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DFT, spectroscopic studies, NBO, NLO and Fukui functional analysis of 1-(1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)ethylidene) thiosemicarbazide
A novel triazole derivative 1-(1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)ethylidene) thiosemicarbazide was synthesized and subjected to density functional theory (DFT) studies employing B3LYP/6-31+G(d,p) basis set. Characterization was done by FT-IR, Raman, mass, 1H NMR and 13C NMR spectroscopic analyses. The stability of the molecule was evaluated from NBO studies. Delocalization of electron charge density and hyper-conjugative interactions were accountable for the stability of the molecule. The dipole moment (?), mean polarizabilty (??) and first order hyperpolarizability (?) of the molecule were calculated. Molecular electrostatic potential studies, HOMO-LUMO and thermodynamic properties were also determined. HOMO and LUMO energies were experimentally determined by Cyclic Voltammetry. 2018 Elsevier B.V. -
Provably secure quantum key distribution By applying quantum gate
The need for Quantum Key Distribution (QKD) is strengthening due to its inalienable principles of quantum mechanics. QKD commences when sender transforms bits into qubits or quantum states by applying photon polarization and sends to the receiver. The qubits are altered when measured in incorrect polarization and cannot be reproduced according to quantum mechanics principles. BB84 protocol is the primary QKD protocol announced in 1984. This paper introduces a new regime of secure QKD using Hadamard quantum gate named as PVK16 QKD protocol. Applying quantum gate to QKD makes tangle to the eavesdroppers to measure the qubits. For a given length of key, it is shown that the error rate is negligible. Also, the authentication procedure using digital certificates prior to QKD is being performed which confers assurance that the communicating entities are legitimate users. It is used as a defensive mechanism on man in the middle attack. The Japan Society for Analytical Chemistry. -
Significance of buoyancy, velocity index and thickness of an upper horizontal surface of a paraboloid of revolution: The case of non-Newtonian carreau fluid
The problem of fluid flow on air-jet weaving machine (i.e. mechanical engineering and chemical engineering) is deliberated upon in this report using the case of non-Newtonian Carreau fluid flow. In this report, the boundary layer flow of the fluid over an upper horizontal surface of a paraboloid of revolution is presented. The dimensional governing equations were nondimensionalized, parameterized, solved numerically and discussed. Maximum horizontal velocity is ascertained at smaller values of thickness parameter, a larger value of buoyancy related parameter and the flow is characterized as shear-thickening. Local skin friction coefficient is an increasing and a decreasing property of Deborah number for Shear thinning and Shear-thickening cases of the flow respectively. The velocity of the flow parallel to the surface (uhspr) is a decreasing property of thickness parameter and increasing function of velocity index parameter. 2018 Trans Tech Publications, Switzerland. -
UVIT observations of the star-forming ring in NGC 7252: Evidence of possible AGN feedback suppressing central star formation
Context. Some post-merger galaxies are known to undergo a starburst phase that quickly depletes the gas reservoir and turns it into a red-sequence galaxy, though the details are still unclear. Aims. Here we explore the pattern of recent star formation in the central region of the post-merger galaxy NGC 7252 using high-resolution ultraviolet (UV) images from the UVIT on ASTROSAT. Methods. The UVIT images with 1.2 and 1.4 arcsec resolution in the FUV and NUV are used to construct a FUV-NUV colour map of the central region. Results. The FUV-NUV pixel colour map for this canonical post-merger galaxy reveals a blue circumnuclear ring of diameter ?10?? (3.2 kpc) with bluer patches located over the ring. Based on a comparison to single stellar population models, we show that the ring is comprised of stellar populations with ages ? 300 Myr, with embedded star-forming clumps of younger age (? 150Myr). Conclusions. The suppressed star formation in the central region, along with the recent finding of a large amount of ionised gas, leads us to speculate that this ring may be connected to past feedback from a central super-massive black hole that has ionised the hydrogen gas in the central ?4?? ?1.3 kpc. ESO 2018. -
A hybrid algorithm for face recognition using PCA, LDA and ANN
Face recognition is an evolving technique in the field of digital device security. The two procedures Principal Component Analysis and Linear Discriminant Analysis (LDA) are standard methodologies commonly used for feature extraction and dimension reduction techniques extensively used in the recognition of face system. This paper discourse, PCA trailed through a feed forward neural network (FFNN) called PCA-neural network and LDA trailed through feed forward neural network as LDA-neural network are considered for development of hybrid face recognition algorithm. In the current research work, a hybrid model of face recognition is presented with the integration of PCA, LDA, and FFNN. The proposed system experimental results indicate better performance compared to the state of the art literature methods. IAEME Publication. -
Smart songs selection in playlists using parallel k-means clustering
