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Green Manufacturing and Performances in Apparel Export Industry: Mediating Role of Green Innovation
Implementing green manufacturing in the production process of garment export-oriented enterprises not only contributes to environmental well-being but also enhances competitiveness in the global market and boosts overall company performance. Furthermore, it is critical to take immediate action to improve sustainable production levels via green innovation. This study aims to investigate the impact of green manufacturing on operational performance, environmental performance, and economic performance in the apparel manufacturing export industry. The study also investigates the mediating role of green innovation as a mediator between the green manufacturing and types of performances. A survey method is used to collect data from 123 garment export units, and structural equation modelling (SEM) is used to analyze the results. This study delivers empirical evidence of the impact of the imple-mentation of green manufacturing on green innovation and economic performance. Moreover, green innovation has a significant impact on economic performance and environmental performance. The results signify that green innovation partially mediates green manufacturing and economic performance. Green innovation fully mediates green manufacturing and environmental performance, and also green manufacturing and operational performance. This study is unique in its focus on the use of green manufacturing and green innovation in garment export production units. It provides insights into how these green practices might improve firm performance and the environment. 2024, Kauno Technologijos Universitetas. All rights reserved. -
Green synthesis and electrochemical characterization of rGO–CuO nanocomposites for supercapacitor applications /
Lonics, Vol.23, Issue 5, pp.1267–1276, ISSN: 9477047. -
Green synthesis and electrochemical characterization of rGOCuO nanocomposites for supercapacitor applications
Reduced graphene oxide (rGO) were prepared from graphene oxide (GO) by using piperine as a green reducing agent extracted from Piper nigrum. The obtained rGO had few defects and lacked connectivity between the layers. To overcome these defects, copper oxide (CuO) nanoparticles were synthesized ultrasonically and nanocomposites of rGOCuO were prepared. The conductivities of the rGO, CuO and rGOCuO nanocomposites were determined by AC impedance spectroscopy in different electrolytes. Morphology, composition and electronic structure of CuO, rGO and rGOCuO nanocomposites were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photon spectroscopy (XPS) and electrochemical techniques. Transmission electron microscopy (TEM) images portrait CuO as a fish caught in the net of rGO layers. The rGOCuO nanocomposite exhibiting lower resistance and higher capacitance was used in fabrication of supercapacitor electrodes. The specific capacitance of the fabricated supercapacitor was found to be 137Fg?1. The supercapacitor performance of the nanocomposite electrode is attributed to the synergistic effect of double-layer capacitance of rGO and redox capacitance of CuO nanoparticles. [Figure not available: see fulltext.] 2016, Springer-Verlag Berlin Heidelberg. -
Green Synthesis of ?-Fe2O3 Nanoparticles Mediated Musa Acuminata: A Study of Their Applications as Photocatalytic Degradation and Antibacterial Agent
The present study was aimed to green synthesize of ?-Fe2O3 nanoparticles (NPs) using flower extract of Musa acuminata and examination of their antibacterial and photocatalytic activities. The synthesized NPs were investigated using UV-visible spectroscopy, which exhibited a colour change pattern, and the maximum absorption peak at 265 nm confirmed the formation of ?-Fe2O3 NPs. The FTIR analysis showed the presence of various functional groups coated over the synthesized ?-Fe2O3 NPs. The XRD pattern showed that the formation of rhombohedral structure with an average crystallite size was 21.86 nm. FESEM micrographs revealed that ?-Fe2O3 NPs were roughly spherical in shape. EDX spectrum confirmed the presence of Fe and O elements. By TEM analysis, the average particle size was calculated to be 32 nm. Using the well diffusion method, the antibacterial activity of ?-Fe2O3 NPs was tested against both gram positive and negative bacterial strains of Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli). The NPs exhibited good antibacterial activity against the tested bacteria. Finally, the synthesized ?-Fe2O3 NPs demonstrated the photocatalytic degradation of Crystal Violet (CV) dye under sunlight. The efficiency of degradation within 150 min was determined to be 90.27% for CV. This effective removal method under sunlight may support a cost-effective method for degradation of CV dyes from wastewater. Copyright T Indhumathi, N Krishnamoorthy, R. Valarmathy, K Saraswathi, S Dilwyn and S. Prabhu. -
