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Extending schizophrenia diagnostic model to predict schizotypy in first-degree relatives
Recently, we developed a machine-learning algorithm EMPaSchiz that learns, from a training set of schizophrenia patients and healthy individuals, a model that predicts if a novel individual has schizophrenia, based on features extracted from his/her resting-state functional magnetic resonance imaging. In this study, we apply this learned model to first-degree relatives of schizophrenia patients, who were found to not have active psychosis or schizophrenia. We observe that the participants that this model classified as schizophrenia patients had significantly higher schizotypal personality scores than those who were not. Further, the EMPaSchiz probability score for schizophrenia status was significantly correlated with schizotypal personality score. This demonstrates the potential of machine-learned diagnostic models to predict state-independent vulnerability, even when symptoms do not meet the full criteria for clinical diagnosis. 2020, The Author(s). -
Benzoyl hydrazine-anchored graphene oxide as supercapacitor electrodes
In this study, benzoyl-hydrazine anchored graphene oxide (BHGO) is synthesised using graphene oxide (GO) and benzoyl hydrazine (BH) via a simple, cost effective ultrasonic assisted chemical route. BH acted as a nitrogen source, reducing agent, and morphology modifier resulting in good electrochemical performance of BHGO. The supercapacitor behaviour of BHGO is investigated in different aqueous electrolytes and it exhibits a specific capacitance of 170 F g?1 at a current density of 1 A g?1 in 1 M H2SO4 and capacitive retention of 85% over 5000 cycles at 5 A g?1. This high performance is attributed to the enrichment of electroactive sites of GO through nitrogen moieties enhancing faradaic redox reactions and thereby the polarization at the electrode surface. 2020 Elsevier B.V. -
Role of supramolecular interactions in crystal packing of Strandberg-type cluster-based hybrid solids
Abstract: Two new Strandberg-type cluster-based phosphomolybdates {H-2a3mp}5[{PO3(OH)}{PO4}Mo5O15], 1 and {H-2a4mp}5[{PO3(OH)}{PO4}Mo5O15]6H2O, 2 have been crystallized via solvent evaporation technique using 2-amino-3-methylpyridine (2a3mp) and 2-amino-4-methylpyridine (2a4mp) respectively. The solids were characterized using single-crystal X-ray diffraction, powder X-ray diffraction, fourier transform infrared spectroscopy, thermogravimetric analysis, scanning electron microscopy and cyclic voltammetry. The solid 1 crystallized in monoclinic system with space group P21/c, a = 8.394(1), b = 27.398(6), c = 21.521(4) ? = 97.68(3), Z = 4. The solid 2 crystallized in triclinic system with space group P-1, a = 11.728(1), b = 14.234(1), c = 19.589(1) ? = 68.906(3), ? = 89.454(3), ? = 66.559(3), Z = 2. The solids 1 and 2 formed a supramolecular framework stabilized by hydrogen bonding interaction between cluster anions and organic moieties. CH? interactions between the organic moieties reinforced the crystal packing in 1 and 2. While crystal packing effects resulted in the formation of solvent-accessible voids in 1; aggregation of lattice water molecules in 2 facilitated the formation of pentameric water cluster. In addition, electrochemical behavior of 1 and 2 has also been investigated. Graphic abstract: Two new Strandberg-type cluster based phosphomolybdates, 1 and 2 have been crystallized via solvent evaporation technique using 2-amino-3-methylpyridine and 2-amino-4-methylpyridine. Detailed structural analysis revealed the role of supramolecular interactions in the crystal packing of these solids. In addition, electrochemical behavior of 1 and 2 has also been investigated.[Figure not available: see fulltext.] 2020, Indian Academy of Sciences. -
Evaluation of Corrosion Mitigation Performance of 1-(3,4,5-Trimethoxyphenylmethylidene)-2-Naphthylamine (TMPNA) Schiffs Base on Carbon Steel Using Electrochemical, Thermodynamic and Theoretical Approaches
A novel Schiff base,1-(3,4,5-trimethoxyphenylmethylidene)-2-naphthylamine(TMPNA) has been synthesized using naphthylamine and 3,4,5-trimethoxybenzaldehyde.The effective corrosion resistance and inhibition effect of TMPNA was studied at different concentrations in water medium on carbon steel by electrochemical techniques. The protective behavior of the passive film formed by the inhibitor was characterized through electrochemical impedance spectroscopy with an increased charge transfer resistance of 954 ?.cm2. The inhibition efficiency exhibited a gradual increase up to 92% with increase in schiff base concentration. Potentiodynamic polarization studies revealed that corrosion current decreased to 0.35 10?5A/cm2 with the