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The Renaissance of Ferrocene-Based Electrocatalysts: Properties, Synthesis Strategies, and Applications
The fascinating electrochemical properties of the redox-active compound ferrocene have inspired researchers across the globe to develop ferrocene-based electrocatalysts for a wide variety of applications. Advantages including excellent chemical and thermal stability, solubility in organic solvents, a pair of stable redox states, rapid electron transfer, and nontoxic nature improve its utility in various electrochemical applications. The use of ferrocene-based electrocatalysts enables control over the intrinsic properties and electroactive sites at the surface of the electrode to achieve specific electrochemical activities. Ferrocene and its derivatives can function as a potential redox medium that promotes electron transfer rates, thereby enhancing the reaction kinetics and electrochemical responses of the device. The outstanding electrocatalytic activity of ferrocene-based compounds at lower operating potentials enhances the specificity and sensitivity of reactions and also amplifies the response signals. Owing to their versatile redox chemistry and catalytic activities, ferrocene-based electrocatalysts are widely employed in various energy-related systems, molecular machines, and agricultural, biological, medicinal, and sensing applications. This review highlights the importance of ferrocene-based electrocatalysts, with emphasis on their properties, synthesis strategies for obtaining different ferrocene-based compounds, and their electrochemical applications. 2023, The Author(s), under exclusive licence to Springer Nature Switzerland AG. -
The Renaissance of Electro-Organic Synthesis for the Difunctionalization of Alkenes and Alkynes: A Sustainable Approach
Electro-organic reactions are now considered as one of the most efficient and environmentally benign methodologies to synthesize highly functionalized motifs like difunctionalized unsaturated compounds from readily available substrates. Excellent regioselectivity, functional group tolerance and broad range of substrates are the main advantages of electrochemical difunctionalization reactions. Alkenes and alkynes readily accept radical or ionic derivatives which makes it vital precursors for the electrochemical synthesis of industrially relevant and biologically active molecules through difunctionalization. This review aims to provide the readers an excellent coverage of the different electrochemical difunctionalization of alkenes and alkynes such as 1,2-homodifunctionalization, 1,2-heterodifunctionalization, rearrangement, ipso-migration, cyclization and dehydrogenative annulation reactions. 2021 Wiley-VCH GmbH -
The relationship of workplace flexibility to employee engagement among information technology employees in India
Historically, organizations have been provisioning flexible work arrangement (FWA) options in the workplace to help employees achieve a balance between work obligations and private obligations. We explore the utilization of FWA offerings in the Indian information technology (IT) industry and its relation to employee engagement (EE). Employees working in IT organizations in Bengaluru, India, were approached and data were obtained from 504 participants. The study found that availability of FWA options coincided with their utilization. Disconcertingly, only 7 per cent of the employees were highly engaged, 51 per cent were neither engaged nor disengaged and 41 per cent of the employees were disengaged with their current organization. FWAs were positively related to EE. We find congruence that FWA options lead to better EE warranting further exploration that can guide FWA policies. 2018 SAGE Publications India Private Limited. -
The relationship between density of drug outlets, crime hot spots and family factors on the consumption of drugs and delinquent behaviour of male adolescent Mexican students
This study examined the relationship between community risk factors (drug outlets density and crime hot spots) and family factors on the risk behaviours (drugs consumption and delinquent behaviour) of male adolescent Mexican students. Results were obtained based on data bank analysis and direct collection of information regarding family factors and risk behaviours of adolescents attending school. Spatial and statistical analysis was performed. The final sample was composed of 1450 male adolescents, from 11 secondary and high schools located in marginal and violent areas of Mexico. Spatial analysis revealed that when considering only the prevalence of the risk behaviours of the adolescents, the area of highest risk was the northwestern area of the city. However, after performing conjunct analysis of all evaluated variables using density point risk (aside from confirming that the northwestern area is still the one with the greatest risk), results indicated that the southern area has a high-density point risk. All densities of the variables showed a statistically significant positive association (p < 0.05). However, the results of the structural equation model indicated than only the family factors influenced the risk behaviours of adolescents (p < 0.05). The spatial distribution of the risk behaviours in male adolescent students and community risk variables surrounding the area where schools are located allows for the description of patterns and hotspot detection that facilitate the prioritization of where interventions must be directed. Besides, the interventions should target family factors. 2021 Elsevier Ltd -
