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Extremal Trees oftheReformulated andtheEntire Zagreb Indices
The first reformulated Zagreb index of trees can take any even positive integer greater than 8, whereas the second reformulated Zagreb index of trees can take all positive integers greater than 47 with a few exceptional values less than 8 and 47, respectively. The entire Zagreb index is defined in terms of edge degrees and incorporates the idea of intermolecular forces between atoms along with atoms and bonds. This intricate significance of studying the entire Zagreb index led to the generalization of the first entire Zagreb index of trees. The inverse problem on the first entire Zagreb of trees gives the existence of a tree for any even positive integer greater than 46. The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd 2024. -
Sustainable Assessment of Advanced Machine Intelligence in Clinical Safety
There is growing acknowledgment that artificial intelligence (AI) is being used to evaluate complex and vast volumes of data, producing findings without human input, in a variety of healthcare contexts, including image analysis, bioinformatics and genomics. Although this technology can offer opportunities in the diagnostic and therapeutic process, various safety-related difficulties and traps can still exist. To shed light on these opportunities and challenges, this article addresses the use of AI in healthcare and its security consequences. To deliver safer technology through AI, this research explores the cost implications of all potential technological systems, while design safety, failure safety, procedural security, and safety margins are the primary methods for identifying risks & uncertainties. Additionally, the suggestion involves the identification and distribution of explicit instructions and procedures to all relevant parties, aiming to facilitate the creation and implementation of safer Al applications within healthcare settings. 2023 IEEE. -
Augmented Reality based Navigation for Indoor Environment using Unity Platform
This paper proposes an augmented reality (AR) navigation system developed for indoor environment. The proposed navigation system is developed using Unity platform which is usually used for developing gaming applications. The proposed navigation system without the aid of Global Positioning System (GPS) tracks users position and orientation accurately by making use of computer vision and image processing techniques. The user can navigate to the desired location using its user friendly and intuitive interface. The proposed system can be extended further to provide indoor navigational guidance within lager buildings such as malls, airports, universities and medical facilities. The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. 2024. -
Complete analysis of differential cross section in 7 Li + ? ? ? 6 Li + n at astrophysical energies
We have carried out complete analysis of differential cross section in 7 Li + ? ? 6 Li + n using model-independent theoretical formalism. A complete analysis of the reaction involves measurements of not only one state of linear polarization of the photon but also another state of linear polarization inclined to the first at 45? and two states of circular polarization of the photon. An analytical study of the differential cross section including all the photon polarization states is carried out at near-threshold energies of interest to Big Bang Nucleosynthesis. 2024 IOP Publishing Ltd -
Lithium photodisintegration with linearly polarized photons at astrophysical energies
We present here a model-independent theoretical discussion of differential cross-sections in photodisintegration of lithium with unpolarized and linearly polarized photons. In recent years, experimental measurements are being carried out on the photodisintegration of lithium in the reaction channel 7Li(?, n)6Li to study the angular dependence of cross-section. In this regard, we have studied the spin structure of amplitudes in 7Li(?, n)6Li by expressing the differential cross-section in terms of Legendre polynomials. 2023 Oxford University Press. All rights reserved. -
7Li Photodisintegration withCircularly Polarized Photons
The study of photodisintegration of 7Li is of importance to Nuclear Physics, Particle Physics and Astrophysics. Primordial abundances of light elements such as D, 3He, 4He and 7Li are predicted by Big Bang theory of early universe and is of great interest to cosmologists. Lithium, being fragile gets destroyed easily at relatively low temperatures. WMAP measurements have inferred that 7Li abundance is two to three times more than that inferred by the low metallicity halo stars [1]. In recent years based on lithium isotopes series of experimental measurements are being carried out using High-Intensity Gamma-Ray Source (HIGS) at Duke Free Electron Laser Laboratory. Experiments [2, 3] were carried out, to measure the differential cross-section of the photoneutron reaction channel in photodisintegration of 7Li, where the progeny nuclei is in the ground state as well as in excited states. Theoretical study on photodisintegration of deuteron was carried out using a model-independent formalism [47] and in these studies, it was shown clearly that there could be 3 different E1? amplitudes leading to final relative n-p state. Subsequently, evidence for the existence of these three amplitudes was found in experimental studies [6] at slightly higher energies in different contexts. Using the same approach, model-independent formalism was developed for photodisintegration of 7Li [8] and an analysis was carried out to study the differential cross section with linearly polarized photons. Extending this study we propose to discuss the reaction channel 7Li+??6Li+n with initially circularly polarized photons. The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. 2024. -
