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Modified Carbon-Based Composites and Their Electrochemical Studies
Energy storage has emerged as the world's most important issue, attracting the focus of researchers and commercial developers due to the economy's rapid growth and the rise in the usage of portable electronics and electronic vehicles. These devices make it possible to efficiently capture and store the excess energy produced during times of high generation, so that it can be used when there is little or no generation. Devices for storing renewable energy contribute to grid stability and lessen the reliance on fossil fuel-based power plants. Moreover, they contribute to the decarbonization of the energy industry, mitigating climate change, and promoting a sustainable future. This thesis explores the potential of modified carbon-based composites as advanced materials for energy storage applications particularly supercapacitors and solar thermal fuels. The research focuses on the careful design and synthesis of ternary composites, incorporating carbonaceous materials such as carbon nanotubes, graphene oxide, and graphitic carbon nitrides, metal sulphides, nitrogen rich moieties, and conductive additives like polyaniline and polypyrrole. A wide variety of methodologies were used to describe the structural and morphological characteristics of the composite materials. Thermogravimetric analysis, Fourier transform infrared spectroscopy, X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, and other techniques were used. These methods gave important information about the composite materials' chemical structure, type of bonding and arrangements, surface morphology, and thermal stability. Electrochemical techniques, such as cyclic voltammetry, galvanostatic charge-discharge, and electrochemical impedance spectroscopy, have been extensively employed to investigate the performance and behaviour of supercapacitor electrodes and devices. The results demonstrate significant improvements in electrochemical performance, including enhanced specific capacitance, excellent cycling stability, and remarkable rate capability. These findings indicate that the modified carbon-based ternary composites hold promise for high-performance energy storage devices. Ultimately, this research contributes to the development of next-generation energy storage technologies, offering more efficient and sustainable solutions for storing energy. -
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Modified carbon substrates for electrocatalytic oxidation of selected heterocyclic carbinols
Electrochemically modified carbon electrodes are used as a substrate for electrocatalytic oxidation of different heterocyclic carbinols. Carbon fiber paper (CFP) is newlineused as the electrode substrate on which various modifications are employed. Modified newlineelectrodes were prepared by using different surface modification strategies such as newlineelectrodeposition of Pd nanoparticles or Pd-Pt bimetallic nanoparticles on a conducting newlinepolymer, polyaniline which is electropolymerized on to CFP. Biomass derived porous carbon nanoparticle coated CFP was also used for electrodeposition of Pd nanoparticles or MnO2-Pi nanoparticles. These modified electrodes were physicochemically characterized by X-ray diffraction (XRD), Field emission scanning electron microscopy (FESEM) with energy-dispersive X-ray spectroscopy (EDS), Transmission electron microscopy (TEM), Raman spectroscopy, Fourier transform infrared (FTIR) spectroscopy, Optical profilometry and X-ray photoelectron spectroscopy (XPS) and electrochemically characterized using Cyclic voltammetry (CV) and Electrochemical impedance spectroscopy (EIS). This modification methods have attracted a lot of attention due to their exceptional stability, high electronic conductivity, mechanical strength, and good adhesive property to the substrate and to the modified electrode. The modified electrodes show excellent electrochemical and newlinephysicochemical properties which are demonstrated using various analytical techniques. The organocatalytic reagent, TEMPO is used as a mediator throughout the studies which helps to carry out the oxidation of organic molecules in an aqueous acidic medium. The developed electrodes have been successfully applied for the oxidation of different heterocyclic alcohol such as 4-pyridinemethanol, 2-thiophene methanol, and 2-Furfuryl alcohol to corresponding 4-pyridinemethanal, 2-thiophene methanol and 2-Furfural. -
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Modified Carbon Based Electrodes for Electrochemical Sensing of Biomolecules
