Browse Items (5511 total)
Sort by:
-
Heat and mass transfer analysis of Casson-based hybrid nanofluid flow in the presence of an aligned magnetic field: An application toward mechanical engineering
This examination explores the flow of a hybridized nanofluid (HyNf) containing silica and tin oxide nanoparticles mixed with engine oil (EO/SnO2-SiO2). The flowing occurs via a permeable material constrained by a semi-infinite flat plate. The study takes into account various factors such as convective heat and mass transference, chemical reactions, the Dufour effect, the Lorentz force, thermal radiative fluxing, and radiative absorbing. The research involves converting the managing formulas of the flowing model into a dimensionless form and applying the regular perturbation procedure to find solutions for the rate of fluid flow, temperature, and species diffusion. The surface frictional factor, Nusselt quantity, and Sherwood quantity reflect the shearing stress, rates of heat transference, and rates of mass transport at the plate, respectively. An analysis is conducted on the impact of several factors, including the suction variable, magnetic variable, radiation-absorbing factor, Casson parameter, and Dufour number, on the flow and related quantities. This analysis is based on an examination of graphs and tables. The findings suggest that the heat transference rate in the Casson hybridized nanofluid is better than that in the mono nanofluid. It is exposed that the temperature reduces at the plate having improved frequency of oscillation and also fluid velocity declines for improving values of aligned magnetized field (Formula presented.), but it shows the reverse phenomenon with Gr1 and Gc1. IMechE 2024. -
Redefined families and subsystems: Reading kinship and hierarchical structures in select Hijra autobiographies
Hijras or transwomen in India are gendered identities, but their identities cannot be reduced to the conceptual framework and analysis of sex, gender and sexuality. Being the minority in India, transgender lives intersect with caste, class, kinship and hierarchy. The study locates these intersections within the scope of the select hijra autobiographies; The Truth About Me: A Hijra Life Story by A. Revathi and I am Vidya by Vidya. The study looks at the notions of family which are traditionally woven in heteronormative and patriarchal setups. It examines the gharanas system or subsystems in hijra communities that redefines the structures and hierarchies of the family, and designating the fellow elder hijras with the relation of mata (mother) and cela (disciple), thus forming a kinship which is located beyond the caste, class and religious structures. The emphasis is to study how families are inserted in heteronormative perspectives and argues a redefining of the notion of family,and to establish and recognize the newer perspectives on family which lies outside the traditional setup. AesthetixMS 2020. -
Cultural Violence, Violent Gendering, and Abjection: Discourses on Sites of Violence through Trans Womens Narratives from India
The conventional cultural construct of gender and sexuality embedded in the dichotomous paradigm makes it challenging for people with queer and trans identities to fit into an assigned social role. Violent gendering takes place where women are seen as secondorder beings, disciplined and controlled by men, the first-order beings. The process of feminization and femininity is linked to women, which fixates on the idea that one is born a woman rather than one becomes a woman. This violent process of acculturation to these set norms comes with a lot of vulnerability for trans people in the form of abiding by the parameters of femininity and the threat of physical violence against their intersecting and transitioning bodies. Kristevas conception of abjection can be used to understand the discriminatory behavior against outcasts whose sexual or gender practices fall outside of the normative standards and conventions. At the same time, cultural violence, which Charlotte Bunch (2015) describes, is the culturally embedded practice and assumption of domination over women in virtually all societies. She also emphasizes that there is a need to understand that all violence against women is supported by cultural attitudes, which she argues is the real cultural challenge of violence. Keeping in perspective the idea put forth by Bunch, this article critically examines the violence reinforced by culture, and the process of gendering, with a central focus on the intersectional experiences of trans bodies as abject between gender, sex, and culture. This leads to the systematic violence enacted upon them by the invisible disciplinarians. The article considers 21st-century trans womens narratives, Laxmi Narayan Tripathis Me Hijra, Me Laxmi (2015) and Red Lipstick: The Men in my Life (2016). This article contextualizes and situates trans narratives, which provide insight into how trans womens bodies are seen as abject and have gone through the violent process of gendering and culturing 2022 Journal of International Womens Studies -