Most songs today are of different tempo, pitch and time signature. In a music player application, the typical shuffle picks the succeeding song or preceding song at random with no parameters to choose the songs. Different songs from different genres can have a tempo range anywhere between forty beats per minute and three hundred beats per minute. In this paper, the quick and efficient parallel k means clustering algorithm is implemented in Hadoop on the million-song dataset subset to form clusters for the songs based on tempo and pitch. The aim of this paper is to reduce the variation that occurs when a typical shuffle picks the succeeding song at random. This variation can be in the form of tempo or other parameters. The formation of clusters and intern the reduction in the variation of tempo can be used in a new 'smart shuffle'. After the clusters have been formed, the smart shuffle picks the songs within that specific cluster. This paper aims at reducing the variation by 50%. This would have many musical benefits and would also be more pleasing to the listener. 2018 IAEME Publication. -
Potential flow simulation through Lagrangian interpolation meshless method coding
From the past many decades, mesh generation posed many challenges in the field of computational sciences for many researches. High rise in computational power has enabled many researches to tackle the problems of complex geometries. Due to the high need of computational power, computational cost also increased abruptly. In today's world, many academic and industry researches are willing to increase the use of present simulation technology; mesh generation plays a vital role in this aspect. we can say that many real-world simulation problems are dependent on mesh generation which has more chances in giving an inaccurate simulation results. In order to make the simulation process simpler, Meshless methods are introduced to the field of Computational Fluid Dynamics. This technique requires a less computational power compared to the computational power needed for generating the mesh. In the present dissertation, our main objective is to develop a scheme for Meshless method for the field of Computational Fluid Dynamics for flow over a blunt body. The performance of the present scheme is evaluated by comparing the simulation results with existing experimental data and also compared with the results obtained by generation of mesh using commercial CFD software. 2018 Isfahan University of Technology. -
Microscale screen printing of large-area arrays of microparticles for the fabrication of photonic structures and for optical sorting
There are a limited number of methods applicable to the large-scale fabrication of arrays of discrete microparticles; however, such methods can be applied to the fabrication of structures applicable to photonics, barcoding, and optoelectronics. This manuscript describes a universal method, "microparticle screen printing" (?SP), for the rational patterning of micron-scale particles onto a variety of 2D substrates with diverse mechanical and chemical properties. Specifically, an array of microparticles of different sizes and compositions were patterned onto an array of materials of varying chemistry and stiffness using ?SP yielding a diversity of homo/heterogeneous microparticle-based structures. Further, this manuscript reports how the Young's moduli of the substrate can be used to calculate contact area and thus interaction energies (quantified using Hamaker constants) between the particle/substrate during ?SP. Generally, ?SP is most effective for substrates with low Young's moduli and large Hamaker constants (A132) with the target particles, as confirmed by the performance (quantified using yield and accuracy metrics) of ?SP for the different empirically investigated particle/substrate combinations. These understandings allow for the design of optimal surface/particle pairing for ?SP and were applied to the fabrication of a diversity of heterogeneous structures, including those with periodic vacancies in HCP (hexagonally closed packed) 2D photonic crystal useful to structural optics, optical particle screening useful to chemical assays, and the fabrication of structural barcodes useful for labeling and anticounterfeiting. 2018 The Royal Society of Chemistry. -
Implementation of digital signature using hybrid cryptosystem
Security is a major concern when it comes to electronic data transfer. Digital signature uses hash function and asymmetric algorithms to uniquely identify the sender of the data and it also ensures integrity of the data transferred. Hybrid encryption uses both symmetric and asymmetric cryptography to enhance the security of the data. Digital Signature is used to identify the owner of the document but it does not hide the information while transferring the document. Anyone can read the message. To avoid this, data sent along with the signature should be secured. In this paper, Digital signature is combined with hybrid encryption to enhance the security level. Security of the data or the document sent is achieved by using hybrid encryption technique along with digital signature. 2018 Authors. -
Dual solutions for unsteady stagnation-point flow of prandtl nanofluid past a stretching/shrinking plate
Dual solutions for the time-dependent flow of a Prandtl fluid containing nanoparticles along a stretching/shrinking surface are presented. The nano Prandtl fluid fills the porous stretching/shrinking surface. The Buongiorno model is employed by accounting Brownian motion and thermophoresis slip mechanisms in the analysis. The relevant nonlinear problem is treated numerically via Runge-Kutta-Fehlberg scheme. The flow profiles are scrutinized with respect to the different governing parameters. Results of this study indicate that the temperature boundary layer thickness increased due to the influence of nanoparticles. 2018 Trans Tech Publications, Switzerland. -
Framework to analyze customer's feedback in smartphone industry using opinion mining