Now-a-days a large variety of biological analytes are detected by highly sensitive newlineelectrochemical sensors which are inexpensive and simple as compared to conventional methods such as UV-vis absorption spectroscopy, spectrofluorometry, HPLC and gas chromatography. Electrochemical analysis is exceptional owing to its economical, low energy consuming and unique approach in the method design, and high sensitivity for the analyte determination. Carbon based electrochemical sensors are commonly used because of their low cost, good electron newlinetransfer kinetics, good chemical stability, and biocompatibility. Recently electrochemical properties of pencil graphite electrodes (PGEs) have been explored in the analysis of various organic compounds. High electrochemical reactivity, easy modification, commercial accessibility, fine rigidity, disposability and low-cost of PGE make it ideal to be used as an effective working electrode. The thesis presented explains different modified PGEs have been employed in the electrocatalytic determination biomolecules such as cholesterol, cortisol, Vitamin B6 and morin. newlineThe modified electrodes are effectively used for the ultra-level sensing of these biomolecules in real samples. The electroactive surface area and the conduvtivity of bare PGE is enhanced newlinedifferent electrode modifiers such as and#946;-CD, graphene, conducting polymer, metal oxides and metal nanoparticles. The modified electrodes are found to exhibit good electrocatalytic behavior towards the target biomolecules. Cyclic voltammetric (CV) studies and electrochemical impedance spectroscopic (EIS) technique were used to investigate the electrochemical properties of the modified sensing platform. The newlinemorphology and step wise fabrication process of the modified electrodes were characterized byvii Ramana spectroscopy, X-ray photoelectron spectroscopy (XPS),scanning electron microscopy (SEM), Transmission electron microscopy (TEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). -
Modified carbon based electrodes for electrochemical sensing of biomolecules
Now-a-days a large variety of biological analytes are detected by highly sensitive newlineelectrochemical sensors which are inexpensive and simple as compared to conventional methods such as UV-vis absorption spectroscopy, spectrofluorometry, HPLC and gas chromatography. Electrochemical analysis is exceptional owing to its economical, low energy consuming and unique approach in the method design, and high sensitivity for the analyte determination. Carbon based electrochemical sensors are commonly used because of their low cost, good electron newlinetransfer kinetics, good chemical stability, and biocompatibility. Recently electrochemical properties of pencil graphite electrodes (PGEs) have been explored in the analysis of various organic compounds. High electrochemical reactivity, easy modification, commercial accessibility, fine rigidity, disposability and low-cost of PGE make it ideal to be used as an effective working electrode. The thesis presented explains different modified PGEs have been employed in the electrocatalytic determination biomolecules such as cholesterol, cortisol, Vitamin B6 and morin. newlineThe modified electrodes are effectively used for the ultra-level sensing of these biomolecules in real samples. The electroactive surface area and the conduvtivity of bare PGE is enhanced newlinedifferent electrode modifiers such as and#946;-CD, graphene, conducting polymer, metal oxides and metal nanoparticles. The modified electrodes are found to exhibit good electrocatalytic behavior towards the target biomolecules. Cyclic voltammetric (CV) studies and electrochemical impedance spectroscopic (EIS) technique were used to investigate the electrochemical properties of the modified sensing platform. The newlinemorphology and step wise fabrication process of the modified electrodes were characterized byvii Ramana spectroscopy, X-ray photoelectron spectroscopy (XPS),scanning electron microscopy (SEM), Transmission electron microscopy (TEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). -
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Modification of Carbon Based Electrodes as Robust Scaffolds for Electrochemical Sensing of Vitamins and Hormones
Electrochemical sensors are for vitamins and hormones are constructed on employing various newlinemodifications (molecular imprinting technology, coating of 2D sheet like materials and also modifying using supramolecular complexing material) on the transducer host, carbon fiber paper electrode (CFP). From our observation, the electrochemical oxidation/reduction current newlineof the analytes studied, intensified significantly on the surface modifications employed over the CFP substrate. Surface morphology was characterized using Field Emission Scanning Electron Microscopy (FESEM), Electron Diffraction X-ray (EDX), X-Ray Photoelectron spectroscopy (XPS), Optical Profilometry and Fourier Transform Infrared Spectroscopy (FTIR). Nyquist plots revealed the least charge transfer resistance at the finally modified working electrodes compared to other control electrodes. Optimization of experimental conditions such as effect of pH, investigating the reaction mechanism via effect of scan rate, number of cycles for the electrodeposition of the film in order to achieve maximum current response and potential window were studied in detail by using cyclic voltammetry (CV). Quantification of the analytes was performed using Differential Pulse Voltammetry (DPV). newlineAnalytical corroboration for real samples were carried out using the finally modified newlineelectrode. Therefore, all the works carried out have established simplicity and selectivity in the principle of the novel approach in the development of an ultrasensitive voltammetric sensor for vitamins and hormones studied. -
