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Electrochemical investigations of chitosan/ZrO2-Bi2O3 composite for advanced energy and environmental applications
Energy needs are on the rise, and the need for effective corrosion resistance measures are also vital to meet the requirements prevailing in society. A multifunctional Chitosan/ZrO2-Bi2O3 composite is synthesized, keeping electrochemical analysis of energy and environmental applications in mind. Various physicochemical methods confirm the impact of integrating ZrO2-Bi2O3 into chitosan, resulting in improved efficacy across applications. The electrocatalytic supercapacitance, hydrogen evolution reaction, and corrosion inhibition studies are carried out to evaluate the efficiency of the synthesized composite. The composite shows a specific capacitance of 636.5 F/g, ensuring the effective utility for supercapacitance applications. The lower overpotential of 135.2 mV is shown by the composite in the electrocatalytic hydrogen evolution reaction. The synthesized composite also shows 96.2 % efficacy in corrosion inhibition studies. The studies conducted demonstrate the increased effectiveness of chitosan when combined with bimetal oxide. The chitosan composite is therefore a competent catalyst for energy and environmental applications. 2024 Elsevier Ltd -
Electrochemical investigation of neodymium doped vanadium pentoxide anchored on reduced graphene oxide nanocomposites for hybrid symmetric capacitor devices
The modern world is highly dependent on portable electronic gadgets, so high-performance energy storage devices are a major demand for human beings. Here, we construct neodymium-doped vanadium pentoxide anchored with reduced graphene oxide nanocomposite (rGO/Nd:V2O5) as the electrode material for a high-performance symmetric capacitor device. The prepared electrodes showed pseudocapacitor behaviour and double layer capacitor behaviour, indicating the hybrid nature of the rGO/Nd:V2O5 electrode. Also, the V2O5, Nd:V2O5 and rGO/Nd:V2O5 electrodes show higher capacitance behaviour of 447, 677 and 1122 F/g at 1 A/g and 89 %, 94 % and 98 % cyclic efficiency at the 1000th cycle. However, the rGO/Nd:V2O5 symmetric capacitor device exhibits a higher capacitance value of 218 F/g at 1 A/g and a cyclic efficiency of 82 % at the 10000th cycle. Also, this electrode shows a low charge transfer resistance value of 12.67 ?. This result shows the prepared rGO/Nd:V2O5 electrode as the high-performance electrode material for the supercapacitor devices. 2023 Elsevier Ltd -
Electrochemical Hydrogenation of Organic Compounds: A Sustainable Approach
Conventional methods for hydrogenation of organic compounds generally use corrosive catalysts and reagents, along with extreme conditions like high temperatures and pressures. Quenching of corrosive materials does not deter its negative impact on the environment, nor is one safe when it comes to working with high temperature and pressure. Electrochemical hydrogenation (ECH) has proven to be safe and green since most of the efficient reactions are conducted at ambient pressure and temperature, minimizing, and sometimes even negating the use of toxic catalysts and corrosive reagents as compared to conventional methods. This review therefore provides different strategies used for ECH in the past, modification of different electrodes, half reactions taken up for efficient energy usage and catalysts used for different hydrogenation reactions. It presents the advances in electrochemical hydrogenation reactions of organic compounds, starting from simple aliphatic compounds to complex polyaromatics and heterocyclic aromatic compounds. 2023 Wiley-VCH GmbH. -
Electrochemical efficacies of coal derived nanocarbons
Carbon based nanomaterials are acknowledged for their admirable optical, electrical, mechanical characteristics and broad class of applications. Choice of precursor and simple synthesis techniques have decisive roles in viable production and commercialization of carbon produce. The intense demand to develop high purity carbon nanomaterials through inexpensive techniques has promoted usage of fossil derivatives as feasible source of carbon. Coal serves as a naturally available, abundant and cheap feedstock for carbon materials. From the crystalline clusters of aromatic hydrocarbons in a cross-linked network, carbon nanostructures can easily be extracted through green synthesis routes. It promotes a potent alternative for the cost effective and scaled up production of nanocarbon. The well-developed pores distribution, presence of numerous active sites and appropriate migration channels for ions enhance the electrochemical parameters necessary for the fabrication of supercapacitors, batteries and electrochemical sensors. The metallic impurities contained in coal contribute towards faradic redox reactions required for an efficient electrode modification. In this review, the potential uses of coal based carbon nanomaterials in energy storage and environmental sectors are discussed in detail. 2020, The Author(s). -
