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Determinants of renewable stock returns: The role of global supply chain pressure
This study investigates the determinants of the global renewable stocks index returns from November 2003 to August 2022. The explanatory variables include global supply chain pressure measures, climate policy uncertainty, global economic activity, and crude oil prices. The long-run panel dynamic Autoregressive Distributed Lag estimations show that the global supply chain pressure, climate policy uncertainty, and global economic activity redound renewable stock returns. These results are robust enough to utilise different long-run estimation techniques. Potential policy implications are also discussed. 2023 The Authors -
Examining the Impact of Argument Quality and Source Credibility on Consumers Behavioral Intention Toward Green Cosmetics: The Moderating Role of Perceived Innovativeness
Purpose: This study integrated the knowledge-attitude-behavior (KAB) model and the theory of planned behavior (TPB) to analyze how elements of electronic word of mouth (eWOM)argument quality (AQ) and source credibility (CR)influenced customers green cosmetics behavioral intention (BI). Methodology: Data were collected from a sample of 350 customers through an online survey, and a two-stage process was used to evaluate the research model. In the first stage, linear associations between the various elements of the theoretical model were determined using structural equation modeling (SEM). The second stage involved evaluating the predicting efficacy of the constructs, using an artificial neural network (ANN) framework. Findings: The findings of the multi-analytical study revealed that attitude (Atd), perceived behavioral control (Pbcon), and source credibility (CR) influenced consumers intentions to buy green cosmetics. Moreover, the sources credibility (CR) and the arguments quality (AQ) also positively influenced consumer attitude (Atd). The models appeared to have acceptable prediction accuracy based on the ANN studys root mean square of error (RMSE) values. Originality: The study contributed to the body of green cosmetics literature by integrating knowledge-attitude-behavior (KAB) and planned behavior (TPB) theory. The novelty of this research also lies in examining the moderating effect of perceived innovativeness (PI) for developing a robust predictive framework for green cosmetics purchase intention using artificial neural networks (ANN). 2024, Associated Management Consultants Pvt. Ltd.. All rights reserved. -
Commercialization potential of PET (polyethylene terephthalate) recycled nanomaterials: A review on validation parameters
Polyethylene Terephthalate (PET) is a polymer which is considered as one of the major contaminants to the environment. The PET waste materials can be recycled to produce value-added products. PET can be converted to nanoparticles, nanofibers, nanocomposites, and nano coatings. To extend the applications of PET nanomaterials, understanding its commercialization potential is important. In addition, knowledge about the factors affecting recycling of PET based nanomaterials is essential. The presented review is focused on understanding the PET commercialization aspects, keeping in mind market analysis, growth drivers, regulatory affairs, safety considerations, issues associated with scale-up, manufacturing challenges, economic viability, and cost-effectiveness. In addition, the paper elaborates the challenges associated with the use of PET based nanomaterials. These challenges include PET contamination to water, soil, sediments, and human exposure to PET nanomaterials. Moreover, the paper discusses in detail about the factors affecting PET recycling, commercialization, and circular economy with specific emphasis on life cycle assessment (LCA) of PET recycled nanomaterials. 2024 Elsevier Ltd -
Platinum decorated phosphorous doped graphitic carbon nitride supported molecularly imprinted carbon fibre electrode as a nano-interface for the detection of butylated hydroxy anisole
This research generated an electrochemical sensor using a carbon fibre (CFP) paper electrode coated using platinum-decorated phosphorous doped graphitic carbon nitride (Pt/PgCN). This sensor was designed to detect butylated hydroxy anisole (BHA) selectively and sensitively. The molecularly imprinted polymers (MIPs) were synthesized onto the Pt/PgCN coated CFP surface through electropolymerization using BHA as a template and 3-thiophene acetic acid as monomer. Numerous analytical methods were used to characterise the sensor electrode, including cyclic voltammetry, impedance spectroscopy, and electron microscopy. The results showed that the synergetic effect of PgCN, Pt nanoparticles, and PTAA, PgCN and Pt had a positive impact on the electrochemical detection, the sensor's linear range was determined to be between 5 10?10 M and 2.1 10?7 M. The sensor demonstrated excellent stability, good reproducibility, and high selectivity for detecting BHA. Moreover, the proposed sensor successfully detected BHA in real samples. 2024 Elsevier Ltd -
