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Electronic structure and intrinsic dielectric polarization of defect-engineered rutile TiO2
Experimental realization of colossal permittivity associated with intrinsic dielectric polarization of defect-engineered (Nb, In) co-doped rutile TiO2 appears to be most suitable for microelectronics and solid-state device applications. Combining resonant photoemission spectroscopy, X-ray absorption spectroscopy, and density functional theory calculations, we here present a coherent understanding of electronic structure, in-gap defect states, doped electron localization, and their connection with macroscopic polarization for various doping configurations. Most often, conventional sample preparation conditions introduce in-gap states of Ti3+? character, limiting the maximum achievable intrinsic polarization value. Our understanding provides a pathway to enhance intrinsic polarization and minimize dielectric loss through suitable defect-engineering. The Royal Society of Chemistry. -
Electron beam mediated synthesis of photoluminescent organosilicon nanoparticles in TX-100 micellar medium and their prospective applications
The inherent advantages of Silicon have made it as one of the most sought-after elements in the field of nanoscience and nanotechnology. Herein, we report an electron-beam induced formation of blue light emitting organosilicon nanoparticles (OSiNPs) in the micellar medium of Triton X-100 (TX-100). The profound role of the micellar medium can be realized from the enhanced colloidal stability as well as photoluminescence (PL) quantum efficiency (from ~9% to ~55%) of as synthesized OSiNPs. Mechanistic investigations revealed the crucial role of hydroxyl radical ([rad]OH) in the formation of OSiNPs. XPS and FTIR studies indicated the presence of siloxane/silicone and silica (SiO2) like units as the major constituents in the NPs. XRD pattern showed the amorphous nature of the NPs, while TEM studies revealed their aggregation. The hydrodynamic size of the NPs was determined to be ~24 nm. Interestingly, the NPs exhibited an excitation-wavelength-dependent PL behaviour, thereby indicating the presence of multiple emission centres (ECs). Detailed investigations based on steady-state as well as time-resolved PL measurements were conducted to analyse these ECs. In addition, pH and temperature-dependent studies were carried out to further substantiate these findings. Moreover, the experimental observations revealed their potential applications in the areas of thermosensing, fingerprinting and cell-imaging. Notably, the internalization of as prepared NPs within cells was evident from the bright fluorescence images obtained from the cytoplasmic region as compared to control cells. This observation also suggests the prospective application of these NPs for image guided drug delivery systems. 2021 Elsevier B.V. -
Electromagnetic Radiation-Driven Plastic Degradation and Energy Recovery for Sustainable Waste Management
The persistent accumulation of plastic waste presents a severe global environmental challenge. This study presents a non-thermal photodegradation and energy-recovery system that selectively cleaves 82 5% of CC/CH bonds in polyethene (PE), polypropylene (PP), and polystyrene (PS) within 30 min of UVC (254 nm) exposure. The bond-dissociation energy is harvested via thermoelectric generators (TEGs), delivering 10 W, and via photoelectric cells, yielding 5 W (10 mA.cm- at ? < 2 eV), for a combined recovery of 15 W. Emissions are held below 0.5 ppm VOCs and 0.1 mg.m- microplastics. A lab-scale prototype processes 0.5 kg.h-1 of mixed plastic per 0.1 m reaction area equivalent to 30 Wh.kg-1 of electrical energy and is scalable to 5 kg.h-1 in a pilot module. Real-time FTIR, Raman, and UV-VIS spectroscopy, integrated with an IoT-PID feedback loop, ensures autonomous optimization. Life-cycle assessment indicates a 25% reduction in greenhouse gas emissions compared to conventional recycling methods. A circular-economy framework envisions recovering oligomeric and monomeric fragments for direct reintegration into polymer production. Feature work will implement digital-twin simulations to refine process control, maximize throughput, and ensure long-term system reliability. 2026 by the authors Licensee: Technoscience Publications. -
Electrochemical Transformation of Thiol-Iodine-Based Reactions toward Multiplexed Sensing Applications for Plant-Stress Hormone and Environmental Contaminant
