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Properties, Synthesis and Emerging Applications of Graphdiyne: A Journey Through Recent Advancements
Graphdiyne (GDY) is a new variant of nano-carbon material with excellent chemical, physical and electronic properties. It has attracted wide attention from researchers and industrialists for its extensive role in the fields of optics, electronics, bio-medics and energy. The unique arrangement of spsp2 carbon atoms, linear acetylenic linkages, uniform pores and highly conjugated structure offer numerous potentials for further exploration of GDY materials. However, since the material is at its infancy, not much understanding is available regarding its properties, growth mechanism and future applications. Therefore, in this review, readers are guided through a brief discussion on GDYs properties, different synthesis procedures with a special focus on surface functionalization and a list of applications for GDY. The review also critically analyses the advantages and disadvantages of each synthesis route and emphasizes the future scope of the material. Graphical abstract: (Figure presented.) The Author(s), under exclusive licence to Springer Nature Switzerland AG 2024. -
A catechism of pentecostal schisms and the efficacy of management in the stabilization of the church in zimbabwe
The Pentecostal church in Zimbabwe has of late experienced a rude awakening with the mushrooming of these incessant schisms which threaten the unity of purpose that should prevail in a religious set up. The current newlineincrease in schisms is of great concern to the Christian community. Are such schisms embedded in its original design, or are there other factors at play. The problem necessitated the commissioning of this study in order to explore the schism scourge with view to arresting it and bring stability to the splintering Pentecostal church. The conceptualization of the study began by identifying six hypothetical perspectives as the root hypothetical causes of church schisms, i.e., doctrinal, controversial relationship, secularization, institutionalism, leadership and management perspectives. Theoretical frameworks in the newlineexisting literature were reviewed to establish knowledge gaps that informed the newlinestudy approach. Using focus group discussion, document analysis, survey questionnaires, and interviews, the study sought causal and remedial validation on the problem at hand. To unveil the intricacies of the problem, an explorative mixed study framework was preferred. In order to generate a desired rich understanding and interpretation of schisms, a more qualitative catechism inquiry based on a combined ethno-methodology and hermeneutics paradigm was adopted. The study proposition was that church schisms are a result of management challenges in the Pentecostal church. The theoretical frame of the study was therefore modeled to explore newlinehow management protocols could be harnessed to induce real growth and stability. The Pentecostal church is renowned for shunning management, considering it secular and hence worldly. On one hand, the church is the most newlinecomplex institution, multifaceted and with multi-bottom lines, yet on the other hand, management is all about dealing with such complexities. -
Engine behavior analysis on a conventional diesel engine combustion mode powered by low viscous cedarwood oil/waste cooking oil biodiesel/diesel fuel mixture An experimental study
Binary biofuel is the best alternative source that completely replaces petroleum-based fuel. In this study, we have experimented with the waste cooking oil and cedarwood oil as biofuel in a DI CI engine for various proportions and related its combustion, emission, and performance characteristics to those of base diesel. This study aims to eliminate the utilization of fossil fuel in a diesel engine by introducing green binary fuel (low viscous fuel resulting from the blending of cedarwood oil with WCO biodiesel) successfully. The objective of the study is to convert cedarwood WCO into green binary fuel and investigate its performance, emission, and combustion properties. The transesterification process is utilized for the enhancement of WCO as biodiesel. It occasioned a reduction in brake thermal efficiency as the addition of waste cooking oil in the blend increased. At the same time, the maximum value of BTE of 27.8% was attained for B10C90 (10% transesterified waste cooking oil and 90% cedarwood oil in volume), whereas it was 28.1% for diesel at maximum load conditions. The BSEC was 15.4 MJ/kW-hr for B10C90 and 12.8 MJ/kWhr for diesel. The emission characteristics, CO, HC, NOx, CO2, and smoke for B10C90 were 17.93 g/kWhr, 0.55 g/kWhr., 20.09 g/kWhr, 2210.9 g/kWhr, and 25.55%. Combustion features such as NHRR, burn duration, MPRR, combustion efficiency, Ignition delay, and coefficient of variance for B10C90 were 53.74 bar, 29.38 CAD, 4.71 bar/CAD, 99.7%, 7.01 CAD, and 4.73% respectively. It showed that B10C90 had comparable performance (BTE) and combustion values to mineral diesel with better emission characteristics. 2024 The Institution of Chemical Engineers -