Post-Operative Brain MRI Resection Cavity Segmentation Model and Follow-Up Treatment Assistance
Post-operative brain magnetic resonance imaging (MRI) segmentation is inherently challenging due to the diverse patterns in brain tissue, which makes it difficult to accurately identify resected areas. Therefore, there is a crucial need for a precise segmentation model. Due to the scarcity of post-operative brain MRI scans, it is not feasible to use complex models that require a large amount of training data. This paper introduces an innovative approach for accurately segmenting and quantifying post-operative brain resection cavities in MRI scans. The proposed model, named Attention-Enhanced VGG-U-Net, integrates VGG16 initial weights in the encoder section and incorporates a self-attention module in the decoder, offering improved accuracy for postoperative brain MRI segmentation. The attention mechanism enhances its accuracy by concentrating on a specific area of interest. The VGG16 model is comparatively lightweight, has pre-trained weights, and allows the model to extract incredibly detailed information from the input. The model is trained on publicly available post-operative brain MRI data and achieved a Dice coefficient value of 0.893. The model is then assessed using a clinical dataset of postoperative brain MRIs. The model facilitates the quantification of the resected regions and enables comparisons with each brain region based on pre-operative images. The capabilities of the model assist radiologists in evaluating surgical success and directing follow-up procedures. 2024 by the authors of this article. -
An ensemble deep learning model for automatic classification of cotton leaves diseases
Cotton plant (Gossypium herbaceum), is one of the significant fiber crop grown worldwide. However, the crop is quite prone to leaves diseases, for which deep learning (DL) techniques can be utilized for early disease prediction and prevent stakeholders from losing the harvest. The objective of this paper is to develop a novel ensemble based deep convolutional neural network (DCNN) model developed on two base pretrained models named: VGG16 and InceptionV3 for early detection of cotton leaves diseases. The proposed ensemble model trained on cotton leaves dataset reports higher training and testing prediction accuracies as compared to the base pretrained models. Given that, deep learning architectures have hyper-parameters, this paper presents exhaustive experimental evaluations on ensemble model to tune hyper-parameters named learning rate, optimizer and no of epochs. The suggested hyper-parameter settings can be directly utilized while employing the ensemble model for cotton plant leaves disease detection and prediction. With suggested hyper-parameters settings of learning rate 0.0001, 20 epochs and stochastic gradient descent (SGD) optimizer, ensemble model reported training and testing accuracies of 98% and 95% respectively, which was higher than the training and testing accuracies of VGG16 and InceptionV3 pretrained DCNN models. 2024 Institute of Advanced Engineering and Science. All rights reserved. -
Patriarchy and Wifehood: A Feminist Reading of One Part Woman and Singarevva and the Palace
Marriage is a socially approved relationship between a man and a woman that binds each other into a permanent, official relation of husband and wife. In a patriarchal culture, the husbands personify dominance and liberty, whereas the wives are expected to be the epitome of fidelity, fecundity and chastity. In the Indian context, the intense devotion of wives towards their husbands defines married women as pativratas. The present study intends to analyze the various aspects that contribute to and shape the formation of the identity of a wife in a marital space through Ponna and Singarevva, the female protagonists of the novels One Part Woman and Singarevva and the Palace, respectively. The paper demonstrates how these female protagonists identity as wives gets suppressed over a period of time and how they succeed in reconstructing their identities, sailing against all odds stacked against them. The paper views these issues through the feminist theoretical lens. 2024 IUP. All Rights Reserved. -
Innovation and Progress: An Insight into the Indian Business Start- Ups and the Promotion of Scientific Temper for Socio-Economic Advancement
