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Green Synthesized ZnO Nanoparticles as Biodiesel Blends and their Effect on the Performance and Emission of Greenhouse Gases
Pollution and global warming are a few of the many reasons for environmental problems, due to industrial wastes and greenhouse gases, hence there are efforts to bring down such emissions to reduce pollution and combat global warming. In the present study, zinc oxide nanoparticles are green synthesized using cow dung as fuel, through combustion. Synthesized material was characterized by FTIR, XRD, UV, and FESEM. The as-prepared ZnO-GS NPs were employed as a transesterification catalyst for the preparation of biodiesel from discarded cooking oil. The biodiesel obtained is termed D-COME (discarded cooking oil methyl ester), which is blended with 20% commercial diesel (B20). Additionally, this blend, i.e., B20, is further blended with varying amounts of as-prepared ZnO-GS NPs, in order to ascertain its effects on the quality of emissions of various greenhouse gases such as hydrocarbons, COx, NOx. Moreover, the brake thermal efficiency (BTHE) and brake specific fuel consumption (BSFC) were studied for their blends. The blend (B20) with 30 mg of ZnO-GS, i.e., B20-30, displays the best performance and reduced emissions. Comparative studies revealed that the ZnO-GS NPs are as efficient as the ZnO-C NPs, indicating that the green synthetic approach employed does not affect the efficiency of the ZnO NPs. 2022 by the authors. Licensee MDPI, Basel, Switzerland. -
Covert Conditioning for Persistent Aggressive Behaviors: A Case Illustration
In psychotherapy practice and training, single case study design plays an indispensable role by effectively articulating the application of textbook knowledge, thereby bridging the gap between theory and practice. This article, on similar lines, illustrates one such successful example of the application of the classical behavioral technique of covert conditioning modified with a component of verbal challenging. A woman in her late-thirties reported with long-standing seemingly-resistant-to-treat symptoms of aggressive behavior of beating children. The client had a total of 10 daily sessions of 6090 minutes each. By the end of one week, she reported not beating children in this period. She felt extremely relieved because it had happened for the first time in 10 years. The intensity of anger had decreased drastically, and she was not shouting any longer. She had to discontinue sessions abruptly due to unavoidable circumstances. Although she was suggested to follow up the intensive sessions again, she was not able to do it due to feasibility issues. The improvement was maintained on follow-up visits after two weeks, four weeks, and three months. 2021 The Author(s). -
Identification of coronary artery stenosis based on hybrid segmentation and feature fusion
Coronary artery disease has been the utmost mutual heart disease in the past decades. Various research is going on to prevent this disease. Obstructive CAD occurs when one or more of the coronary arteries which supply blood to myocardium are narrowed owing to plaque build-up on the arteries inner walls, causing stenosis. The fundamental task required for the interpretation of coronary angiography is identification and quantification of severity of stenosis within the coronary circulation. Medical experts use X-ray coronary angiography to identify blood vessel/artery stenosis. Due to the artefact, the image has less clarity and it will be challenging for the medical expert to find the stenosis in the coronary artery. The solution to the problem a computational framework is proposed to segment the artery and spot the location of stenosis in the artery. Here the author presented an automatic method to detect stenosis from the X-ray angiogram image. A unified Computational method of Jerman, Level-set, fine-tuning the artery structure, is developed to extract the segmented artery features and detect the arterys stenosis. The current experimental outcomes illustrate that this computational method achieves average specificity, sensitivity, Accuracy, precision and F-scores of 95%, 97.5%, 98%, 97.5% and 97.5%, respectively. 2023 The Author(s). Published by Informa UK Limited, trading as Taylor & Francis Group. -
Advanced Computational Method to Extract Heart Artery Region