Blockchain enabled energy efficient red deer algorithm based clustering protocol for pervasive wireless sensor networks
Energy efficiency and security are considered as important issues in the design of pervasive wireless networks. Since the nodes in pervasive wireless networks are battery-operated, it becomes essential to develop an energy-efficient method to minimize energy consumption and prolong the network lifetime. This paper presents new energy-efficient and secure clustering based data transmission in pervasive wireless networks using red deer algorithm (RDA) based clustering technique with blockchain enabled secured data transmission, named as RDAC-BC. The proposed RDAC-BC technique undergoes node initialization and performs the clustering process using the RDAC technique. The clustering technique performs cluster head (CH) selection and cluster construction process is carried out. Once the CHs are chosen, blockchain enabled secure data transmission takes place among cluster members (CMs) as well as CHs. The application of RDAC and blockchain technology helps to achieve energy efficiency and security. The experimental validation of the RDAC-BC technique is assessed under several aspects and the results are compared with existing methods. The obtained results ensured that the RDAC-BC technique has shown superior results interms of energy, network lifetime, packet delivery ratio (PDR), and throughput. 2020 Elsevier Inc. -
Jet-driven AGN feedback on molecular gas and low star-formation efficiency in a massive local spiral galaxy with a bright X-ray halo
It has long been suspected that powerful radio sources may lower the efficiency with which stars form from the molecular gas in their host galaxy, however so far, alternative mechanisms, in particular related to the stellar mass distribution in the massive bulges of their host galaxies, have not been ruled out. We present new, arcsecond-resolution Atacama Large Millimeter Array (ALMA) CO(1-0) interferometry, which probes the spatially resolved, cold molecular gas in the nearby (z=0.08), massive (Mstellar= 4 1011 M?), isolated, late-type spiral galaxy 2MASSX J23453269-044925, which is outstanding for having two pairs of powerful, giant radio jets, and a bright X-ray halo of hot circumgalactic gas. The molecular gas is in a massive (Mgas=2.0 1010 M?), 24 kpc wide, rapidly rotating ring, which is associated with the inner stellar disk. Broad (FWHM=70-180 km s-1) emission lines with complex profiles associated with the radio source are seen over large regions in the ring, indicating gas velocities that are high enough to keep the otherwise marginally Toomre-stable gas from fragmenting into gravitationally bound, star-forming clouds. About 1-2% of the jet kinetic energy is required to power these motions. Resolved star-formation rate surface densities derived from Galaxy Evolution Explorer and Wide-Field Infrared Survey Explorer fall by factors of 30-70 short of expectations from the standard Kennicutt-Schmidt law of star-forming galaxies, and near gas-rich early-type galaxies with signatures of star formation that are lowered by jet feedback. We argue that radio Active Galactic Nucleus (AGN) feedback is the only plausible mechanism to explain the low star-formation rates in this galaxy. Previous authors have already noted that the X-ray halo of J2345-0449 implies a baryon fraction that is close to the cosmic average, which is very high for a galaxy. We contrast this finding with other, equally massive, and equally baryon-rich spiral galaxies without prominent radio sources. Most of the baryons in these galaxies are in stars, not in the halos. We also discuss the implications of our results for our general understanding of AGN feedback in massive galaxies. N. P. H. Nesvadba et al. 2021. -
Footloose Culture: Migrant Workers and Cultural Meanings of Labour
[No abstract available] -
Fluorescent imidazole derived sensor for selective in vitro and in vivo Fe2+ detection and bioimaging in zebrafish with DFT studies
Herein, we have developed imidazole derivatized fluorescent probes IM-1 and IM-2 for extremely selective detection of Fe2+ with rapid response (LOD: 3.245 ?M for IM-1 and 0.297 ?M for IM-2) and excellent binding constants (0.214 105 M?1 and 1.004 105 M?1). Aqueous ethanol system was employed to assess the sensing potency of the probes both in vitro and in vivo in zebrafish is the main highlight of this work. The synthesized fluorophores possess admirable quantum yields of 0.61 and 0.78. The 1:1 binding mechanism of ligands with Fe2+ ions is supported by Job's plot and ESI-Mass spectrum. The synthesized probes demonstrated limited cytotoxicity both in vitro (MDA-MB-231 cells) and in vivo (zebrafish, Danio Rerio) studies. These results prompted us to employ the probes IM-1 and IM-2 to trace out intra cellular Fe2+ ions in zebrafish embryos. 2024 Elsevier B.V. -