The Constitution of India through its 42nd Amendment of 1976, incorporated scientific temper' as one of the Fundamental Duties to every Indian citizen under Article 51 A (h). The first Prime Minister of India, Pandit Jawahar Lal Nehru mentions this term in his book Discovery of India where he characterized scientific temper as a mind-set to change or alter one's intuition in the light of evidences and not to accept anything which appears to be irrational or without proof. Our country has consistently put forth attempts to concede to the scientific temper, time and again and emphasised its significance. In 2013, the Science, Technology, and Innovation policy, developed by the Government of India pushed on the advancement of scientific temper amongst every citizen. However, it needs to go quite far to appropriately show this temperament while fostering the resolutions for achieving socio-economic goals of the country. Presently, it has been noticed that business ventures are intensely reliant uponscientific temper and this will be ultimately essential for the entrepreneurs to succeed. Thus, small and micro undertakings backed by competitive and state of the art technology will be the foundation for greater enterprises in the country, resulting in economic boom. All future businesses will be driven by science and technology and hence, it is called for addition of new avenues and enterprises, with changing time and further with scientific temper as its major ingredient. Start-ups can be considered as one such innovation that has been leading businesses growing by leaps and bounds. In India, the last decade emerged with great start-ups like CRED, Meesho, Swiggy, Zomato, Delhivery, Oyo and many more, making itself one of the most important start-up hubs in Asia and perhaps even in the world. The scientific temper in start-ups can further do wonders to Indias socioeconomic growth in the long run. Hence, in this paper, the authors shall make an attempt to bring out the essence of scientific temper in bringing forth the technologically advanced start-ups in India and its capacity to form the basis of India's future in the global market, in terms of both technological advancements and entrepreneurship. The paper will also highlight the hindrances to its growth and suggest measures in contributing to the growth of start-up ecosystem in India. 2024, Department of Law, University of North Bengal. All rights reserved. -
A computational approach for the generalised GenesioTesi systems using a novel fractional operator
This article presents the novel fractional-order GenesioTesi system, along with discussions of its boundedness, stability of the equilibrium points, Lyapunov stability, uniqueness of the solution and bifurcation. The efficient predictorcorrector approach is employed to quantitatively analyse the GenesioTesi system in fractional order. The findings enable conceptualisation and visualisation of the presented novel fractional-order GenesioTesi systems. The modified systems are proposed for future study on chaos control and applying the same for secure communication. Bifurcation analysis is carried out to see the variation in the systems behaviour from stability to chaos. The results of the bifurcation analysis support the results obtained for the stability of the equilibrium points. The system behaves chaotically since all the equilibrium points are unstable. The findings demonstrate a torus attractor for some of the suggested systems and a chaotic attractor for some of the novel fractional-order GenesioTesi systems. The systems torus attractor changes into a steady state when the order is reduced from integer to fractional. Changing the parameter values for one of the modified systems also shifts the systems behaviour, with the point attractor replacing the torus attractor. The point attractor of one of the systems changes into a steady character when the systems order is reduced from integer to fractional. The behaviour for one modified system is the same for fractional and integer orders. This discovery paves the way for the future study of the modified GenesioTesi system. This article gives a new direction to utilise these proposed GenesioTesi systems and study them extensively. The chaotic behaviour of the modified system can be used for secure communication. The synchronisation and chaos control of the modified system is recommended. 2024, Indian Academy of Sciences. -
Rationally designed CeO2 decorated Ti3C2 MXene interface for efficient water splitting and enhanced supercapacitor performance
MXenes serve as competent electrodes for applications such as energy storage and conversion owing to their unique characteristics, which include substantial surface area, excellent conductivity, abundant surface-terminating groups, and high hydrophilicity. However, MXene nanosheets exhibit a pronounced tendency to restack via Van der Waals force, hindering the active sites and resulting in sluggish electronic and ionic kinetics. This phenomenon limits the capabilities, processability, and overall performance of MXene. In this study, CeO2 is utilized as an interlayer spacer for the Ti3C2 MXene substrate, providing a promising noble metal-free multifunctional electrode. The Ti3C2/CeO2 composite, synthesized via the hydrothermal method, efficiently mitigates restacking while exhibiting excellent conductivity, substantial surface area, and enhanced kinetics. The as-synthesized catalysts undergo diverse physiochemical characterizations and electrochemical measurements to understand their properties and potential multiapplications. The fabricated electrode material, Ti3C2/CeO2, shows excellent specific capacitance of 1908.5 Fg?1 at 1 Ag?1 in a three-electrode setup using 3 M KOH as electrolyte. It has a capacitive retention of 91% even after 4000 cycles. Besides, Ti3C2/CeO2 also functions as a proficient electrode material for overall water splitting, having a lower overpotential of 178 mV and 350 mV for hydrogen and oxygen evolution reactions, respectively, at a current density of 10 mAcm?2. It also displays a lower cell voltage of 1.78 V to obtain a current density of 10 mAcm?2. This study introduces the multi applications of a well-designed interface between Ti3C2 layers and CeO2 within the realm of electrochemical energy storage and conversion. 2024 Elsevier B.V. -
