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Human Resource Development Climate and its Impact on Stress Among Teachers in Unaided Education Institutions in Bangalore
Global Journal of Finance & Management, Vol-4 (4), ISSN-0975-6477 -
MnO2 anchored NTi3C2 MXene as a bifunctional electrode for enhanced water splitting
The domain of energy research is vigorously exploring a wide array of materials, from advanced carbon-based substances like graphene and carbon nanotubes to emerging contenders like MXenes. Ti3C2 MXene offers exceptional performance in electrochemistry, benefiting from its remarkable electronic conductivity, considerable surface area, chemical stability, cost-effectiveness, hydrophilicity, and eco-friendliness. However, it undergoes self-accumulation, which diminishes the number of electrochemically active sites, resulting in decreased performance. In this study, MnO2 particles are intricately anchored onto the surfaces and within the layers of nitrogen-doped Ti3C2 (NTi3C2), resulting in the creation of innovative interface engineered NTi3C2/MnO2 nanosheets. Due to its distinctive heterostructure and favourable interfacial interaction, the NTi3C2/MnO2 electrode shows better performance in both the hydrogen and oxygen evolution reactions, exhibiting low overpotentials of 130 mV and 289 mV, respectively, at a current density of 10 mA cm?2. Furthermore, it requires a cell voltage of 1.7 V to achieve a current density of 10 mA cm?2 during the overall water splitting process. The NTi3C2/MnO2 composite also maintains sustained durability for a period of 4 h. This enhanced electrochemical activity of NTi3C2/MnO2 can be due to the synergistic effects resulting from the intricate contact between NTi3C2 and MnO2. This research presents a simple methodology for designing MXenes-based multicomponent electrodes for electrochemical water splitting reactions and its potential application for electrochemical water splitting. 2024 Hydrogen Energy Publications LLC -
Rationally designed CeO2 decorated Ti3C2 MXene interface for efficient water splitting and enhanced supercapacitor performance
MXenes serve as competent electrodes for applications such as energy storage and conversion owing to their unique characteristics, which include substantial surface area, excellent conductivity, abundant surface-terminating groups, and high hydrophilicity. However, MXene nanosheets exhibit a pronounced tendency to restack via Van der Waals force, hindering the active sites and resulting in sluggish electronic and ionic kinetics. This phenomenon limits the capabilities, processability, and overall performance of MXene. In this study, CeO2 is utilized as an interlayer spacer for the Ti3C2 MXene substrate, providing a promising noble metal-free multifunctional electrode. The Ti3C2/CeO2 composite, synthesized via the hydrothermal method, efficiently mitigates restacking while exhibiting excellent conductivity, substantial surface area, and enhanced kinetics. The as-synthesized catalysts undergo diverse physiochemical characterizations and electrochemical measurements to understand their properties and potential multiapplications. The fabricated electrode material, Ti3C2/CeO2, shows excellent specific capacitance of 1908.5 Fg?1 at 1 Ag?1 in a three-electrode setup using 3 M KOH as electrolyte. It has a capacitive retention of 91% even after 4000 cycles. Besides, Ti3C2/CeO2 also functions as a proficient electrode material for overall water splitting, having a lower overpotential of 178 mV and 350 mV for hydrogen and oxygen evolution reactions, respectively, at a current density of 10 mAcm?2. It also displays a lower cell voltage of 1.78 V to obtain a current density of 10 mAcm?2. This study introduces the multi applications of a well-designed interface between Ti3C2 layers and CeO2 within the realm of electrochemical energy storage and conversion. 2024 Elsevier B.V. -
Strategic design of MXene/CoFe2O4/g-C3N4 electrode for high-energy asymmetric supercapacitors
MXenes are emerging as the next-generation materials for energy storage due to their substantial surface area, exceptional conductivity, and abundant surface-terminating groups. However, the tortuous path for ion transfer within the restacked layers significantly limits the electrochemical performance of multilayered MXenes. To overcome this, interlayer spacers have been introduced. These spacers help mitigate ion diffusion barriers and enhance the accessibility of active sites, thereby improving the overall efficiency and longevity of MXene-based supercapacitors and related devices. In this study, a rational material is designed by incorporating CoFe2O4 and g-C3N4 into the layers of MXene through ultrasonication for supercapacitor application. The physicochemical properties of the synthesized materials have been comprehensively characterized using diverse techniques, revealing that MXene/CoFe2O4/g-C3N4 has successfully evolved into a multilayered structure possessing enhanced surface area, low restacking tendency, high pore diameter, and excellent pore volume. Leveraging these properties, it performs as a viable material for fabricating the working electrode with a specific capacitance (Csp) of 1506.2 F g?1 at a current density of 5 A g?1 in 3 M KOH. It shows good stability with 89 % capacitance retention over 7000 cycles. An asymmetric supercapacitor (ASC) constructed with MXene/CoFe2O4/g-C3N4 as positive electrode and activated carbon as negative electrode exhibits an energy density of 79.8 Wh Kg?1 and power density of 1343.3 W Kg?1. Furthermore, it shows a capacitive retention of 91 % over 10,000 cycles. This MXene based composite, with excellent capacitance and outstanding stability, offers an appreciable performance in the field of sustainable energy storage. 2024 Elsevier B.V. -