Detection and Classification of Colorectal Polyp Using Deep Learning
Colorectal Cancer (CRC) is the third most dangerous cancer in the world and also increasing day by day. So, timely and accurate diagnosis is required to save the life of patients. Cancer grows from polyps which can be either cancerous or noncancerous. So, if the cancerous polyps are detected accurately and removed on time, then the dangerous consequences of cancer can be reduced to a large extent. The colonoscopy is used to detect the presence of colorectal polyps. However, manual examinations performed by experts are prone to various errors. Therefore, some researchers have utilized machine and deep learning-based models to automate the diagnosis process. However, existing models suffer from overfitting and gradient vanishing problems. To overcome these problems, a convolutional neural network- (CNN-) based deep learning model is proposed. Initially, guided image filter and dynamic histogram equalization approaches are used to filter and enhance the colonoscopy images. Thereafter, Single Shot MultiBox Detector (SSD) is used to efficiently detect and classify colorectal polyps from colonoscopy images. Finally, fully connected layers with dropouts are used to classify the polyp classes. Extensive experimental results on benchmark dataset show that the proposed model achieves significantly better results than the competitive models. The proposed model can detect and classify colorectal polyps from the colonoscopy images with 92% accuracy. 2022 Sushama Tanwar et al. -
A survey of blockchain: concepts, applications and challenges
With the development of Bitcoin, organisations, be it businesses or institutions, are centring on leveraging Bitcoins blockchain technology to non-monetary based applications to improve efficiency of the activities. Having various benefits like anonymity, decentralised, audibility etc. Blockchain technology can be vastly implemented in various sectors other than financial too. This paper gives an overview the blockchain technology. It briefs about various technical concepts used in the blockchain, its types and where it can be used. It also discusses some proposed applications of the technology and tools or frameworks that can be used to develop such. It also presents the limitations of the technology. Copyright 2023 Inderscience Enterprises Ltd. -
A review on quantum utility for secure authentication protocol towards cryptographic standard in quantum dot cellular automata
QCA, which stands for Quantum Dot-Cellular Automata, is a nanotechnology model that offers an alternative solution to the widely used CMOS technology. Unlike CMOS, QCA is a semiconductor-less technology that transmits information based on the charge of electrons and the electrostatic repulsion between them. This technology provides several advantages over CMOS, including higher device density, faster switching speed, and lower power consumption. When it comes to cryptographic applications, QCA circuits can be extremely useful. Both encryption and decryption processes can be implemented using logic circuits based on QCA. The research paper describes a basic method for generating ciphertext in QCA, which is useful in secure nano communication based on QCA. The paper discusses how to achieve secure authentication in encrypted communication using QCA. To evaluate the performance and test the proposed method, the researchers used the QCA Designer-2.0.3 tool. This is a software tool specifically designed for designing and simulating QCA circuits. It enables researchers to model and analyze the behavior of QCA-based systems, allowing them to evaluate the effectiveness and feasibility of their proposed encryption technique. Overall, the research paper aims to present a secure encryption method using QCA and demonstrates its implementation and testing using the QCA Designer-2.0.3 tool. By leveraging the unique properties of QCA, such as high device density and low power consumption, the researchers aim to provide a novel approach for secure nano communication and cryptographic applications. Taru Publications. -
In silico molecular docking study of Andrographis paniculata phytochemicals against TNF-? as a potent anti-rheumatoid drug