The Relationship between Assertiveness and Decision Making Styles among Emerging Adults
Emerging adulthood, the prolonged years from late teens through twenties marked by change and exploration before arriving at enduring life choices is becoming a normative period for young people worldwide. Past researches have described the emerging adults to be optimistic, assertive, self confident and making independent and effective decisions at the same time as miserable and indecisive. Lack of coherence in the conception about this new and distinct period in human development, the likelihood that it is pervading Indian culture and significance of this stage make it an important area to be explored. Hence, the current study investigates the relationship between assertiveness and decision making styles of emerging adults and attempts to identify the gender differences in their assertiveness and decision making styles.The Melbourne Decision Making Questionnaire that measures self-reported decision making coping patterns and Rathus Assertiveness schedule that assesses self reported assertiveness level were administered to 1209 (Male, N = 581; Female, N= 628) undergraduate and post graduate students who were in the age range of 18-25 from five colleges in the city of Bangalore. The results of one way analysis of variance shows that decision making styles do have an influence on assertiveness such that assertiveness is significantly different for vigilance and buck-passing; vigilance and procrastination; vigilance and hyper-vigilance; buck-passing and procrastination and buck-passing and hyper-vigilance. Assertiveness was not significantly different for procrastination and hyper-vigilance. The emerging adults with vigilant style found to be more assertive than those with other decision making styles. 69% of the total sample had vigilant decision making style which is considered to be the effective coping style while only 31% had maladaptive coping styles like buck-passing (10%), procrastination (10%) and Hyper-vigilance (11%). A multiple regression results indicates that decision making style and assertiveness are moderately correlated (R=0.661); decision making style can predict assertiveness with a 0.661 accuracy level and that this value is significant at the 0.01 level of significance and that decision making style explains 43.7% of the variance in assertiveness (R2=0.437). No statistically significant gender differences were found in assertiveness and decision making styles. The study reveals that emerging adults choice and the frequency of usage of decision making style indicate the individual differences like assertiveness. It is recommended that existing literature on the decision making style and assertiveness can be enhanced with additional research that further examines the relationships among these constructs with a sample of emerging adults from different social, economic, cultural and academic background, adopting both qualitative and quantitative methods to reduce the sampling error and weaknesses of self report measures. In line with the findings obtained from the research, a training programme for improving decision making styles like assertiveness skill training could be developed even in educational settings. The results have implications for professionals working with university-aged individuals, particularly in the area of career and guidance and making stressful personal decisions with regard to life. Key Words: Emerging adults, Decision-Making Styles, vigilance, buck-passing, procrastination, hyper-vigilance, Assertiveness -
The red terror and a state of uncertainty: United Nations' role In the Indian maoist struggle
In this paper, the authors argue that the long drawn armed conflict between the Maoists and the Indian State has acquired the status of a non-international armed conflict due to the organized nature of the Maoists and the scale of violence arising out of the conflict. The systematic human rights abuses by both parties and forceful displacement of civilians is a tangible threat to international peace and security in the region. In light of the deadlock between the parties, the authors make a case for United Nations' intervention in mediating an end to the conflict and restoring peace and security in the region. Drawing inspiration from the role played by the UN in ending civil wars across the globe, this paper argues for a similar intervention in the non-international armed conflict in India. The authors argue that the UN should venture to exert pressure on the State to eliminate any further abuses of human rights, and remove the impasse between both the parties to facilitate a constructive dialogue. Copyright 2012 De Gruyter. All rights reserved. -