Coronary artery disease, also known as coronary heart disease, is the thinning or blockage of heart arteries, which is generally caused utilizing the build-up of fatty material called plaque. The coronary angiogram test is currently the most utilized method for identifying the stenosis status of arteries in the heart. The objective of the proposed hybrid segmentation method is to extract the artery region of the heart from angiogram imagery. Numerous angiogram video clips have been considered in the dataset in this research work. These video clips were acquired from a healthcare center with the due consent of patients and the concerned healthcare personnel. Most angiogram videos consist of unclear images, or the contents are generally not clear, and medical experts fail to acquire accurate information about the damages or blocks formed in arteries due to the same reason. A hybrid computational method to extract well-defined images of heart arteries using Frangi and motion blur features from angiogram imagery has been proposed to address this issue. Fifty patients' information has been used as the dataset for experimentation purposes in this research work. The enhanced Frangi filter is used on the dataset to obtain edge information to enhance the input image based on the Hessian matrix. Further, the motion blur helps in automatically tracking/tracing the pixel direction using the optical flow method. In this method, the complete structure of the artery is extracted. The results, when compared to the existing methods, have proven to be novel and more optimal. 2022 Seventh Sense Research Group. -
A Perspective on Challenges and Opportunities of Supply Chain Management
Global Journal of Arts and Management Vol. 2, No. 3, pp. 227 - 231, ISSN No. 2249-2658 -
Stocks and throughput Accounting on Material Management and its Impact on Cost Management
Global Journal of Arts and Management, Vol. 2, No. 3, pp. 244-246, ISSN No. 2249-2658 -
Nouveau shoppers buying behavior pattern and perception towards luxury brands
The customer perception towards purchasing luxury brands has various psychological patterns and the behviour towards purchasing such brands differs accordingly. The main objective of the study is to map the nouveau shoppers mind-set towards shopping malls and to analyze the buying behavior pattern and perception towards luxury brand on shopping malls. For this purpose a sample of 130 was collected from the respondents were percentage analysis, descriptive statistics, Kruskall Wallis test and Oneway anova were used as tools to analye the data. The conclusion is that shopping malls have higher potentiality to pull the customers to visit their places but the conversion of making every customers purchasing in the mall is based on various factors of each individual shops. The conversion towards making the consumers purchasing the products can be done to attractive displays and understanding the mindset of modern shoppers towards various products and brand. 2020 Webology Center. -
Smart Home Systems Using Wireless Sensor Network - A Comparative Analysis
International Journal of Computer Engineering & Technology, Vol-3 (3), pp. 94-103. ISSN-0976-6367 -
Design and performance analysis of eight channel demultiplexer using 2D photonic crystal with trapezium cavity
In this work, an eight-channel dense wavelength division multiplexing demultiplexer is designed with a 2D photonic crystal triangular lattice. The proposed demultiplexer consists of a centre bus waveguide, an isosceles trapezium resonant cavity, and an eight-circular ring cavity (CR1, CR2, CR3, CR4, CR5, CR6, CR7, and CR8). The point defect resonant cavity consists of seven rods to drop different wavelengths from eight cavities, each of eight drop waveguides. The design is very simple to realise. The finite difference time domain and plane wave expansion method methods were used to analyse the proposed designs band structure and transmission spectrum. The resonant wavelengths are 1.5441 ?m, 1.5443 ?m, 1.544 49 ?m, 1.5447 ?m, 1.5449 ?m, 1.5451 ?m, 1.5453 ?m, and 1.5455 ?m respectively. The proposed device provides a high-quality factor, transmission efficiency, and low crosstalk. The devices footprint is 490.0 ?m2, which can be easily incorporated into photonic integrated circuits. 2023 IOP Publishing Ltd. -
Evaluation of phytoconstituents of Triticum aestivum grass extracts on nutritional attributes, antioxidant, and antimicrobial activities against food pathogens with molecular in silico investigation
The plant-based medicine and diet is gaining importance in recent days. The consumption of Triticum aestivum grass in the form of juice and tablets is increasing among common people. The present study elaborates on the nutritional, antioxidant, and antimicrobial potential of a nongenetically modified type of T. aestivum grass, along with the evidence of molecular docking studies. The T. aestivum grass extracts like decoction, aqueous, ethanol, and chloroform were subjected to preliminary phytochemical tests, quantitative estimation, antioxidant analysis, and antimicrobial activity determination. The ethanolic extract that had good antioxidant and antimicrobial potential was subjected to gas columnmass spectroscopy (GCMS) analysis and the compounds identified were docked against the antioxidant and antimicrobial receptors. The decoction and aqueous extracts performed well in preliminary qualitative tests with the presence of most of the