Electrochemical determination of Vitamin B6 using coral-like MnO2-Pi on Ti3C2Tx MXene
MXenes are 2D nanomaterials that are considered the materials of the future generation due to their high electrical conductivity, good biocompatibility, and ease of functionalization. This research work reports the electrochemical sensing of Vitamin B6 using the Manganese dioxide-inorganic phosphate/MXene brush-coated Carbon fiber paper electrode (MnO2-Pi/MXene/CFP) electrode for the first time. The three-dimensional Ti3C2Tx MXene nanosheets consisting of highly ordered, vertically aligned nanosheets with electrochemically deposited MnO2-Pi are capable of yielding a synergistic effect in combination with high electrochemical performance and large surface area of MnO2-Pi. The reported electrochemical sensor exhibited a wide linear dynamic range (0.06650 M) and a low-level detection limit of 0.021 M. An increase in the anodic peak current confirms the rapid transfer of electrons transfer arising between the Ti3C2Tx MXene and MnO2-Pi. The results attained substantiate that the fabricated sensor has enhanced selectivity, reproducibility, and stability toward the electrochemical determination of Vitamin B6 in real samples. 2023 Elsevier Ltd -
Electrochemical deposition for metal organic Frameworks: Advanced Energy, Catalysis, sensing and separation applications
The advent of metalorganic frameworks has gathered ever-increasing attention owing to their versatility, unparalleled porosity, tuneability, and rich topography. The need for an efficient synthetic method and the trending appeal for thin film MOFs has brought in huge data on electrochemical deposition techniques. Thin films have immense applications in the field of electronics (including energy devices such as batteries and supercapacitors), sensors, catalysis, and as liquid/gas separation devices. Here, the electrodeposition method requires no pre-treatment step, allows miniaturization, a homogeneous film with desirable thickness, and is observed to be an eco-friendly method. The limited number of articles focusing on the supremacy of the technique has motivated the authors to collectively summarize the scattered data. To limit the discussion to reasonable bounds, the article focuses on a critical comparison of electrodeposition techniques with other synthetic methods, and different types of electrodeposition methods, and familiarize them with the various electrodeposited MOF-composite designs. Finally, we discuss extensively the existing as well as future applications. This will encourage future researchers to exploit this electrochemical technique for designing & developing newer MOF films and similar next-generation materials which are energy-efficient, rapid, and accurate while in use. This review article hopes to list out significant advances in the area to the advantage of both commercial and academic aspects. 2023 Elsevier B.V. -
Electrochemical characteristics of Co3O4 nanoparticles synthesized via the hydrothermal approach for supercapacitor applications
Cobalt oxide (Co3O4), a transition metal oxide known for its favourable capacitive properties and surface characteristics, is a promising candidate for electrode materials in supercapacitive energy storage applications. This study presents a comprehensive analysis of cobalt oxide nanoparticles synthesized through the hydrothermal method at varying synthesis temperatures, focusing on their structural, optical, electrochemical, and surface properties. X-ray diffraction analysis confirmed the cubic spinel structure of Co3O4, while Raman spectroscopy verified the phase composition of the nanoparticles. X-ray photoelectron spectroscopy offered insights into the near-surface chemistry of the synthesized material. The study determined two direct bandgaps of Co3O4 through absorption spectra and Tauc plots. To assess surface morphology and particle size distribution, field-emitting scanning electron microscopy and transmission electron microscopy were employed. Electrochemical investigations involved cyclic voltammetry and Nyquist plots, while galvanostatic chargedischarge tests demonstrated a specific capacitance (Csp) of 450 Fg?1 at 1 Ag?1. Impedance analysis indicated favourable capacitive behaviour with low charge transfer resistance. Furthermore, the study observed cyclic stability with a capacitive retention rate exceeding 88% at a current density of 20 Ag?1 over 10,000 cycles. The paper also discusses the capacitive and diffusion-controlled charge storage mechanisms at lower scan rates, emphasizing the potential of Co3O4 nanoparticles as the electrode material in the development of supercapacitor devices. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. -
