Browse Items (5592 total)
Sort by:
-
Star formation in a massive spiral galaxy with a radio-AGN
We present an analysis of new VLT/MUSE optical imaging spectroscopic data of 2MASX J23453268-0449256 (J2345-0449), a nearby (z = 0:0755) massive (Mstellar = 4*1011 M) spiral galaxy. This is a particularly interesting source for a study of active galactic nucleus (AGN) feedback since it hosts two pairs of bright, giant radio jets and a massive, luminous X-ray halo, but it has no massive bulge. The galaxy has a 24 kpc wide ring of molecular gas, and a source-averaged star formation rate that is factors 30 to 70 lower than expected from the Kennicutt-Schmidt law. With MUSE, we have analyzed the stellar continuum and bright optical line emission and have constrained the spatially resolved past and present star formation on scales of approximately 1 kpc. More than 93% of the stellar mass formed ?10 Gyrs ago including in the disk. Optical emission from the AGN is very faint and contributes 2% of the continuum around the nucleus at most. Most line emission is predominantly excited by shocks and old stellar populations except in 13 young star-forming regions that formed ?11 Myrs ago, of which only seven are associated with the molecular ring (the others are at larger radii). They avoid a region of high electron densities aligned with the radio source, and form stars at efficiencies that are comparable to those in normal spiral galaxies. We discuss the implications of our findings for the regulation of star formation in galaxies through AGN feedback in the absence of competing mechanisms related to the presence of a massive stellar bulge, such as morphological quenching. The Authors 2023. -
Bacillus velezensis-synthesized silver nanoparticles and its efficacy in controlling the Aedes aegypti
Abstract: Dengue fever and dengue haemorrhagic fever are diseases that do not have any potential medications. The severity of these diseases is fatal and thus poses a severe threat to mankind. Aedes aegypti is the vector that carries and spreads the dengue virus. Therefore, controlling the development and population of mosquitoes is crucial. Many insecticides and other strategies of control have not become successful in their purpose. Therefore, establishing potential compounds that are environmentally safe and productive in inhibiting the growth of mosquitoes is still to be acquired. Bacillus velezensis (MW219533) was utilized in the synthesis of silver nanoparticles with silver nitrate as the metal ion source. The silver nanoparticles were characterized and confirmed using UVvisible spectrometry that indicated a peak at 421 nm. Further analytical measurements such as X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy and energy dispersive X-ray analysis confirmed the presence of crystalline, cylindrical-shaped silver nanoparticles of size 5659 nm. The LC50 was found to be 581.39, 616.37, 760.93, 801.94 and 867.66 g l?1 when tested against the five developmental stages of Aedes aegypti, such as first instar, second instar, third instar, fourth instar stages of larvae and pupae, respectively. The predatory efficacy of Poecilia reticulata was calculated with exposure to silver nanoparticles. Our study aims on developing an environmentally safe and economical approach to reduce the development of mosquitoes in the environment. The work signifies the biological method towards controlling the larvae and pupae stages of A. aegypti as well as to mark its safety at the aquatic level of the life cycle that leaves no traces of pollution on the environment. Graphical abstract: [Figure not available: see fulltext.] 2023, Indian Academy of Sciences. -
Solvent-solute polarity, electrophilic, steric effects, reactive sites, themodynamic quantities discussion and biological evaluation of lung cancer antiproliferative activities of spirobrassinin derivatives
The current study of spirobrassinin and its related compounds, 1-methoxyspirobrassinol and the 5-bromo analogue of methoxyspirobrassinin is performed to reveal a comparison among these molecules to understand which is the most reactive and bioactive. DFT (Density Functional Theory) studies comprising geometry optimisation (energy minimisation), FMO (Frontier Molecular Orbital) Analysis, theoretical UV analysis, NLO (Non-Linear Optics), NBO (Natural Bond Orbital) and thermodynamics studies are performed using Gaussian 09W. IEFPCM model is employed to investigate the solvent effect on the reactivity and stability of the title compounds. ADME profiles are generated using SwissADME, PreADMET and ADMETLab 2.0. Interesting lung cancer target proteins are docked with the title compounds is finally performed to obtain insight into the molecules' anticancer potential. 2023 Elsevier B.V. -
Comparing Influence of Depression and Negative Affect on Decision Making
