Browse Items (5511 total)
Sort by:
-
Levelling Up Organisational Learning Through Gamification: Based on Evidence from Public Sector Organisations in India
The concept of sustainability brought into focus the need for research into how to measure and achieve sustainable growth. The triple bottom line framework and the resource-based view of the firm suggest the need for organisations to look beyond profits and take into consideration the needs and effectiveness of its workforce. Research suggests that an effective workforce can be achieved through constant learning and development. Organisations have also expressed the need for training techniques that are more effective than the traditional methods. Gamification has been proposed as one such technique, and in the current study, the researchers evaluate the effectiveness of gamification in organisational training. For the purpose of the current study, 120 participants were chosen from public sector organisations in India. This is primarily because the technology-enhanced training effectiveness model (TETEM) suggests that the effectiveness of gamification would depend on the culture of the organisation, and prior research has been based in privately owned firms. The findings are in line with the theory of gamified learning and suggest that participants of the gamified module reported higher levels of learning, reaction and learner motivation. Additionally, learner motivation was found to strengthen the impact of gamification on the learning and reaction. The Author(s) 2022. -
Stereotype threat and psychological wellbeing in children of prisoners
Stereotypes are ideas that one holds regarding individuals because of their membership to a specific group. The current research was undertaken to study stereotype perception and stereotype threat on the psychological wellbeing of children of prisoners. Eight children of prisoners in the age range of 17 to 25 (females = 4), whose fathers were in prison for more than a year, participated in the study. Semi-structured interview method was used to collect data from the participants and data were analyzed using thematic network analysis method. Results revealed that children of prisoners strongly perceive stereotypes against them and they conform to stereotypes. Further to this, it was found that stereotype threat had positive effects in terms of increased goal-directed behavior and negative effects in terms of reduced happiness and increased feelings of anger and sadness. These Undings are discussed in light of previous literature on the effects of stereotypes on behavior. 2019 International Journal of Criminal Justice Sciences (IJCJS). -
Oxidation reactions of carbaryl in aqueous solutions
Hydroxyl radical induced oxidation of carbaryl has been studied using steady state photolysis followed by high-resolution mass spectrometry (LC-Q-TOF-MS), pulse radiolysis, and theoretical (DFT) calculations. The reaction of ?OH with carbaryl resulted in a number of hydroxylated adduct radicals (?max - 330 nm and 390 nm; k2 - 1.2 1010 dm3 mol-1 s-1). The DFT calculations and results obtained from LC-Q-TOF-MS analysis shows the possible addition of ?OH at C1 (energetically most stable) and C7 positions of carbaryl leading to the generation of resonance stabilized hydroxycyclohexadienyl-type radicals as the immediate intermediates, which eventually converted into naphthol and a hydroxylated naphthols. LC-Q-TOF-MS results also revealed the formation of other hydroxylated derivatives and naphthoquinones that are most likely originated from the consecutive ?OH attack on the initially formed products. Naphthoquinones are found to undergo ring opening and the corresponding products are identified. The reaction of SO4?- with carbaryl, on the other hand, results the radical cation of parent molecule (?max - 320 nm and 390 nm) which exhibits reasonable stability in the pulse radiolysis timescale. Total organic carbon (TOC) analysis after H2O2/UV photolysis revealed that nearly 70% of the organic content is mineralized after 35 min of irradiation, which demonstrates the potential application of oxidative methods towards the degradation of carbaryl. 2021 Elsevier B.V. -
Spectroscopic, crystal structure and DFT-assisted studies of some nickel(II) chelates of a heterocyclic-based NNO donor aroylhydrazone: in vitro DNA binding and docking studies
Five new nickel(II) complexes have been synthesised with an NNO donor tridentate aroylhydrazone (HFPB) employing the chloride, nitrate, acetate and perchlorate salts, and all the complexes are physiochemically characterized. Elemental analyses suggested stoichiometries as Ni(FPB)(NO3)]2H2O (1), [Ni(HFPB)(FPB)]Cl (2), [Ni(FPB)(OAc)(DMF)] (3), [Ni(FPB)(ClO4)]DMF (4), [Ni(FPB)2] (5). Aroylhydrazone is found coordinating in deprotonated iminolate form in four of the complexes (1, 3, 4, 5) however in one case (complex 2), two aroylhydrazone moieties are binding to the metal centre in the neutral and anionic forms. The structure of the bisligated complex 5, found using single crystal X ray diffraction studies confirmed that the metal has a distorted octahedral N4O2 coordination environment, with each of the two deprotonated ligands coordinating through the pyridine nitrogen, imino-hydrazone nitrogen and the enolate oxygen of the hydrazone moiety. To compare and study, the electronic interactions and stabilities of the metal complexes, various quantum chemical parameters were calculated. Moreover, Hirshfeld surface analysis was carried out for complex 5 to determine the intermolecular interactions. The biophysical attributes of the ligand and complex5 have been investigated with CT-DNA and experimental outcomes show that the Ni(II) complex exhibited higher binding propensity towards DNA as compared to ligand. Furthermore, to specifically understand the type of interactions of the metal complexes with DNA, molecular docking studies were effectuated. In addition, the electronic and related reactivity behaviors of the ligand and five Ni(II) complexes were studied using B3LYP/631 + + G**/LANL2DZ level. As expected, the obtained results from Natural Bond Orbital (NBO) computations displayed that the resonance interactions (n ? ?