Co-Electrodeposited Pi-MnO2-rGO as an Efficient Electrode for the Selective Oxidation of Piperonyl Alcohol
- Title
- Co-Electrodeposited Pi-MnO2-rGO as an Efficient Electrode for the Selective Oxidation of Piperonyl Alcohol
- Creator
- Rodrigues R.M.; Thadathil D.A.; Shanker G.; Sirimahachai U.; Varghese A.; Hegde G.
- Description
- Pi-MnO2-rGO-CFP electrode was developed through a concurrent deposition of Pi-MnO2 and reduced graphene oxide (rGO) on carbon fiber paper (CFP). Cyclic voltammetry (CV) and electrochemical impedance studies (EIS) were applied for the electrochemical characterization of the electrode. The electro catalytic activity of the modified electrode was improved by the increased synergistic characteristics of the CFP and electrochemically deposited rGO-Pi-MnO2 composite. The performance of the modified electrode was remarkable due to its lowest charge transfer resistance (R ct), and highest surface area offering more active sites and quicker electron transport kinetics. X-ray diffraction spectroscopy (XRD), Raman spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and optical profilometry (OP) were employed to study the physicochemical properties. Furthermore, the modified electrode was availed to oxidize piperonyl alcohol mediated by 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxyl (4-acetamido TEMPO or 4-ACT). The product obtained was purified and characterized by 1HNMR. The turnover frequency of 4-ACT was studied at different concentrations of the reactant, and the reaction parameters were also optimized using statistical tool design of experiment. This methodology is demonstrated to be economical, environmentally benign, and highly efficient in obtaining piperonal as it is carried out under milder reaction conditions. 2023 The Electrochemical Society (ECS). Published on behalf of ECS by IOP Publishing Limited.
- Source
- Journal of the Electrochemical Society, Vol-170, No. 3
- Date
- 2023-01-01
- Publisher
- Institute of Physics
- Coverage
- Rodrigues R.M., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bengaluru, 560029, India, Department of Chemistry, St Agnes College (Autonomous), Karnataka, Mangaluru, 575002, India; Thadathil D.A., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bengaluru, 560029, India; Shanker G., Department of Chemistry, Bangalore University, Jnana Bharati Campus, Bengaluru, India; Sirimahachai U., Center of Excellence for Innovation in Chemistry, Division of Physical Science, Faculty of Science, Prince of Songkhla University, Hat Yai, Songkhla, 90110, Thailand; Varghese A., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bengaluru, 560029, India; Hegde G., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bengaluru, 560029, India, Centre for Advanced Research and Development (CARD), CHRIST (Deemed to be University), Karnataka, Bengaluru, 560029, India
- Rights
- Restricted Access
- Relation
- ISSN: 134651; CODEN: JESOA
- Format
- Online
- Language
- English
- Type
- Article
Collection
Citation
Rodrigues R.M.; Thadathil D.A.; Shanker G.; Sirimahachai U.; Varghese A.; Hegde G., “Co-Electrodeposited Pi-MnO2-rGO as an Efficient Electrode for the Selective Oxidation of Piperonyl Alcohol,” CHRIST (Deemed To Be University) Institutional Repository, accessed February 23, 2025, https://archives.christuniversity.in/items/show/14357.