Drivers of Rural Non-farm Sector Employment in India, 19832019
Using the national-level employment and unemployment surveys (NSS and PLFS) and the macro-level data for the period 20052019, this article explores the trends and recent growth patterns of rural non-farm sector employment in India. It also examines the micro-level factors determining individuals preference towards non-farm sector jobs and the macro-level factors responsible for the growth of non-farm sector employment in rural India. The main findings of the study suggest that although rural non-farm sector employment is rising in absolute terms, its growth rate has slackened in recent years. While the level of education and skill training, market wage rates and socio-cultural setups are among the key micro-level factors determining farmnon-farm employment choices of rural folks, at the macro-level, the growth of investment in capital goods, the number of factories, investment in infrastructure development and the growth of the manufacturing sector are crucial for the growth of non-farm sector jobs in India. Based on these findings, it is argued that the improvement of human capabilities through increased investment in education and skill, and the growth of non-farm sector employment through the development of rural infrastructure and industrialization measures, are necessary to sustain the structural transformation and to harness the demographic dividend in India. JEL Codes: J01, J21, J43, J64 2024 Research and Information System for Developing Countries & Institute of Policy Studies of Sri Lanka. -
Precise surface molecular engineering of 2D-Bi2S3 enables the ultrasensitive simultaneous detection of dopamine, epinephrine, serotonin and uric acid
Multiple biomolecule detection at a single read is an emerging and highly desirable technology in point-of-care diagnostics. Thus, functional nanoscale materials with high precision and stability at an affordable cost are required to fabricate adaptable multiplex biosensing devices with exceptional performance. Herein, an ultrasensitive molecularly engineered 2D-Bi2S3 biosensor is developed via a two-step synthetic approach. Simultaneous detection of dopamine (DA), epinephrine (EP), serotonin (ST), and uric acid (UA) is achieved at the nanomolar level. The surface molecular engineered 2D-Bi2S3 by 4-mercaptobenzoic acid (MBA) exhibits a well crystalline nature and consists of 36 stacked layers with creased-paper-like morphology after an MBA molecule has been precisely linked at the basal plane of Bi2S3. Bi2S3-MBA's surface/vibrational spectroscopic and scanning tunneling microscopic studies demonstrate the Bi2S3-MBA electronic nature and the linked molecule present on the Bi2S3 surface with a comparatively large random distribution of MBA molecules at the basal plane than the edge plane. The density functional theory (DFT) calculation verifies the proposed molecular interaction mechanism. The success of this unique surface molecular engineering strategy, which effectively modified the electronic and surface configuration of the 2D-Bi2S3, offers an exciting possibility for building different variants of the versatile biosensor for real-world diagnostic device applications. 2024 -
Classification of adaptive back propagation neural network along with fuzzy logic in chronic kidney disease
A steady deterioration in kidney function over months or years is known as chronic kidney disease (CKD). Through a range of techniques, such as pharmacological intervention in moderate cases and hemodialysis and renal transport in severe cases, early identification of CKD is crucial and has a substantial influence on reducing the patient's health development. The outcomes show the patient's kidneys' present state. It is suggested to develop a system for detecting chronic renal disease using machine learning. Finding the best feature sets typically involves using metaheuristic algorithms since feature selection is an NP-hard issue with amorphous polynomials. Semi-crystalline tabu search (TS) is frequently used for both local and global searches. In this study, we employ a brand-new hybrid TS with stochastic diffusion search (SDX)-based feature selection. The adaptive backpropagation neural network (ABPNN-ANFIS) is then classified using fuzzy logic. Fuzzy logic may be used to combine the ABPNN findings. Consequently, these techniques can aid experts in determining the stage of chronic renal disease. The Adaptive Neuron Clearing Inference System (ABPNN-ANFIS) was utilised to develop adaptive inverse neural networks using the MATLAB programme. The outcomes demonstrate that the suggested ABPNN-ANFIS is 98 % accurate in terms of efficiency. 2024 -
