Browse Items (11810 total)
Sort by:
-
Switchable surface activity of Bi2Al4O9 nano particles: A contemporary approach in heterocyclic synthesis
Ferroelectric catalysis is emerging as an efficient chemical transformation strategy, especially in the field of clean energy production, wastewater treatment and degradation of pollutants. The core of ferroelectric catalysis is the dynamically switchable electrical polarization on their surface. It enables them to switch their surface activity, more precisely due to binding strength with the substrate. Even though a plethora of reports are available, the introduction of ferroelectric catalytic surfaces for the generation of heterocyclic compounds is a novel aspect. Here, we introduce ferroelectric Bismuthaluminate nanoparticles as catalysts for generating derivatives of azalactone, tetrahydro-benzopyran and pyranopyrazole with improved catalytic efficiency. This can be achieved by switching the direction of polarization of the catalyst which indeed alters the surface electronic states and stimulates the reaction followed by the excellent yield. Here the switchable property is due to the thermally induced polarization of water. Graphical Abstract: [Figure not available: see fulltext.]. 2023, The Author(s), under exclusive licence to Springer Nature B.V. -
Co-Electrodeposited Pi-MnO2-rGO as an Efficient Electrode for the Selective Oxidation of Piperonyl Alcohol
Pi-MnO2-rGO-CFP electrode was developed through a concurrent deposition of Pi-MnO2 and reduced graphene oxide (rGO) on carbon fiber paper (CFP). Cyclic voltammetry (CV) and electrochemical impedance studies (EIS) were applied for the electrochemical characterization of the electrode. The electro catalytic activity of the modified electrode was improved by the increased synergistic characteristics of the CFP and electrochemically deposited rGO-Pi-MnO2 composite. The performance of the modified electrode was remarkable due to its lowest charge transfer resistance (R ct), and highest surface area offering more active sites and quicker electron transport kinetics. X-ray diffraction spectroscopy (XRD), Raman spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and optical profilometry (OP) were employed to study the physicochemical properties. Furthermore, the modified electrode was availed to oxidize piperonyl alcohol mediated by 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxyl (4-acetamido TEMPO or 4-ACT). The product obtained was purified and characterized by 1HNMR. The turnover frequency of 4-ACT was studied at different concentrations of the reactant, and the reaction parameters were also optimized using statistical tool design of experiment. This methodology is demonstrated to be economical, environmentally benign, and highly efficient in obtaining piperonal as it is carried out under milder reaction conditions. 2023 The Electrochemical Society (ECS). Published on behalf of ECS by IOP Publishing Limited. -
A survey on artificial intelligence for reducing the climate footprint in healthcare
The primary mission of the healthcare sector is to protect from various ailments with improved healthcare services and to use advanced diagnostic solutions to promote reliable treatments for complex diseases. However, healthcare is among the significant contributors to the current climate crisis. Therefore, research is underway to identify various measures to reduce the emissions from advanced healthcare systems. Modern healthcare facilities invest significantly in renewable energy, efficient energy solutions, and intelligent climate cooling and control technologies. Furthermore, innovative technologies like artificial intelligence (AI) are proposed to enable automation for patient health monitoring. With the advances in AI, there are green AI goals for potentially reducing emissions through data-driven and well-optimized models for healthcare. Furthermore, novel machine learning and deep learning techniques are continually proposed for improved efficiency to reduce emissions. Therefore, the scope of the research is to review the potential of AI in healthcare for lowering emission rates and its methodologies, current approaches, metrics, challenges, and future trends to attain a straightforward pathway. 2022 -
Spectrum of corona products based on splitting graphs
Let G be a simple undirected graph. Three new corona products of graphs based on splitting graph of G are defined. The adjacency spectra of the three new graphs based on splitting graph of G are determined. The number of spanning trees and the Kirchoff index of the new graphs are determined using their nonzero Laplacian eigenvalues. 2023 World Scientific Publishing Company. -
Design optimisation and fabrication of amino acid based molecularly imprinted sensor for the selective determination of food additive tartrazine
In this work, we developed a new molecularly imprinted polymer detector for tartrazine's rapid and selective detection. Electropolymerisation using L-Methionine resulted in the polymer immobilised on the carbon fibre paper electrode's surface. MIP film was formed by electropolymerisation in the presence of the template tartrazine. The polymer frame comprises cavities after template removal, which can specifically bind to the analyte molecule. Without pre-treatment, the developed sensor MIPMet/CFP detects tartrazine in beverage samples precisely and rapidly. The sensor has a linear response in the concentration range of 0.6 nM- 160 nM, high sensitivity (601964 AM-1cm?2), and a low detection limit of 27 pM under optimum conditions. MIPMet/CFP sensor displayed the ability to distinguish target analyte from interferants selectively. The performance of the MIPMet/CFP sensor in assessing tartrazine in different saffron powder and packed juice samples suggests that it could be used to detect tartrazine fast and effectively. 2022 Elsevier Ltd -
Zomato Instant - "10-Minute Delivery Plan" Controversy
[No abstract available] -
Public debt - economic growth nexus in emerging and developing economies: Exploring nonlinearity