Tumor necrosis factor-? (TNF-?) is a proinflammatory cytokine which plays a crucial role in controlling inflammatory responses. The pathway of Rheumatoid arthritis (RA) leading to TNF-alpha is activated by macrophages and quite often by natural killer cells and lymphocytes. In the inflammatory phase, it is believed to be the main mediator and to be anchored with the progression of different diseases such as ankylosing spondylitis, Crohn's disease, and Rheumatoid arthritis (RA). The major goal of this study is to use in silico docking studies to investigate the anti-inflammatory potential of a bioactive molecule from the medicinal plant Andrographis paniculata. The three-dimensional structures of different phytochemicals of A. paniculata were obtained from PubChem database, and the receptor protein was derived from PDB database. Docking analysis was executed using AutoDock vina, and the binding energies were compared. Bisandrographolide A and Andrographidine C revealed the highest score of ?8.6 Kcal/mol, followed by, Neoandrographolide (?8.5 Kcal/mol). ADME and toxicity parameters were evaluated for these high scoring ligands and results showed that Andrographidine C could be a potent drug, whereas Neoandrographolide and Bisandrographolide A can be modified in invitro and can lead to a promising drug. Further, the top scorer (Andrographidine C) and control drug (Leflunomide) were subjected to 100 ns MD Simulation. The protein complex with Andrographidine C had more stable confirmation with lower RMSD (0.28 nm) and higher binding energy (?133.927 +/? 13.866 kJ/mol). In conclusion, Andrographidine C may be a potent surrogate to the disease-modifying anti-rheumatic drugs (DMARDs) & Non-steroidal anti-inflammatory drugs (NSAIDs) that has fewer or minor adverse effects and can aid in RA management. 2022 Informa UK Limited, trading as Taylor & Francis Group. -
Heat and mass transfer of triple diffusive convection in boussinesq-stokes suspension using ginzburg-landau model
The nonlinear stability of triple diffusive convection in Boussinesq-Stokes suspension is analysed by using Ginzburg-Landau model. Using the Bernoulli equation obtained from Ginzburg-Landau model, Nusselt number and Sherwood numbers of different solutes are studied to quantify the heat and mass transfer. It is found that the effect of couple stress parameter is to stabilize the system. 2017 Pushpa Publishing House, Allahabad, India. -
Time-periodic heating in boussinesq-stokes suspension with three diffusing components
The effect of time-periodic heating in Boussinesq-Stokes suspension with three diffusing components has been carried out for the linear case. The correction Rayleigh number is obtained by applying the perturbation method to effectually control the convective flow by varying amplitude and frequency of modulation, and the eigenvalues are obtained by the Venezian approach. The time-periodic heating has been carried out for three cases: symmetric, asymmetric, and modulating only the lower boundary. It is found that the system is stable for smaller values whereas unstable for moderate values of frequency of modulation. 2021 by the authors. -
Need for an Evolved Groundwater Justice in Rural Areas of Uttar Pradesh, India
As groundwater is the primary element of life, countries all over the world are experimenting with legal reforms. The degree to which law reforms combine justice and sustainability is a crucial question. In response to this question, the present article focuses on a case study of Uttar Pradesh, India. Our response is based on a content analysis of the Uttar Pradesh Groundwater (Management and Regulation) Act, 2019, and the Uttar Pradesh Groundwater (Management and Regulation) Rules, 2020. Three conclusions emerged from our investigation. First, the 2019 Groundwater Act and the 2020 Draft Groundwater Rules are primarily motivated by concerns about resource sustainability, particularly in areas where the water table is steadily declining. Still, neither the 2019 Groundwater Act nor the 2020 Draft Groundwater Rules propose any proactive groundwater justice measures. Second, we suggest that some locally defined basic elements are critical in supporting sustainability and to a lesser extent groundwater justice. These characteristics include a communitys ability to (1) recognize a crisis and show a willingness to address it; (2) establish a rule-bound community groundwater resource; (3) demonstrate leadership and a sense of community; and (4) make use of awareness, information, and knowledge. Our third conclusion is that there is a need for community practices and state-led groundwater law to co-evolve; this co-evolution has the potential to create groundwater arrangements that support both groundwater justice and sustainability. 2024 Technoscience Publications. All rights reserved. -
Deciphering the non-linear nexus between government size and inflation in MENA countries: an application of dynamic-panel threshold model
Contradictory to conventional economic theory, which foresees any increase in the size of government as inflationary, this article provides evidence that the reaction of price levels to changes in the size of government is nonlinear. The price levels do not necessarily increase in response to a rise in the size of the government but only up to a certain threshold or optimal level. Accordingly, this paper utilizes the dynamic panel threshold model to examine the threshold effects of government size (measured as government final consumption expenditure as a proportion of GDP) on inflation using a sample of 10 selected MENA countries from 1980 to 2019. The findings of this study stand out in several ways. First, the results support the nonlinear relationship between government size and inflation in the study area. Second, the government sizes estimated threshold level is equivalent to 12.46%. Third, government size negatively impacts inflation in the regime of small governments up to the threshold level. The impact turns positive once the government size goes beyond the threshold level in a regime of large size of government. These findings have ramifications for the conduct of fiscal policy. Policymakers in the MENA region can increase the size of government till it reaches the threshold level without exerting any upward pressure on price levels. The Author(s) 2024. -