Electrochemical behavior of cast and forged aluminum based in-situ metal matrix composites
The present work focuses on the electrochemical behaviour of Al6061 alloy and Al6061-TiB 2 in-situ metal matrix composites. Al6061-TiB 2 in-situ Composites were synthesized by a stir casting route at a temperature of 860C using potassium hexafluorotitanate (K 2 TiF 6 ) and potassium tetrafluoroborate (KBF 4 ) halide salts. Percentage of TiB 2 was kept at 0 wt% and 10wt%. The cast Al6061 alloy and Al6061-TiB 2 composites (0wt% &10wt %) were subjected to open die hot forging process at a temperature of 500C. Both cast and forged Al6061 alloy and its composites were subjected to micro-structural and electrochemical characterization. Corrosion behaviour of alloy and composites in both cast and forged conditions were evaluated using electrochemical impedance spectroscopy and the results were backed up by a potentiodynamic polarization test. Results indicate that addition of TiB 2 particles increases the corrosion rate and reduces the polarization resistance of aluminium alloy in both cast and forged condition owing to galvanic coupling between the reinforcements and base metal. Further, when compared with cast alloy and its composites, forged alloy and its composites exhibited poor corrosion resistance under identical test conditions. 2019 Author(s). -
Electrocatalytic oxidation of morin on electrodeposited Ir-PEDOT nanograins
Nanoclusters of Ir were electrochemically deposited on carbon fiber paper (CFP) substrate modified with poly(3,4-ethylenedioxythiophene) (PEDOT), a conducting polymer between the potential range 0.0 V and 0.6 V at 0.05 V/s scan rate. The electrocatalytic activity of IrPEDOT/CFP electrode towards oxidation of morin, a flavonoid was significantly greater than that of PEDOT/CFP and bare CFP electrodes. Factors affecting the anodic peak of morin namely, effect of pH, scan rate and number of cycles were optimized. The electrochemical route involved adsorption controlled and irreversible processes. Under optimal conditions, the linear dynamic range for the determination of morin was found to be 0.12 nM2.80 nM. The significantly low detection limit (42.18 pM) demonstrates the ultrasensitivity of the proposed method. The reliability of the method was evaluated for the quantification of morin present in mulberry leaves, guava leaves and grape wine. 2018 Elsevier Ltd -
Electrocatalytic oxidation and determination of morin at a poly(2,5-dimercapto-1,3,4-thiadiazole) modified carbon fiber paper electrode
Voltammetric determination of morin on carbon fiber paper (CFP) electrode modified by electropolymerization of 2,5-dimercapto- 1,3,4-thiadiazole (DMTD) in phosphate buffer solution (PB, pH 9.0) have been studied. This modified electrode showed strong electrocatalytic activity toward the oxidation of morin, a flavonoid at physiological pH (PB, pH 7.0). Morin gave a sensitive anodic peak at 0.245 V (vs. SCE). The parameters influencing the anodic peak of morin such as effect of pH, effect of scan rate and concentration have been optimized. The electrochemical process was found to be irreversible and adsorption-controlled. Under the optimum conditions, the anodic peak current was linear to concentration of morin in the range of 2.5 10-10-2.75 109 M and detection limit was found to be 8.3 10-11 M. The practical application of the modified electrode was successfully demonstrated for the determination of morin in mulberry leaves. 2016 The Electrochemical Society. All rights reserved. -
Electrocatalytic oxidation and determination of morin at a poly (2,5-dimercapto-1,3,4-thiadiazole) modified carbon fiber paper electrode /
Journal Of The Electrochemical Society, Vol.163, Issue 8, ISSN:0013-4651 (print) 1945-7111 (web). -
Electro-sprayed Quaternary Composite of Poly(aniline-co-pyrrole), Graphene Oxide, and Iron Oxide as an Efficient Electrode for Hybrid Supercapacitor Application