Green synthesis of Cobalt Oxide nanoparticles with in-vitro cytotoxicity assessment using pomegranate (Punica granatumL.) seed oil: A promising approach for antimicrobial and anticancer applications
Green synthesis of nanoparticles and their pharmacological implementation have gained importance in the field of nanotechnology. This study primarily aims to explore the use of Punica granatum L. seed oil as a reducing agent for the synthesis of cobalt nanoparticles, making it both economically and pharmacologically valuable. Gas chromatography-mass spectroscopy analysis was carried out to study the active metabolites present in P. granatum seed oil. The green synthesis of cobalt nanoparticles was established based on the color change of the reaction mixture from dark green to light green. These particles showed a ?max at 279.88 nm for UV-visible spectrometry analysis. Furthermore, X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Field Emission Scanning Electron Microscope (FE SEM) and Dynamic Light Scattering (DLS) were performed to confirm the nature of these nanoparticles. The pharmacological potential of these cobalt oxide nanoparticles was tested against microbial pathogens. The results suggest that these nanoparticles exhibited significant activity against various human bacterial and fungal pathogens. Additionally, in in vitro cytotoxicity analysis, demonstrated that CoONPs selectively targeted MCF-7 cancer cells with a significant IC50 value compared to non-cancerous cells (L929). In conclusion, this study demonstrated that green synthesized CoONPs using P. granatum show significant potential against eukaryotic cancer cells and microbial pathogens. Furthermore, this study has implications for medical research centers and pharmaceutical industries in addressing modern challenges such as increasing antibiotic resistance in communities. 2024 Horizon e-Publishing Group. All rights reserved. -
Green Synthesis of Hydroxyapatite Nanoparticles Using Semecarpus anacardium Linn leaf Extract: Examination of Anticancer Activity and its Apoptosis Induction
Nanotechnology and biomedical sciences enable diverse molecular and cellular applications. Plant-mediated biosynthesis of nanoparticles, a green chemistry approach, offers a cost-effective, eco-friendly alternative to traditional methods. This study focuses on developing hydroxyapatite nanoparticles (HA-NPs) using Semecarpus anacardium Linn (SAL) leaf extract (termed SAL@HA-NPs) as a capping agent and reducing agent. The presence of needle-shaped nanostructures was verified using SEM and TEM investigation. The presence of well-defined rings in the selected area electron diffraction (SAED) patterns provided evidence for the polycrystalline nature of the SAL@HA-NPs). The XRD spectrum exhibited clear peaks that closely corresponded to the hexagonal patterns of HA, indicating a mean crystalline diameter of 54.25nm. The FTIR analysis revealed the presence of biomolecules from Semecarpus anacardium Linn leaves on the surface of the nanoparticles. The suspension of SAL@HA-NPs displayed a polydispersity index of 0.445 and demonstrated excellent stability, as indicated by the zeta potential of -32.2 mV, as observed in the DLS tests. The SAL@HA-NPs exhibited a harmful effect on the HeLa cervical and HepG2 liver cancer cells, with an IC50 value of 52g/mL. Fluorescence microscopy revealed the deformation of the damaged cell membrane, fragmentation, and cell death following treatment with SAL@HA-NPs. The Annexin V-FITC and PI staining confirmed the mode of apoptosis by flow cytometric analysis. Thus, the SAL@HA-NPs acquired in this study could have a crucial impact on the biomedical domain of cancer treatment. The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. -