Functionalized thiophenes are potential electroactive species that serve as efficient molecular electrochemical sensors. This work describes the fabrication of a 3-thiophene acetic acid (TAA)-modified screen-printed carbon electrode/multi-walled carbon nanotube (SPCE/MWCNT) platform via a facile electrochemical method in an aqueous medium. The effectual PT-Redox (product of TAA formed postpotentiostatic polarization) integration over SPCE/MWCNT was confirmed through various spectroscopic and electrochemical investigations. The SPCE/MWCNT showcased exceptional interaction with PT-Redox, creating a resilient platform for its precise binding, thereby enhancing the electrodeelectrolyte electroactive region, topographic roughness, electron conductivity, host response, and comprehensive electrochemical properties. The as-prepared electrode (SPCE/MWCNT@PT-Redox) was employed for the selective detection and quantification of glutathione (GT) as well as hydrazine (HyD) in an aqueous medium. The sensor showed excellent electrocatalytic oxidation responses toward these analytes, yielding a good sensitivity of 0.32 ?A mM1, a low detection limit (DL) of 0.225 ?M, a broad linear dynamic window of 0400 ?M for GT, a high sensitivity of 0.13 ?A mM1, a low DLof 0.56 ?M, and a linear window of 0350 ?M for HyD, obtained via the differential pulse voltammetry (DPV) technique. This substantiates that the modification with PT-Redox significantly boosted the electrodes interfacial activity and catalytic potential. Furthermore, the electrode exhibited robust antifouling and anti-interference traits, suggesting the composites enhanced stability and sensing capabilities for real-world applications. The captivating features, including excellent specificity, fast response dynamics, and simple sample preparation necessities of the proposed system, reveal a promising platform that accomplishes significant potential in futuristic sensing applications. 2025 American Chemical Society -
Electrochemical synthesis, photodegradation and antibacterial properties of PEG capped zinc oxide nanoparticles
The effect of surfactant and dopant on the properties of zinc oxide nanoparticles were studied by preparing polyethylene glycol (PEG) capped ZnO and tungsten doped PEG capped ZnO nanoparticles via the electrochemical method. These nanoparticles were characterized using X-Ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Ultraviolet Diffuse Reflection Spectroscopy (UV-DRS), Scanning Electron Microscopy (SEM) and Electron Dispersive Analysis of X Rays (EDAX). The photocatalytic degradation of malachite green dye using these nanoparticles was studied under visible light. The effects of various reaction parameters like dye concentration, catalyst concentration, pH and time were studied to optimize the photodegradation reaction. Reusability of these nanoparticles was studied and no significant change was observed in the degradation efficiency of PEG capped ZnO till the fourth cycle, while there was a gradual decrease in the degradation efficiency of tungsten doped PEG capped ZnO. Langmuir- Hinshelwood kinetic model well describes the photodegradation capacity and the degradation of malachite green follows pseudo-first order kinetics.Photocatalytic studies reveal that PEG capping increases the degradation properties of ZnO while tungsten doping decreases the extent of PEG capping and has a detrimental effect on the degradation properties of ZnO. The prepared nanoparticles exhibit significant antibacterial properties against gram-positive Bacillus cereus and gram-negative Escherichia coli bacterial strains by agar well diffusion method. 2018 Elsevier B.V. -
Electrochemical synthesis of ribonolactone-A precursor for anti-covid drug remdesivir /
Patent Number: 202141035480, Applicant: Dr B S Praveen Kumar.
The invention aims to create an energy use model for a chiller in heating, ventilation, and air conditioning system using the artificial neural network learning method. Input layers that included several input variables, quantity (percentage) of training data and number of neurons were measured for accuracy by the suggested chiller energy consumption model. A standard reference structure was also designed to provide operating data for the chiller system during long refrigeration periods (warm weather months). -
Electrochemical synthesis of nanoparticles
Nanomaterials possess diverse applications across environmental, medical, and energy sectors, owing to their unique properties dictated by structure, size, composition, and morphology. These characteristics of nanoparticles are pivotal in materials science. Their distinctive properties made an interest in specific applications, prompting the exploration of synthesis methods tailored for various purposes, particularly in electrochemistry. This chapter examines a nanoparticle synthesis technique capable of producing nanoparticles suitable for diverse applications, emphasizing electrochemical synthesis. This method offers efficient fabrication of nanoparticles at low temperatures with high purity, presenting an environmentally friendly preparation approach. Electrochemical synthesis, particularly through electrodeposition, involves the controlled passage of an electric current between the electrodes immersed in an electrolyte solution. This method yields stable nanoparticles with robust electrical contact, poised for utilization in batteries, fuel cells, supercapacitors, catalysis, optoelectronics, and beyond. The chapter elucidates the electrochemical synthesis process, underscoring its potential for advancing nanoparticle-based technologies across multiple disciplines. 2025 Elsevier Inc. All rights reserved. -