Beyond the basics: mapping the inflation response to fiscal deficit in India with smooth transition autoregressive model
Purpose: Indias historical fiscal performance has featured elevated deficit levels. Driven by the imperative need for fiscal stimulus measures in response to the crisis, efforts toward fiscal consolidation from 2003 to 2008 were reversed in 20082009 due to the financial crisis. These stimulus actions are believed to have wielded a notable influence on inflation dynamics. Presumably, a high inflation rate hinders growth and inflicts severe welfare costs. Accordingly, the principal objective of this paper is to scrutinise the threshold effects of fiscal deficit on inflation within the context of the Indian economy. Design/methodology/approach: We employed the Smooth Transition Autoregressive (STAR) Model, a robust tool for capturing non-linear relationships, to discern the specific threshold level of fiscal deficit. Our analysis encompasses annual data spanning from 1971 to 2020. Additionally, we have leveraged the Toda-Yamamoto causality test to establish the existence and direction of a causal connection between fiscal deficit and inflation in the Indian economy. Findings: Our analysis pinpointed a critical threshold level of 3.40% for fiscal deficit, a value beyond which inflation dynamics in India undergo a marked transition, signifying the presence of significant non-linear effects. Moreover, the results derived from the Toda-Yamamoto causality test offer substantiating evidence of a causal relationship originating from the fiscal deficit and leading to inflation within the Indian economic framework. Research limitations/implications: The findings of our study carry significant implications, particularly for the formulation and execution of both fiscal and monetary policies. Understanding the threshold effects of fiscal deficit on inflation in India provides policymakers with valuable insights into achieving a harmonious balance between these two critical economic variables. Originality/value: To the best of our knowledge, this study is the first of its kind to empirically investigate threshold effects of fiscal deficit on inflation in India from a non-linear perspective using the Smooth Transition Autoregression (STAR) model. 2024, Emerald Publishing Limited. -
Emotion Regulation and Psychological Well-being as Contributors Towards Mindfulness Among Under-Graduate Students
Emotion regulation is generally described as the ability of an individual not only to manage emotions effectively but also to respond effectively to the emotional experience. It has also been viewed as a crucial aspect for psychological well-being. It is a psychological state which means more than just being free from stress and not having any other psychological disorder reported by the individual. At the same time, students with higher emotion regulation and psychological well-being are expected to be more attentive and able to observe, describe and participate in the present moment, effectively, with non-judgmental awareness, which is in turn defined as mindfulness. Hence, it has been expected that participants with higher emotion regulation and psychological well-being would also report higher levels of mindfulness. Therefore, the present empirical investigation has been conducted with an objective of assessing the level of emotion regulation, psychological well-being and mindfulness among under-graduate students. Additionally, it was also expected that all the said variables would be positively correlated and emotion regulation and psychological well-being would predict mindfulness positively for under-graduate students. For this purpose, ex post facto research design was adopted, and standardized tools pertaining to emotion regulation, psychological well-being and mindfulness were administered on a sample of 104 under-graduate students. The results of correlation statistics revealed that emotional regulation (r=0.27; p<0.01) and psychological well-being (r=0.21; p<0.01) are the positive and significant correlates of mindfulness. Additionally, statistical outcomes of stepwise multiple regression analysis confirm that emotion regulation and psychological well-being are the significant predictors of mindfulness and contribute collectively towards a 11% variance towards the same. 2020, Springer Nature Switzerland AG. -