Green synthesis of MgO nanoparticles and its antibacterial properties
Magnesium oxide nanostructured particles (NP) were prepared using a simple solution combustion technique using different leaf extracts such as Mangifera indica (Mango - Ma), Azadirachta indica (NeemNe), and Carica papaya (PapayaPa) as surfactants. The highly crystalline phase of MgO nanostructures was confirmed by PXRD and FTIR studies for 2h 500C calcined samples. To analyze the characteristics of obtained materialMaNP, NeNP, and PaNP for dosimetry applications, thermoluminescence (TL) studies were carried out for Co-60 gamma rays irradiated samples in the dose range 1050KGy; PaNP and NeNP exhibited well-defined glow curve when compared with MaNP samples. In addition, it was observed that the TL intensity decreases, with increase in gamma dose and the glow peak temperature is shifted towards the higher temperature with the increase in heating rate. The glow peak was segregated using glow curve deconvolution and thermal cleaning method. Kinetic parameters estimated using Chens method, trap depth (E), and frequency factor (s) were found to be 0.699, 7.408, 0.4929, and 38.71, 11.008, and 10.71 for PaNP, NeNP, and MaNP respectively. The well-resolved glow curve, good linear behavior in the dose range of 1050, KGy, and less fading were observed in PaNP as compared with MaNP and NeNP. Further, the antibacterial activity was checked against human pathogens such as Escherichia coli, Staphylococcus aureus, and Pseudomonas aeruginosa. A visible zone of clearance was observed at 200 and 100?g/mL by the PaNP and NeNP, indicating the death of colonies by the nanoparticles. Therefore, PaNP nanomaterial is a potential phosphor material for dosimetry and antibacterial application compared to NeNP and MaNP. Copyright 2023 Rotti, Sunitha, Manjunath, Roy, Mayegowda, Gnanaprakash, Alghamdi, Almehmadi, Abdulaziz, Allahyani, Aljuaid, Alsaiari, Ashgar, Babalghith, Abd El-Lateef and Khidir. -
Green Synthesis of Reduced Graphene Nanostructure from Cinnamomum Camphora
A facile green synthesis for carbon nanoparticle production using Cinnamomum camphora (Camphor) is presented. Camphor upon carbonization and chemical oxidation leads to the formation of nano-carbon structures with lateral size 7.33nm to 4.14nm, respectively. The nanomaterial's stacking height is about 2.76nm and 3.10nm, leading to the formation of about 10 layers of carbon. The AFM analysis confirms that the graphene layer formed is wrinkled or folded. Developments of a layered structure with spheroids are observed on the sample's surface, confirming the graphitization of the amorphous carbon. The relative intensity of the defect to the graphite band is found to be 0.98 for the nanostructure indicating a lesser degree of defects. The C1s band of the nanostructure is deconvoluted to components at 284.7, 286.5, 287.3, and 289 eV, which are assigned to non-oxygenated ring carbon (sp2 carbon), C in C-O (bound to O either as epoxy or hydroxyl), C in C=O (of alcohols, phenols or ether), and C in C(O)O (carboxylic acid) respectively. The study reveals the formation of few-layer oxygenated carbon layers from the botanical hydrocarbon. 2020 by the authors. -
Green synthesis of reduced graphene oxide using Plectranthus amboinicus leaf extract and its supercapacitive performance
A rapid, efficient, green and eco-friendly approach for the preparation of reduced graphene oxide (rGO) using Plectranthus amboinicus (Indian borage) leaves extract (PAE) is explored in this study. The improvement in the reduction process was studied by varying the concentration of graphene oxide (GO), temperature and time duration. The physical and chemical properties of rGO are studied using Raman spectroscopy, Fourier transform infrared spectroscopy, X-ray diffraction (XRD) and field emission scanning electron microscope. The result obtained from XRD analysis confirms the removal of an oxygen-containing functional group of GO significantly by PAE. Raman analysis showed a higher ID/IG ratio for rGO (1.297) than GO (1.07), which indicates a higher level of disorder in the rGO with a decrease in the average size of the sp2 domain. From the electrochemical studies, a significant specific capacitance of 92.05Fg1 (5mVs1) is obtained from the cyclic voltammetry (CV) curves and 73.20Fg1 (0.1Ag1) from the galvanostatic chargedischarge (GCD) curve. 2021, Indian Academy of Sciences. -