addition of the inhibitor, TMPNA. Through various electrochemical studies such as impedance, polarization and electrochemical noise analysis (ENA), the concentration of TMPNA was optimized to 300ppm at which the maximum corrosion resistance was observed. Inhibition efficiency was found to decrease with increase in temperature. Also, the increased activation energy (Ea) value of 27kJ/mol confirmed that the inhibitor hindered the metal dissolution reaction. Adsorption of TMPNA on carbon steel/electrolyte interface was found to obey Langmuir adsorption isotherm. Scanning electron microscope (SEM) was used to evaluate the surface morphology. The Quantum chemical analysis (QCA) revealed that there was an electron transfer between TMPNA and the metal surface at ? 6.340eV. Molecular dynamic simulation study was carried out to investigate the adsorption of TMPNA on Fe (1 1 0) surface and adsorption energy value for the gaseous form was found to be ? 4197cal/mol. 2020, Springer Nature Switzerland AG. -
A Study of Factors of Internet Addiction and Its Impact on Online Compulsive Buying Behaviour: Indian Millennial Perspective
Compulsive Buying occurs when a person indulges in excessive purchasing overcome by social pressures and negative emotions. The main objective in this study is to garner insights into this issue from a marketing perspective and also to understand whether the millennials preference to avoid social contact physically but to crave for it in a virtual space has an impact. Conducted over a seven-month period with data collected and analyzed from 202 respondents in Bangalore, the study revealed that emotions like loneliness, depression, low self-esteem and anxiety encourage the respondents to go ahead and maintain relationships in a virtual space rather than engage in face-to-face interactions. Furthermore, it was realized that the growing Internet Addiction can also be positively related to online Compulsive Buying. This study is of high significance as it allows marketers to reach out and capture that segment of elusive customers who are always online and are guaranteed to make a purchase. Therefore, allowing companies can align their marketing strategies accordingly develop products and services, resulting in better sales revenues and repeat purchases. 2019 International Management Institute, New Delhi. -
Experimental Investigations on the Thermal Diffusion Characteristics and Photoluminescence in Multiphase Micro Fluids Containing ZnO Micro Tubes and Fluorescein Dye
Abstract: Scattering of light by disordered structures is normally detrimental to their applicability in many optoelectronic devices. However, some micro and nanostructures are useful in enhancing several optical and thermal properties like emission, heat diffusion etc. For this purpose, we have optimized the low temperature hydrothermal growth method for the ZnO micro tubes which leads to the growth of ZnO as mono dispersed micro tubes. Further, these samples were used to enhance the fluorescence efficiency of disordered media consisting of micro tubes of ZnO and fluorescein dye and to optimize the thermal diffusion of the mixture which will help us optimize the composition of these microscopic inclusions in designing a random lasing medium. Dual beam thermal lens method was used for this purpose. 2020, Pleiades Publishing, Ltd. -
Yulu: Moving Towards a Sustainable Future
The rapidly rising rate of urbanization, which is closely linked to economic growth, has exposed the world to several challenges such as inequality, environmental degradation, traffic congestion, infrastructural concerns and social conflicts. Therefore, urban sustainability has emerged as one of the most debatable discussions across the world. The existing network of transportation can no longer keep up with the growing demand in metropolitan cities. Short distance travel has become an unresolved issue for daily commuters. The case presents how MMVs have emerged as an alternative mode of transport for resolving issues of daily commuters regarding the first-mile connectivity, last-mile connectivity and short distance travel to reach their final destination. MMVs are basically light-weight vehicles which occupy less space on road. These vehicles include bicycles, e-bikes, skateboards, hoverboards and other battery-operated vehicles. The case narrates the journey of Yulu, a dockless bike-sharing venture which promoted the concept of green consumerism among the daily commuters at affordable rates. The venture initially started in the IT city of Bangalore and later expanded its operations to other cities such as Pune, Navi Mumbai, Gurugram and Bhubaneswar. The speciality of this venture is that it offers a sustainable solution to ever-increasing problems of