Model independent approach to photodisintegration of 7Li at the range of energies of interest to BBN
One of the elements that was synthesized primordially in the standard Big Bang Nucleosynthesis is lithium. Lithium, being fragile gets easily destroyed at relatively low temperatures in the mixing process between stellar surface and hot internal layers. So that, at the end of the stellar lifetime the lithium content is believed to be depleted. Series of experimental measurements on lithium isotopes were carried out at High Intensity Gamma Ray Source (HIGS) at Duke Free Electron Laser Laboratory. More recently experiments [1]-[2] were performed, to measure the differential cross section of the photo-neutron reaction channel in photodisintegration of 7Li, where the progeny nuclei is in the ground state as well as in excited states. The purpose of present contribution is to study the reaction channel 7Li + ? ? 6Li + n using linearly polarized photons.The model independent irreducible tensor formalism [3]-[5] will be used to study the differential cross section of the reaction. We study the angular dependence of differential cross section by expressing differential cross section in terms of legendre polynomials. In view of the several theoretical and ongoing experimental studies, a detailed theoretical study of the spin structure of the amplitudes in 7Li+ ? ? 6Li+ n and their expansion in terms of'electric' and 'magnetic' amplitudes is needed to analyze the measurements of spin observables as well as differential cross section, which leads to a better understanding of the problem at astrophysical energies. 2022 Institute of Physics Publishing. All rights reserved. -
Lithium photodisintegration with unpolarized photon beams at near threshold energies
The study of photonuclear reactions with lithium targets i.e. photodisintegration of lithium in addition to other photonuclear reactions is of considerable interest to the fields of nuclear physics, astrophysics, laser physics and several applications such as non - destructive testing of nuclear materials. We propose to study photodisintegration of lithium with unpolarized photon beams at near threshold energies. Our model independent theoretical approach, which makes use of irreducible tensor techniques, is well suited for making predictions on the spin observables as well as the differential cross section. In this paper we analyze the reaction channel 7Li + ? ? 6Li + n by using unpolarized photons. 2022 -
Green synthesis of nanoparticles from biodegradable waste extracts and their applications: a critical review
The contemporary world is concerned only with non-biodegradable waste management which needs more sophisticated procedures as compared to biodegradable waste management. Biodegradable waste has the potential to become useful to society through a simple volarization technique. The researchers are behind sustainable nanotechnology pathways which are made possible by using biodegradable waste for the preparation of nanomaterials. This review emphasizes the potentialities of biodegradable waste produced as a viable alternative to create a sustainable economy that benefits all humans. Volarization results in the utilization of biowastes as well as provides safer and hazard-free green methods for the synthesis of nanoparticles. Starting from different sources to the application which includes therapeutics, food industry and water treatment. The review hovers over the pros and cons of biowaste-mediated nanoparticles and concludes with possible advances in the application. In the present scenario, the combination of green synthesis and biowaste can bring about a wide variety of applications in nanotechnology once the hurdles of bulk-scale industrial production are resolved. Given these points, the review is focused on the cost-effective synthesis of metal and metal oxide nanoparticles. 2022, The Author(s), under exclusive licence to Springer Nature Switzerland AG. -
Synergistic g-c3n4/v2o5/pani composite for electrochemical energy storage