Green synthesis of silver nanoparticles using calendula officinalis and its anti-bacterial studies /
Mapana Journal of Sciences, Vol.17, Issue 2, pp.11-17, ISSN No: 0975-3303. -
Green synthesis of zirconium phosphate by combustion method: photocatalytic application and microwave-assisted catalytic conversion of aldehyde to nitriles
Water pollution has increased swiftly, especially the dyes from industries that have disturbed aquatic eco-system. Photocatalytic degradation (PCD) is one of the attractive methods to eliminate dyes from industrial effluents. Zirconium phosphate (ZP) nanoparticles were synthesized by combustion method using zirconyl nitrate and phosphorous pentoxide as precursors. The obtained ZP was characterized by powder X-ray diffractogram, Fourier transform infrared, scanning electron microscopy, high-resolution transmission electron microscopy, Raman spectroscopy, photoluminescence spectroscopy, BrunauerEmmettTeller surface area. PCD was carried out using methylene blue as a model pollutant in aqueous medium in the presence of UV light irradiation with different concentrations of dye, catalyst and pH. Higher degradation efficiency was observed in basic medium. ZP is employed as a catalyst to form nitrides from aldehydes using different solvents with different aldehydes. Graphic abstract: [Figure not available: see fulltext.]. 2021, Indian Academy of Sciences. -
Green synthesis, characterization of silver nanoparticles using aqueous leaf extracts of Solanum melongena and in vitro evaluation of antibacterial, pesticidal and anticancer activity in human MDA-MB-231 breast cancer cell lines
The present study validated the green synthesis and characterization of AgNPs using the leaf extracts of Solanum melongena (SM-AgNPs). The efficiency of the phytocompounds in the leaf extract in reducing Ag+ to Ag0 ions was studied. The synthesized SM-AgNPs were characterized by spectroscopic methods and standard methods were adopted for the antioxidant activity, HPTLC, cytotoxicity and antimicrobial assays and pesticidal activity as well. The synthesised nanoparticle was measured to be 20.54 nm which was confirmed by the characterization. The total phenolic content was 5.98 0. GAE/g which indicated potent antioxidant activity. HPTLC profile showed thirteen peaks corresponding to the phenolic compounds with Rf values ranging from 0.05 to 0.95. The average particle size and zeta potential was 75.14 nm-19.8 mV respectively. Cytotoxicity assay of the synthesized AgNP's showed viability percentage of 50.23 at 100 mg/mL. Treatment of MDA-MB-231 cell lines with the SM-AgNPs induced early apoptosis in a greater number of cells. The synthesizedAgNPs were effective against the bacterial isolates Escherichia coli, Pseudomonas aeruginosa, Shigella flexneri, Proteus vulgaris, Klebsiella pneumoniae and Staphylococcus aureus. High mortality of Bemisiatabaci was observed in the100 g/mL of the SM-AgNPs treated concentrations. The study demonstrated the efficiency of SM-AgNPs against cancer cell lines, microbial isolates and insect pests. 2023 The Author(s) -
Green synthesized cobalt nanoparticles from Trianthema portulacastrum L. as a novel antimicrobials and antioxidants
Trianthema portulacastrum is a dietary and medicinal plant that has gained substantial importance due to its pharmacological properties. This plant was used for its various healing properties since the ancient period in ayurvedic system of medicine. The green synthesis technique is an eco-friendly as well as cost effective technique which can produce more biocompatible nanoparticles when compared with those fabricated by physio-chemical methods. Therefore, nanoparticles produced by green synthesis are credible alternatives to those which are produced by conventional synthesis techniques. This research mainly aims to produce nanoparticles with the methanolic leaf extract of T. portulacastrum. The optimized nanoparticles were further analyzed for anti-fungal, anti-bacterial and antioxidant properties. Disk diffusion assay was used for the determination of the antimicrobial property and on the other hand, DPPH radical scavenging assay as well as hydrogen peroxide scavenging activity proved the antioxidant property of the formulation. The study revealed that Escherichia coli (gram negative strain) shows greater zone of inhibition when compared with Bacillus subtilis (gram positive bacteria). The nanoparticles have also been reported to show significant anti-fungal activity against the strains of Aspergillus niger and Fusarium oxysporum which proves its desirability for its further use against both bacterial as well as fungal infections. The novel formulation can be explored dually as antimicrobial and antioxidant agent. 2023 Taylor & Francis Group, LLC. -