In the present age, cellular phones are the largest selling products in the world. Big Data Analytics is a method used for examining large and varied data, which we know as big data. Big data analytics is very useful for understanding the world of cellphone business. It is important to understand the requirements, demands, and opinions of the customer. Opinion Mining is getting more important than ever before, for performing analysis and forecasting customer behavior and preferences. This study proposes a framework about the key features of cellphones based on which, customers buy them and rate them accordingly. This research work also provides balanced and well researched reasons as to why few companies enjoy dominance in the market, while others do not make as much of an impact. 2018 Institute of Advanced Engineering and Science. All rights reserved. -
Medical aptitude and its assessment
The assessment of the suitability of an individual for the profession of medical science is carried out worldwide on the basis of several yardsticks. While a few methods assess domain knowledge of sciences, others focus on evaluating the cognitive aptitude skills of the candidate, while few others assess communicative skills. Though it has been considered that the possession of an aptitude for the profession is a prerequisite, considering its strenuous demands from the candidate, a comprehensive assessment of these areas under the construct of medical aptitude has not been analysed so far, though medical aptitude has been socially defined. This article attempts to develop a comprehensive construct to Medical aptitude, meant for the pre-medical student, which has been encapsulated with respect to the areas of its assessment. We did an extensive survey of the literature pertaining to the mode of selection of students towards medical profession and analysed their areas of assessments for admittance. This enabled to identify similarities in the areas of assessment which were then classified under several domains of assessment. Special reference to the keywords involving Aptitude and Medical Aptitude was made. We analysed the definitions to the construct of aptitude from the literature with respect to its relevance in the profession of medical science to be possessed by the premedical aspirantin context. From this, a new construct of medical aptitude was formulated incorporating the existing construct of medical aptitude. Medical aptitude is a comprehensive construct that encompasses the dimensions of a consistent core, a peripheral content and the support of a scaffold. Each of these dimensions have their importance and distinct objective in being assessed in the pre-medical student. A perfect intertwining of these 3 dimensions can prove beneficial in assessing individuals to be fit for the profession of medical science. The National Medical Journal of India 2018. -
In-plant production of bricks containing waste foundry sandA study with Belgaum foundry industry
The main objective of this study is to utilize waste foundry sand (WFS) from Belgaum foundry industry in manufacturing of bricks. The process involved production of bricks in a fully functioning brick manufacturing plant, which has a production capacity of approximately 50000 bricks per month. The entire process of combining clay-sand mixtures, forming of bricks, drying and firing was done with local conditions. With minimum process it was possible to introduce upto 50% WFS in clay bodies to produce bricks of desirable properties. The minimum average wet compression resistance of 3.3 Mpa, and maximum average water absorption of 21.6% was obtained for bricks containing 50% WFS, when fired at 900 C. There was insignificant difference in apparent porosity, water absorption, and specific gravity of bricks containing WFS, when compared to commercial bricks. The addition of WFS reduced the bulk density of the bricks, which has also caused reduction in compressive strength. WFS bricks can be classified as class III bricks, based on recommendations of IS 1077 standard specification. These bricks can be used in single storied load bearing structures, and also in the construction of infill walls in multi-storied framed structures. The structure, composition, and morphology of the raw materials, as well as bricks were studied by XRD, XPS, and SEM, respectively. 2018 The Authors -
Rayleigh-benard convection in a dusty newtonian nanofluid with and without coriolis force
Theoretical investigation of the Rayleigh-Bard convection (TRBC) in nanofluid (NF) submerged with dust particles is carried out. Convection in dusty nanofluid is considered between two horizontal free boundaries. Effect of nanoparticles shape is also accounted. The Saffmans dusty fluid model is used to simulate the influence of dust particles, whereas the KVL (Khanafer-Vafai-Lightstone) model is employed to estimate the effective nanofluid properties. The fluid, dust particles and nanoparticles are in the thermal equilibrium state and move with the same velocity. The exact solutions are obtained using Normal Mode Analysis (NMA) method for two different cases namely (1) TRBC in dusty nanofluid (DNF) without Coriolis force (2) TRBC in DNF with Coriolis force. It is established that for the stationary convection, the effect of suspended particles hasten the onset of convection whereas the Coriolis force postpones the onset of convection. 2018 by American Scientific Publishers All rights reserved. -
Exploration of non-linear thermal radiation and suspended nanoparticles effects on mixed convection boundary layer flow of nanoliquids on a melting vertical surface