Informal Waste Recycling in Dharavi A Marxist Feminist Reading of The Women of Wasteland
[No abstract available] -
Tweaking the electrocatalytic ability of Cu-MOF by the inclusion of PTA: a selective electrochemical sensor for resorcinol
Resorcinol (RL) is a phenolic compound that is extensively utilized in the industrial sector, mostly for skin care applications as an antiseptic and disinfectant. However, this chemical has the potential to be very hazardous to people and the environment due to its pernicious nature in the environment owing to its high degree of toxicity and weak degradation capacity. Finding novel analytical techniques to monitor RL is therefore crucial. A facile and superior electrochemical fabrication route was procured to develop the composite of Cu-BTC-MOF/PTA/CFP for the sensitive detection of resorcinol (RL). The modified Cu-BTC-MOF/PTA/CFP (copper benzene-1,3,5-tricarboxylate-poly-3-thiophene acetic acid) electrode displayed improved electron transport features as well as excellent electrocatalytic performance. The developed electrode was characterized using physicochemical and electrochemical techniques. The enhanced electrochemical activity of the Cu-BTC-MOF/PTA/CFP electrode compared to the individual MOF and polymer electrode was examined using electrochemical characterization, which revealed a 10-fold increase in the current response for Cu-BTC-MOF/PTA/CFP (0.004 A) compared to the bare electrode. The cyclic voltammetric analysis of the Cu-BTC-MOF/PTA/CFP electrode in the presence of 120 nM analyte gave an oxidation peak at 0.62 V and a 5.4-fold increase in the current peak compared to the bare CFP electrode suggesting a higher sensitivity in sensing the analyte. The limit of detection for RL under optimal conditions was calculated to be 8 nM with a broad linear range from 0.025 ?M to 350 ?M. In addition, the Cu-MOF/PTAA/CFP electrode was scrutinized for its stability, reproducibility, and selectivity. Real sample analysis was carried out to validate the analytical applications. 2024 RSC. -
USER EXPERIENCES OF CHATGPT AMONG ENGINEERING STUDENTS, TEACHERS, AND WORKING PROFESSIONALS IN INDIA
The introduction of Chat Generative Pre-Trained Transformer (ChatGPT) in November 2022 brought about rapid changes in the workplace and academia. Its usage ranged from student assignments to workplace targets in the engineering field. Although it has brought novel ideas to its application in various fields and task efficiency in the workplace, its perceived application varies among students, teachers, and professionals. This study employed the snowball sampling technique and interviews with eight students, eight faculty members, and eight working professionals from computer science engineering who used ChatGPT regularly. The study adopted a qualitative research design and employed the narrative data analysis technique. Researchers conducted in-depth, semi-structured interviews to elicit user experiences from the recruited samples. The findings brought out six main and twelve subordinate themes regarding ChatGPT user experiences: adapt, adopt, embrace, ease, speed, engage, and automate. The inclusion criteria involved ChatGPT users from the computer science engineering domain only. Future research may focus on developing ChatGPT user policies for various fields of their applications. 2024, Grand Canyon University. All rights reserved. -
Heat transfer in a dissipative nanofluid passing by a convective stretching/shrinking cylinder near the stagnation point
This contemporary article examines the transfer of heat properties and the flow behavior of water-based nanofluid suspended with silver nanoparticles. These silver nanoparticles have a very huge thermal conductivity and hence it is presumed that the resulting nanofluid shall have enhanced thermal conductance. This article is more focused on the study of (Formula presented.) nanofluid flowing past a cylinder that is modeled mathematically using the cylindrical coordinate system. The initial modeling is designed using a system of partial derivatives while at a later stage, this system is transformed into a nonlinear group of ordinary differential equations (ODEs). The equations in this system are solved to obtain the dual solutions by implementing the RKF-45 method which has a greater rate of convergence and additionally, it is computationally very effective. The findings of the study are dealt by plotting graphs and the discussions are based on the appearance of graphs. It is further noticed that the critical point (Formula presented.) remains constant at (Formula presented.) for any changes made in the values of heat generation/absorption coefficient. Similarly, the critical value remains constant at (Formula presented.) for any change made in the values of the Eckert number. Meanwhile, it is also observed that the increase in the Eckert number increases the temperature absorbed by the nanofluid whereas it decreases the Nusselt number. Furthermore, the higher values of the velocity slip reduce the skin friction coefficient. 2023 Wiley-VCH GmbH. -