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The reality of distribution faced by SMEs: A UK perspective
[No abstract available] -
The realist approach for evaluation of computational intelligence in software engineering
Secured software development must employ a security mindset across software engineering practices. Software security must be considered during the requirements phase so that it is included throughout the development phase. Do the requirements gathering team get the proper input from the technical team? This paper unearths some of the data sources buried within software development phases and describes the potential approaches to understand them. Concepts such as machine learning and deep learning are explored to understand the data sources and explore how these learnings can be provided to the requirements gathering team. This knowledge system will help bring objectivity in the conversations between the requirements gathering team and the customer's business team. A literature review is also done to secure requirements management and identify the possible gaps in providing future research direction to enhance our understanding. Feature engineering in the landscape of software development is explored to understand the data sources. Experts offer their insight on the root cause of the lack of security focus in requirements gathering practices. The core theme is statistical modeling of all the software artifacts that hold information related to the software development life cycle. Strengthening of some traditional methods like threat modeling is also a key area explored. Subjectivity involved in these approaches can be made more objective. 2021, The Author(s), under exclusive licence to Springer-Verlag London Ltd. part of Springer Nature. -
The Rayleigh-Bard problem for water with maximum density effects
Linear stability and weakly nonlinear stability analyses are developed for Rayleigh-Bard convection in water near 3.98 C subject to isothermal boundary conditions. The density-temperature relationship (equation of state) is approximated by a cubic polynomial, including linear, quadratic, and cubic terms. The continuity equation, the Navier-Stokes momentum equation, the equation of state, and the energy equation constitute the governing system. Linear stability analysis is used to investigate how the maximum density property of water affects the onset of convective instability and the choice of unstable wave number for four different types of boundary conditions. Then, a weakly nonlinear stability study is done using the spectral Fourier method for isothermal tangential stress-free boundary conditions to quantify the heat transport of the system and demonstrate the transition from regular/periodic convection to chaotic convection. A Stuart-Ginzburg-Landau equation is obtained using the multiscale expansion method. Streamlines and isotherms are presented and analyzed. The influence of maximum density has been shown to delay the onset of instability and is, therefore, a stabilizing mechanism for thermal instability. Due to the maximum density, the onset of chaotic convection is also delayed. Among four different boundaries, the impermeable rigid boundaries require the highest Rayleigh number for instability to begin. Increasing boundary temperatures advance the onset of chaotic convection and improve the heat transport situation. 2023 Author(s). -
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The quantum key distribution, attenuation and data loss over foggy, misty and humid environment
The quantum encryption is a method of key transfer in cryptography by using quantum entanglement of photons. The real power of quantum entanglement is instantaneous communication that is non interceptable. The advantage of quantum encryption method is, it can be incorporated with conventional encryption methods safely. The quantum cryptography can replace conventional key exchange mechanism with the polarized photons using channels like optic fiber cables. Quantum cryptographic can also provide far and secure data communication. The present day experiments clearly proved that the quantum cryptography can be implemented through medium like optic fiber cable or air. But the distance of transmission through the air is limited by rule of line of sight propagation. The quantum key distribution will have uses in different types of communication between distant parts of earth. So this paper discussing various aspects of Quantum key distribution and successfully calculated polarized photon loss during transmission of Quantum cryptography link, while using in various type of atmospheric conditions like Mist Fog Haze. Also successfully calculated probability of single polarized photon missing by successfully utilizing the Light transmission characteristics and power measurements in various Atmospheric conditions. 2019, Institute of Advanced Scientific Research, Inc.. All rights reserved. -
The Quantification of Human Facial Expression Using Trapezoidal Fuzzy Membership Function