Electrochemical Synthesis of Heterocyclic Carbonyls Using Carbon Based Electrocatalysts
Electro-organic synthesis (EOS) is emerging as a powerful and sustainable technique newlinefor synthesizing organic compounds. EOS offers a compelling alternative to newlineconventional synthetic methods, driven by the need for cleaner and more efficient newlineprocesses and a growing focus on environmental impact. This approach minimizes newlineenvironmental impact by reducing dependence on hazardous chemicals and solvents. newlineAdditionally, EOS enables precise control over reaction parameters, leading to selective newlineproduct formation and potentially novel reaction pathways. newlineThis work presents the development of electrocatalysts for the electro-oxidation of newlineselected heterocyclic alcohols, namely piperonyl alcohol (PA), thiophene-2-ylmethanol newline(TM), furfuryl alcohol (FA) and indole-3-carbinol (IC) to their corresponding newlinealdehydes. A Toray carbon fiber paper (TCFP) substrate modified with 2D materials, newlineconducting polymers, metal oxides, and metal oxide nanoparticles are employed in newlinethefabrication of the electrodes. newlineThe efficiency of the developed electrode was studied employing different newlineelectrochemical and physicochemical studies. X-ray Diffraction Spectroscopy (XPS), newlineField Emission Scanning Electron Microscopy (FESEM), Energy Dispersive X-ray newlineSpectrometry (EDS), X-ray Photoelectron Spectroscopy (XPS), and Optical newlineProfilometry (OP) techniques were utilized for the physicochemical studies of the newlinefabricated electrodes. Cyclic voltammetry (CV), Electrochemical Impedance newlineSpectroscopy (EIS), Chronoamperometry (CA) and Bulk Electrolysis (BE) techniques newlinewere employed for the electrochemical studies, including optimization and synthesis of newlineheterocyclic aldehydes. The fabricated electrocatalysts demonstrated remarkable newlinestability, higher electrocatalytic activity, and good conductivity. The electro-oxidation newlinereactions were carried out in a three-electrode system via BE using 4-acetamido- newline2,2,6,6-tetramethylpiperidine 1-oxyl (4-ACT) mediator. The products obtained were newlinecharacterized by Proton Nuclear Magnetic Resonance (1H NMR) spectroscopy. -
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Electrochemical Synthesis of Carbocyclic and Heterocyclic Motifs
Programmability has left its mark on every facet of business, with technology playing newlinean integral role. Social networking industry trends underscore technology s ubiquity in newlinenearly every business transaction. Traditional networks grapple with numerous challenges, rendering them ill-equipped to process and handle the demands of the modern newlinelandscape effectively. The lack of programming in these networks leads to stagnation, newlineinhibiting their ability to evolve or enhance performance. The advent of Software Defined Networks (SDN) has introduced increased flexibility into conventional networks, newlineopening avenues for creating innovative services. newlineSDN technology addresses challenges in large-scale networks, offering solutions for newlinehigh throughput, virtualization, fault detection, and load balancing, providing effective network management. The rapid expansion of network services and applications newlinein SDN environments demands sophisticated load-balancing solutions that adapt to newlinedynamic traffic patterns and varying service requirements. This study presents a pioneering algorithm, the Dynamic Load Balancing Algorithm (DLBA), which utilizes the newlineProgramming Protocol-independent Packet Processors (P4) language. The algorithm is newlinespecifically crafted to tackle the issues associated with optimizing traffic distribution in newlinethe data plane of SDN. newlineP4 programming language, recognized as one of the most robust languages, addresses newlinethe limitations of traditional networking, enhancing programmability and agility by newlinedistributing the load across the network. The research implements a novel quotDynamic newlineLoad Balancing Algorithmquot using the P4 language to instill dynamism and achieve load newlinebalance in large-scale networks. The P4-based implementation showcases dynamicity, scalability, flexibility, and adaptability. This research commences with thoroughly newlineexamining existing load-balancing algorithms implemented using the P4 language, followed by a comparative analysis between these algorithms and DLBA. -
Electrochemical sensors using conducting polymer/noble metal nanoparticle nanocomposites for the detection of various analytes: a review