Controlling RayleighBard Magnetoconvection in Newtonian Nanoliquids by Rotational, Gravitational and Temperature Modulations: A Comparative Study
The effect of three different types of time periodic modulations on the RayleighBard magnetic system involving Newtonian nanoliquids is studied. Multiple-scale analysis (homogenization method) is used to arrive at the GinzburgLandau equation. The curiosity in the work is to know the individual effects of (1) rotation, (2) gravity and (3) temperature modulations on RayleighBard magnetoconvection in weakly electrically conducting Newtonian nanoliquids. A significant effort in this research is devoted toward linear and nonlinear stability analyses as well as the homogenization method which leads to the GinzburgLandau evolution equation. Although several studies have concluded similar results for nanoliquids compared with those of pure base fluids, many fundamental issues like the choice of phenomenological models for the thermo-physical properties and the best type of nanoparticles are not well understood. This research focuses on several important issues involving mathematical and computational problems arising in heat transfer analysis in the presence of nanoliquids. Effects of various nanoliquid parameters, frequency and amplitude of modulation on heat transport are analyzed. This investigation focuses on five nanoliquids, with water as a carrier liquid and five nanoparticles, viz. copper, copper oxide, silver, alumina and titania. Enhanced heat transport was observed for rotation, gravity and temperature modulations. In the case of rotation modulation, it is found that increase in the amplitude of modulation results in a decrease in the critical Rayleigh number and thereby to an increase in the mean Nusselt number. The increase in the amplitude of the gravity modulation is shown to enhance the heat transport, whereas increase in frequency is to inhibit the heat transport. Two types of temperature modulations are considered, viz. in-phase (synchronous) and out-of-phase (asynchronous) temperature modulations with the assumption that the boundary temperatures vary sinusoidally with time. The amplitudes of modulation are considered to be very small. In the case of in-phase modulation, there is no significant difference between the heat transports in the presence and in the absence of temperature modulation. On this reason, out-of-phase temperature modulation is used to either enhance or diminish heat transport by suitably adjusting the frequency and phase difference of the modulated temperature. The effect of magnetic field, in all three cases of modulations, is to inhibit the onset of convection and thereby diminish the heat transport. 2022, King Fahd University of Petroleum & Minerals. -
A study on significance of cashback offered by online companies and its impact on customer preferences in online purchases
The emergence of e-commerce is redefining the entire business process across the word. This mode of doing business is presently being used in every industry and sale of all products. The retail industry has seen the major shift towards e commerce business model. With more and more customers opting for online purchases, a number of companies have entered into this sector. This had led to extreme competition in the market. The companies compete each other fiercely with sharp marketing tactics. The price based sales strategy is the one that attracts the customers more. The research study is being done to understand the significance of the cashback strategy used by online companies to generate more sales. The study will try to analyse the perception of the customers towards cashbacks and what are the factors related to cashbacks that attracts them. The findings will help the online companies in designing the best cashback model. The study has been carried out in Bangalore as it is one of the leading locations for online business. 2019, Institute of Advanced Scientific Research, Inc. All rights reserved. -
A study on the influence of sustainability related factors on the online purchase decisions of customers
The e-commerce business is growing at a tremendous rate in India. More and more customers prefer to buy for the online website due to the discounts, ease of purchase and the larger variety of products available. The e-retail companies majorly use discounts as major attraction to gain more customers. In this process of trying to increase the market share the sustainability factors are not given importance in various ways. This research paper tries to find if customers give importance to sustainability related factors and if these factors can be advertised by the e-retailers. The paper tries to find if this will have an impact on the customer purchase decisions from the e retailers. Then the e-retailers will have to have a different business strategy with sustainability factors included to attract more customers. 2019 SERSC. -
Skincare Products as Sources of Mutagenic Exposure to Infants: An Imperative Study Using a Battery of Microbial Bioassays