Green Synthesized ZnO Nanoparticles as Biodiesel Blends and their Effect on the Performance and Emission of Greenhouse Gases
Pollution and global warming are a few of the many reasons for environmental problems, due to industrial wastes and greenhouse gases, hence there are efforts to bring down such emissions to reduce pollution and combat global warming. In the present study, zinc oxide nanoparticles are green synthesized using cow dung as fuel, through combustion. Synthesized material was characterized by FTIR, XRD, UV, and FESEM. The as-prepared ZnO-GS NPs were employed as a transesterification catalyst for the preparation of biodiesel from discarded cooking oil. The biodiesel obtained is termed D-COME (discarded cooking oil methyl ester), which is blended with 20% commercial diesel (B20). Additionally, this blend, i.e., B20, is further blended with varying amounts of as-prepared ZnO-GS NPs, in order to ascertain its effects on the quality of emissions of various greenhouse gases such as hydrocarbons, COx, NOx. Moreover, the brake thermal efficiency (BTHE) and brake specific fuel consumption (BSFC) were studied for their blends. The blend (B20) with 30 mg of ZnO-GS, i.e., B20-30, displays the best performance and reduced emissions. Comparative studies revealed that the ZnO-GS NPs are as efficient as the ZnO-C NPs, indicating that the green synthetic approach employed does not affect the efficiency of the ZnO NPs. 2022 by the authors. Licensee MDPI, Basel, Switzerland. -
Green-Synthesized Sm3+-Doped ZnO Nanoparticles for Multifunctional Applications
The present study focuses on the green-mediated synthesis of pristine and Sm3+-doped ZnO nanoparticles using Syzygium cumini fruit extract. The prepared material was characterized by various characterization techniques. Photocatalytic degradation of a fast orange red (FOR) dye under UV light resulted in 88% degradation, with a minimal decrease (87.90%) observed even after five successive runs, indicating the stability and effectiveness of the catalyst. The enhancement in degradation efficiency is attributed to the incorporation of Sm3+ ions into the ZnO lattice. Utilizing the optimized Sm3+ (5 mol%)-doped ZnO nanoparticles, cyclic voltammetry (CV) and electrochemical impedance spectra (EIS) were performed on the prepared electrode, demonstrating the excellent CV properties; this enhancement is attributed to the modification of ZnO's redox chemistry and the alteration of charge transfer kinetics at the electrode-electrolyte interface due to the addition of Sm3+ into the ZnO structure. The antibacterial activity was performed against two pathogenic strains, i.e., Escherichia coli and Streptococcus aureus. The obtained results suggest that the prepared material holds great promise for catalytic, energy storage, antibacterial, and other multifunctional applications. 2024 Lavanya R. et al. -
Grey Wolf Optimization Guided Non-Local Means Denoising for Localizing and Extracting Bone Regions from X-Ray Images
The key focus of the current study is implementation of an automated semantic segmentation model to localize and extract bone regions from digital X-ray images. Methods: The proposed segmentation framework uses a pre-processing stage which follows convolutional neural network (CNN) obtained segmentation stage to extract the bone region from X-ray images, mainly for diagnosing critical conditions such as osteoporosis. Since the presence of noise is critical in image analysis, the X-ray images are initially processed with a grey wolf optimization (GWO) guided non-local means (NLM) denoising. The segmentation stage uses a Multi-Res U-Net architecture with attention modules. Findings: The proposed methodology shows