This work illustrates the synthesis of a ternary hybrid composite (g-C3N4/V2O5/PANI) from graphitic carbon nitride, vanadium pentoxide, and Polyaniline via hydrothermal method followed by in-situ polymerization. Morphological analysis confirms the integration of vanadium pentoxide (V2O5) and polyaniline (PANI) within the interlayer spaces of graphitic materials. The resultant hybrid composite structure facilitates rapid diffusion and ion movement at the electrode-electrolyte interface. Additionally, incorporating V2O5 within a polymer matrix alongside graphitic material generates diverse electrical profiles, enhancing electrochemical performance. The electrochemical characteristics of g-C3N4/V2O5/PANI composites were examined by Cyclic voltammetry (CV), Galvanostatic charge-discharge (GCD), and Electrochemical impedance spectroscopy (EIS). The GCD analysis shows that the g-C3N4/V2O5/PANI composite exhibits a specific capacitance of 880 Fg?1 at a current density of 1 Ag?1, retaining 78 % of its initial capacitance after executing 2000 cycles at 3 Ag?1. Furthermore, a symmetric supercapacitor was constructed using g-C3N4/V2O5/PANI composite material as the electrode, showing a capacitance of 246 Fg?1 when measured at an input current density of 1 Ag?1. This study demonstrates g-C3N4/V2O5/PANI is a potential electrode material for supercapacitor application. 2024 -
Defect engineered unzipped multiwalled carbon nanotube/vanadium pentoxide composite for high-performance supercapacitor application
In the pursuit of next-generation energy storage systems, the advancement of high-performance electrode materials with enhanced capacitance and durability remains critical. This study presents a binary composite of unzipped multi-walled carbon nanotubes (UzMWCNTs) integrated with vanadium pentoxide (V2O5). The unzipping process introduces surface defects and oxygen functional groups, which enhance dispersion and provide numerous active sites. V2O5 nanoparticles uniformly anchor onto the UzMWCNT surface, offering pseudocapacitive behavior and boosting redox activity. The synergistic interaction between electric double-layer capacitance and faradaic charge storage delivers superior electrochemical performance. Structural and morphological characterization confirms successful composite formation, while electrochemical evaluations reveal a specific capacitance of 1135 F g?1 and cycling stability with 88% retention over 2000 cycles. This work highlights the potential of UzMWCNT/V2O5 hybrids as promising candidates for high-efficiency, next-generation supercapacitor electrodes. This journal is The Royal Society of Chemistry, 2026 -
Synergistic g-c3n4/v2o5/pani composite for electrochemical energy storage
This work illustrates the synthesis of a ternary hybrid composite (g-C3N4/V2O5/PANI) from graphitic carbon nitride, vanadium pentoxide, and Polyaniline via hydrothermal method followed by in-situ polymerization. Morphological analysis confirms the integration of vanadium pentoxide (V2O5) and polyaniline (PANI) within the interlayer spaces of graphitic materials. The resultant hybrid composite structure facilitates rapid diffusion and ion movement at the electrode-electrolyte interface. Additionally, incorporating V2O5 within a polymer matrix alongside graphitic material generates diverse electrical profiles, enhancing electrochemical performance. The electrochemical characteristics of g-C3N4/V2O5/PANI composites were examined by Cyclic voltammetry (CV), Galvanostatic charge-discharge (GCD), and Electrochemical impedance spectroscopy (EIS). The GCD analysis shows that the g-C3N4/V2O5/PANI composite exhibits a specific capacitance of 880 Fg?1 at a current density of 1 Ag?1, retaining 78 % of its initial capacitance after executing 2000 cycles at 3 Ag?1. Furthermore, a symmetric supercapacitor was constructed using g-C3N4/V2O5/PANI composite material as the electrode, showing a capacitance of 246 Fg?1 when measured at an input current density of 1 Ag?1. This study demonstrates g-C3N4/V2O5/PANI is a potential electrode material for supercapacitor application. 2024 -
Ternary composite of unzipped multiwalled carbon nanotubes (curved graphenes) for next-generation capatteries
Polyaniline (PANI) and Nickel ferrite (NiFe2O4) based hybrid materials have garnered significant interest in energy storage applications because of their exceptional electrical conductivity, redox properties, and structural stability. In this study, a hybrid ternary composite combining UzMWCNT with NiFe2O4 and PANI (UzMWCNT/NiFe2O4/PANI) is successfully synthesized using a two-step synthesis method involving hydrothermal and in-situ polymerization, as an efficient electrode material for supercapacitor application. The crystalline structure, functional groups, and surface morphology of the synthesized composite materials were analyzed through X-ray diffraction studies (XRD), Raman spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The electrochemical performance was evaluated utilizing cyclic voltammetry (CV), galvanostatic chargedischarge (GCD), and electrochemical impedance spectroscopy (EIS). The interaction between the various components and the unique composition structure yields a specific capacitance of 1022 F g?1 at 1 A g?1, with a capacitance retention of 84 % after 2000 GCD cycles. The synthesized ternary hybrid composite maximizes the accessibility of multiple active sites while reinforcing structural stability, enhancing its energy storage performance. The research unveils the compelling advantages of the UzMWCNT/NiFe2O4/PANI ternary composite, positioning it as a cutting-edge candidate for next-generation energy storage devices. 2025 Elsevier Inc. -
Assessing anticancer properties of PEGylated platinum nanoparticles on human breast cancer cell lines using in-vitro assays