Crystal shape engineering and studies on the performance of vapour deposited InSe platelets
The influence of growth conditions on the morphology of stoichiometric indium monoselenide (InSe) crystals has been explored. Crystalline habits such as microfibres, needles, platelets and spherulites were obtained from physical vapour deposition by optimizing supersaturation, which sturdily depends on the temperature difference between charge (TC) and substrate (TS) zones ?T, (= TC ? TS). Morphology and growth mechanism were investigated with the aid of scanning electron microscopy and high-resolution transmission electron microscopy, which justified the layer by layer addition of atoms as per the KosselStranskiVolmer model. Thermogravimetric measurements revealed the stability of InSe, confirming its melting point, M.P. = 611C, which reflects the formation of monophase. The mobility and carrier concentration calculated from the Hall effect experiment are found to be 11.14cm2V?1s?1 and 1.52 1020cm?3 respectively. Furthermore, optical characterizations such as UVVisNIR and photoluminescence spectrometric analysis established the value of band gap as 1.45eV, manifesting the versatility of the grown semiconducting platelets for photovoltaic applications. 2018, Springer Science+Business Media, LLC, part of Springer Nature. -
Grain-growth engineering and mechanical properties of physical-vapour-deposited InSe platelets
The present work demonstrates a novel use of physical vapour deposition for grain-growth engineering by optimizing supersaturation, which led to the evolution of stoichiometric indium monoselenide crystals, employing a custom-fabricated dual-zone furnace. The growth zone was kept at a constant temperature for different experimental runs (673-883K), while the source zone was kept at a stable temperature of 1123K. In this way, the temperature difference ?T = 240-450K resulted in a significant increase of the mass transport between the zones so as to accomplish bulk crystallization. At comparatively low supersaturation (?T = 240K), the presence of nodules and flakes was observed. When ?T = 250K, multiple grains were formed owing to temperature asymmetry at the rough vapour-solid interface. A further increase in supersaturation (?T = 330K) facilitated polyhedral grain growth, with distinct grain boundaries. A subsequent increment in ?T (400K) led to evolution of the polycrystalline morphology to well developed hexagonal platelets owing to adsorption of atoms on surface steps and kinks in accordance with the leading-edge growth mechanism. Energy-dispersive analysis by X-rays and X-ray diffraction experiments were carried out to confirm the structure and phase of crystals. Microindentation studies were done to assess the hardness and mechanical stability of the as-grown crystals in response to external loads in order to explore their suitability for solar cell applications. The investigations of bulk vapour phase transport, morphology and strengthening of InSe platelets provide pathways for the production of crystalline textures with versatile properties. International Union of Crystallography 2017. -
Architecture of monophase InSe thin film structures for solar cell applications
Control of microstructural evolution during the crystallization of InSe thin films is an inevitable strategy to mold their fundamental properties and potential for the fabrication of solar cells. Impact of annealing as well as substrate temperature on the crystallization progress and physical characteristics of thermally evaporated InSe was examined systematically, which eventually dictates the overall performance of resulting device. Structural and compositional characterizations have been thoroughly investigated by X-ray diffraction and energy dispersive X-ray analyses. InSe films form hexagonal structure with a preferred orientation of crystallites along the (004) direction upon crystallization. The layer of InSe is formed by two concomitant processes, deposition and recrystallization. Application of heat treatment resulted in topographical modification, which was probed by an atomic force microscope. Surface roughness was enhanced due to the influence of temperature and thereby the growth of grains. Investigations of electrical and optical properties, thus provided ample evidence for the use of crystallized monophase InSe as an absorber layer in photovoltaic conversion devices. Carrier concentration and mobility of charge carriers estimated from the Hall measurements were found to be 19.43020cm?3 and 2.01cm2V?1s?1 respectively. Moreover, this research work explores power conversion efficiency of p-InSe/n-CdS heterojunction solar cells. 2017 Elsevier B.V. -
Anchored ferrocene based heterogeneous electrocatalyst for the synthesis of benzimidazoles