traffic congestion and aggravating air pollution issues in metropolitan cities. Dilemma: How to offer a sustainable solution to the ever-increasing problem of traffic congestion and aggravating air pollution due to rising vehicular traffic? How to make short distance travel affordable and more convenient for daily commuters? Theory: Three pillars of sustainable development. Type of Case: Problem solving applied case. Protagonist: Present. Discussion and Case Questions: What strategies should be employed by the start-up to make it a more popular form of commute? How can the increasing rate of damage to the vehicles be brought down? How does organization structure and cluster management practices of Yulu help it to become more sustainable? How can the regulatory bodies and government promote and adopt such start-ups in their urban planning projects? 2020 SAGE Publications. -
Humour as a moderator of stress and defence based coping mechanisms among the youth of Kerala, India
The goal of this study was to examine the effect of the moderators of adaptive and maladaptive humour on stress and on the four levels of defence based coping mechanism amongst the youth of Kerala, India. Four hundred and fifty-three youth between the age of 18 and 40, selected from two different cities of North Kerala, India (Calicut, Malappuram) and Central Kerala, India (Cochin, Trissur), were asked to fill out three questionnaires assessing stress, coping and humour. Pearson's test of product-moment correlation indicated that stress had a positive and moderate statistically significant correlation with the first three levels of defence based coping mechanism (pathological defences, immature defences and neurotic defences). Furthermore, there was a positive and weak statistically significant correlation between stress and level-IV coping (mature defences). When positive and moderate correlation was found for stress with maladaptive humour, no significant correlation was found with adaptive humour. When coping was studied in relationship with humour, a negative and weak statistically significant correlation was found for level-I coping (pathological defences) with adaptive humour, whereas a positive and moderate statistically significant correlation was found with maladaptive humour. Here level-IV coping (mature defences) was found to have a positive and moderate statistically significant relationship with adaptive and maladaptive humour. Moderator analysis showed that maladaptive humour moderated the association between stress and four levels of defence based coping mechanism. The study implied that youth should be trained to use more of mature means of coping and adaptive humour styles in life. Universiti Putra Malaysia Press -
A hybridized semantic trust-based framework for personalized web page recommendation
The World Wide Web is constantly evolving and is the most dynamic information repository in the world that has ever existed. Since the information on the web is changing continuously and owing to the presence of a large number of similar web pages, it is very challenging to retrieve the most relevant information. With a large number of malicious and fake web pages, it is required to retrieve Web Pages that are trustworthy. Personalization of the recommendation of web pages is certainly necessary to estimate the user interests for suggesting web pages as per their choices. Moreover, the Web is tending towards a more organized Semantic Web which primarily requires semantic techniques for recommending the Web Pages. In this paper, a framework for personalized web page recommendation based on a hybridized strategy is proposed. Web Pages are recommended based on the user query by analyzing the Web Usage Data of the users. An array of strategies is intelligently integrated together to achieve an efficient Web Page Recommendation system. Latent Semantic Analysis is applied to the User-Term Matrix and the Term-Frequency Matrix that are built from the Web Usage Information to form a Term Prioritization Vector. Further, techniques like Latent Dirichlet Allocation for Topic-based Segregation of the URLs and Normalized Pointwise Mutual Information strategies are used for recommending web pages based on users queries. The Personalization is achieved by prioritizing the Web pages based on the Prioritization Vector. Also, a unique methodology is incorporated into the system to retrieve trustworthy websites. An overall Accuracy of 0.84 is achieved which is better than the existing strategies. 2018 Informa UK Limited, trading as Taylor & Francis Group. -
Facile synthesis of nickel nanoparticles and its efficient dye degradation