This study describes the in-vitro cytotoxic effects of PEG-400 (Polyethylene glycol-400)-capped platinum nanoparticles (PEGylated Pt NPs) on both normal and cancer cell lines. Structural characterization was carried out using x-ray diffraction and Raman spectroscopy with an average crystallite size 5.7 nm, and morphological assessment using Scanning electron microscopy (SEM) revealed the presence of spherical platinum nanoparticles. The results of energy-dispersive x-ray spectroscopy (EDX) showed a higher percentage fraction of platinum content by weight, along with carbon and oxygen, which are expected from the capping agent, confirming the purity of the platinum sample. The dynamic light scattering experiment revealed an average hydrodynamic diameter of 353.6 nm for the PEGylated Pt NPs. The cytotoxicity profile of PEGylated Pt NPs was assessed on a normal cell line (L929) and a breast cancer cell line (MCF-7) using the 3-(4, 5-dimethylthiazol-2-yl)-2, 5-diphenyltetrazolium bromide (MTT) assay. The results revealed an IC50 of 79.18 ?g ml?1 on the cancer cell line and non-toxic behaviour on the normal cell line. In the dual staining apoptosis assay, it was observed that the mortality of cells cultured in conjunction with platinum nanoparticles intensified and the proliferative activity of MCF-7 cells gradually diminished over time in correlation with the increasing concentration of the PEGylated Pt NPs sample. The in vitro DCFH-DA assay for oxidative stress assessment in nanoparticle-treated cells unveiled the mechanistic background of the anticancer activity of PEGylated platinum nanoparticles as ROS-assisted mitochondrial dysfunction. 2024 IOP Publishing Ltd. All rights, including for text and data mining, AI training, and similar technologies, are reserved. -
Betulinic acid: A natural promising anticancer drug, current situation, and future perspectives
Natural products serve as the single most productive source for the discovery of drugs and pharmaceutical leads. Among the various chemicals derived from microbes, plants, and animals, phytochemicals have emerged as potential candidates for the development of anticancer drugs due to their structural diversities, complexities, and pleiotropic effects. Herein, we discuss betulinic acid (BA), a ubiquitously distributed lupane structured pentacyclic triterpenoid, scrutinized as a promising natural agent for the prevention, suppression, and management of various human malignancies. Ease of availability, common occurrences, cell-specific cytotoxicity, and astonishing selectivity are the important factors that contribute to the development of BA as an anticancer agent. The current review delineates the mechanistic framework of BA-mediated cancer suppression through the modulation of multiple signaling pathways and also summarizes the key outcomes of BA in preclinical investigations. 2022 Wiley Periodicals LLC. -
Transition Metal Nanoparticles, Semiconductor Nanoparticles: Synthesis and Applications
Semiconductor nanoparticles of CdSe are currently under investigation because their emissions can be tuned easily to cover the broad spectrum (from red to blue) by decreasing the particle size. In this work we have employed different experimental routes for synthesis of Zn doped CdSe nanoparticle and Ni nanoparticle and a brief description about their characterisation techniques are employed. In this present study, the Zn doped CdSe and Ni nanoparticles have been prepared by precipitation method. Upon characterisation, it was found that Zn dopants decreased the band gap thereby acting as a good photocatalyst. The crystallite size obtained from XRD was 26.84 nm and the average particle size calculated using DLS was below 100 nm. The results obtained from XRD are matching with the results obtained from DLS. The photocatalytic activities of the synthesized nanoparticles were analysed using methylene blue under irradiation of visible light. 73.9% degradation is observed for methylene blue catalysed by Zn doped CdSe nanoparticles for 4hr. Synthesis of nickel (Ni) nanoparticles (NPs) have been achieved by the chemical reduction of nickel chloride using hydrazine hydrate without the need for an inert atmosphere from an external source. The photocatalytic activity, structure and morphology of the NPs were studied by employing UV-Visible (UV-Vis) spectroscopy, powder X-ray diffraction (PXRD) and transmission electron microscopy (TEM). Degradation of Methylene Blue (MB) and Rhodamine B (Rh-B) dyes using Ni NPs was investigated to see the feasibility in degrading these dyes from polluted water at low cost. Ni NPs showed a good photocatalytic activity of 840.1% under visible light for the degradation of MB when compared to Rhodamine B (Rh-B) which showed an efficiency of 47.3 %. -
An Efficient Deep Learning Framework FPR Detecting and Classifying Depression Using Electroencephalogram Signals