Abstract: Conducting polymer/noble metal nanoparticle (CP/NMNP) composites have made a history of sorts since its inception in the field of electrochemical research, which resulted to be an impetus for scientists to indulge and explore the opportunities it can unleash. This review throws light on the synergic effects and the enhancement in the electrocatalytic activity on dispersing noble metal particles on conducting polymers. This review aids the readers to analyse the electrochemical sensing efficiency of CP/NMNP composites, and provides a platform for the researchers to engineer and develop CP/NMNP composite materials for electrochemical sensing. This work also draws the attention of the readers to the application of NMNP (Ag, Au, Pt, Pd, Ir, and Ru) dispersed on CPs [polyaniline (PANI), polypyrrole (PPy) and poly(3,4-ethylenedioxythiophene) (PEDOT)] and their composites with other materials like carbon nanotubes (CNTs), graphene, zeolites, and peptide nanotubes (PNTs) for sensing of various analytes. Graphic abstract: This review draws the attention of the readers to the application of NMNP (Ag, Au, Pt, Pd, Ir and Ru) dispersed on CPs (polyaniline (PANI), polypyrrole (PPy) and poly(3,4-ethylenedioxythiophene) (PEDOT)) and their composites with other materials like carbon nanotubes (CNTs), graphene, zeolites, and peptide nanotubes (PNTs) for sensing of various analytes.[Figure not available: see fulltext.]. 2021, Islamic Azad University. -
Electrochemical sensor based on PVP coated cobalt ferrite/graphite/PANI nanocomposite for the detection of hydrazine
In this study, we developed a multi-layered electrode as an efficient nanocomposite electrochemical sensor for detecting carcinogenic hydrazine in water. Nano-cobalt ferrite (CoFe2O4) was prepared using poly (vinylpyrrolidone) (PVP), mixed with an optimum quantity of graphite and pasted on a stainless-steel current collector. The nanocomposite was further hybridised by electrodepositing with polyaniline (PANI). The obtained composite was characterized using XRD, FTIR, SEM, and electrochemical techniques. XRD analysis shows the successful formation of composite from individual precursors. According to SEM, wrinkled and layered morphology for graphite and aggregate clusters for cobalt with spike or tubular structure for polyaniline were observed. When subjected to amperometry current, the prepared electrode showed different peaks for different concentrations of hydrazine, such as 1 ?M to 100 ?M. Cyclic voltammetry studies showed an increase in oxidation and reduction peaks. These studies will lead to a new platform for their potential applications in detecting toxic materials in real samples such as water, plastic bottle, water etc., 2023 The Author(s). Published by IOP Publishing Ltd. -
Electrochemical sensing of vitamin B6 using platinum nanoparticles decorated poly(2-aminothiazole)
Vitamin B6 (Vit B6), also known as pyridoxine, is pivotal in fundamental physiological and metabolic processes within the body. Insufficient levels of this essential nutrient may contribute to various health complications. We introduce an electrochemical sensor designed to determine Vit B6 levels precisely. This sensor is constructed through a two-step process: first, by modifying a bare carbon fiber paper electrode (CFP) with poly(2-aminothiazole) (PAT), and second, by electrodepositing platinum nanoparticles onto the modified electrode surface, giving the final working electrode- Pt/PAT/CFP. Electrochemical impedance spectroscopy (EIS) and Cyclic voltammetry (CV) were utilized to examine the electrochemical characteristics of the developed sensor. The characterization of the sensor was done through a range of analytical techniques, including X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and optical profilometric studies. Furthermore, we optimized the sensor's performance by assessing the impact of pH, scan rates, and analyte concentrations. The sensor showed a wide linear dynamic range of 5.0 nM80 M and a low detection limit of 0.054 M. We have successfully quantified Vit B6 levels in tablet formulations and dried palm date fruits. The outcomes of this study hold the promise of substantial progress in Vit B6 quantification, with far-reaching implications across pharmaceuticals, healthcare, and nutritional science. 2024 Elsevier B.V. -
Electrochemical sensing of vitamin B12 deficiency marker methylmalonic acid using PdAu-PPy tailored carbon fiber paper electrode