superior results while segmenting bone regions from real X-ray images. The experiments include an ablation study that substantiates the need for the proposed denoising approach. Several standard segmentation benchmarks such as precision, recall, Dice-score, specificity, Intersection over Union (IOU), and total accuracy have been used for a comprehensive study. The proposed architectural has good impact compared to the state-of-the-art bone segmentation models and is compared both quantitatively and qualitatively. Novelty: The denoising using GWO-NLM adaptively chose the denoising parameters based on the required conditions and can be reused in other medical image analysis domains with minimal finetuning. The design of the proposed CNN model also aims at better performance on the target datasets. 2023 Biomedical & Pharmacology Journal. -
Grey Wolf optimization-Elman neural network model for stock price prediction
Over the past two decades, assessing future price of stock market has been a very active area of research in financial world. Stock price always fluctuates due to many variables. Thus, an accurate prediction of stock price can be considered as a tough task. This study intends to design an efficient model for predicting future price of stock market using technical indicators derived from historical data and natural inspired algorithm. The model adopts Elman neural network (ENN) because of its ability to memorize the past information, which is suitable for solving stock problems. Trial and error-based method is widely used to determine the parameters of ENN. It is a time-consuming task. To address such an issue, this study employs Grey Wolf optimization (GWO) algorithm to optimize the parameters of ENN. Optimized ENN is utilized to predict the future price of stock data in 1day advance. To evaluate the prediction efficiency, proposed model is tested on NYSE and NASDAQ stock data. The efficacy of the proposed model is compared with other benchmark models such as FPA-ELM, PSO-MLP, PSOElman,CSO-ARMA and GA-LSTM to prove its superiority. Results demonstrated that the GWO-ENN model provides accurate prediction for 1day ahead prediction and outperforms the benchmark models taken for comparison. 2020, Springer-Verlag GmbH Germany, part of Springer Nature. -
Group Movie Recommendations via Content Based Feature Preferences
International Journal of Scientific & Engineering Research Vol. 4, Issue 2, pp.1-5 ISSN No. 2229-5518 -
Growth and microindentation analysis of pure and doped Sb2 Se3 crystals
Pure and doped antimony selenide (Sb2 Se3, Sb 2 Se2.8 Te0.2, and Sb2 Se 2.6 Te0.4) crystals have been grown from melt by the Bridgman Stockbarger method. X-ray powder diffraction analysis was carried out to determine the lattice parameters of the grown samples. The morphology of cleavage planes was observed using SEM. Energy dispersive analysis by X-rays (EDAX) was done to find out the chemical composition of the grown samples. Correlation of microhardness with other mechanical characteristics such as toughness, brittleness, and yield strength, has been investigated. The effects of Te doping on the mechanical behaviour and energy gap were also studied on the cleavage faces. Ti?tak. -
Growth of mobile applications and the rise of privacy issues
Mobile apps are used by more and more internet users for daily chores, but processing personal data with them poses a major security risk. The wide range of data and sensors in mobile devices, the use of different types of identifiers and the increased ability to monitor consumers, the complex mobile application ecosystem and application developer limitations, and the extensive use of third-party technologies and services, are the main risks. Privacy concerns extend beyond mobile users. Corporate executives need fast, global access to their database. White goods/smart building equipment suppliers offer mobile apps for remote use. This research study will integrate these concerns. Due to these factors, smartphone applications have struggled to enforce the General Data Protection Regulations (GDPR) data protection rules. Mobile app designers and service providers may struggle to meet GDPR rules for data disclosure and permission, data protection by design and default, and operational secrecy. Copyright 2024 Inderscience Enterprises Ltd.