The present investigation involves the synthesis of nickel (Ni) nanoparticles (NPs) by the chemical reduction of nickel chloride using hydrazine hydrate without the need for an inert atmosphere from an external source. The photocatalytic activity, structure and morphology of the NPs were studied by employing UV-Visible (UV-Vis) spectroscopy, powder X-ray diffraction (PXRD) and transmission electron microscopy (TEM). Degradation of methylene blue(MB) and rhodamine B(Rh-B) dyes using Ni NPs was investigated to see the feasibility in degrading these dyes from polluted water at low cost. Ni NPs showed a good photocatalytic activity of 84.1% under visible light for the degradation of MB when compared to Rh-B which showed an efficiency of 47.3 %. 2020 World Research Association. All rights reserved. -
Preparation, characterization, and evaluation of corrosion inhibition efficiency of sodium lauryl sulfate modified chitosan for mild steel in the acid pickling process
The polar head and a hydrophobic long alkyl chain end of surfactants show effective adsorption on the metal surfaces and metal/solution interfaces. The present study deals with the investigation of corrosion inhibition efficiency of chitosan modified with an anionic surfactant, namely sodium lauryl sulfate. The modified chitosan was characterized using spectral techniques such as ATR- FTIR and NMR, thermal analytical methods that include TGA and DSC. The surface charge and particle size distribution were analyzed using Zeta potential analyzer. The corrosion inhibition efficiency of the water-soluble modified chitosan was evaluated using gravimetric and electrochemical methods. A maximum corrosion inhibition efficiency of 96.44% for 6 h of immersion period at 303 K was obtained. The adsorption process obeyed Langmuir isotherm. The adsorption mechanism involved both physisorption and chemisorption. Tafel and impedance studies showed results in agreement with the gravimetric method. Tafel plot indicates the inhibitor controlled both cathodic hydrogen evolution and anodic metal dissolution reactions. AC impedance study supports the increase in surface coverage of the metal surface by the inhibitor, forming a protective film. Further evidence comes from the surface characterization of the inhibited metal surface by contact angle measurement, SEM, EDAX spectra, and atomic force microscopic studies. DFT and Monte Carlo simulation studies showed a proper alignment with the experiment results. 2020 Elsevier B.V. -
Experimental investigation of turbulent flow behavior in an air to air double pipe heat exchanger using novel para winglet tape
Double pipe Heat exchangers are some of the important equipment which is seen in a variety of industrial applications. In the current study a new type of insert, namely Para-Winglet Tape inserts are investigated for thermal and flow behavior from Reynolds number 6000 to 30000. The Para-Winglet Tape inserts are investigated for three sets of pitches and para-inclinations. The inclusion of para-winglet tape on the tube has intensified the turbulent kinetic energy and has resulted in recirculation in-between the inserts. The arrangement of the para-winglet tape has proved their worthiness over the plain tube. The highest Nusselt number was obtained for Case9 at Reynolds number 30000 with an enhancement of 407% and the least was obtained by Case7 at Reynolds number 6000 with an enhancement of 88% compared to plain double pipe heat exchanger. The highest friction factor was obtained for Case3 at Reynolds number 30000 with an enhancement of 846% and the least was obtained by Case7 at Reynolds number 24000 with an enhancement of 286% compared to plain double pipe heat exchanger. The maximum and minium performance optimization index value of 2.69 and 1.09 was achieved for Case9 and Case1 at Reynolds number 30000 and 6000. 2020 The Author(s). -
Natural convection of water-copper nanoliquids confined in low-porosity cylindrical annuli
Natural convection in cylindrical porous annuli saturated by a nanoliquid whose inner and outer vertical radial walls are respectively subjected to uniform heat and mass influxes and out fluxes is studied analytically using the modified Buongiorno-Darcy model (MBDM) and the Oseen-linearization technique. Nanoliquid-saturated porous medium made up of water as base liquid, copper nanoparticles of five different shapes, viz., spheres, bricks, cylinders, platelets and blades, and glass balls porous material is considered as working medium for investigation. The thermophysical properties of nanoliquid -saturated porous medium is modeled using phenomenological laws and mixture theory. The effect of various parameters and individual effects of five different shapes of copper nanoparticles on velocity, temperature and heat transport are found. From the study, it is clear that the addition of a dilute