phytochemicals tested. The decoction, aqueous, and ethanolic extracts possessed good concentrations of the phytochemicals. The decoction had about 210.839.16 and 154.160.33mg/g of carbohydrates and proteins, respectively, while the aqueous extract had about 10.910.08mg/g of amino acids and the ethanolic extract had about 52.51.4mg/g of phenolic content, which were the highest concentration of the phytochemicals observed among the extracts. Along with phytochemical potential, good antioxidant potential in the DPPH and ABTS by decoction as well as ethanolic extract with nearly 40 and 90% inhibition, respectively, and in FRAP by aqueous extract with maximum OD value. The ethanolic extract exhibited the best inhibition potential against the Staphylococcus aureus about 281mm, Pseudomonas aeruginosa with 202mm, Bacillus cereus at 201mm by the ethanolic extract at 200?g concentration, and Aspergillus fumigatus and A. niger at 150mm by the aqueous extract at 200?g concentration. The GCMS analysis revealed the presence of terpenoids, alkaloids, and phenols, which on docking had highest binding capacity toward the antioxidant and antimicrobial receptors. 2023 The Authors. Food Frontiers published by John Wiley & Sons Australia, Ltd and Nanchang University, Northwest University, Jiangsu University, Zhejiang University, Fujian Agriculture and Forestry University. -
Machining Characteristics Evaluation of Al7075TiB2 In Situ Composite Using Abrasive Water Jet Machining with Varied Test Parameters
The study delves into the abrasive water jet (AWJ) cutting of an Al7075TiB2 metal matrix composite that was synthesized in situ. The primary goal is to investigate how variations in three key process parameters, namely, stand-off distance (SOD) ranging from 0.5 to 2.5mm, abrasive flow rate (100 to 300gmin), and traverse speed (100 to 500mmmin), affect three critical performance metrics: volumetric material removal rate (VMRR), dimensional accuracy, and surface roughness (SR). The study's findings were represented graphically, highlighting the relationships between these responses and the aforementioned process parameters. Scanning electron microscopy (SEM) was also used to examine the machined surfaces. It was discovered that increasing traverse speed resulted in significant increases in surface roughness, VMRR, and dimensional errors. An increase in the SOD, on the other hand, resulted in an increase in surface roughness, VMRR, and a decrease in dimensional accuracy. Furthermore, increasing the abrasive flow rate resulted in lower surface roughness and dimensional accuracy while achieving a higher VMRR. 2023, The Institution of Engineers (India). -
Mathematical approach for impact of media awareness on measles disease
During the recent pandemic caused by COVID-19, media awareness played a crucial role in educating people about social distancing, wearing masks, quarantine, vaccination, and medication. Media awareness brought individual behavioral changes among the people, which in turn helped reduce the infection rate. Motivated by this, we have formulated a mathematical model introducing a media compartment to mitigate measles disease transmission. In this paper, the SEIR model is used to study measles disease in three cases: one with a delay in vaccination, the second with regular vaccination, and the third with the impact of media awareness on the spreading of measles disease. Further, the dynamical behavior of the models is studied in terms of positivity, boundedness, equilibrium, and basic reproduction number (BRN). The sensitivity analysis of the models is conducted, which verifies the importance of the BRN ((Formula presented.)) to be less than one for disease eradication. The numerical study confirms the impact of media awareness on exposed and infected populations. 2023 John Wiley & Sons Ltd. -
Modelling temperature-dependent malaria transmission vector model considering different levels of immunity in host population
Malaria is spread by female Anopheles mosquitoes, which complete their life cycle by feeding on human blood. Parasites from the mosquito's saliva enter the human bloodstream through a mosquito bite. Thus, the link between humans and mosquitoes to parasites is established. According to WHO statistics, malaria appears widespread in tropical and subtropical locations around the equator, including most of Sub-Saharan Africa, Latin America, and Asia. The most prevalent causes of malaria transmission might be amicable temperature, which aids in the growth of the mosquito life-cycle, and a failure to maintain the local socio-economic condition, which reduces individual immunity. This study proposes the vector-host model to understand the spread of malaria infection. A vector model is used to understand the effects of temperature on the development of egg, larval, pupal, and adult mosquito populations. Furthermore, the role of immunity is being explored using the host model. Numerical simulations support the influence of temperature on disease transmission. The study draws attention to the fact that, along with issues like global warming and climate change, managing the socio-economic conditions of the area (healthcare facilities, environmental improvement) is essential for malaria eradication. CSP - Cambridge, UK; I&S - Honda, USA, 2023 -