This paper explores the nonlinear dynamics between public debt and economic growth by estimating the threshold level of debt for thirty-nine emerging and developing economies. The study found a considerable variation amongst the debt thresholds in these countries, ranging between 24 and 132 per cent. We observed the evidence for an inverted U-shape relationship either partially or fully only in six countries. On the contrary, our study found that expanding debt even beyond the threshold promotes economic growth in some countries, while debt hinders growth even at low debt levels in a few countries. 2022 Elsevier Inc. -
Does the green finance initiatives transform the world into a green economy? A study of green bond issuing countries
Green finance initiatives have received global support in modern times, relatively in response to safeguard the environment and preserve natural resources through channelizing the investments to create a green economy. This paper attempts to evaluate and compare the green finance growth in green bond issuing nations across the world. This study also assesses the effect of green finance growth on the dependence of non-renewable energy resources especially fossil fuels that have been creating several environmental issues for the past years. This study develops a pressure-state-response framework to evaluate the comprehensive system of green finance growth that depicts the interaction of sub-aspects. We employ the entropy technique to calculate the weights at each level within the evaluation system. We also constructed empirical models to assess the relationship between green finance growth and dependence on fossil fuel consumption and found that there exists a negative relationship between the two. The results convey that proliferation of green finance instruments can reduce the dependence on fossil fuels and smoothen the transition towards a carbon negative world. 2023, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature. -
EFFECTS OF VIRTUAL PRIVATE SOCIAL NETWORKING IN ACADEMIC PERFORMANCE OF STUDENTS
A virtual private social network (VPSN) is generated automatically amongst peers using a social media app to build ties. One of the most significant repercussions of students' excessive usage of social networking sites is a decline in their academic performance. In a study of medical students, social media and the internet were shown to harm students' academic performance and classroom attentiveness. An increasing number of studies link the use of social media to poorer academic performance, such as fewer students doing their assignments and lower test scores. Students who receive specialised training in deep learning will have the superior cognitive abilities needed to succeed in today's more cognitively demanding workplaces. It teaches children to be critical thinkers, productive members of society, and active participants in a democratic society. As a perceptron used in image recognition and processing, a convolutional neural network (CNN) processes pixel data from social networks. A CNN uses multiplayer perception to lessen the processing needs of pupils. Humans and neurons make up the VPSN-CNN network, which the article explains. Neurons generate dendrites and axons to receive and transmit signals, while humans engage with long-reaching telecommunication equipment or biological communication systems. These will help remember, learn, unlearn, and relearn what has already been learned. In courses where social networking sites were utilised in addition to traditional teaching methods, most students reported feeling more socially engaged and more positive about their educational experiences. Students' and instructors' concerns regarding the educational usage of social media are addressed with recommendations for further study and practice in better performance and accuracy for student's data secure and comparison with existing methods. 2023 Little Lion Scientific. All rights reserved. -
Psychological impact of olfactory branding: The future of smell marks in India
Scents have been used by business organizations for commercializing their products since historic times. Because of the psychological connect that a consumer immediately makes as he smells something unique, olfactory branding is considered as a very productive and effective marketing tool. Trademark law attempts to protect a brand's identity with the ultimate motive of preventing consumers from deceptively similar goods. Scholars and businesses have been raising their voice in a demand call for smell mark protection under trademark law, arguing that smell is just as important for identifying the origin-point of a product for a consumer as is the brand's logo or name or product shape. While the US courts have been liberal in granting smell mark registrations, EU courts have interpreted the graphical representation requirement under trademark law very strictly. Indian law, though not entirely closed on the prospect of smell mark protection, is inclined toward the EU position. After analyzing the current legal scenario, this article explores the more fundamental question as to the feasibility of smell marks, questioning their justification under the philosophical foundations of trademark law, the subjective associations of consumers with respect to smells, the difficulty in evidence analysis by courts in infringement suits and the apprehension relating to the functionality doctrine. 2022 John Wiley & Sons Ltd. -
Bio-Decolorization and Degradation of Reactive Blue 222 by a Novel Isolate Kucoria marina CU2005