concentration of nanoparticles increases the effective thermal conductivity of the system and thereby increases the velocity and the heat transport, and decreases the temperature. In other words, the heat transport is more in the case of heat and mass driven convection compared to purely heat-driven convection. Among the five different shapes of nanoparticles, blade-shaped nanoparticles facilitate the transport of maximum temperature compared to all other shapes. Maximum heat transport is achieved in a shallow cylindrical annulus compared to square and tall circular annuli. The increase of the inner solid cylinder's radius is to decrease heat transport. The results of the KVL single-phase model are obtained from the present study by setting to zero the value of the nanoparticles concentration Rayleigh number. Also, neglecting the curvature effect in the present problem, we obtain the results of the rectangular enclosure problem. 2020 The Physical Society of the Republic of China (Taiwan) -
A Note on J-colouring of Jahangir Graphs
In this paper, we discuss J-colouring of the family of Jahangir graphs.Note that the family of Jahangir graphs is a wide ranging family of graphs which by a generalised definition includes wheel graphs. We characterise the subset of Jahangir graphs which admit a J-colouring. 2019, The National Academy of Sciences, India. -
Investigation on Electrode/Electrolyte Interfaces through Impedance Spectroscopy
In the present paper, impedance measurements of the battery configuration, Anode?lithium borophosphate glass electrolyte?LiCoO2 cathode, has been carried out to throw some light on the electrochemical interfacial behavior between the chosen electrodes and electrolyte. The cathode material, lithium cobalt oxide (LiCoO2) has been prepared by three different techniques and characterized. Sol-gel synthesized LiCoO2 showed uniformly distributed spherical shape particles with an average size of 500 nm and also exhibited better electrochemical performance. Charging and discharging (23 cycles) of the battery indicated an OCV of 2 V. However, the theoretical OCV of 4 V could not be achieved. The poor performance of the battery could be attributed to the electrochemical processes and SEI film formation at the electrode/electrolyte interfaces. Impedance spectroscopy shows that the major contributions to the impedance of the battery are the electrolyte resistance and the electrode/electrolyte interfacial resistance. With each recharging cycle, the value of electrolyte resistance remains almost constant; however, the interface resistance increases, during the passage of current, due to the interfacial passive layer formation. 2020 Taylor & Francis Group, LLC. -
An organocatalytic C-C bond cleavage approach: A metal-free and peroxide-free facile method for the synthesis of amide derivatives
A facile organocatalytic approach has been devised towards the synthesis of amide derivatives using 1,3-dicarbonyls as easily available acyl-sources under peroxide-free reaction conditions. This transformation was accomplished by the cleavage of the C-C bond in the presence of TEMPO as an organocatalyst and excludes the use of transition-metals and harsh reaction conditions. A broad range of substrates with diverse functional groups were well tolerated and delivered the products in high yields. The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. -
Development and Validation of Emotion Recognition Software in the Indian Population
Though written extensively, recent debates on universality of emotions have shown that age, gender, and ethnicity have greater implications in the ability to identify expressions from faces. Facial emotion recognition deficits have been consistently shown in psychiatric conditions, which necessitates the need to construct a culturally sensitive tool. Fourteen actors depicted emotions such as happy, sad, anger, fear, surprise, disgust, and neutrality. From a total of 126 images, participants rated in terms of intensity and accuracy. Final software was developed with 28 images, and mean accuracy and reaction time were obtained. Friedmans significance test revealed a significant effect of emotion on its different dimensions. This study helped establish a culturally sensitive emotion recognition tool with the Indian population, which can be used in mental health settings for screening purposes and aid in developing rehabilitation modules. 2020, National Academy of Psychology (NAOP) India. -
Cation-controlled wetting properties of vermiculite membranes and its promise for fouling resistant oilwater separation