Vitamin B12 is very important for human metabolism and its deficiency can cause anemia and the production of large red blood cells. An increased concentration of methylmalonic acid (MMA) is detected much before the transformation of blood cells, which thereby is an early indicator for mild or serious Vitamin B12 deficiency. A simple electrochemical sensor based on PalladiumGold (PdAu) was developed by electrodeposition of PdAu nanoparticles on Polypyrrole (PPy) modified carbon fiber paper (CFP) electrode. The modified electrodes were characterized by High resolution transmission electron microscopy (HRTEM), Field emission scanning electron microscopy (FESEM) with energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and electroanalytical techniques. Differential Pulse Voltammetric (DPV) studies have established that under optimum conditions, the developed sensor exhibits a broad linear dynamic range (4.01 pM - 52.5 nM) with a very low detection limit (1.32 pM). The proposed method was effectively applied in the non-enzymatic determination of MMA at an ultralow level in human blood serum and urine samples. The method displayed high selectivity toward MMA in the presence of other interfering substances. 2020 Elsevier B.V. -
Electrochemical Sensing of Formaldehyde in Fish Samples Using a Polydopamine-Modified Stainless Steel Electrode
Electrodeposited polydopamine (pDA) on a stainless steel substrate was developed for electrochemical sensing of formaldehyde in fish samples. Experimental conditions such as influence of scan rate, pH, and concentration were optimized. The pDA modified electrode was sensitive enough to detect formaldehyde at a potential of 0.8 V in an acidic aqueous solution. The lLinear dynamic range for the detection of formaldehyde was in the range of 0.43 to 1.60 ?m under optimal conditions. The detection and quantitation limits were found to be 0.14 and 0.43 ?m respectively. The method was effectively employed for the detection of formaldehyde in fish samples. 2021 The Electrochemical Society ("ECS"). Published on behalf of ECS by IOP Publishing Limited. -
Electrochemical recognition of MMA-A biomarker for vitamin B12 deficiency based on ?-cyclodextrin self-assembled on polyaminothiazole
For the first time, the efficient electroreduction and identification of methyl methacrylate (MMA) was achieved using a carbon fiber paper (CFP) electrode modified with polyaminothiazole-?-cyclodextrin (PAT-?-CD). The recognition capabilities of the ?-CD/PAT/CFP and PAT/CFP electrodes were investigated using cyclic voltammetry, revealing the significant influence of ?-CD on the observed electroanalytical behaviour. Specifically, a PAT-?-CD modified CFP electrode was fabricated by electropolymerizing aminothiazole, serving as a substrate for ?-CD self-assembly through hydrogen bonding between the hydroxyl groups of ?-CD and the nitrogen atoms of the polyaminothiazole ring system. This as-prepared electrode exhibited a novel electrochemical method for the identification of MMA. Notably, the final ?-CD/PAT/CFP electrode demonstrated superior electrocatalytic activity towards MMA reduction under optimized conditions compared to bare CFP and other modified electrodes. This modified electrode displayed an extended linear concentration range of 10 nM to 270 nM and a low limit of detection (LOD) of 0.6 nM. Furthermore, the electrocatalyst demonstrated excellent stability, repeatability, and negligible interference from other species. Finally, the developed ?-CD/PAT/CFP electrode was successfully applied for the quantitative determination of MMA in human urine samples. 2025 The Royal Society of Chemistry. -
Electrochemical performance of ZnxCo3-xO4/N-doped rGO nanocomposites for energy storage application
In this study, nanocomposites consisting of zinc-doped cobalt oxides with a spinel structure and nitrogen-doped reduced graphene oxide (ZnxCo3-xO4 (x = 0 and 1))/N-doped rGO) were synthesized using a solvothermal method. The synthesized materials were investigated using XRD, TEM, EDS, BET, Raman, and XPS for their phase formation, morphology, elemental composition, surface area, and chemical states. XRD analysis revealed that the metal oxides (Co3O4 and ZnCo2O4) present in the composites exhibited a single-phase cubic spinel structure, with a nanocrystalline nature and crystallite size ranging from 8 nm to 20 nm. Raman and TEM analyses revealed the co-existence of metal oxide nanoparticles and N-doped rGO phases in the composites. Electrodes were fabricated using the synthesized nanocomposite materials and subjected to electrochemical testing, including CV, GCD and EIS. The specific capacitiance (Cs) of samples determined to be 181 F/g and 234 F/g for CO/NrGO (Co3O4/N-doped rGO) and ZCO/NrGO (ZnCo2O4/N-doped rGO) nanocomposites, respectively, at lower current density (0.5 A/g). At all current densities, the CS of ZCO/NrGO nanocomposite electrode is observed to be higher than the CO/NrGO nanocomposite, probably due to structural defects and uniform anchoring of ZnCo2O4 particles over the layers of NrGO. The ZCO/NrGO composite electrode exhibits ?86 % capacitance retention after 3000 cycles. 2024 Elsevier B.V. -
Electrochemical Oxidation of Hydrazine Hydrate Using Subja Seeds-Green Redox Chemistry-Impregnated Carbon-Modified Platform: Harmonizing Sustainable Sensing