* and ? ? ?*) play a determinant role in evaluating the chemical attributes of the reported compounds. Graphical abstract: (Figure presented.). The Author(s), under exclusive licence to Springer Nature Switzerland AG 2023. -
Synthesis, spectral and DNA/Protein binding evaluation of novel Cu(II) chelates of an NNO donor tridentate aroylhydrazone: Halogen bonding directed close packing
An NNO donor aroylhydrazone monohydrate, HFPBH2O (3-fluoropyridine-2-carbaldehyde benzoylhydrazone monohydrate) was synthesized from 3-fluoropyridine-2-carbaldehyde and benzhydrazide and physicochemically characterised. The coordination behaviour of the aroylhydrazone with the metal ion is investigated through various physicochemical techniques and it is concluded that it binds to the metal ion predominantly in the enolate resonance form, while few complexes exhibit keto form of the ligand. The structure of [Cu(FPB)(OAc)(H2O)]H2O (4a) established by single-crystal X-ray diffraction method unveiled that the metal ion has a distorted square-pyramidal geometry in this complex. The coordination sites of Cu(II) ion are occupied by azomethine N, pyridyl N and iminolate O from a monodeprotonated hydrazone moiety and the remaining two positions are occupied by two oxygen atoms, one each from acetate ion and the water molecule. Potential applications of the complexes were studied by subjecting them to DNA/protein (BSA) binding studies using electronic and fluorescence spectroscopy. The complexes were found to bind with DNA/protein (BSA) with binding constants in the order of 104 M?1 to 105 M?1. The intercalative mode of binding of the complexes with DNA was proved using spectral studies and molecular docking. Furthermore, the complex [Cu(FPB)(N3)(H2O)2] (5) was found to cleave the DNA from form I to form II during gel electrophoresis studies. 2020 Elsevier B.V. -
Automated epileptic seizure classification using adaptive fast Fourier transform with non-uniform sampling and improved deep belief network
In automated brain-computer interaction (BCI), EEG signals are essential. This research uses AI to detect epileptic seizures, employing data from the BONN dataset (UCI), CHB-MIT dataset (physionet server), and Bangalore EEG Epilepsy Dataset (BEED). The goal is to develop an automated system for accurate seizure detection using adaptive fast Fourier transform with non-uniform sampling (AIFFT-NS) and an improved deep belief network (IDBN) model to enhance classification accuracy. The AIFFT-NS model serves as a channel for transforming spectro-temporal data. Using various EEG datasets, a number of extensive experiments are carried out, resulting in the validation of the efficacy of the proposed approach. High accuracy metrics, with 96.16% for the BEED dataset, 99.41% for the BONN dataset, and 96.31% for the CHB-MIT dataset, represent the evidentiary outcomes. This study emphasises the critical function of AI-facilitated spectro-temporal EEG analysis within the domain of medical diagnostics, going beyond the realm of automated seizure onset classification. Copyright 2024 Inderscience Enterprises Ltd. -
Progressive crude oil distillation: An energy-efficient alternative to conventional distillation process
Distillation, the major process in crude oil refineries as of now. In this work we focused the attention to energy saving with respect to an industrial crude oil distillation unit. An alternative to the conventional crude oil distillation model present in the Bharat Petroleum Corporation, Kochi Refinery is proposed and simulated. The theoretical predictions as well as the simulated results indicate that the Progressive crude oil distillation reduces the utility burden as well as increase the extraction of more valuable light components. The simulation was carried out using Aspen HYSYS V8.8.2. Different crudes are taken into account and their properties and amount of distillate are analyzed. The optimization is done in an easy manner rather than the conventional mathematical method, together with the advanced process control tools; make it profitable in the operation in real time. 2018 Elsevier Ltd -
Simulation, optimisation and analysis of energy saving in crude oil distillation unit
Physical distillation is the major process in crude oil refineries as of now. To ensure quality control in the final products, it is essential to ascertain the true boiling point of the crude oil and the products. The work is mainly concentrated to an industrial crude oil distillation unit. The objective of the paper is to present the simulation and optimisation of crude distillation unit (CDU) along with the analysis of energy saving, using Aspen HYSYS V8.8.2. Different crudes are taken into account, their properties and amount of distillate are analysed. The process optimisation is done in an easier manner using Aspen HYSYS rather than the conventional mathematical method, together with the advanced process control tools; make it profitable in the operation in real-time. The simulation results are validated with the actual plant results. Copyright 2018 Inderscience Enterprises Ltd. -