The current study aimed to explore differential value-based decision-making patterns across three groupsindividuals diagnosed with mild-to-moderate depression, a healthy matched control group, and a negative mood induction group. In the current study, drug- and therapy-nae individuals diagnosed with first episode of mild-to-moderate depression (n = 40), healthy individuals matched on age, gender, and education (n = 40), and healthy individuals with no current, past, or family history of any psychiatric conditions in a negative mood-induced state (n = 40) were administered the IOWA Gambling Task (IGT) and the Balloon Analog Risk Task (BART). Results indicated that individuals with depression showed heightened punishment sensitivity on both the IGT and the BART (p < 0.05 on the BART and p < 0.05 on the IGT), andperformed poorly on the IGT indicating poor and slow learning (p < 0.01). A similar, less severe, pattern was observed in the negative mood induction group. Individuals with mild-to-moderate depression performed poorly on tasks of value-based decision making. The significance of process factors in decision making, such as reward and punishment sensitivity, valuation of outcomes and learning, was highlighted in this study. The study also demonstrated how a negative affective state, without the other clusters of depressive symptomatology, can also lead to a less severe, but impaired decision making. 2023, The Author(s) under exclusive licence to National Academy of Psychology (NAOP) India. -
Some New Results on ?(k) -Coloring of Graphs
Let ? be the minimum number of distinct resources or equipment such as channels, transmitters, antennas and surveillance equipment required for a system's stability. These resources are placed on a system. The system is stable only if the resources of the same type are placed far away from each other or, in other words, they are not adjacent to each other. Let these distinct resources represent different colors assigned on the vertices of a graph G. Suppose the available resources, denoted by k, are less than ?. In that case, placing k resources on the vertices of G will make at least one equipment of the same type adjacent to each other, which thereby make the system unstable. In ?(k)-coloring, the adjacency between the resources of a single resource type is tolerated. The remaining resources are placed on the vertices so that no two resources of the same type are adjacent to each other. In this paper, we discuss some general results on the ?(k)-coloring and the number of bad edges obtained from the same for a graph G. Also, we determine the minimum number of bad edges obtained from ?(k)-coloring of few derived graph of graphs. The number of bad edges which result from a ?(k)-coloring of G is denoted by bk(G). 2023 World Scientific Publishing Company. -
Robust Bidirectional Long Short-Term Memory-Based Class Imbalance Handling in Dyslexia Prediction at its Early Stage
Dyslexia is a neurological condition that presents difficulties and obstacles in learning, particularly in reading. Early diagnosis of dyslexia is crucial for children, as it allows the implementation of appropriate resources and specialized software to enhance their skills. However, the evaluation process can be expensive, time-consuming, and emotionally challenging. In recent years, researchers have turned to machine learning and deep learning techniques to detect dyslexia using datasets obtained from educational and healthcare institutions. Despite the existence of several deep learning models for dyslexia prediction, the problem of handling class imbalance significantly impacts the accuracy of detection. Therefore, this study proposes a robust deep learning model based on a variant of long short-term memory (LSTM) to address this issue. The advantage of Bidirectional LSTM, which has the ability to traverse both forward and backward, improves the pattern of understanding very effectively. Still, the problem of assigning values to the hyper-parameters in BLSTM is the toughest challenge which has to be assigned in a random manner. To overcome this difficulty, the proposed model induced a behavioral model known as Red Fox Optimization algorithm (RFO). Based on the inspiration of red fox searching behavior, this proposed work utilized the local and the global search in assigning and fine-tuning the values of hyper-parameters to handle the class imbalance in dyslexia dataset. The performance evaluation is conducted using two different dyslexia datasets (i.e., dyslexia 12_14 & real-time dataset). The simulation results explore that the proposed robust Bidirectional Long Short-Term Memory accomplishes the highest detection rate with reduced error rate compared to other deep learning models. 2023, The Author(s), under exclusive licence to Springer Nature Singapore Pte Ltd. -
Theoretical Prediction of the Number of Bénard Cells in Low-Porosity Cylindrical/Rectangular Enclosures Saturated by a Fast Chemically Reacting Fluid