Abstract: A novel quaternary nanocomposite has been developed using a cost-effective and user-friendly method called electro-spraying. This composite consists of poly(aniline-co-pyrrole), Graphene Oxide (GO), and Iron Oxide (Fe3O4), aimed at achieving improved electrochemical stability and performance. The composite electrodes displayed an impressive specific capacitance of 950 Fg1 at a current density of 0.5 Ag1 when tested in a 1 M H2SO4 solution. Furthermore, even after 2000 cycles at a current density of 1 Ag1, the electrode exhibited an outstanding capacitance retention rate of 91%, showcasing its remarkable stability and long-lasting performance. These exceptional properties can be attributed to the synergistic effects arising from the combination of the conducting polymer, metal oxide, and graphene oxide components within the electrode material. Additionally, significant advancements in other electrochemical properties make this nanocomposite a promising candidate for use as an electrode material in supercapacitors. Pleiades Publishing, Ltd. 2024. -
Electro-osmotic effect on the three-layer flow of Binary nanoliquid between two concentric cylinders
The three-layer flow of an immiscible nanoliquid in composite annulus with an electro-kinetic effect is analyzed using Buongiornos model. This model helps in analyzing the impact of two major phenomena, namely thermophoresis and Brownian motion. In this model, an interfacial layer is formed between the liquids due to the immiscibility of the base liquids. The use of a multilayer model especially in cooling systems brings more applications in many industries such as nuclear, biomedical, and solar. Different from the earlier studies on multilayer channel flow, this paper explains the three-layer flow between two concentric cylinders in the presence of cross-diffusion which makes the work unique. Further, the middle region is assumed to be porous and heat source or sink is applied to the entire system. Also, the flux conservation condition for nanoparticle volume fraction is considered. The equations governing the problem are simplified and are solved using the differential transform method. The results indicate that the electroosmotic parameter enhances the velocity but reduces the electrostatic potential. Further, the diffusion ratio improves the temperature and decreases the solute concentration of the fluid. 2022, Akadiai Kiad Budapest, Hungary. -
Electro fabrication of molecularly imprinted sensor based on Pd nanoparticles decorated poly-(3 thiophene acetic acid) for progesterone detection /
Electrochimica Acta, Vol.408, ISSN No: 0013-4686.
In recent years, scientific community has witnessed substantial interest in the design and engineering of electrodes as sensing platforms towards sensitive and selective detection of hormones. An electrochemical strategy for the detection of progesterone was proposed by generating a composite film comprising of palladium nanoparticles with 3-thiophene acetic acid (3-TAA) coupled with molecular imprinting technology. Progesterone molecule was employed as the template while generating molecular imprints by electropolymerization on the surface of the Carbon Fibre Paper (CFP) electrode. Electrochemical impedance spectroscopy (EIS) and cyclic voltammetry were used to analyse the various modified working electrodes (CV). -
Electro fabrication of molecularly imprinted sensor based on Pd nanoparticles decorated poly-(3 thiophene acetic acid) for progesterone detection
In recent years, scientific community has witnessed substantial interest in the design and engineering of electrodes as sensing platforms towards sensitive and selective detection of hormones. An electrochemical strategy for the detection of progesterone was proposed by generating a composite film comprising of palladium nanoparticles with 3-thiophene acetic acid (3-TAA) coupled with molecular imprinting technology. Progesterone molecule was employed as the template while generating molecular imprints by electropolymerization on the surface of the Carbon Fibre Paper (CFP) electrode. Electrochemical impedance spectroscopy (EIS) and cyclic voltammetry were used to analyse the various modified working electrodes (CV). Characterization methods included field emission scanning microscopy, energy dispersive X-ray spectrometry, optical profilometry, and X-ray photon electron spectroscopy. Pd nanoparticles resulted in enhanced sensitivity and molecular imprinting technology contributed to its specificity. Because of the molecular cavities created on the removal of the template molecule, Nyquist plots data showed that the MIP/Pd/CFP electrode had the lowest charge transfer resistance compared to other control electrodes. 2022 Elsevier Ltd -
Electrically small S-band antenna for cubesat applications