Coronal Elemental Abundances During A-Class Solar Flares Observed by Chandrayaan-2 XSM
The abundances of low first ionization potential (FIP) elements are three to four times higher in the closed loop active corona than in the photosphere, known as the FIP effect. Observations suggest that the abundances vary in different coronal structures. Here, we use the soft X-ray spectroscopic measurements from the Solar X-ray Monitor (XSM) onboard the Chandrayaan-2 orbiter to study the FIP effect in multiple A-class flares observed during the minimum of Solar Cycle 24. Using time-integrated spectral analysis, we derive the average temperature, emission measure, and the abundances of four elements Mg, Al, Si, and S. We find that the temperature and emission measure scales with the sub-class of flares while the measured abundances show an intermediate FIP bias for the lower A-flares (e.g. A1), while for the higher A-flares, the FIP bias is near unity. To investigate it further, we perform a time-resolved spectral analysis for a sample of the A-class flares and examine the evolution of temperature, emission measure, and abundances. We find that the abundances drop from the coronal values towards their photospheric values in the impulsive phase of the flares and, after the impulsive phase, they quickly return to the usual coronal values. The transition of the abundances from the coronal to photospheric values in the impulsive phase of the flares indicates the injection of fresh unfractionated material from the lower solar atmosphere to the corona due to chromospheric evaporation. However, explaining the quick recovery of the abundances from the photospheric to coronal values in the decay phase of the flare is challenging. 2023, The Author(s), under exclusive licence to Springer Nature B.V. -
Derris Indica Leaves Extract as a Green Inhibitor for the Corrosion of Aluminium in Alkaline Medium
The corrosion inhibitive effect of Derris indica leaves extract (DILE) on aluminium in 1 M NaOH is investigated at different temperatures. For this purpose, weight loss studies and electrochemical methods including potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) technique are employed. Surface analysis of the treated and untreated aluminium coupons are done by using metallurgical microscopy. About 60.2% of maximum corrosion inhibition efficiency is attained with an optimum inhibitor concentration of 1.2 g/L. Both weight loss and electrochemical studies confirmed that DILE plays a crucial role in the formation of a protective layer over metal surfaces. Also, electrochemical measurements revealed that DILE behaves as a mixed type of corrosion inhibitor. The kinetic parameters and thermodynamic parameters are calculated using Arrhenius theory and transition state theory. Langmuir adsorption isotherm was found to be the best fit and physical adsorption mechanism was proposed. En ineered Science Publisher LLC 2022 -
Predictors of behavioral and emotional issues in children involved in custody disputes: A cross sectional study in urban Bengaluru
Background: The increasing rates of divorce in urban India has led to the subsequent parental battle for the child's custody. This paper discusses the behavioral and emotional issues of these children in relation to their psychosocial environmental factors and other relevant socio-demographic variables. Methods: We used samples from parent interviews concerning 52 children aged 717-years-old, involved in child custody cases in the Family court of urban Bengaluru. The Strengths and Difficulties Questionnaire was used to measure response variables of behavioral and emotional issues in these children. Predictor models of quantile and multiple linear regression were used to assess the influence of psychosocial environmental factors and socio-demographic variables on the response variables. Results: The predictor models revealed that risk of child suffering emotional and behavioral issues increased with factors such as excessive parental control, change of academic environment, general unrest at school, frequency of child's court visit, child's visitation of non-custodian parent on occasions and vacations, and negatively altered family relationship. The model however intriguingly showed that residing in nuclear household rather than with their grandparents in a non-nuclear household, decreased the risk of mental health issues in these children. Conclusions: This study is a novel attempt to understand the influence of the psychosocial issues on the child's mental health in the context of custody cases in India. Despite the minimum sample size, the findings imply that family-based intervention is the need of the hour in these cases. The implications for clinical practice and research are discussed. 2021 Elsevier B.V. -
Protection of intellectual property and human rights during health emergencies: an assessment of the patent waiver proposal