Fuzzy Inference System is an interesting approach. Major benefit of the FIS is, it permits the natural narration in linguistic terms of tribulations that can be resolved rather than in requisites of associations between accurate arithmetical points. This helps, handling with the complicated systems in easy way, is the major motive why fuzzy system is broadly incorporated in practice. In the present research paper, an effective approach is proposed that quantifies the human facial expression using Mamdani implication based fuzzy logic system. The recent principle engages in retrieving arithmetical values from persons face and feed them to a fuzzy classifier. Fuzzification and Defuzzification process issues trapezoidal fuzzy membership function for input as well as output. The diverse characteristic of this method is its effortlessness and maximum correctness. Experimental outcome on Image dataset depicts excellent accomplishment of the proposed methodology. In this paper, a legitimate procedure proposed for quantification of human facial expression from the features of the face by means of Mamdani type fuzzy inference system, which is proficient to set up a convenient membership association involving the various dimensions of the happy expression. Values representing features of the face are fed to a Mamdani-type fuzzy classifier. This system recognizes three levels of same happy expression namely Normal, Bit Smiley and Loud Laugh. The total output expressions for this proposed scheme is three. Another discrete element of the proposed methodology is the membership method model of expression outcome which stands on various surveys and readings of psychology. Springer Nature Singapore Pte Ltd. 2019. -
The QSPR study of butane derivatives: (A mathematical approach)
The QSPR analysis provides a significant structural insight into the physiochemical properties of butane derivatives. We study some physiochemical properties of fourteen butane derivatives and develop a QSPR model using four topological indices and butane derivatives. Here we analyze how closely the topological indices are related to the physiochemical properties of butane derivatives. For this we compute analytically the topological indices of butane derivatives and plot the graphs between each of these topological indices to the properties of butane derivatives using Origin. This QSPR model exhibits a close correlation between Heavy atomic count, Complexity, Hydrogen bond acceptor count, and Surface tension of butane derivatives with the Redefined first Zagreb index, the Redefined third Zagreb index, the Sum connectivity index and the Reformulated first Zagreb index, respectively. 2018 Oriental Scientific Publishing Company. All Rights Reserved. -
The puzzle of pheromones in nature and their mysterious influence: a comprehensive review
Pheromones are chemical signals that are given off by creatures to communicate with other conspecifics. Because of their influence on animal behavior and relationships throughout the animal world, pheromones have fascinated scientists for decades. The newest findings and new perspectives on the intriguing field of pheromones are synthesized in this thorough review article. We investigate the many roles played by pheromones, from mating attraction and territorial marking to alarm signaling and social organization. The chemical diversity of pheromones is explored in depth in this paper, highlighting the variety of substances used by different animals as messengers. We go over the processes involved in pheromone detection and processing to help understand how chemosensory receptors and brain circuits interact in complex ways. Additionally, we discuss the role that pheromones play in ecology and evolution by promoting speciation and adaptation. This review emphasizes both the new research on pheromones in humans as well as their function in the animal world. We investigate the data supporting human pheromones and their possible impact on social and reproductive behaviors. The review aims to offer a detailed exploration and insight into the role and effects of pheromones in the natural world. This includes examining the chemical essence of pheromones and their functionality as communication signals across different species, investigating the specificity of these chemicals to certain species and how non-specific pheromones come about, and delving into the evolution of pheromones with a focus on the physiological and evolutionary mechanisms that drive communication. Additionally, the review seeks to understand the role pheromones play in pest management, specifically how species-specific pheromones can be utilized in eco-friendly pest control strategies. It will also explore the enigmatic impact pheromones have on the behavior and interactions within and among species. Drawing from a variety of sources, such as scientific research articles, studies on pheromone evolution, and articles on pheromone application in pest management, the review aspires to synthesize existing knowledge to provide a comprehensive overview of pheromones and their intriguing influence in nature. This study intends to not only summarize existing information but also encourage further research, shedding light on these cryptic chemical signals and their tremendous influence on the biology and behavior of species. It does this by offering a comprehensive perspective on the complex world of pheromones. 2024 Mighila Rixon, et al. -