In this study, a novel bacterial strain, Kucoria marina CU2005, was isolated and identified using 16S rRNA gene sequencing from an industrial wastewater sludge sample capable of degrading Reactive Blue 222 (RB222) dye. Batch mode bio stimulation studies were performed with minimal salt media to optimize key physiological parameters for effective decolorization of RB222. When cultured at 35 C and pH 7 under static conditions, this bacterium decolorized 82 percent of the dye after 24 hours. Decolorization was monitored using UV-vis spectrophotometry. Isolates ability to decolorize the complex dye was attributed to its degradation potential rather than a passive surface adsorption. FTIR, HPLC, GC-MS studies were used to confirm microbial dye metabolism. The results indicated breakdown of dye upon decolorization as some peaks were shifted and generation of aromatic amine for monosubstituted benzene ring as intermediates of dye degradation in decolorized solutions. This study has shown the potential of Kucoria marina CU2005 to decolorize RB222 dye at a better pace and efficiency than previously reported bacterial strains. Thus, we propose that our isolated strain can be utilized as a potential dye decolorizer in environmental biotechnology as effluent treatment for decolorization of RB 222. 2023, Association of Biotechnology and Pharmacy. All rights reserved. -
Bi Functional Manganese-Pyridine 2,6 Dicarboxylic Acid Metal Organic Frameworks with Reduced Graphene Oxide as an Electroactive Material for Energy Storage and Water Splitting Applications
In recent years, metal organic frameworks (MOFs) with porous carbon materials have significantly improved the design and engineering of high performance electrode materials and have found applications in energy storage devices. This study explores the supercapacitor and electrocatalytic water splitting applications of Mn-MOF/reduced graphene oxide (rGO) composite synthesized via a hydrothermal technique using pyridine 2,6 dicarboxylic acid as a linker. Mn-MOF/rGO exhibits a specific capacitance of 428.28 F g?1 with a rate capability of 83.7% and high cyclic stability. The oxygen evolution reaction of the composite is evaluated using linear sweep voltammetry, and the overpotential is calculated to be 400 mV. Our primary goal is to investigate the effect of rGO on the electrochemical response of MOF. The dielectrode (Mn-MOF/rGO) electrolysis system exhibits long-run stability with a low cell potential of 1.8 V, indicating its prospective application as an excellent water electrolyzer. The combination of Mn-MOF with rGO helps in increasing the number of active sites, thereby improving its electronic conductivity by enhancing the electron transfer rate. The outstanding electrochemical behaviour of Mn-MOF/rGO paves the way for the use of rGO-incorporated Mn-MOF in bifunctional applications as energy-generating and storage devices. 2023 The Electrochemical Society (ECS). Published on behalf of ECS by IOP Publishing Limited. -
A Review of Historical Context and Current Research on Cannabis Use in India
Background: The cultivation and use of cannabis is historically rooted in the Indian subcontinent and this rich heritage of cannabis use dates back to at least two thousand years. Cannabis remains an illicit substance in India despite its changing status globally with many countries legalizing cannabis use in recent years. Scientific research on cannabis use in India has also been sparse. Method: Extensive search of online databases resulted in the identification of 29 original research studies pertaining to one of three areas of cannabis research; a) prevalence of cannabis use b) psychological correlates of cannabis use, c) cannabis use in substance use treatment settings. Findings: We found that most Indian studies used very basic quantitative research designs and had poor scientific rigor. Samples were small, region specific and included only males. Data analyses were limited to descriptive methods. The criteria for cannabis use in most of the reviewed studies were not rigorous and prone to biases. Conclusion & Implications: With changing attitudes and loosening of restrictions on cannabis use, the prevalence of new users is rising dramatically particularly in the college going population. This presents a strong need for research on motivations and attitudes to cannabis use and how those can influence patterns of use, and also the short- and long-term effects of use. More studies with stronger research designs (both cross sectional and longitudinal) are required for the study of cannabis use and this knowledge will be critical for managing the growing substance epidemic, generating public health solutions as well as formulating effective policy frameworks. 2022 The Author(s). -
Labour migration, the Arabian Gulf, and the expanding territorial imagination in Malayalam cinema
Mainstream Malayalam cinema of the south Indian state of Kerala has, for the most part, attempted to sidestep the significance of Gulf migration to the regions development. Part of the reason for this historical neglect has been the prevalence of a particular hegemonic vantage point within the films that has centralized the narratives of the landed elites in Kerala, eliding the various historically marginalized communities within the state. This article engages with a recent development within the film industry. It examines how Gulf migration has shaped the affective dimensions and expanding territorial imagination of the New Malayalam Cinema, which has positioned labour migration as one of its central thematic concerns. It is argued that this shift was made possible by the displacement of the universalized territorial imagination of the landed elites in the state that dominated its film industry for most of its history. Subsequently, this article will closely study how director Zakariya places his debut film Sudani from Nigeria (2018) within this new cinematic category, and will demonstrate how he portrays the region of rural Malappuram in north Kerala as a nexus of various migrant experiences, crucially invoking an underlying older order of cosmopolitanism prevalent in the region, fuelled partly by the history of Gulf migration and partly by a tradition and history of migration and transnationalism that predates the formation of the Indian state. The Author(s) 2023. -
Does financial inclusion control corruption in upper-middle and lower-middle income countries?
