Synthesis, characterization, magnetic, thermal and electrochemical studies of Oxovanadium(IV) Complex of 2-thiophenecarba benzhydrazone
- Title
- Synthesis, characterization, magnetic, thermal and electrochemical studies of Oxovanadium(IV) Complex of 2-thiophenecarba benzhydrazone
- Creator
- Vijayan J.G.
- Description
- The hydrazone ligand obtained from 2-thiophene carboxaldehyde and benzhydrazide react with an equimolar mixture of vanadyl acetyl acetonate in methanol to yield oxovanadium(IV) complex of 2-thiophenecarba benzhydrazone. The prepared compound shows effective solubility in organic solvents like acetonitrile, DMF and DMSO. Molar conductivity data of oxovanadium( IV) complex of 2-thiophenecarba benzhydrazone revealed its nonelectrolytic behavior in DMF and DMSO. EPR spectra of 2-thiophenecarba benzhydrazonato oxovanadium(IV) was recorded in DMF at LNT and g and A values were calculated. The complex was proposed to be square pyramidal in geometry. Cyclic voltammograms of the complex in DMF were studied by changing the scan rates 50, 100, and 200 mV/s. ? E values of the complex showed the reversible criterion and ipc/ipa values which were close to 1 indicating the redox couple as reversible. Thermograms of the complex were recorded to find the weight loss at different temperature ranges. Matrix-assisted laser desorption ionization time-of-flight (MALDI-TOF) mass spectra showed mass number of the molecular ions. 2018 River Publishers.
- Source
- Advanced Polymeric Materials: Synthesis and Applications, pp. 59-72.
- Date
- 2018-01-01
- Publisher
- River Publishers
- Coverage
- Vijayan J.G., Department of Chemistry, Christ University, Bengaluru, India
- Rights
- Restricted Access
- Relation
- ISBN: 978-879360967-9; 978-879360968-6
- Format
- Online
- Language
- English
- Type
- Book chapter
Collection
Citation
Vijayan J.G., “Synthesis, characterization, magnetic, thermal and electrochemical studies of Oxovanadium(IV) Complex of 2-thiophenecarba benzhydrazone,” CHRIST (Deemed To Be University) Institutional Repository, accessed February 23, 2025, https://archives.christuniversity.in/items/show/18896.