Examining the relationship between e-service recovery quality and e-service recovery satisfaction moderated by perceived justice in the banking context
Purpose: The study focuses on the core issue faced by bankers on how to retain existing customers who have encountered an e-service failure and who are skeptical about the justice received through the service recovery process. It further endeavors to create an internal bench-marking model for assessing e-service recovery satisfaction. Design/methodology/approach: By the experimental study, the authors confirm a measurement model using structural equation modeling for examining the impact of perceived service recovery quality antecedents on e-service recovery satisfaction moderated by perceived justice. In total, responses from 399 e-banking customers, who had experienced a e-service failure, were recorded using a 5-point Likert scale with a structured questionnaire. Findings: The perceived e-service recovery quality antecedents identified were perceived information quality, digital commitment, perceived employee performance and perceived service orientation of organization. The empirical results revealed that perceived information quality was the most significant predictor of e-service recovery satisfaction. Perceived justice moderates the relation between perceived service recovery quality and e-service recovery satisfaction. Research limitations/implications: The research does not contemplate the e-service recovery satisfaction of customers who have undergone multiple service failures. Practical implications: The conclusions of the investigation suggest that the four antecedents of perceived e-service recovery quality model are suitable instruments for creating benchmarks for e-service recovery satisfaction for banks, and that perceived justice moderates the relationship between e-service recovery quality and e-service recovery satisfaction. Therefore, policymakers in banks can use this model to assess the e-service recovery quality, and they ought to enhance the perceived justice feel of the customers who have experienced a service failure. Originality/value: There remains scarcity of empirical research focusing on perceived information quality and digital commitment as antecedents of perceived e-service recovery quality and its effect on e-service recovery satisfaction in the banking context. Furthermore, similar studies within the banking sector have rarely considered perceived justice as a moderator variable. Hence, this paper attempts to accomplish the research gap by empirically testing the e-service recovery satisfaction level of a large sample of the population toward four antecedents of perceived e-service recovery quality rendered by banks and create a benchmark model to ascertain e-service recovery satisfaction. 2020, Emerald Publishing Limited. -
CoFe2O4/g-C3N4 intercalated Ti3C2 MXene for efficient electrocatalytic hydrogen evolution reaction
Seeking high-efficiency and stable electrocatalysts remains key to boosting electrocatalytic water splitting. Herein, a well-designed nontoxic MXene based composite, Ti3C2-CoFe2O4/g-C3N4 is prepared via ultrasonication for enhancing the hydrogen evolution reaction (HER). Intercalation of CoFe2O4 and g-C3N4 within the multi-layered Ti3C2 MXene results in improved properties such as high surface area, large pore volume, and a low restacking tendency that leads to enhanced electrochemical active sites, high charge carrier separation, and stability. The prepared composite is characterized via various physicochemical techniques. The amalgamated composite shows a lower overpotential of 223 mV in an alkaline medium at a current density of 10 mA cm?2. The Tafel slope and charge transfer resistance (Rct) value for the HER are 48.5 mV dec?1 and 3.94 ?, respectively. The heterojunction formation improves the efficacy of the MXene composite and provides a new perception that can be beneficial for water splitting applications. 2023 The Royal Society of Chemistry. -
Advanced electrochemical performance of N-Ti3C2/MnO2 MXene as a promising electrode for energy storage
In this study, we demonstrate a simple and efficient two-step synthetic strategy to design a high-performance N-Ti3C2/MnO2 composite for energy storage application. Nitrogen doping alters the electronic structure of electrode materials and enhances pseudocapacitance. N-Ti3C2 serves as a supporting substrate for MnO2, boosting the active surface area by preventing Ti3C2 layer stacking. Benefitting from the collaborative contribution and synergistic interaction within this multicomponent system, N-Ti3C2/MnO2 results in exceptional specific capacitance of 2107.1 Fg?1 at 1 Ag?1. It also exhibits a low internal resistance and maintains a capacitive retention of 94% over 3000 cycles. The asymmetric capacitor also delivers an energy density of 117.1 Whkg?1 at a power density of 1290.1 Wkg?1. This work presents a straightforward method for modifying Ti3C2 through nitrogen doping and the insertion of MnO2 as an interlayer spacer to enhance electrochemical performance. Qatar University and Springer Nature Switzerland AG 2024. -