The Puzzle of Hereditary Spastic Paraplegia: From Epidemiology to Treatment
Inherited neurodegenerative pathology characterized by lower muscle tone and increasing spasticity in the lower limbs is termed hereditary spastic paraplegia (HSP). HSP is associated with changes in about 80 genes and their products involved in various biochemical pathways, such as lipid droplet formation, endoplasmic reticulum shaping, axon transport, endosome trafficking, and mitochondrial function. With the inheritance patterns of autosomal dominant, autosomal recessive, X-linked recessive, and mitochondrial inheritance, HSP is prevalent around the globe at a rate of 15 cases in every 100,000 individuals. Recent technology and medical interventions somewhat aid in recognizing and managing the malaise. However, HSP still lacks an appropriate and adequate therapeutic approach. Current therapies are based on the clinical manifestations observed in the patients, for example, smoothing the relaxant spastic muscle and physiotherapies. The limited clinical trial studies contribute to the absence of specific pharmaceuticals for HSPs. Our current work briefly explains the causative genes, epidemiology, underlying mechanism, and the management approach undertaken to date. We have also mentioned the latest approved drugs to summarise the available knowledge on therapeutic strategies for HSP. 2022 by the authors. -
The Problem of Perception in Sandor Mais Embers: An Advaitic Study
This article attempts to study the problem of perception in Sandor Mais celebrated novel Embers from the standpoint of the pramana (a method of knowledge) of Advaita Vedanta. An epistemic problem, the problem of perception, concerns the overwhelming questions of life, culminating in an enigmatic amalgamation of dilemmas and paradoxes. Genuine dilemmas and paradoxes problematize human relationships, which is evident in the complex narrative of Embers. Our contention in this article is to show how, even though enacted within the periphery of the purely fictional, Embers bears testimony to the complexities of life that are quickened by the limits of human perception, which keeps one from seeing how things really are by creating a shadow or reflected consciousness. Set against the backdrop of the Austro-Hungarian Empire, the novel opens up a dialogic space at the intersection of a triangular relationship enacted on the threshold of perception and its multidimensional problems. 2024 Management Centre for Human Values. -
The Preservative Technology in the Inventory Model for the Deteriorating Items with Weibull Deterioration Rate
An EOQ model for perishable items is presented in this study. The deterioration rate is controlled by preservative technology. This technology only enhances the life of perishable items. So, retailers invested in this technology to get extra revenue. The Weibull deterioration rate is considered for the ramp type demand. Shortages consider partially backlogged, and discount is provided to loyal customers. The concavity of the profit function is discussed analytically. Numerical examples support the solution procedure; then, Sensitivity analysis is applied to accomplish the most sensitive variable. 2021, The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. -
The presence of others increases prosociality: examining the role of dating Partners accompany on donation
Research in the field of prosocial behavior has shown that the presence of others has a significant effect on individuals prosociality. However, no research has explored such an effect of romantic partners presence. Studies in evolutionary psychology have shown benevolence/prosociality as an important factor when choosing a romantic partner. Therefore, in the present study, we hypothesized that people will donate more in the presence of dating partners to maintain a positive impression on them. The research followed a mixed-method approach. The first study, a vignette-based experiment showed that people believed the presence of a dating partner significantly enhances the chances of donation. The second study was a between-subject experiment that confirmed the findings of study 1 from both donors and receivers perspectives. The third study was a qualitative investigation, where a semi-structured interview method was used to find out how and why the presence of a dating partner may influence donation. The interviews showed that the presence of dating partners increases prosociality mainly because donors want to make a good impression and project the right image of them in their partners eyes. The research overall suggests that the human need for self-presentation that projects them more socially likable shapes their willingness to extend a helping hand to others in the presence of their romantic partners. 2024 Taylor & Francis Group, LLC. -
The power of a learner-driven classroom
Extensive research supports the idea that the learner-centred model improves retention and prepares graduates better.