Presence of corruption in a system is always a path breaker for transparent distribution of public services in the economy. Therefore, controlling corruption is a high priority for progress of a countrys growth. The main objective of this study was to empirically examine the impacts of financial inclusion on control of corruption in selected upper-middle and lower-middle income countries. Using cross-country annual data from 2004 to 2018, the study applied fixed effect, random effect, panel corrected standard errors, feasible general least square and 2SLS (two-stage least-squares regression) models to evaluate the impacts of financial inclusion on control of corruption across all samples from upper-middle and lower-middle income countries. The results from the upper-middle income (UMI) countries demonstrated that a basic level of financial inclusion has no impact on the control of corruption, whereas higher intensification of financial inclusion beyond the basic level positively impacts it. Similarly, the findings from lower-middle-income (LMI) countries indicated that financial inclusion up to a certain threshold level helps to control corruption, whereas financial inclusion above the threshold level negatively impacts the control of corruption. These empirical findings suggest that in the overall sample, financial inclusion plays an important role to control corruption. 2022, The Japan Section of the Regional Science Association International. -
Design and Implementation Bidirectional DC-AC Converter for Energy Storage System
This article proposes a bidirectional single-phase dc-ac converter with triple port converter (T-PC) for application of energy storage. This proposed converter provides three ports such as ac port, dc port, and dc bus port to achieve three power interfacing ports. For the direct conversion process, dc port is directly connected to T-PC, and direct power will be exchanged between energy storage device (ESD) and grid when the ESD voltage peak amplitude is lower than the ac voltage. Thus, a dc-dc converter downstream power process gets reduced, and power loss is decreased considerably. Due to multilevel characteristics, switching losses in the T-PC can be reduced. The efficiency of the overall bidirectional dc-ac conversion process can be increased significantly. The circuit model, working principle, and modulation control of T-PC-based bidirectional dc-ac conversion concepts are analyzed. A 1.5-kW test-bench model is developed and its effectiveness is verified to find the merits of suggested conversion. 2021 IEEE. -
An integrated framework for digitalization of humanitarian supply chains in post COVID-19 era
Digital Supply Chains (DSCs) are transforming industries across various domains. Digitalization can improve coordination, increase data collection and retention capacities, enhance funding mechanisms, and improve operational performance and resource utilization. However, DSC adoption is constrained by lack of funding, operational complexities, infrastructure issues, etc. Thus, the need emerges to explore the digitalization of the Humanitarian Supply Chain (HSC) and provide solutions that can ease the adoption of DSC. In this study, a framework is created to facilitate the digitalization process of HSC in post COVID-19 era. Nineteen related drivers are identified with the potential to digitalize the HSC. The drivers are identified from the previous literature and finalized with the assistance of HSC stakeholders. A Principal Component Analysis is carried out to discover the most pertinent drivers from the identified list of drivers. A Kappa analysis is adopted to perfect the priority map of the digitalization drivers. Further, the neutrosophic DEMATEL methodology is adopted to prioritize the potential drivers and find their dependency on each other. The results from the study indicate that the most influential drivers fall under the operational and technological categories. However, the social drivers have the potential to play a significant contribution in an effort to HSC digitalization. In addition, the study presents strategies for enhancing funds collection and data management using emerging technologies. These strategies can assist HSC decision-makers in formulating relevant policies and strategic interventions. 2023 Elsevier Ltd -
Ion-imprinted chitosan-stabilized biogenic silver nanoparticles for the electrochemical detection of arsenic (iii) in water samples