Many applications including chemical engineering and meteorology require the study of a chemically driven convection in cylindrical, as well as rectangular enclosures. The present paper reports a unified analysis of a chemically driven convection in densely packed porous cylindrical/rectangular enclosures saturated by a chemically reactive binary fluid mixture. Employing the degeneracy technique and the single-term Galerkin method involving Bessel functions in a linear stability analysis, an analytical expression for the critical Rayleigh number, (Formula presented.), was obtained. An analytical expression for the number of cells that manifest in a given enclosure, at the onset of convection, was derived from (Formula presented.). The connection between the stabilizing and destabilizing effects of various parameters and the size or the number of Bénard cells that manifest are described in detail. The results depicted that the chemical parameters related to the heat of reaction destabilize and the parameter depending inversely on the rate of the chemical reaction stabilizes the system. In the latter case, a greater number of smaller cells were formed in the system compared to the former case. Hence, we concluded that the chemically reactive fluid advances the onset of convection compared to the chemically non-reactive fluid. The results of a similar problem in rectangular enclosures of infinite horizontal extent and chemically non-reactive liquid-saturated porous medium were recovered as limiting cases. Thus, the present model presents a unified analysis of six individual problems. 2023 by the authors. -
Exploring Socio-Variational Patterns in Indian Adolescents Lexical Diversity: Insights for Education
Following the COVID-19 pandemic, vast data emerged regarding the plummeting literacy and readability levels among Indian adolescents, posing a challenge to address in its present condition of a vastly heterogeneous socio-demographic environment. This study is grounded in Bourdieu and Passeron's (1977) theory, which acknowledges schools as places with societal relevance that perpetuate social inequality. This implies the need to formulate robust policies to address educational inequalities. To this extent, the researchers used an exploratory design to evaluate lexical diversity by purposively sampling 100 volunteer teenagers across three schools. In addition to the data received from school officials, survey questionnaires collected socio-economic information (age, gender, area of stay, socio-economic scale [SES], and school type). The authors used the Kuppuswamy SES scale (2022) to determine socio-economic scale measures, as well as the calculation of Lexical Diversity scores through the computational open-source software TextElixir. The findings reveal that age and gender do not affect lexical diversity. However, school type, SES, and area of stay significantly affect adolescents from the lower social class, who need targeted interventions to bridge gaps of educational inequity. This study addresses the limitations of previous correlational studies by offering educational insights to ensure educational equity amidst prevalent social class inequalities. Authors. -
Effect of post annealing on DC magnetron sputtered tungsten oxide (WO3) thin films for smartwindow applications
Tungsten oxide (WO3) thin films were deposited on Fluorine Doped Tin Oxide (FTO) and Corning Glass (CG) glass substrate by DC magnetron sputtering. The annealing temperature was varied to study its effect on surface morphology, structural, electrochromic (EC), and optical properties and these are investigated by Scanning Electron Microscope (SEM), X-ray Diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), Raman spectroscopy, Cyclic voltammetry, and ultraviolet (UV) spectroscopy. From SEM analysis WO3 thin films annealed at 27 C, 100 C, 200 C, and 300 C were shown to crack free after that cracked film was observed for 400 C. From the XRD investigation that the WO3 thin films annealed at 27 C, 100 C, 200 C, and 300 C were amorphous and crystallized at 400 C. The optical band gap (Eg) of WO3 films was decreased from 2.98 eV to 2.30 eV with an increase in annealed temperature. The coloration efficiency (CE) was observed at 51.26 cm2/C at 300 C and 35.06 cm2/C at 400 C and the lowest diffusion coefficient was observed at 5.86 10?10 cm2/s at 400 C. On coloring efficiency, which can be very important in electrochromic (EC) applications, post-annealing has been seen to have a strong influence. 2023 Elsevier B.V. -
IOT based prediction of rainfall forecast in coastal regions using deep reinforcement model
This research proposes an IoT based technique for predicting rainfall forecast in coastal regions using a deep reinforcement learning model. The proposed technique utilizes Long Short-Term Memory (LSTM) networks to capture the temporal dependencies between the rainfall data collected from the coastal regions and the prediction model parameters. The proposed technique is evaluated on a dataset of rainfall data collected from the coastal regions of India and compared to traditional methods of rainfall forecasting. The accuracy and reliability of these models are evaluated by comparing them to prior models. Precipitation in coastal locations may be predicted with an average accuracy of 89% using the suggested model, as shown by the results. The suggested framework is computationally efficient and can be trained with little input. The results of this research give strong evidence that the proposed model is an effective tool for coastal precipitation forecasting. 2023 The Authors -