Purpose: Several countries, such as South Africa and India, believe that intellectual property rights (IPRs), including patents, impede the efficient increase in vaccine production to inoculate the global population as they scramble to recover from the COVID-19 pandemic. Their proposal at the World Trade Organization (WTO) to waive these pharmaceutical patents has been met with resistance from a few developed countries, who believe that the abrogation of IPRs is unnecessary, even during a pandemic. The purpose of this paper is to discuss the impact of a potential waiver of medical patents at the WTO versus the status quo of IPR laws in the global economy. Design/methodology/approach: This study examines key arguments from economic and moral standpoints regarding the provisions of the Trade-Related Aspects of Intellectual Property Rights (TRIPS) agreement and other related international agreements and their validity based on the premise of the internalisation of positive externalities posed by vaccines. Findings: The effectiveness of the TRIPS agreement in securing medical access is weak on account of the ability of profit-making multinationals to secure IP rights and on account of the Trans-Pacific Partnership, a multilateral agreement that supports patent evergreening and a period of protection on test data which challenges the access to medicines and the fundamental human right to health. Originality/value: This study examines international IPRs through the lens of human rights and proposes a new system that balances the two. 2022, Emerald Publishing Limited. -
Continuity and changes in food consumption pattern among Tibetan refugee community in India
The Food consumption pattern of refugee communities is being carried out by many scholars and few acknowledged the food continuity, its implications on the health of refugees in the host country. The present study highlights food continuity among Tibetan refugees in the Bylakuppe settlement, India. 200 household data were administered to understand food consumption patterns by employing a structured household questionnaire. Simultaneously, 23 individual data were collected consisting of first migrants (15) and second-generation (8) for the qualitative study. Households derive energy mainly from carbohydrates and animal fats, and there is a prevalence of food insecurity among the Tibetan community. It is a proven fact that food insecurity will have serious health consequences in terms of emotional and mental well-being and suggest the need for further study of food insecurity among Tibetan refugees across the world. 2021 -
Influence of remittances oncapital endowment of Tibetan refugees in India
Purpose: An issue concerning Tibetan refugees in India is the poverty and unemployment among Tibetan youth. This often leads to households adopting a strategy of sending one of its members abroad towards North American or European countries in search of better income opportunities. Incomes in the form of remittances from these forward migrants have numerous impacts on living standard of left behind families. This study aims to focus on the influence of forward migrants remittances on livelihood in terms of human, financial and social capital development of Tibetan refugees in India. Design/methodology/approach: The paper includes 400 households from high-economic and low-economic-access regions of Tibetan settlements in India. Ordinary least square method was used to study these impacts. Findings: Findings show that remittances have significantly influenced human and financial capital development. However, it was found to be statistically not significant for social capital development. Originality/value: The present paper is original work. 2019, Emerald Publishing Limited. -
Titania Doped CDs as Effective CT-DNA Binders: A Novel Fluorescent Probe via Green Synthesis
Carbon dots (CDs), which belong to the class of zero-dimensional carbon-based nanomaterials, have garnered significant interest owing to their wide array of applications spanning from the electronics industry to the healthcare sector. This work employs a facile, inexpensive approach to synthesize green luminescent carbon dots (J-10) from a potential medicinal plant named Justicia Wynaadensis by the one-step hydrothermal method. A nanocomposite (JT-10) of the CDs is prepared by adding TiO2 nanoparticles derived from green synthesis of Lavandula leaves. The J-10 and JT-10 are further characterized by X-ray Diffraction spectroscopy (XRD), Transmission Electron Microscopy (TEM), Raman analysis X-ray Photoelectron Spectroscopy (XPS), and Fourier transform infrared techniques (FTIR), UVvis spectroscopy, Photoluminescence (PL), and Fluorescence or PL lifetime analysis. The average size of synthesized CDs is 1.85 nm and exhibits an excitation-dependent fluorescence nature at 320 nm. PL lifetime analysis of J-10 and JT-10 is calculated to be 5.80 and 2.84 ns respectively. Offering these unique optical properties and biocompatibility, the synthesised material is suitable for investigating their binding affinity and interaction mechanisms with DNA. The use of JT-10 in DNA binding studies contributes to the development of sustainable and efficient nanomaterials for applications in biosensors, drug delivery, and gene therapy. 2024 Wiley-VCH GmbH. -
Thermorheological effect on RayleighBard magnetoconvection in a biviscous Bingham fluid with rough boundary condition on velocity and Robin boundary condition on temperature