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Modernizing Electrical Grids with TCR-Based Flexible AC Transmission Systems
Modernizing electrical grids is imperative to meet the growing demand for reliable, efficient, and sustainable energy. Thyristor-Controlled Reactors (TCRs) are integral components of modern Flexible AC Transmission Systems (FACTS). These systems offer a robust solution for enhancing grid stability, improving power quality, and optimizing transmission efficiency, ensuring that electric grids can support future energy needs. TCR-based FACTS are a collection of technologies designed to enhance the controllability, stability, and power transfer capability of AC electrical grid systems. In this paper, we will discuss the role of TCRs in modernizing AC transmission systems and their role in addressing grid challenges and improving performance, highlighting their critical role in future grid infrastructure. To discuss the future prospects and developments in TCR technology, with ongoing advancements and research efforts paving the way for more efficient, reliable, and flexible grid management solutions. The Authors, published by EDP Sciences, 2024. -
Modernized energy management system: A review
The usage of renewable energy system (RES) and its management is vital for reliable electrical energy delivery without pollution. In the scenario of increase in distributed generations (DGs), to utilize the generated electricity from RES without any wastage, to avoid the consumption of electricity during peak hours, to store and retrieve energy in an efficient way from the battery, there is a need for overall energy management system (EMS). As the prices for electricity and pollution are reduced, the review of available methodologies is discussed in this paper. The EMS takes decision based on the predicted load demand. So, the different prediction methodologies and their benefits are also discussed here. Though the electric vehicles (EVs) are considered as load in power system, the storage facility of the EVs are also used as power backup facilities through vehicle to grid (V2G) technology. This paper provides a review on the complete management of RES, EVs, batteries and load. Published under licence by IOP Publishing Ltd. -
Modernization of Rural Electric Infrastructure
In the recent digital era, the energy sector in India is truly challenging. But some way or another digital technology has the potential to change the scenario of energy supply in industry. One of the important developments in this decade is the application of Artificial Intelligence (AI). This technology will help us to control smart software and optimize our decision-making and operations. We cannot ignore the need of energy to become sustainable after the introduction of the Internet of Things (IoT). Smart grid technology in IoT is used to detect even minute changes in electricity supply and demand. These two technologies (AI and IOT) jointly provide us a magical tool to improve operational performance in the energy industry. In rural areas, there is a lack of electricity infrastructure supply and demand technologies. A large portion electricity supply is shifting from manufacturing industry to rural areas. They are using grid technology to transform electricity and the load is highly variable. From the demand side, lack of infrastructure and industrial equipment affect consumer devices. An increasing need for electricity in all aspects presents a significant challenge to utilization and cost efficiency. An important issue for the delivery of electricity to rural areas is the infrastructure and administrative policies and regulations. Power plants need to be constructed in rural areas to supply the electricity. This is the modernization of a rural electricity infrastructure. In modernization techniques, smart grid technology can be used to meet low carbon emission and cost-efficiency. It will be interconnected with the traditional grid architecture of electricity energy. Based on recent research, the smart grid should be robust and agile and it might dynamically optimize the grid operations, energy-efficient resources, and so on. Without affecting the nature of village environments, an alternate technology, such as the consumption of solar energy, can also be mutually considered in order to utilize renewable energy. In this chapter we focus on the comparison of traditional and modern technology used for the supply and demand of electricity in rural areas, issues on the implementation of modern technologies, research and development in modernization of electric power systems, and so on. The Author(s), under exclusive license to Springer Nature Switzerland AG 2023. -
Modern Technology Usage for Education Field during COVID-19: Statistical Analysis