Lie group analysis of flow and heat transfer of a nanofluid in conedisk systems with Hall current and radiative heat flux
A study of the rheological and heat transport characteristics in conedisk systems finds relevance in many applications such as viscometry, conical diffusers, and medical devices. Therefore, a three-dimensional axisymmetric flow with heat transport of a magnetized nanofluid in a conedisk system subjected to Hall current and thermal radiation effects is investigated. The simplified NavierStokes (NS) equations for the conedisk system given by Sdougos et al. [18] Journal of Fluid Mechanics, 138, 379404 are solved by using the asymptotic expansion method for the four different models, such as rotating cone with static disk (Model I), rotating disk with static cone (Model II), co-rotating cone and disk (Model III), and counter-rotating cone and disk (Model IV). The KhanaferVafaiLightstone (KVL) model along with experimental data-based properties of 37 nm Al2O3H2O nanofluid is considered. To obtain the transformations leading to self-similar equations from the NavierStokes (NS) and energy conservation equations, the Lie group technique is used. The self-similar nonlinear problem is solved numerically to examine the effects of physical parameters. There are critical values of the power exponent at which no heat transport from the disk surface occurs. Nanoparticles significantly enhance heat transport when both the cone and disk rotate in the same or opposite directions. The centrifugal force and thermal radiation improve the heat transport in conedisk systems. 2023 John Wiley & Sons Ltd. -
Future perspectives on new innovative technologies comparison against hybrid renewable energy systems
The increase in the dispatchable amount of renewable energy and rural access to the point is proposed. The fuel is used to generate power and electrical energy for the machine. This causes the electricity to manage the single connection point to analyze the hybrid generations. Improving this hybrid generator of renewable power resources can be enabled for the analysis. Photovoltaic power sources have been introduced for converting the power loads and the dumps. The vehicle energy power management technique and the renewable energy system have been used for the analysis. This study shows how vehicle and renewable energy management can help develop geothermal against hydrothermal vents. Hydropower and vehicles can enable bioethanol for vehicle biodiesel. This study allows for the analysis of hydrothermal and biodiesel. In this study, the power of the energy enables the hybrid system, and the combination of the power generator to access the vehicle is proposed. 2023 -
Non-Noble Bifunctional Amorphous Metal Boride Electrocatalysts for Selective Seawater Electrolysis
The global scarcity of freshwater resources has recently driven the need to explore abundant seawater as an alternative feedstock for hydrogen production by water-splitting. This route comes with new challenges for the electrocatalyst, which has to withstand harsh saline water conditions with selectivity towards oxygen evolution over other competing reactions. Herein, a series of amorphous metal borides based on the iron triad metals (Co, Ni, and Fe), synthesized by a simple one-step chemical reduction method, displayed excellent bifunctional activity for overall seawater splitting. Amongst the chosen catalysts, amorphous cobalt boride (Co?B) showed the best overpotential values of 182 mV for HER and 305 mV for OER, to achieve 10 mA/cm2, in alkaline simulated seawater. This superior activity was owed to the enrichment of the metal site with excess electrons (HER) and the in-situ surface transformation (OER), as confirmed by various means. In alkaline simulated seawater, the overall cell voltage required to achieve 100 mA/cm2 was 1.85 V for the Co?B catalyst when used in a 2-electrode assembly. The Co?B catalyst showed negligible loss in activity even after 1000 cycles and 50 h potentiostatic tests, thus demonstrating its industrial viability. The selectivity of the catalyst was established with Faradaic efficiency of above 99 % for HER and 96 % for OER, with no detection of chloride products in the spent electrolyte. This study using the mono-metallic boride catalysts will turn to be a precursor to exploit other complex metal boride systems as potential candidates for seawater electrolysis for large-scale hydrogen production. 2023 Wiley-VCH GmbH. -
Role of mixed molecular weight PEO-PVDF polymers in improving the ionic conductivity of blended solid polymer electrolytes