The thermorheological effect on the onset of RayleighBard convection in a biviscous Bingham fluid in the presence of a horizontal magnetic field is investigated considering rough boundary conditions on velocity and Robin boundary conditions on temperature. The viscosity of the electrically conducting fluid is assumed to be sensitive to temperature variation. Linear and global nonlinear stability analyses are performed using the Chebyshev pseudospectral method to determine the existence of instability or otherwise. A general interpretation is made from the results to show the effects of the magnetic field and the variable viscosity on the system's stability. The biviscous Bingham parameter and the Chandrasekhar number are shown to have a delay in the onset of convection, while the effect of temperature sensitivity is to advance the onset. It is found that the results of linear and global nonlinear stability are not in agreement, so the region of subcritical instability exists. Also, the results obtained for RayleighBard convection agree pretty well with those of Platten and Legros and Siddheshwar et al. for the limiting cases. 2023 Wiley Periodicals LLC. -
Study of Influence of Combustion on DarcyBard Convection with Inherent Local Thermal Non-equilibrium Between Phases
This work deals with a DarcyBard convection problem in the presence of combustion and with local thermal non-equilibrium between the fluid and the solid phases. The effects of combustion and local thermal non-equilibrium on the onset of convection is studied in the linear and nonlinear regimes. Unlike all reported local thermal non-equilibrium problems reported so far, the present problem has a unique situation of having thermal non-equilibrium not only in the perturbed state but also in the basic state. Further, we observe that local thermal non-equilibrium does not, under any circumstance, lead to local thermal equilibrium except in an approximate sense when the combustion is quite weak. The effect of combustion is to advance the onset of convection compared to that in its absence. The effect of local thermal non-equilibrium is to reinforce the effect of combustion. In the presence of both these effects, sub-critical instability exists. The results are obtained numerically and have implication in practical porous medium convection problems. 2022, The Author(s), under exclusive licence to Springer Nature B.V. -
THE MONOCHROME TAPESTRY OF SOLO EXISTENTIAL TRAVEL IN 21ST CENTURY HOLLYWOOD: A CRITICAL ANALYSIS
Solo existential travel films of Hollywood enjoyed their heyday in the first two decades of the 21st century with most of them emerging as cult classics that have inspired millions to venture out on backpacking trips. The solo travel beyond the margins of a materialistic society that promises the traveller some existential clarity, in theory, is a truly existential endeavour that lets the individual exercise their Sartrean freedom and responsibility. But a quick survey of the films produced by Hollywood over the decades reveals a rather stealthy racism within. Solo existential travellers in Hollywood films of the 21st century have predominantly been white Americans. Despite being a powerful tool to create ones meaning and authentic identity in society, solo travel is still an instrument of self-redemption that is kept away from people of colour, especially the black American community. The paper will look into the significance, relevance and consequences of this seemingly invisible omission. From an embodiment perspective, the paper will attempt to analyze the absence of racial diversity in the genre to shed light on why the coloured body is to find its space in Hollywoods tapestry of solo existential travel. Copyright 2024 Namitha Nandan. -
Cyanogenic glycosides: A sustainable carbon and nitrogen source for developing resilient Janus reversible oxygen electrocatalysts for metal-air batteries
Most of the transition metal based heteroatom doped carbon electrocatalysts, utilizes the fossil fuel derived commercially available precursors as source of nitrogen and carbon which may question our environmental generosity. Herein, we have developed Ni-based efficient bifunctional electrocatalysts using apple seeds (that contains cyanogenic glycosides) as the precursor for nitrogen and carbon. With tuning the temperature, we were able to optimize the nitrogen doping up to ?3 at.%. The optimized electrocatalyst catalyses the oxygen reduction reaction (ORR) process with muted peroxide generation (for 0.7500.1 V the % HO2 ? generation ?3 - 2%), preferential 4e? reduction pathways (n ? 3.93 to 3.98 in 0.750.1 V range) and electron transfer via inner-sphere electron transfer mechanism which ensures the maximum utilization of instituted active centres owing to the direct interaction of reactant species. Alike to ORR, the superior oxygen evolution reaction (OER) performance with smaller Eonset, EJ=10, Tafel slope and enduring accelerated stability test advocates its potential as a bifunctional oxygen electrocatalyst. Moreover, smaller potential gap ?E (EJ10_OER - E1/2_ORR) of 0.845 V further warrants the energy efficient OER/ORR process. A porotype of Al-air battery system using our catalysts as oxygen electrode and chocolate wafer as anode material is well capable of powering the light emitting diodes. This study hopefully opens a new avenue to explore cyanogenic glycosides plants product to develop multifunctional electrocatalysts. 2019 Elsevier Ltd