Manipulating the surface energy, and thereby the wetting properties of solids, has promise for various physical, chemical, biological and industrial processes. Typically, this is achieved by either chemical modification or by controlling the hierarchical structures of surfaces. Here we report a phenomenon whereby the wetting properties of vermiculite laminates are controlled by the hydrated cations on the surface and in the interlamellar space. We find that vermiculite laminates can be tuned from superhydrophilic to hydrophobic simply by exchanging the cations; hydrophilicity decreases with increasing cation hydration free energy, except for lithium. The lithium-exchanged vermiculite laminate is found to provide a superhydrophilic surface due to its anomalous hydrated structure at the vermiculite surface. Building on these findings, we demonstrate the potential application of superhydrophilic lithium exchanged vermiculite as a thin coating layer on microfiltration membranes to resist fouling, and thus, we address a major challenge for oilwater separation technology. 2020, The Author(s). -
Sentiment Analysis of COVID-19 tweets by Deep Learning ClassifiersA study to show how popularity is affecting accuracy in social media
COVID-19 originally known as Corona VIrus Disease of 2019, has been declared as a pandemic by World Health Organization (WHO) on 11th March 2020. Unprecedented pressures have mounted on each country to make compelling requisites for controlling the population by assessing the cases and properly utilizing available resources. The rapid number of exponential cases globally has become the apprehension of panic, fear and anxiety among people. The mental and physical health of the global population is found to be directly proportional to this pandemic disease. The current situation has reported more than twenty four million people being tested positive worldwide as of 27th August, 2020. Therefore, it is the need of the hour to implement different measures to safeguard the countries by demystifying the pertinent facts and information. This paper aims to bring out the fact that tweets containing all handles related to COVID-19 and WHO have been unsuccessful in guiding people around this pandemic outbreak appositely. This study analyzes two types of tweets gathered during the pandemic times. In one case, around twenty three thousand most re-tweeted tweets within the time span from 1st Jan 2019 to 23rd March 2020 have been analyzed and observation says that the maximum number of the tweets portrays neutral or negative sentiments. On the other hand, a dataset containing 226,668 tweets collected within the time span between December 2019 and May 2020 have been analyzed which contrastingly show that there were a maximum number of positive and neutral tweets tweeted by netizens. The research demonstrates that though people have tweeted mostly positive regarding COVID-19, yet netizens were busy engrossed in re-tweeting the negative tweets and that no useful words could be found in WordCloud or computations using word frequency in tweets. The claims have been validated through a proposed model using deep learning classifiers with admissible accuracy up to 81%. Apart from these the authors have proposed the implementation of a Gaussian membership function based fuzzy rule base to correctly identify sentiments from tweets. The accuracy for the said model yields up to a permissible rate of 79%. 2020 Elsevier B.V. -
Education for All: How Schooling Is Creating Social Changes for Lowered-Caste Girls in Rural India
Arguments for the expansion of formal schooling have long focused on individual outcomes from schooling, including increasing income, reducing poverty, delaying marriage, and improving health, particularly for girls and women. For nearly three decades now, global education agendas have supported girls education in an effort to achieve these outcomes. A large body of research analyzes girls individual empowerment from schooling, but less attention is given to how schooling is creating change in families and communities, particularly for lowered-caste girls in India. This article places longitudinal data from a three-year qualitative interview study of schoolgirls in Rajasthan alongside qualitative life-history interviews of girls who completed secondary school in Uttarakhand to understand how schooling affects social changes for lower castes. The analysis, using an intersectional and relational approach, illustrates how girls schooling shifts kin and caste relations connected to marriage and work but in ways that do not transform the stickiness of caste and gender norms. We argue that educational policies and programs must attend to the ways in which caste is implicated in achieving outcomes of delayed marriage and formal employment for lowered-caste girls in Indian communities if schooling is to create positive social change. 2020 by The Author(s).