The inclusion and interpretation of various phyto-based natural moieties embodying health gains is a critical and worthwhile scientific investigative focus. The descriptions comprehend their fundamental build-up, redox data, with significant electron shuttling, and strenuous obstacles in regard to the green-plant bioactives. Thus, a pressing and transformative undertaking toward simplistic electrocatalytic probe applications exploiting their reactive sites is a key focus, time demanding, or immediate call for top priority. Plant-sourced Basil or Subja seeds-redox entrapped within the mesoporous carbon spheres on a glassy carbon (GC) surface has been established (GC/graphitized mesoporous carbon [(GMC)@Subja] in this work. Unlike other established research constituting conventional approaches with limited access toward nonspecific or featureless voltammetric signals, we report a well-defined, sharp faradic response with an electrode potential E0' = 0.23 V (A1/C1) and 0.3 V (A2/C2) signals. The model Subja seeds-redox (GC/GMC@Subja) has been developed in an aqueous pH 7 phosphate buffer (PB) solution, contributing toward a sustainable and resilient strategy. This electrochemical methodology involved an underlying sp2-based mesoporous carbon framework for the ?-electron interaction and adsorption of the Subjaredox, leading to sp3 hybridization. The electrocatalytic function of GC/GMC@Subja showcased selective hydrazine (HZ) oxidation with a sensitivity and detection limit of 0.98 ?A mM-1 and 1.20 ?M (s/n = 3), respectively. Furthermore, the as-prepared system demonstrated HZ sensing in real samples with a recovery value of ?101.3%. 2026 IEEE. -
Electrochemical non-enzymatic strategy with green synthesized Fe2O3CuO nanocomposite for detection of amiprofos-methyl herbicide in industrial effluents and soils
Iron oxide-Copper oxide nanoparticles composite (Fe2O3CuO NPs) was synthesized through a green phytosynthetic approach using Ocimum sanctum Linn (commonly known as Tulsi) leaf extract. The evaluation of electrocatalytic properties were evaluated by carrying out electrochemical detection of amiprofos-methyl (APM), an organophosphorus herbicide. It is moderately toxic to mammals and aquatic biodiversity and is considered to be an acetylcholinesterase inhibitor. The presence of specific natural phytochemicals such as eugenol, naringenin, apigenin, quercetin, and high amount of ascorbic acid in the aqueous extract of Ocimum sanctum Linn plant parts, has been widely used for the synthesis of various metallic nanoparticles where these compounds serve as reducing, stabilizing, and capping agents. The synthesized Fe2O3CuO NPs were characterized using scanning electron microscope (SEM), energy dispersive X-ray analysis (EDX), X-ray diffraction analysis (XRD), UVVis spectroscopy, Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA). The modified electrode was electrochemically characterized by cyclic voltammetry and differential pulse voltammetry (DPV) techniques for the detection of APM. The electrochemical signals have increased by three folds in the detection of APM with Fe2O3CuO nanocomposite compared to the bare glassy carbon electrode. The electrochemical sensor showed a linear range of 0.05 to 30 g/mL with a limit of detection of 0.0065 g/mL. The developed electrochemical sensor was successfully applied for the detection of APM in different water and soil samples with recoveries ranging from 96.00?99.00%. The electrode showed good stability and reproducibility over a period of 10 days with a 95% of peak current than the former. The newly synthesized nanoparticles, thus, proved to be an interesting material for electrochemical and biological studies. 2023 The Authors -
Electrochemical investigations of chitosan/ZrO2-Bi2O3 composite for advanced energy and environmental applications
Energy needs are on the rise, and the need for effective corrosion resistance measures are also vital to meet the requirements prevailing in society. A multifunctional Chitosan/ZrO2-Bi2O3 composite is synthesized, keeping electrochemical analysis of energy and environmental applications in mind. Various physicochemical methods confirm the impact of integrating ZrO2-Bi2O3 into chitosan, resulting in improved efficacy across applications. The electrocatalytic supercapacitance, hydrogen evolution reaction, and corrosion inhibition studies are carried out to evaluate the efficiency of the synthesized composite. The composite shows a specific capacitance of 636.5 F/g, ensuring the effective utility for supercapacitance applications. The lower overpotential of 135.2 mV is shown by the composite in the electrocatalytic hydrogen evolution reaction. The synthesized composite also shows 96.2 % efficacy in corrosion inhibition studies. The studies conducted demonstrate the increased effectiveness of chitosan when combined with bimetal oxide. The chitosan composite is therefore a competent catalyst for energy and environmental applications. 2024 Elsevier Ltd