Depression is a common and real clinical disease that has a negative impact on how you feel, how you think, and how you behave. It is a significant burdensome problem. Fortunately, it can also be treated. Feelings of self-pity and a lack of interest in activities you once enjoyed are symptoms of depression. It can cause a variety of serious problems that are real, and it can make it harder for you to work both at home and at work. The main causes include family history, illness, medications, and personality, all of which are linked to electroencephalogram (EEG) signals, which are thought of as the most reliable tools for diagnosing depression because they reflect the state of the human cerebrum's functioning. Deep learning (DL), which has been extensively used in this field, is one of the new emerging technologies that is revolutionizing it. In order to classify depression using EEG signals, this paper presents an efficient deep learning model that allows for the following steps: (a) acquisition of data from the psychiatry department at the Government Medical College in Kozhikode, Kerala, India, totaling 4200 files; (b) preprocessing of these raw EEG signals to avoid line noise without committing filtering; (c) feature extraction using Stacked Denoising Autoevolution; and (d) reference of the signal to estimate true and all. According to experimental findings, The proposed model outperforms other cutting-edge models in a number of ways (accuracy: 0.96, sensitivity: 0.97, specificity: 0.97, detection rate: 0.94). 2023, The Author(s), under exclusive license to Springer Nature Switzerland AG. -
A Comprehensive Review on Antibacterial, Anti-Inflammatory and Analgesic Properties of Noble Metal Nanoparticles
Their health industry is facing challenges due to a rise in mortality rates brought on by various multi-drug-resistant bacterial strains. As a result, new and improvedantibacterial drugs are urgently needed. Similarly, when some unwanted foreign pathogensenter the cellular premises to disturb its homeostasis, inflammation develops as an immune reaction. However, these immune responses also become a double-edged sword when the inflammatory reaction lasts for a long time, and pain is also linked to inflammatory responses. Inflammation and pain are both signs of tissue injury. Pain is,by definition, an unpleasant experience that ultimately interferes with their normalwell-being. Hence, bacterial infection, inflammation, and pain need medical assistance to maintain homeostasis. Conventional medicines possess so many repercussive effects, which then demand a replacement with a less toxic and more efficient modern drug. In their review article, for the first time, they present recent advancements in biomedical applications such as the antimicrobial, anti-inflammatory, and analgesic properties of noble metal nanoparticles. Noble metals have limited availability in the earth's crust. Hence, their physicochemical characterizations and applications are greatly limited. Still, there are some interesting research findings that offer a significant ray of hope for the health sector all over the world. 2023 Wiley-VCH GmbH. -
A hybrid level shifted carrier-based PWM technique for modular multilevel converters
This paper presents a hybrid level shifted carrier-based pulse width modulation (HLSC-PWM) technique for modular multilevel converters (MMCs). The concept of the proposed HLSC-PWM method is developed by combining the principles of phase disposition PWM (PD-PWM), phase opposition disposition PWM (POD-PWM), and alternate phase opposition disposition PWM (APOD-PWM) methods. The main aim of the proposed HLSC-PWM method is to generate an output voltage with half-wave and quarter-wave symmetries. The generated symmetrical PWM output voltage based on the proposed HLSC-PWM method provides less total harmonic distortion (THD) and enhances the DC-Link voltage utilization (DCLVU). A generalized mathematical model is formulated to develop a single HLSC for MMC with an N number of submodules (SMs) per arm. Theoretical analysis of DCLVU for the proposed method is described. The functionality and performance of the HLSC-PWM method are carried out on a three-phase five-level MMC in MATLAB/Simulink. A hardware prototype of a single-phase five-level MMC is designed for experimental validation. The proposed HLSC-PWM method is implemented on an Altera/Cyclone I series (EP1C12Q240C8N) field-programmable gate array (FPGA), simulation and experimental results are presented. 2021 The Authors. IET Power Electronics published by John Wiley & Sons Ltd on behalf of The Institution of Engineering and Technology -
Customer Evaluation of Internet Banking Services: Analysing South Indian Bank's Digital Banking Experience
This research intends to assess the valuation of Christ University's customers on internet banking services provided by South Indian Bank. The research objectives are to evaluate the impact of efficiency, security, ease of use, reliability and social influence on customer satisfaction in the context of internet banking. Consumers of Christ University were selected to answer in the survey to give their view and experience toward the internet banking services offered by the South Indian Bank. The strategies used in data analysis incorporated regression analysis to realize correlation between such factors and extent of customer satisfaction. The research offers huge information on how it is possible to enhance the levels of customer satisfaction specifically in internet banking services of South Indian Bank. Therefore, the study underpins an importance of enhancing digital banking platforms to fulfil the need and expectation of customers. The study is also beneficial for other financial institution with the aim at improving the level of customer satisfaction and ability to retain the clients in the realm of digital banking. 2025 IEEE.