Infant skin is highly absorptive and sensitive to exposure from external agents (microbes, toxicants, heat, cold, etc.). Many specialized infant skincare products are currently commercially available. Although the manufacturers claim that their products are mild enough to suit the infant skin, these products need to be studied for their safety. Using animal models to examine the safety of the ever-increasing number of skincare products is not economically or logistically feasible. To overcome this problem, we suggest using a battery of microbial bioassays as a robust system for monitoring the mutagenic potential of skincare products. We picked popular infant skincare products from the Indian market and assessed them by using a battery of three microbial mutagenicity bioassays. Most of them showed significant and reproducible mutagenic potential. Our study results raise concerns about regular use of infant products and emphasize the need to enforce strict regulations for the manufacturing and safety assessment of infant products. 2021, The Author(s), under exclusive licence to Springer Science+Business Media, LLC part of Springer Nature. -
Assessment of mutagenicity caused by popular baby foods and baby plastic-ware products: An imperative study using microbial bioassays and migration analysis
Specialized products for infants have become every parent's first choice. Although these products claim to be safe and mild for infant use, yet there is a need to monitor them using different tools for mutagenicity detection to ensure further safety. In this study, a range of popular ready to eat and powdered baby foods, formula milk powders and attractive plasticware for infants were picked from the Indian market and tested for their mutagenicity using two microbial bioassays based on Salmonella typhimurium, viz., Ames bacterial reversion assay and fluctuation assay. Furthermore, chemical migration analysis was done on the most toxic baby food and baby plasticware samples as shown by the bioassays to detect possible leaching of Bisphenol a (BPA), lead and Di-2 ethyl hexyl phthalate (DEHP). It was surprising to find that the products made for the most risk-prone group in the society, i.e., infants have a significant potential to cause mutagenicity. 2018 Elsevier Inc. -
Gender Differences In Health Habits And Psychological Well- Being Among Early Adults
The concept of health is both complex and important. Health and its importance is one of the universally recognized concepts. The aim of the study was to explore the gender differences among early adults with regard to their health habits and their psychological well-being. Total sample consisted of 100 participants of whom 50 were men and 50 were women. The sampling technique used was random sampling. The age range was 18 -25 years. Health promoting lifestyle profile (HPLP), developed by Walker, Sechrist & Pender (1982). It includes both health-protecting (preventive) behaviors that decrease risk for illness and health-promoting behaviors that sustain or increase well-being, self-actualization and personal fulfillment. Health Behavior checklist was developed by the researcher to understand the patterns of health behavior on the dimensions of nutrition, physical activity, medical care, alcohol consumption, smoking and dieting and PGI General well Being Measure (PGI GWBM) Psychological well-being- PGI GWBM (English Version) by S.K Verma and A.Verma was used to assess the psychological wellbeing of early adults. This is a twenty item simplified test to measure positive mental health. Results showed that there are no gender differences in health habits among early adults. There were gender differences in psychological well-being among early adults. Correlation between health habits and psychological well-being was not observed. The results from the analysis of the checklist indicate some differences between men and women; more men were involved in external physical activity than women and women seemed to be not worried about their health and not visiting hospitals for checkups than men. Key words: gender differences, health habits, psychological well-being. -
A Study on the Influence of Geometric Transformations on Image Classification: A Case Study
The present research work involves the study of the geometrical transformations which influences the training and validation accuracies of machine learning models. For the study, rice plant leaf disease dataset of 2096 images consisting of 4 classes with 523 images per class were used. The dataset subjected to 24 models out of which three models namely - DenseNet201, Densenet169 and InceptionResNetV2 are selected based on highest training accuracy and less difference between training and validation accuracy. To evaluate the performance of the selected three models, loss functions and accuracies have been computed. 2021, The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. -
Emotional intelligence and self esteem in cannabis abusers