Methodical investigation of filtering algorithms for human brain MRI
Retrieving useful information from the given data through a systematic and organized way can help to learn more about the data in a much better and clear way. Information is hidden in medical images. The medical images like Magnetic Resonance Images (MRI), Computed Tomography (CT), ultrasound, X-ray are suggested by the physicians depending upon the available symptoms of the disease. These medical images contain valuable information about a particular disease in hidden format. Identification of that potentially useful information is crucial in further treatments of a particular disease. In image mining the images are processed and extraction or mining of knowledge is done, to get original, valid, potentially useful, and understandable patterns from the available images. The obtained patterns are a good source for further research work. This research work uses brain Magnetic Resonance Images (MRI) of human beings. Different image filtering algorithms were used to retrieve noise free images. International Science Press. -
The business of education and ethical quest
[No abstract available] -
Mechanical and Dielectric Properties of InTe Crystals
Crystal Structure Theory and Applications, Vol-1, pp. 79-83. -
Super strongly perfect graphs
Some of the published results on super strongly perfect graphs are found to be erroneous. We provide some examples and counter examples on the concepts associated with super strongly perfects. 2022 World Scientific Publishing Company. -
Coloring of Non-zero Component Graphs
The non-zero component graph of a finite dimensional vector space V over a finite field F is the graph G(V?) = (V, E), where vertices of G(V?) are the non-zero vectors in V, two of which are adjacent if they share at least one basis vector with non-zero coefficient in their basic representation. In this paper, we study the various types of colorings of non-zero component graph. (2024), (Universidad Catolica del Norte). All rights reserved. -
Centrality measures-based sensitivity analysis and entropy of nonzero component graphs
The nonzero component graph of a finite-dimensional vector space over a finite field is a graph whose vertices are the nonzero vectors in the vector space, and any two vertices are adjacent if the corresponding linear combination contains a common basis vector. In this paper, we discuss the centrality measures and entropy of the nonzero component graph and also analyze the sensitivity of the graph using the centrality measures. 2024 World Scientific Publishing Company. -
New results on orthogonal component graphs of vector spaces over Zp
A new concept known as the orthogonal component graph associated with a finite-dimensional vector space over a finite field has been recently added as another class of algebraic graphs. In these types of graphs, the vertices will be all the possible non-zero linear combinations of orthogonal basis vectors, and any two vertices will be adjacent if the corresponding vectors are orthogonal. In this paper, we discuss the various colorings and structural properties of orthogonal component graphs. 2024 Azarbaijan Shahid Madani University. -
Hybrid homomorphic-asymmetric lightweight cryptosystem for securing smart devices: A review
The Internet of Things (IoT) has emerged as a new concept in information and communication technology, and its structure depends on smart device communications. It was evolving as a significant factor of the Internet and made the interconnection of huge devices likely, accumulating huge amounts of information through innovative technologies. Thus, the requirement for IoT security is more significant. Scalable services and applications are susceptible to information leakage and attacks, demanding higher privacy and security. Cryptography is a technique to secure data integrity, confidentiality, authentication, and network access control. Owing to several limitations of IoT devices, the classical cryptographic protocols are not appropriate for all IoT smart devices like smart cities, smart homes and so forth. Consequently, researchers have introduced numerous lightweight cryptographic (LWC) protocols and algorithms for IoT security. Numerous solutions are available in the research field regarding security using cryptographic algorithms in IoT environments; however, such solutions have not attained satisfactory outcomes. So, finding a solution by examining the recent issues is open research. This article investigates the various LWC protocols for IoT devices and provides a reasonable enquiry into existing ubiquitous ciphers. Furthermore, the article appraises various recently presented lightweight (LW) block ciphers and hybrid homomorphic LWC regarding security. In addition, this article assists in comprehending the significance of security features and progression in cryptographic algorithms. Finally, the article reports on the necessary changes and recommends upcoming research focuses. Also, this article assists in realizing the importance of security and progressions in cryptographic algorithms. 2023 John Wiley & Sons, Ltd. -