Development and Validation of the UV-Spectrophotometric Method for the Determination of Cordycepin, a Nucleoside
The primary, bioactive component of Cordyceps militaris, known as cordycepin (3'-deoxyadenosine), has been utilized extensively as a traditional medicinal ingredient and a nutritious diet in Asian nations. To determine the amount of cordycepin in the C. militaris, high-performance liquid chromatography (HPLC) is shown to be an effective, sensitive, and straightforward analytical technique. Other methods for estimating cordycepin include near infrared spectroscopy and capillary electrophoresismass spectrometry. The UV-Vis spectroscopy approach was used to quantify cordycepin, and the results were statistically confirmed and compared with an HPLC method. For linearity, repeatability, precision, reproducibility, limit of detection and limit of quantification, the method was verified. The established approach can be utilized for routine, quality control analysis of cordycepin, as it is easy to use, sensitive, accurate, precise, repeatable, and most importantly, cost-effective. Springer Science+Business Media, LLC, part of Springer Nature 2024. -
Need of integrated care model for positive childbirth experience in Indian maternity care services
BACKGROUND: Integrated care (IC) models are an emerging trend in healthcare reforms worldwide, especially in the maternal healthcare system. This research focuses on the scope of an integrated model for intrapartum care of women and explores the experience of birth under two intrapartum care modelsbiomedical and midwifery models, respectively. The term positive childbirth experience (PCE) is a concept defined by the World Health Organization (WHO) in the recommendations on intrapartum care for a PCE. MATERIALS AND METHOD: This study is convinced to employ a qualitative approach to explore how birth is experienced by women under maternity healthcare services in Kerala. A semi?structured interview was conducted to tap into the lived reality of birthing of sixteen first?time mothers (primipara) aged between 20 and 30 years under these two models. Furthermore, five participants have been specifically interviewed after their vaginal birth after a C?section (VBAC) experience. To achieve a systematic cross?case thematic analysis, systematic text condensation (STC) has been employed as a data analysis method. RESULTS: Four main categories were identified through the analysis as follows: (1) information and knowledge, (2) confidence, (3) quality of care, and (4) health?promoting perspective. These central themes evolved from 11 subthemes. CONCLUSION: The data analysis reveals both negative and positive experiences under two care models. It emphasizes the urgent need to reframe the biomedical?focused care model and adopt an integrated approach that aligns with the global intrapartum care model proposed by the World Health Organization (WHO) in 2018 and the definition of IC mentioned in the paper. 2024 Journal of Education and Health Promotion. -
Synthesis of SnO2-Sodium alginate-polyethylene glycol-crocin nanocomposite for enhanced antimicrobial and anticancer activity
Bacteria and fungi contribute to antibiotic resistance, posing a growing threat to human health, while cervical cancer remains a significant health concern, impacting women's well-being and mortality rates worldwide. In the present work, the efficiency of formulated tin oxide-sodium alginate-polyethylene glycol-crocin nanocomposites (SnO2-SAPEG-Cro-NCs) on antimicrobial as well as growth inhibition and apoptosis induction in cervical cancer cells was evaluated. The developed nanostructure was exposed to several spectroscopic investigations, including UV, FTIR, XRD, PL, EDAX, DLS studies, and FESEM structural observation. The results of the antimicrobial study revealed increased inhibition zones from 8.5 to 16 mm around the SnO2-SAPEG-Cro-NCs treatment over different pathogens, which proves its antimicrobial efficacy. The findings of the MTT study demonstrated that SnO2-SAPEG-Cro-NCs (0.510 ?g/mL) treatment remarkably inhibited the HeLa cell viability with IC50 concentration of 5 ?g/mL. The SnO2-SAPEG-Cro-NCs-treated HeLa cells also revealed increased intracellular ROS generation at 5 and 7.5 ?g/mL, which may facilitate oxidative stress-mediated cell death. Further, the dual staining and DAPI staining results demonstrated that the SnO2-SAPEG-Cro-NCs treatment effectively increased the apoptosis in the cervical cancer HeLa cells. Overall, the outcomes authorized that SnO2-SAPEG-Cro-NCs is an excellent antimicrobial and anticancer agent for future use. 2024 Elsevier B.V.