Arsenic is one of the most harmful heavy metals, and needs constant monitoring and control. A susceptible and selective sensor for arsenic (iii) detection in polluted water samples has been developed by using chitosan-stabilized silver nanoparticles (AgNPs). A glassy carbon electrode (GCE) is modified with chitosan-stabilized silver nanoparticles, which provides sufficient sites for interaction with the analyte. The synthesized silver nanoparticles are characterized using different characterization techniques, such as UV-Visible spectroscopy, transmission electron spectroscopy (TEM) and particle size distribution. The particle size and polydispersity index (PDI) value of the chitosan stabilized silver nanoparticles are found to be 6 nm and 0.3, respectively, which enhances the electroactive surface area and hence the sensor sensitivity. The ion imprinting technique is used to improve the selectivity of the sensor. The arsenic sensor is found to be very selective in the presence of other possible interferents like Pb2+, Zn2+, Cu2+, Ag+ and Fe2+. The detection of As(iii) was performed using differential pulse anodic stripping voltammetry (DPASV) and the detection limit was found to be 11.39 pM. The developed sensor is successfully tested for the picomolar level detection of arsenic (iii) in different water samples. 2023 The Royal Society of Chemistry. -
Designing of a Free-Standing Flexible Symmetric Electrode Material for Capacitive Deionization and Solid-State Supercapacitors
In this work, a highly efficient free-standing flexible electrode material for capacitive deionization and supercapacitors was reported. The reported porous carbon shows a high surface area of 2070.4 m2 g-1 with a pore volume of 0.8208 cm3 g-1. The material exhibited a high specific capacitance of 357 F g-1 at 1 A g-1 in a two-electrode symmetric setup. A solid-state supercapacitor device has been fabricated with a total cell capacitance of 152.5 F g-1 at 1 A g-1 in a solid PVA/H2SO4 gel electrolyte with an energy density of 21.18 W h kg-1 at a 501.63 W kg-1power density. A long-run stability test was carried out up to 15,000 cycles at 5 A g-1 that showed capacitance retention of 99% with ?100% Coulombic efficiency. Furthermore, the electrosorption experiment was conducted by a flow-through test by coating on commercially available cellulose thread that was employed, which shows electrosorption ability up to 16.5 mg g-1 at 1.2 V in a 500 mg L-1 NaCl solution. Complete experiments were conducted with a proper procedure, provided by scientific approaches with analytical data. Thus, the reported electrode material showed bifunctional application for energy storage and environmental remediation. 2023 American Chemical Society. -
Optimized production of keratinolytic proteases from Bacillus tropicus LS27 and its application as a sustainable alternative for dehairing, destaining and metal recovery
The present study describes the isolation and characterization of Bacillus tropicus LS27 capable of keratinolytic protease production from Russell Market, Shivajinagar, Bangalore, Karnataka, with its diverse application. The ability of this strain to hydrolyze chicken feathers and skim milk was used to assess its keratinolytic and proteolytic properties. The strain identification was done using biochemical and molecular characterization using the 16S rRNA sequencing method. Further a sequential and systematic optimization of the factors affecting the keratinase production was done by initially sorting out the most influential factors (NaCl concentration, pH, inoculum level and incubation period in this study) through one factor at a time approach followed by central composite design based response surface methodology to enhance the keratinase production. Under optimized levels of NaCl (0.55 g/L), pH (7.35), inoculum level (5%) and incubation period (84 h), the keratinase production was enhanced from 41.62 U/mL to 401.67 9.23 U/mL (9.65 fold increase) that corresponds to a feather degradation of 32.67 1.36% was achieved. With regard to the cost effectiveness of application studies, the crude enzyme extracted from the optimized medium was tested for its potential dehairing, destaining and metal recovery properties. Complete dehairing was achieved within 48 h of treatment with crude enzyme without any visible damage to the collagen layer of goat skin. In destaining studies, combination of crude enzyme and detergent solution [1 mL detergent solution (5 mg/mL) and 1 mL crude enzyme] was found to be most effective in removing blood stains from cotton cloth. Silver recovery from used X-ray films was achieved within 6 min of treatment with crude enzyme maintained at 40 C. 2023 Elsevier Inc.