Blended solid polymer electrolytes (BSPE) were prepared by mixing different molecular weight polymers PEO6 (Mw = 1 106 g/mol), PEO5 (Mw = 1 105 g/mol), and PVDF (Mw = 5.25 105 g/mol) complexed with lithium salt. Conductivity and dielectric studies at different temperatures were carried out on these BSPE systems by varying the wt% of PEO5 and PVDF with respect to PEO6, keeping the wt% of lithium salt constant. The electrical characterizations of BSPE systems have been investigated using impedance spectroscopy in the frequency range 0.1106 Hz. The conductivity data shows that inclusion of PEO5 and PVDF into the PEO6 matrix improved the overall lithium-ion dynamics in the polymer matrix. The composition, PEO6 (94 wt%)-PEO5 (3 wt%)/PVDF (3 wt%)-LiClO4, exhibited maximum conductivity of 6.44 10?4 Scm?1 at 303 K. TheDC conductivity variation with temperature of BSPE systems follows Arrhenius relation and variation of AC conductivities with frequency obeys Jonschers power law. The real and imaginary part of dielectric constant and the dielectric relaxation were also investigated. 2023, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature. -
HQA Bot: Hybrid AI Recommender Based Question Answering Chatbot
The COVID pandemic has presented a number of challenges for education, particularly when it comes to reaching and engaging students. As a result, online education has become increasingly important, and artificial intelligence (AI) has played a crucial role in supporting this shift. The proposed tutor assistance question-answering system uses AI to automatically generate responses to student questions. This system includes a feedback mechanism, known as a satisfaction index that measures the efficiency of the generated responses and suggest relevant follow-up questions. The proposed Hybrid Recommender-based Dijkstras algorithm (HRD) improves the system's accuracy. This algorithm uses a combination of techniques to group relevant questions based on context, which improves the accuracy of identifying the next relevant question. In our customized dataset, this approach achieved an accuracy of 96% and an average accuracy of 82% across benchmarked datasets. With this system, we aim to bridge the gap between students and education by providing a more engaging and personalized learning experience. 2023, Ismail Saritas. All rights reserved. -
Delayed in sensorimotor reflex ontogeny, slow physical growth, and impairments in behaviour as well as dopaminergic neuronal death in mice offspring following prenatally rotenone administration
The environment is varying day by day with the introduction of chemicals such as pesticides, most of which have not been effectively studied for their influence on a susceptible group of population involving infants and pregnant females. Rotenone is an organic pesticide used to prepare Parkinson's disease models. A lot of literature is available on the toxicity of rotenone on the adult brain, but to the best of our knowledge, effect of rotenone on prenatally exposed mice has never been investigated yet. Therefore, the recent work aims to evaluate the toxic effect of rotenone on mice, exposed prenatally. We exposed female mice to rotenone at the dose of 5mg/Kg b.w. throughout the gestational period with oral gavage. We then investigated the effects of rotenone on neonate's central nervous systems as well as on postnatal day (PD) 35 offspring. In the rotenone group, we observed slow physical growth, delays in physical milestones and sensorimotor reflex in neonates and induction of anxiety and impairment in cognitive performances of offspring at PD-35. Additionally, immunohistochemical analysis revealed a marked reduction in TH-positive neurons in substantia nigra. Histological examination of the cerebellum revealed a decrease in Purkinje neurons in the rotenone exposed group as compared to the control. The data from the study showed that prenatally exposure to rotenone affects growth, physical milestones, neuronal population and behaviour of mice when indirectly exposed to the offspring through their mother. This study could provide a great contribution to researchers to find out the molecular mechanism and participating signalling pathway behind these outcomes. 2023 International Society for Developmental Neuroscience. -
Students Satisfaction with Remote Learning During the COVID-19 Pandemic: Insights for Policymakers
Purpose: This study aimed to learn more about the factors influencing student happiness and involvement in remote learning in Indian higher education institutions (HEIs). The study aims to assist administrators, strategists, and politicians in efficiently dealing with educations new normal. Methodology: The study used a quantitative research approach to fulfill the research aims. A sample of 546 students from various Indian HEIs was chosen, and data were gathered using standardized questionnaires. Structural equation modeling, confirmatory factor analysis, and importance-performance analysis (IPA) were used to calculate the student satisfaction index and examine the impact of various factors. Findings: The findings of this study revealed that institutional and faculty support emerged as the most influential