Bob Dylan: Poet of disruption, dissonance and an aesthetic of dissent
This paper is a brief study of the pivotal figure of folk rock, Bob Dylan. Acclaimed as a songwriter and singer, he was also the poetic voice of the counter culture of the nineteen sixties in America. The counter culture sought to unseat the mainstream establishment that seemed obsessed with war, conservative ideals and religious nationalism. Dylan burst onto this scene 'already a legend' and 'the unwashed phenomenon' (Baez, 1975) projecting the image of the original vagabond and troubadour. A glance at a selection of some of his best known lyrics disabuses one of the notions of his being uninitiated into the discourse of philosophy and literature. He draws freely on and engages with ideas from texts that are sometimes even obscure. The Nobel he was awarded in October 2016 recognized his art for evolving new modes of poetic expression. This paper studies Dylan, the performer and the writer who has masterfully disrupted most accepted literary modes using the dissonance-rich space of Rock music while retaining some of the traditional forms of poetic utterance. AesthetixMS 2016. -
Pink floyd's time: An aural metanarrative exploring time through form, lyric, and musical arrangement
The inability of language to capture the essence of time is a crisis that has been expressed by philosophers starting from St. Augustine to Paul Ricoeur. Appearing on their seminal album, Dark Side of the Moon, Pink Floyd's Time is a profound artistic attempt which transcends this language barrier by using music to bring the listeners to a more direct confrontation with time; doing so by juxtaposing time as calibrated and as experienced through the music and the lyrics, and by making the reader experience time-based affects such as impatience, expectation, monotony, and such. As a direct function of song, time is experienced as musical time in the song, thereby ensuring that the listener's confrontation with time is immersive, with lyrics that describe the nature of experienced and calibrated time working synchronously with the music to complete the image. In the context of its release in 1974, the 6:52 minute song was in engagement with the concept of time as well, in that it was among the pioneering ones which redefined radio broadcast time beyond the standard 3 minutes afforded to popular music tracks, with the commercially preferred listener span in mind. The matter of time thus becomes a multi-layered formal engagement in the song, at the level of lyric, recording, music and listening, thereby making possible an image of time that is polished and rounded. These aural, lyrical and production-based concepts will be addressed and expanded upon to show how Pink Floyd's Time functions as a metanarrative in how it uses and invokes the elements of time to talk about time. AesthetixMS 2020. -
Critical concepts of restrained domination in signed graphs
A signed graph ? is a simple undirected graph in which each edge is either positive or negative. Restrained dominating set D in ? is a restrained dominating set of the underlying graph |?| where the subgraph induced by the edges across ?[D: V D] and within V D is balanced. The minimum cardinality of a restrained dominating set of ? is called the restrained domination number, denoted by ?r(?). In this paper, we initiate the study on various critical concepts to investigate the effect of edge removal or edge addition on restrained domination number in signed graphs. 2022 World Scientific Publishing Company. -
Restrained domination in signed graphs
A signed graph ? is a graph with positive or negative signs attatched to each of its edges. A signed graph ? is balanced if each of its cycles has an even number of negative edges. Restrained dominating set D in ? is a restrained dominating set of its underlying graph where the subgraph induced by the edges across ?[D: V\D] and within V\D is balanced. The set D having least cardinality is called minimum restrained dominating set and its cardinality is the restrained domination number of ? denoted by ?r(?). The ability to communicate rapidly within the network is an important application of domination in social networks. The main aim of this paper is to initiate a study on restrained domination in the realm of different classes of signed graphs. 2020 Anisha Jean Mathias et al., published by Sciendo 2020. -
REMEMBERING PLACE: The Temporality of Trauma in Rudraprayag after the 2013 Flash Floods
The 2013 flash floods reproduced an everyday that was textural, the returning past of the event combined with gestures from within the everyday, to disorient survivors of the event. I attempt in this essay to analyze the return of the event as producing psycho-spatial affects, drawn from the psyches own propensity to return while repressing the event that causes the return, described within psycho-analytic literature as afterwardsness. Such afterwardsness is conditioned by the sheer incomprehensibility of environmental change that took place in just three days in the Mandakini Valley between June 15 and June 17, 2013. Following the flood, delays with the recovery process, and particularly with the process of compensation, exacerbate this trauma, leading to an extension of the temporality of trauma infinitely forward. (2024), (American Anthropological Association). All rights reserved.
