Strategic design of MXene/CoFe2O4/g-C3N4 electrode for high-energy asymmetric supercapacitors
- Title
- Strategic design of MXene/CoFe2O4/g-C3N4 electrode for high-energy asymmetric supercapacitors
- Creator
- Mathew S.; Devi K.R. S.; Saravanakumar B.; Pinheiro D.
- Description
- MXenes are emerging as the next-generation materials for energy storage due to their substantial surface area, exceptional conductivity, and abundant surface-terminating groups. However, the tortuous path for ion transfer within the restacked layers significantly limits the electrochemical performance of multilayered MXenes. To overcome this, interlayer spacers have been introduced. These spacers help mitigate ion diffusion barriers and enhance the accessibility of active sites, thereby improving the overall efficiency and longevity of MXene-based supercapacitors and related devices. In this study, a rational material is designed by incorporating CoFe2O4 and g-C3N4 into the layers of MXene through ultrasonication for supercapacitor application. The physicochemical properties of the synthesized materials have been comprehensively characterized using diverse techniques, revealing that MXene/CoFe2O4/g-C3N4 has successfully evolved into a multilayered structure possessing enhanced surface area, low restacking tendency, high pore diameter, and excellent pore volume. Leveraging these properties, it performs as a viable material for fabricating the working electrode with a specific capacitance (Csp) of 1506.2 F g?1 at a current density of 5 A g?1 in 3 M KOH. It shows good stability with 89 % capacitance retention over 7000 cycles. An asymmetric supercapacitor (ASC) constructed with MXene/CoFe2O4/g-C3N4 as positive electrode and activated carbon as negative electrode exhibits an energy density of 79.8 Wh Kg?1 and power density of 1343.3 W Kg?1. Furthermore, it shows a capacitive retention of 91 % over 10,000 cycles. This MXene based composite, with excellent capacitance and outstanding stability, offers an appreciable performance in the field of sustainable energy storage. 2024 Elsevier B.V.
- Source
- Journal of Alloys and Compounds, Vol-1008
- Date
- 2024-01-01
- Publisher
- Elsevier Ltd
- Subject
- Electrode; Energy; MXene; Supercapacitor; Ultrasonication
- Coverage
- Mathew S., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bengaluru, 560029, India; Devi K.R. S., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bengaluru, 560029, India; Saravanakumar B., Department of Physics, Dr. Mahalingam College of Engineering and Technology, Tamil Nadu, Pollachi, 642003, India; Pinheiro D., Department of Chemistry, CHRIST (Deemed to be University), Karnataka, Bengaluru, 560029, India
- Rights
- Restricted Access
- Relation
- ISSN: 9258388; CODEN: JALCE
- Format
- Online
- Language
- English
- Type
- Article
Collection
Citation
Mathew S.; Devi K.R. S.; Saravanakumar B.; Pinheiro D., “Strategic design of MXene/CoFe2O4/g-C3N4 electrode for high-energy asymmetric supercapacitors,” CHRIST (Deemed To Be University) Institutional Repository, accessed March 14, 2025, https://archives.christuniversity.in/items/show/12680.