This research paper deals with the design and development of a circularly polarized S-band rectangular patch antenna providing performance suitable for application in CubeSat. A CubeSat is a type of miniaturized satellite used primarily by university research groups for demonstration of technology. They are low earth orbiting sun-synchronous (LEOSS) type of satellites. The design protocol specifies maximum outer dimensions equal to 100 mm00 mm00 mm and weighing a mass between 1.3-6 kg. However, being small in size, they pose some challenges such as low profile antenna, possibility for cross-link communication with other similar satellites and high reliability of communication in a swarm without the prior knowledge of their positions. Additionally CubeSats dictate the space limitation for placing the antenna within it. With all these, it also requires small antenna with high gain and wide directivity. The most suitable antennas that address most of the aforementioned challenges are planar antennas. The design and simulation of the proposed design of electrically small sband antenna for CubeSat achieves gain of 5.01 dBi with a narrow bandwidth of 100 MHz. The analysis is performed using MATLAB and HFSS (High Frequency Structural Simulator). 2017 IEEE. -
Electrical transport and magnetoresistance studies on the magnetic moment compensated Mn2V1-xCoxZ (Z=Ga, Al; x=0, 0.25, 0.5, 0.75, 1) Heusler alloys
We report the electrical resistivity and magnetoresistance properties of arc-melted Mn2V1-xCoxZ (Z=Ga, Al; x =0, 0.25, 0.5, 0.75, 1) alloys, which possess compensated ferrimagnetic behaviour with high TC when x=0.5. Apart from metallicity, the alloys in the Ga series with x= 0, 0.75, 1 composition showed a positive to negative crossover in the magnetoresistance versus temperature curves. This crossover was absent for Mn2V0.75Co0.25Ga and the fully compensated ferrimagnet Mn2V0.5Co0.5Ga. In contrast to this, Co-substituted Mn2VAl exhibits distinctly different resistive behaviour. While the alloys Mn2VAl and Mn2CoAl exhibit metallic and semiconducting behaviour respectively, the intermediate compositions show a gradual metallic to semiconducting transition as the Co concentration increases. The compensated ferrimagnet Mn2V0.5Co0.5Al showed a mixed transport behaviour of metallic and semiconducting nature with a resistivity minimum at 140 K. In contrast to this mixed response of the arc-melted bulk sample, the Mn2V0.5Co0.5Al melt-spun ribbon shows a clear semiconducting nature throughout the temperature range, indicating that the sample preparation methods could highly influence the electrical properties of the investigated compensated ferrimagnets. 2024 Elsevier B.V. -
Electrical and mechanical properties of vapour grown gallium monotelluride crystals
The physical vapour deposition (PVD) of gallium monotelluride (GaTe) in different crystalline habits was established in the growth ampoule, strongly depending on the temperature gradient. Proper control on the temperatures of source and growth zones in an indigenously fabricated dual zone furnace could yield the crystals in the form of whiskers and spherulites. Optical and electron microscopic images were examined to predict the growth mechanism of morphologies. The structural parameters of the grown spherulites were determined by X-ray powder diffraction (XRD). The stoichiometric composition of these crystals was confirmed using energy dispersive analysis by X-rays (EDAX). The type and nature of electrical conductivity were identified by the conventional hot probe and two probe methods, respectively. The mechanical parameters, such as Vickers microhardness, work hardening index, and yield strength, were deduced from microindentation measurements. The results show that the vapour grown p-GaTe crystals exhibit novel physical properties, which make them suitable for device applications. 2013 University of Science and Technology Beijing and Springer-Verlag Berlin Heidelberg. -
Electrical and Mechanical Properties of Vapour Grown Gallium Monotelluride Crystals
International Journal of Minerals, Metallurgy and Materials, Vol-20 (10), pp. 967-971. ISSN-1674-4799 -
Electric Vehicle Traction Motor Hardware in Loop (HIL) Regulation for Adaptive Cruise Control Scenario
This paper aims at developing a adaptive cruise control system using model predictive algorithm which operates on a Software-in- loop system. The vehicle modelling performed in IPG Car Maker operates with a Matlab based Model Predictive Controller at the back end. The Model Predictive Controller works on the relative distance between the leader vehicle and the ego vehicle. The primary focus is on optimizing the ACC performance to enhance energy efficiency, taking into account the specific dynamics of electric power trains. The study places particular emphasis on the integration of IPG Car Maker software to provide a realistic and dynamic simulation environment, enabling the evaluation of the proposed ACC-MPC system under an urban driving scenario and environmental conditions. 2024 IEEE.