A facile and sustainable electrochemical synthetic strategy for phenyl benzimidazoles has been developed using a ferrocene-based electrocatalyst anchored on Toray carbon paper (TCP) coated with conducting polymeric film. The developed electrode was used for the electrochemical dehydrogenative cyclization reaction of o-phenylene diamine and benzaldehyde using lithium perchlorate/acetonitrile as electrolyte. The surface characteristic properties of the developed electrode were characterized by FESEM, Optical profilometer and X-ray photoelectron spectroscopy. Electron transfer mechanism of the anchored ferrocene-based electrocatalyst was thoroughly studied. To determine the efficacy of the catalyst, the electron transfer coefficient (0.5) and apparent rate constant 41.4 s?1 were determined. The cyclic voltammetry studies reveal that the electrochemical oxidation peak for the synthesis of benzimidazole occurs at 0.48 V. The formation of the product was confirmed by Gas chromatography and Nuclear Magnetic Resonance spectroscopy. A comparison chart is presented for the green metrics and sustainability of the present strategy with other electrochemical approach. 2022 Elsevier Ltd -
Immobilized proline-based electro-organocatalyst for the synthesis of bis-?-diketone via Knoevenagel condensation reaction
In the quest for more sustainable chemical processes, we devised a technique using electro-organocatalysis to synthesize bis-?-diketone compounds via Knoevenagel condensation of benzaldehyde and dimedone. Our approach involves a modified electrode fabricated via anchoring L-proline onto a carbon fiber paper electrode supported by poly-3,4-diaminobenzoic acid (PDABA), which enhances efficiency in addition to the simple catalyst separation from the reaction mixture in heterogeneous catalysis. The electrochemical and surface topographical studies for the fabricated electrode were carried out, revealing high efficiency in comparison to the bare carbon fiber paper electrode. This electrochemical reaction operates under mild conditions utilizing lithium perchlorate and acetonitrile, yielding high amounts of the desired product. This study showcases a promising pathway for producing valuable organic compounds in an environmentally friendly manner, marking a significant stride forward in sustainable synthesis practices. 2024 Elsevier Ltd -
Enzyme based bioelectrocatalysis over laccase immobilized poly-thiophene supported carbon fiber paper for the oxidation of D-ribofuranose to D-ribonolactone
A modified electrode based on laccase immobilized poly-thiophene-3-carboxylic acid supported on carbon fiber paper was developed for the electrocatalytic oxidation of D-ribofuranose to otherwise difficult-to-access D-ribonolactone, a precursor for C-nucleoside based drug like Remdesivir. The electrochemical oxidation of D-ribofuranose was achieved by the TEMPO-mediated electrochemical process. The experimental parameters were optimized and validated using Design of Experiment (DoE) statistical tool indicating the concentration of TEMPO and stirring as important parameters in bulk electrolysis. The mechanism for the electrochemical oxidation of D-ribofuronose followed single electron anodic oxidation of TEMPO mediated by laccase to the corresponding oxoammonium nitrosonium species which was vital for the mediated electrochemical oxidation. The mechanism for the electrochemical oxidation was established using cyclic voltammetry and computational studies. The plausible interactions of laccase enzyme with TEMPO mediator were studied using molecular docking experiments. This facile method was successfully applied for the oxidation of D-ribofuranose to D-ribonolactone. 2022 -
An Insight into Photophysical Investigation of (E)-2-Fluoro-N-(1-(4-Nitrophenyl)Ethylidene)Benzohydrazide through Solvatochromism Approaches and Computational Studies
A fluoro-based Schiff base (E)-2-fluoro-N?-(1-(4-nitrophenyl)ethylidene)benzohydrazide (FNEB) has been synthesized from condensation of 2-fluorobenzohydrazide and 4?-nitroacetophenone catalyzed by glacial acetic acid with ethanol as the solvent. The dipole moment of FNEB in both the electronic states were found using different solvatochromic approaches such as Lippert-Mataga, Bakhshiev, Kawski-Chamma-Viallet, Reichardt and Bilot-Kawski. The experimental ground state dipole moment of FNEB was calculated using Guggenheim-Debye method and theoretical ground state dipole moment using Bilot-Kawski solvatochromic approach. The solvatochromic behavior of the Schiff base in different solvents was studied using absorption and emission spectra. Catalan and Kamlet-Abboud-Taft parameters were used from the multiple linear regression (MLR) analysis in order to study the solute-solvent interaction. The dipole moments were also calculated using Time Dependent-Density Functional Theory (TD-DFT). The chemical stability of FNEB was determined using computational and Cyclic Voltammetry by the use of obtained energy gap between the frontier orbitals. Using the frontier orbitals energy gap, global reactivity parameters were computed. Further, Light Harvesting efficiency was determined to comprehend the photovoltaic property of the Schiff base. 2019, Springer Science+Business Media, LLC, part of Springer Nature.