMERGING ECONOMY VIA ARTIFICIAL NEURAL NETWORKS
Purpose. This study investigates the factors influencing consumers intentions to purchase organic food products in an emerging economy. It addresses the knowledge gap regarding the slower growth of the organic food market in these regions despite the global trend toward environmental sustainability. Methodology / approach. A survey approach involving 350 participants was used. Structural equation modeling (SEM) with SmartPLS 4 and Artificial Neural Network (ANN) with IBM SPSS 28 were used to analyse the impact of awareness of need, personal norms, environmental concern, and health consciousness on the intention to purchase organic food products. Results. The study found significant positive influences of awareness of need, personal norms, environmental concern, and health consciousness on the intention to purchase organic food products, explaining 63.1 % of the variance. Both the analysis approaches (PLS-SEM & ANN) revealed that, health consciousness, followed by awareness of need, emerged as the most important factor related to the intention to purchase organic food products. The results highlight the importance of awareness and personal values in driving pro-environmental behaviour. Originality / scientific novelty. This research offers essential insights into the determinants of organic food purchase intentions in an emerging economy. It emphasises the significance of awareness and personal values in fostering sustainable consumption behaviour, addressing a less explored area in existing literature. Practical value / implications. The findings have important implications for policymakers and marketers. Strategies focused on consumer education about the benefits of organic food can enhance awareness and appeal. Understanding core psychological needs and beliefs that shape consumer motivations can guide the development of effective marketing strategies. The study highlights the strong environmental consciousness among consumers and their desire to protect the environment. 2024, Institute of Eastern European Research and Consulting. All rights reserved.