This study was taken up to investigate emotional intelligence and self esteem in cannabis abusers. Cross sectional hospital based study, Study is based on a sample of 200 individuals. 100 Cannabis dependent, diagnosed based on DSM-IV TR was selected from two different hospitals in north India. 100 healthy matched subjects constituted the control group. Assessment was done using MINI, General Health Questionnaire, Indian Adaptation of Emotional Intelligence Scale and Rosenberg Self Esteem Scale. Significant differences were seen in Emotional Intelligence between the Cannabis dependent group and normal control group. The cannabis dependent groups scored significantly low on emotional intelligence in comparison with control group. Further, cannabis dependent group scored significantly lower on score of self esteem than the normal control group. Relationship between emotional intelligence and self esteem was found to be positively correlated. Our study suggests an association between low emotional intelligence, low self esteem and cannabis dependence and the prevention and treatment of cannabis dependence should lay focus on these factors. Journal of the Indian Academy of Applied Psychology. -
Does fdi intensify economic growth? Evidence from china and India
[No abstract available] -
Twitter Sentiment Analysis and Emotion Detection Using NLTK and TextBlob
On an average, approximately 7000 tweets are communicated each second and in total it piles up to around 300 billion tweets every year. Society are free to contribute their opinions on public platform and hence it acts as a reliable interface to assess society ongoing viewpoint and attitude over any matter or event. Consumers very often make use of social media to exchange their views about anything. Business may get domain for enhancement and smooth interpretation of the behavior of people regarding various facts through opinion mining. Thus to carry out this mining of opinions on social media interface, textual categorization with language analysis is of great help. With the help of NLP token tool, phrases can be divided into various word series after dropping stop phrases. Larger tweets tokenizing and classifying into distinct labels is a concern. Thus, the main objective of this framework is to process the tweets based on specific keywords given by user, categorize these phrases into negative, positive and neutral ones. TextBlob module assists users and developers to interpret user sentiments about a news. This research tries to give suggestion a textual opinion assessment on social media samples utilizing the NLTK and TextBlob modules. 2023 IEEE. -
Sustainable Marketing Initiatives and Consumer Perception of Fast Fashion Brands
The fast fashion industry has been criticized for negatively impacting the economy, environment, and social justice. Consequently, many brands adopt sustainable marketing practices to promote eco-friendly manufacturing and encourage sustainable purchase behaviour. To explore this trend, a cross-sectional survey was conducted among fashion brand consumers using a quantitative research design. The survey data was analyzed using variance-based partial least squares-structural equation modelling (PLS-SEM). The results showed that sustainable marketing practices can be supported by creating a positive brand image and building trust. Such practices can positively influence consumers' perception of sustainability and promote brand loyalty, which can lead to sustainable purchasing behaviour. The study provides valuable insights into sustainable marketing strategies that fashion brands can adopt to promote sustainable practices and policies in local markets. 2024, idd3. All rights reserved. -
Fast Fashion Brands: Sustainable Marketing Practices and Consumer Purchase Behaviour; [Blagovne znamke hitre mode: trajnostne trne prakse in nakupovalno vedenje potronikov]
The fast fashion boom is faced with economic, environmental and social justice objections. Sustainable marketing initiatives have become a new style statement, and brands are shifting to environment-friendly manufacturing. This study explores how fashion apparel brands adopt sustainable marketing practices to promote sustainable purchase behaviour. A cross-sectional survey using a quantitative research design was followed to collect responses from fashion brand consumers. Variance-based partial least squares-structural equation modelling (PLS-SEM) was used to assess the hypothesized model. Two-step bootstrapping was conducted to explore the mediating role of brand perception in the relationship between sustainable marketing activity and brand loyalty. The study suggests that firms can support sustainable marketing practices by creating a brand image and building trust. This can influence consumers' perceptions of sustainability and promote brand loyalty. The study also emphasizes the significance of brand loyalty in developing sustainable purchase behaviour that endures over time. The study provides insights into sustainable marketing strategies and policies in indigenous markets. 2024, University of Ljubljana Press. All rights reserved.