In this paper, the significance of increasing nonlinear thermal radiation on boundary layer flow of some nanofluids is deliberated upon. The effects of magnetic field, melting and viscous dissipation are also considered. The numerical results are obtained for governing flow equations and compared with the previously published results for a special case and found to be in excellent agreement. The effects of various physical parameters such as melting parameter, thermal radiation parameter, temperature ratio parameter and Eckert number on velocity and temperature profiles are analyzed through several plots. The numerical results of physical quantities of engineering interest such as skin friction coefficient and local Nusselt number are presented and discussed in detail. It is found that the nonlinear thermal radiation effect is favourable for heating processes than linear thermal radiation effect. Additionally, the moving parameter and melting parameter can be used to reduce the friction or drag forces. 2018 by American Scientific Publishers All rights reserved. -
Study on testing the stationarity and co-integration among the sectoral indices of national stock exchange of India
The Stock Market is a market for the trading of company stocks. It is an organized market place where members of the organization gather to trade company stocks and other securities. An index is important to measure the performance of investments against a relevant market index. Sectoral indices serve as a benchmark for measuring the performance of the stocks or portfolios. This study explores stationarity and co-integration relationship among stock market returns and the eight important NSE sectoral indices for the period of January 2013 to December 2017. Sectoral Index series indicates the existence of co integration among the sectoral indices of NSE. Co integration exists in long run equilibrium and in short run they diverge from each other or they have disequilibrium. This study is useful to find out the determinant factors of the National Stock Exchange and led lag relationship among the Sectoral Indices in National Stock Exchange. IAEME Publication. -
Marangoni convection in Casson liquid flow due to an infinite disk with exponential space dependent heat source and cross-diffusion effects
Present work aims to investigate the features of the exponential space dependent heat source (ESHS) and cross-diffusion effects in Marangoni convective heat mass transfer flow due to an infinite disk. Flow analysis is comprised with magnetohydrodynamics (MHD). The effects of Joule heating, viscous dissipation and solar radiation are also utilized. The thermal and solute field on the disk surface varies in a quadratic manner. The ordinary differential equations have been obtained by utilizing Von Km transformations. The resulting problem under consideration is solved numerically via Runge-Kutta-Fehlberg based shooting scheme. The effects of involved pertinent flow parameters are explored by graphical illustrations. Results point out that the ESHS effect dominates thermal dependent heat source effect on thermal boundary layer growth. The concentration and temperature distributions and their associated layer thicknesses are enhanced by Marangoni effect. 2018 -
Revisiting Television in India: Mapping the Portrayal of Women in Soap Operas
This article attempts to map the portrayal of women in popular soap operas on television in India. It begins with the discourses around portrayal of women on Doordarshan in the pre-liberalisation era and goes on to analyse a few soap operas in the past one decade. With substantive review of visual texts, it aims to disprove the claim that there is a paradigm shift especially with respect to the portrayal of women in the contemporary and so-called progressive soap operas. It concludes by comparing all the phases of development of television in India with respect to construction of women and stating how very little and inconsequential change has occurred in this regard in spite of all the efforts from the state and the intellectual community. 2018 Indian Sociological Society. -
History of gestational diabetes mellitus, self-efficacy and coping in postpartum women: A pilot study
The present study investigates whether the history of gestational diabetes mellitus (GDM) influences self-efficacy and coping among postpartum women. Purposive sampling technique was used to collect data from 100 postpartum women, 50 with a history of GDM and 50 without. The General Perceived Self-Efficacy Scale was used to measure the self-efficacy of the participants. The Brief COPE developed by Carver was used to measure coping. A Mann-Whitney U-test showed postpartum women with a history of GDM are higher in self-efficacy and coping than those without such a history. Even though self-efficacy showed a relationship to coping, the two groups differed in the use of coping strategies. 2018 by the Research Institute of Asian Women, Sookmyung Women's University. All rights reserved. -
The relationship of workplace flexibility to employee engagement among information technology employees in India
Historically, organizations have been provisioning flexible work arrangement (FWA) options in the workplace to help employees achieve a balance between work obligations and private obligations. We explore the utilization of FWA offerings in the Indian information technology (IT) industry and its relation to employee engagement (EE). Employees working in IT organizations in Bengaluru, India, were approached and data were obtained from 504 participants. The study found that availability of FWA options coincided with their utilization. Disconcertingly, only 7 per cent of the employees were highly engaged, 51 per cent were neither engaged nor disengaged and 41 per cent of the employees were disengaged with their current organization. FWAs were positively related to EE. We find congruence that FWA options lead to better EE warranting further exploration that can guide FWA policies. 2018 SAGE Publications India Private Limited.