Mathematical modeling to investigate the influence of vaccination and booster doses on the spread of Omicron
The emergence of new variants, such as Omicron, has raised concerns regarding the transmission dynamics of COVID-19 and the effectiveness of vaccination strategies. This paper proposes a mathematical model to investigate the impact of vaccination and booster doses on Omicron transmission dynamics, considering various infection compartments. The model incorporates multiple compartments representing different stages of infection, including susceptible individuals, vaccinated individuals, boosted individuals, and those infected with Omicron. The infection dynamics are captured by parameters such as vaccine efficacy, vaccination with booster received efficacy, and infection rate. Using mathematical analysis and numerical simulations, we explore how different vaccination and booster strategies affect the spread of Omicron. The normalized sensitivity analysis method of R0 is investigated to understand the importance of parameters in disease transmission. Furthermore, we assess the influence of infection compartments, such as asymptomatic and symptomatic cases, on overall transmission dynamics. 2023 Elsevier B.V. -
High-affinity binding of celastrol to monomeric ?-synuclein mitigates invitro aggregation
?-Synuclein (?Syn) aggregation is associated with Parkinsons disease (PD). The region ?Syn36-42 acts as the nucleation 'master controller and ?Syn1-12 as a secondary nucleation site. They drive monomeric ?Syn to aggregation. Small molecules targeting these motifs are promising for disease-modifying therapy. Using computational techniques, we screened thirty phytochemicals for ?Syn binding. The top three compounds were experimentally validated for their binding affinity. Amongst them, celastrol showed high binding affinity. NMR analysis confirmed stable ?Syn-celastrol interactions involving several residues in the N-terminus and NAC regions but not in the C-terminal tail. Importantly, celastrol interacted extensively with the key motifs that drive ?Syn aggregation. Thioflavin-T assay indicated that celastrol reduced ?Syn aggregation. Thus, celastrol holds promise as a potent drug candidate for PD. Communicated by Ramaswamy H. Sarma. 2023 Informa UK Limited, trading as Taylor & Francis Group. -
Identification of negative comments from positive sentences through data analysis
Social media has become a part, where people say what they think. It has made remarkable condition for individuals to impart their thoughts to the world. More consumers are writing their reviews which help people to make decisions about the quality and whether they should purchase the product. With respect to distinguishing perspectives out of this immense pool of conclusions, it turns into a laborious task and doing it physically is in every practical sense impossible. When we want to purchase things the best way to choose the finest product is to rely upon the opinions of others who already purchased those items. Sentiment analysis is utilized to choose whether the author's view is positive, negative, or neutral towards a specific item. This paper provides a review of apple mobile phone where we find polarity of a product based on scoring. We also worked on identifying negative comments in a positive sentence. We found the count of different polarity of words from overall positive feedbacks and stored the negative words so that we can identify which feature of the product is not acceptable and should be work with. We are representing our final result using wordcloud where we can detect which features has flaws. IAEME Publication. -
An Efficient Inclusion Complex Based Fluorescent Sensor for Mercury (II) and its Application in Live-Cell Imaging
The formation of an inclusion complex between hydroxypropyl-?-cyclodextrin (H-CD) and 4-acetylphenyl-4-(((6-chlorobenzo[d]thiazol-2-yl)-imino)-methyl)-benzoate (L) was investigated by FT-IR, 1H-NMR, X-ray diffraction (XRD), FT-Raman, scanning electron microscope (SEM) techniques in the solid-state, absorption and emission spectroscopy in the liquid state and the virtual state as molecular docking technique. The binding properties of the inclusion complex (H-CD: L) with cations in deionized water was observed via absorbance and photoluminescence (PL) emission spectroscopy. The fluorescence probe (H-CD: L) inclusion complex (IC) was examined for several heavy metal cations, and identified that the PL emission wavelength of the complex displayed a continuous rise in the fluorescence intensity for Hg2+. A linearity range of 1 108 11 108M and limit of detection value of 2.71 1010M was found to be achieved for the detection of Hg2+. This outcome proves that the inclusion complex H-CD: L would be a promising material for the development a solid-state fluorescence probe for detecting Hg2+. It also shows application in real sample analysis and cell imaging. 2022, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature. -