The COVID-19 pandemic has had vast effects on the concept of education as a whole. During the pandemic, students had no access to physical teaching practices, which had been adapted worldwide as the principal way of education since the 1800's. Due to the restrictions imposed to garner safety from the spread of the virus, this methodology had to be modified based on the situation at hand. Alternatives through the usage of Virtual Learning Platforms (VLP), Online Tutoring Platforms (OTP), Web Conferencing Platforms (WCP) and multiple assessment tools like plagiarism checker, poll sites, quiz platforms, online proctored examinations (OPE) started gaining popularity among all institutes to cope with the limitations levied. The technologies molded a path for student-teacher interaction, performance assessments, document sharing and online tutoring. This research highlights the lack of online tutoring equipment, educators' limited expertise with online learning, the knowledge gap, a inimical atmosphere for independent study, equity, and academic success in postsecondary learning. The goal of this review is to present an overview of available technologies for online teaching that can be used to improve the quality of education during COVID-19. 2022 IEEE. -
Moderation of Income and Age on Customer Purchase Intention of Green Cosmetics in Bangalore
Cracking the code of customer purchase behaviour is a challenge for market researchers as myriad factors interfere. Marketers are puzzled as competitors position a new product category in the market to create demand. Indian public perceived cosmetics composition as blend of healthy chemical extracts. Television commercials portrayed the presence of chemicals in cosmetics as a product performance booster. People attributed chemical presence to superior product performance. Saturated markets witnessed competitors aiming at increased sales with similar commercials. Under pressure to differentiate, the idea of organic cosmetics started. Companies invested heavily on product development, marketing and branding. Expected success was not achieved as buyers measured performance of cosmetics weighing the absence of chemicals. Scepticism on organic level of the products emerged as various brand commercials claimed their respective compositions a true organic product. Fewer studies explained purchase intention of green cosmetics without focus on health consciousness and consumer innovativeness. Product diffusions were strategized on the basis of consumer innovativeness. Health consciousness captured individuals weightage on health and well-being while purchasing a product. This paper explores relationship of health consciousness and consumer innovativeness with purchase intention development conducting exploratory factor analysis, regression analysis and interaction analysis on selected independent variables using dependent variables. The study found both consumer innovativeness and health consciousness leading to development of purchase intention of green cosmetics. Age and income moderated the relationship of consumer innovativeness and purchase intention. 2022, The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. -
Moderation effect of flexibility in projects on senior management commitment in achieving success in financial services IT projects
Senior management commitment and flexibility improve project responsiveness to volatile and high-impact scenarios, especially in large projects and programs. The aim of this study is to determine how project flexibility interacts with and affects the relationship between senior management commitment and success in IT projects. A cross-sectional survey of 166 managers was used to derive empirical data from the financial services industry and used to test the conceptual framework based on recent project management literature. Ordinal regression analysis demonstrated a significant relationship between senior management commitment and success in projects which is influenced by significantly positive moderations established through flexibility in projects. The study findings can assist project managers and senior leaders to accomplish their short-term and long-term project goals and achieve success in projects by reducing the chances of failures. This paper adds value to existing research in the context of IT projects and the role of project flexibility on their performance. Copyright 2023 Inderscience Enterprises Ltd. -
Moderating Role of Project Innovativeness on Project Flexibility, Project Risk, Project Performance, and Business Success in Financial Services
Project risk management is crucial for project success and for achieving short-term and long-term project goals. This study examines the linkage between the management of project risks and project flexibility for information technology projects in Financial Services. A conceptual framework establishing the link between project risks, project flexibility, project performance, and business success, with project innovativeness as a moderating variable, has been introduced. To test the model, data were collated from over 400 managers working in Financial Services projects. The empirical outcomes through a Ordinal regression analysis demonstrate a substantial association between the management of project risks, project flexibility, and success of projects. Project innovativeness moderates the effects of project risks and project flexibility on project performance. Furthermore, managing project risks is vital to reduce the likelihood of failures in projects. This paper enriches existing research by applying a contingency perspective to project risk management and provides practical guidance for managing risks in projects professionally and also the relevancy of project flexibility. 2021, Global Institute of Flexible Systems Management. -