factor impacting students satisfaction through remote learning. It also highlighted the need for HEIs to redesign the assessment process and evaluation techniques to adapt to the remote learning environment. Practical Implications: The findings of this study indicated the practical consequences for administrators, strategists, and policymakers at Indian HEIs. It was advised that improving institutional and teacher support should be a major concern in order to improve student happiness in remote learning situations. Furthermore, redesigning assessment procedures and evaluation processes may improve learning outcomes and student engagement. Originality: This study contributed to the existing body of knowledge by specifically investigating the factors influencing student satisfaction in remote learning within Indian HEIs. The findings shed light on the unique challenges and opportunities the shift to remote education presented. They offered valuable insights for managing and improving the quality of education during and beyond the pandemic. 2023, Associated Management Consultants Pvt. Ltd.. All rights reserved. -
Structural, optical, and electrochromic properties of RT and annealed sputtered tungsten trioxide (WO3) thin films for electrochromic applications by using GLAD technique
Tungsten oxide (WO3) thin films were prepared on the GLAD DC magnetron sputtering (GDMS) and substrate angles were varied from 70 to 80. The WO3 thin films were deposited at room temperature (RT) on corning glass (CG) and fluorine-doped tin oxide (FTO), and substrates and annealed at 400C/2h. The XRD, UvVis spectrometer, and electrochemical analyzer were used to determine the structural, optical, and electrochromic (EC) properties. According to an XRD study, RT-deposited samples were amorphous, but annealed samples displayed crystalline structures. The optical transmittance of RT and annealed samples varied from 59 to 71% and 14 to 28% respectively. The colored/bleached ability of the cyclic voltammograms was RT samples shows greater than in annealed samples. Since the coloration ability and diffusion coefficient of WO3 RT samples show greater than annealed samples. 2023, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature. -
Rational design of PANI incorporated PEG capped CuO/TiO2 for electrocatalytic hydrogen evolution and supercapattery applications
Synthesis of efficient electrocatalysts for energy applications is a major area scientists are currently focusing on to address the twin challenges of energy shortfall and the production of clean energy. Herein, an efficient electrocatalyst, polyaniline incorporated with polyethylene glycol capped CuO/TiO2 is prepared, which is effective in hydrogen evolution reactions and energy storage applications. The characterizations like XPS, XRD, FT-IR, FE-SEM, HR-TEM, and BET have been carried out to confirm the successful formation of the synthesized PANI/CuO/TiO2 composite. At 10 mA/cm2 current density, the prepared composite exhibits a lesser overpotential of 536 mV and 1587.2 C/g at 1 A/g as the specific capacity. The electrode prepared using the PANI/CuO/TiO2 composite also shows cyclic stability up to 2000 cycles. The synthesized composite is an efficient electrocatalyst for energy related applications. 2023 Hydrogen Energy Publications LLC -
Development of smart energy monitoring using NB-IOT and cloud
IoT-based applications are growing in popularity nowadays because they offer effective answers to numerous current problems. In this research, With the aim of decreasing human efforts for monitoring the power units and increasing users' knowledge of excessive electricity usage, an IoT-based electric metre surveillance system utilising an Android platform has been developed. With the help of an Arduino Uno and an optical sensor, the electric analyser pulse is captured. To reduce human mistake and the expense of energy usage, a low-cost wireless network of sensors for digital energy metres is implemented alongside a smartphone application that can autonomously read the metre of the unit. In this research, an intelligent power monitoring system with effective communication modules has been developed to make wise use of the electricity. The controller, NB-IoT connection module, and cloud are the three main components of an IOT-based smart energy metre system. The controller is essential for maintaining the functionality of each component. This solution reduces the need for human involvement in electricity maintenance by connecting energy metres to the cloud using an NB-IoT communication module. The IoT-based metre reading system in the proposed work is created to monitor and analyse the metre reading, and the service provider can cut off the source of electricity whenever the customer fails to pay the monthly bill. It also eliminates the need for human intervention, provides accurate metre reading, and guards against billing errors. The proposed SPM improves the overall accuracy ranges of 7.42, 27.83, and 20% better than DR, OREM, and SLN respectively. 2023