Biomass derived carbon quantum dots embedded PEDOT/CFP electrode for the electrochemical detection of phloroglucinol
Carbon nanocomposites have garnered a lot of attention among various nanomaterials due to their distinct characteristics, such as large surface area, biocompatibility, and concise synthetic routes. They are also a viable contender for electrochemical applications, notably sensing, due to their intriguing electrochemical features, which include large electroactive surface area, outstanding electrical conductivity, electrocatalytic activity, and high porosity and adsorption capability. Herein, an electrochemical sensor for phloroglucinol (PL) was designed using a CFP electrode modified with biomass-derived carbon quantum dots (S-CQD) doped on conducting organic polymer poly(3,4-ethylene dioxythiophene) (PEDOT) via electrodeposition method. The obtained nanocomposite (S-CQD+PEDOT) on the CFP electrode possesses a high surface area. The higher electrocatalytic activity of S-CQD and significant conductivity of PEDOT- modified electrode enhance the electrocatalytic activity for the phloroglucinol oxidation. The oxidation peak current of PL shows a higher response on the finally modified electrode than the other electrodes. The developed electrochemical sensor for the selective and sensitive detection of PL showed a good linear range of 36 -360 nM and a detection limit of 11 nM. The modified electrodes were characterized using Transmission electron spectroscopy (TEM), Fourier Transform infrared spectroscopy (FT-IR), and X-ray photon spectroscopy (XPS). Finally, the developed method was successfully used to detect Phloroglucinol from industrial effluents with RSD (0.841.02%) and (98.5101.2%) of recovery. 2023 -
Dual ion specific electrochemical sensor using aminothiazole-engineered carbon quantum dots
A novel electrochemical sensor capable of concurrently detecting Pb2+ and Hg2+ ions has been innovatively engineered. This sensor utilizes the anodic stripping voltammetry technique (ASV) with a composite consisting of carbon quantum dots and aminothiazole (CQD-AT). In this composite, both the carbon quantum dots and aminothiazole contribute significantly to the electroactive surface area, boasting an abundance of functional groups that include oxygen and nitrogen atoms. These functional groups serve as active sites that enhance sensor sensitivity by facilitating the electrostatic interaction-based adsorption of heavy metal ions. Aminothiazole surface is evenly covered with CQDs, which are essential for metal gets reoxidized into metal ions for stripping analysis. Due to this unique modification, the Pb2+ and Hg2+ electrochemical sensor using the CQD-AT composite coated on carbon fiber paper electrode (CQD-AT/CFP) exhibits superior analysis performance such as wide linear range (0.6 1011160 106 M) for Pb2+ and Hg2+ with a limit of detection (LOD) of 3.0 pM and 6.2 pM for Pb2+ and Hg2+. CQD-AT/CFP modified electrode can be considered as a potential material for electrochemical simultaneous determination of Pb2+ and Hg2+ in different water samples. 2023 Elsevier B.V. -
A ratiometric fluorescent sensor based on dual-emissive carbon dot for the selective detection of Cd2+
Cadmium (Cd2+), a heavy metal ion used in numerous industries, has toxic adverse effects on the environment; it is crucial to develop a quick and reliable method for Cd2+ determination. Fluorescent biomass-derived carbon quantum dots (CD) with rich carboxyl groups on the surface were synthesized using water amaranth leaves by hydrothermal method with a 12.1% quantum yield. The surface of CD was further modified with 1-pyrene carboxaldehyde (PC) to synthesize pyrene carboxaldehyde-carbon quantum dots (PC-CD). This study developed a fluorescent ratiometric nanosensor using a covalently functionalized CD with pyrene derivative and demonstrates highly selective identification capability towards Cd2+ over competing metal ions. The Nano sensor has significant selectivity towards Cd2+ in an excellent linear range of 0-70 ?M with a detection limit as low as 15 nM and demonstrates excellent water solubility and biocompatibility. Transmission electron spectroscopy (TEM), Fourier Transform infrared spectroscopy (FT-IR), and X-ray photon spectroscopy (XPS) were used to identify the surface functionalization of PC-CD. Finally, the developed ratiometric sensor was used for detecting Cd2+ metal ions from various water effluents. 2023 Elsevier Ltd.