Moderating role of location autonomy on technostress and subjective wellbeing in information technology companies
Integrating digital tools into day-to-day work activities has become an undeniable reality. However, the unprecedented reliance on technology has brought with it the escalating degrees of technostress evident through health concerns like chronic musculoskeletal problems and decreased job satisfaction. And the COVID-19 pandemic accelerated the negative impact, as IT industries adopted the hybrid workplace approach, especially in developing countries like India. This paper aims to find whether location autonomy moderates the effect of technostress on subjective wellbeing among IT employees working in a hybrid model. A purposive sampling method gathered 440 responses from IT professionals in Bengaluru tech parks. IBM SPSS and AMOS software were used to assess the constructs by SEM analysis, in line with the job demand-control theory. The results showed that location autonomy accounts for 31.6% of the variance in subjective wellbeing, while technostress explains 33.2% of the variance, with dimensions ranging from 21% to 46%. Additionally, location autonomy moderates and strengthens the link between technostress and subjective wellbeing. The study recommends that organizational leaders adopt HR policies that allow employees to choose their workplace rather than mandating a specific location for scheduled days in the week. This approach can potentially improve overall employee wellbeing, offering a favorable resolution to the challenges posed by technostress in the IT industry. Pallavi Datta, Sathiyaseelan Balasundaram, Sridevi Nair, Rekha Aranha, 2024. -
Moderating role of firm characteristics on the relationship between corporate social responsibility and financial performance: evidence from India
Purpose: The effect of corporate social responsibility (CSR) on corporate financial performance (CFP) is shown to depend on both firm-specific and external factors. This study investigates the moderating role of two firm-specific factors the firm life-cycle stage and ownership structure on the CSRCFP relationship in a developing economy setting India. Design/methodology/approach: The study covers 1,419 listed companies in India during 201521. The firm lifecycle is represented using firm age and future growth prospects. Ownership is represented through a dummy variable and promoters holding percentages. Return on assets (RoA) is used as a measure of CFP, while CSR intensity, i.e. the ratio of CSR expenditure to profit after tax (PAT), is used to represent CSR. Fixed effect panel regression and generalized method of moments (GMM) models are used for data analysis. Findings: CSR expenditure has a significant negative impact on CFP. Firm age and future growth prospects amplify this negative impact, indicating that the firm life-cycle has a significant negative moderating effect on the CSRCFP relationship. Furthermore, the impact of CSR on CFP is worse for government companies than private ownership. Promoters holdings have a positive impact on the CSRCFP relationship. Research limitations/implications: The results question the validity of mandatory CSR expenditure on companies operating in developing countries and call for a differentiated policy approach to CSR expectations based on firm characteristics. This study also enhances the existing literature on CSRCFP. Originality/value: The growing research on CSRCFP has limited coverage of firm characteristics as contributing factors. Hence, this paper helps in enhancing the existing literature on CSRCFP and makes it more relevant to firms with specific characteristics. 2024, Nisha Prakash and Aparna Hawaldar. -
Moderating influence of critical psychological states on work engagement and personal outcomes in the telecom sector /
Sage Journals, Vol.4, Issue 2, pp.584-592. -
Moderating influence of critical psychological states on work engagement and personal outcomes in the telecom sector
Organizations want their employees to be engaged with their work, exhibiting proactive behavior, initiative, and responsibility for personal development. Existing literature has a dearth of studies that evaluate all the three key variables that lead to optimal employee performancecritical psychological states (CPSs), work engagement, and personal outcomes. The present study attempts to fill that gap by linking the variable CPSs (which measures experienced meaningfulness, responsibility, and knowledge of results) with the other two. The study surveyed 359 sales personnel in the Indian telecom industry and adopted standardized, valid, and reliable instruments to measure their work engagement, CPSs, and personal outcomes. Analysis was done using structural equation modeling (SEM). Findings indicated that CPSs significantly moderate the relationship between personal outcomes and work engagement. The Author(s) 2014.