Browse Items (11810 total)
Sort by:
-
Electrocatalytic oxidation of morin on electrodeposited Ir-PEDOT nanograins
Nanoclusters of Ir were electrochemically deposited on carbon fiber paper (CFP) substrate modified with poly(3,4-ethylenedioxythiophene) (PEDOT), a conducting polymer between the potential range 0.0 V and 0.6 V at 0.05 V/s scan rate. The electrocatalytic activity of IrPEDOT/CFP electrode towards oxidation of morin, a flavonoid was significantly greater than that of PEDOT/CFP and bare CFP electrodes. Factors affecting the anodic peak of morin namely, effect of pH, scan rate and number of cycles were optimized. The electrochemical route involved adsorption controlled and irreversible processes. Under optimal conditions, the linear dynamic range for the determination of morin was found to be 0.12 nM2.80 nM. The significantly low detection limit (42.18 pM) demonstrates the ultrasensitivity of the proposed method. The reliability of the method was evaluated for the quantification of morin present in mulberry leaves, guava leaves and grape wine. 2018 Elsevier Ltd -
Amorphous Ru-Pi nanoclusters coated on polypyrrole modified carbon fiber paper for non-enzymatic electrochemical determination of cholesterol
A facile electrochemical sensor based on Ruthenium-Phosphate (Ru-Pi) was developed by electrodeposition of Ru-Pi on Polypyrrole (PPy) modified carbon fiber paper (CFP) electrode. Phosphate buffer solutions of neutral pH containing RuCl3 was used for voltammetric deposition of Ru-Pi on PPy/CFP electrode. The modified electrodes were characterized by High resolution transmission electron microscopy (HRTEM), High-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM), Field emission scanning electron microscopy (FESEM) with energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and electroanalytical techniques. A significant amount of phosphate (Pi) and Ru centers in higher oxidation states were present on Ru-Pi film deposited on PPy/CFP substrate. Pi plays a significant role during catalyst deposition and in its activity toward determination of Cholesterol. DPV studies demonstrated that under optimum conditions, the developed sensor has displayed a wide linear dynamic range between 0.16 nM and 20.0 nM with a superior detection limit of 0.54 10-10 M. The proposed method was effectively applied in the nonenzymatic determination of cholesterol at an ultralow level in human blood serum samples. The method displayed high selectivity toward cholesterol in the presence of other interfering substances. 2019 The Electrochemical Society. -
Implementation of hybrid machine learning approach for intrusion detection system
The Intrusion Detection System (IDS) enforces information security and is responsible to identify attacks and vulnerabilities inside a network. It does this by analyzing the packet stream throughout the network. In traditional IDS systems, the analysis is done by looking for signatures of known attacks or deviations of normal activity as described by the rules provided for the IDS system. Machine learning helps in deriving predictive knowledge and this makes it ideal to apply Machine learning in an IDS system to detect attacks. This paper focuses on creating a hybrid model that is best to implement in an IDS system. A hybrid model is implemented which combine multiple machine learning algorithms using Ensemble method. The experiments include evaluating machine learning algorithms such as Decision Tree, MLP (Multi-Layer Perceptron), Gradient Boosting etc. The algorithms with the best results are taken to construct Hybrid model. This Hybrid approach will improve the accuracy and efficiency for identifying the attacks by the IDS system. Depending on the type of attack, the IDS system can classify packets as DoS (Denial of Service), Probe, R2L (Root to Local), U2R (User to Root) or Normal. The experiments are carried using NSL-KDD Dataset. 2019, Institute of Advanced Scientific Research, Inc.. All rights reserved. -
Effectiveness of information and communication technologies on the learning outcomes of management graduates in public and private sector institutes
In most of the countries, information and communication technology (ICT) has a made a strong impact on the development of educational sector and it is considered to be the strongest pedagogy in delivering the communication effectively. This is the era of Information and Communication and to increase the efficiency and effectiveness of Education sector the role of ICT is indispensable. The performance of the students can be made better with the help of information and communication technology (ICT). ICT will help the students to gather the information very effectively and help in in developing their knowledge skills as well as to improve their learning skills. To understand the effectiveness and also the impact of ICT in Education sector especially in management education, for the current study the data is been collected from 158 respondents who are MBA graduates from 15 B-schools from Bangalore city, the study is being conducted with the help of convenient sampling from various B-schools from Bangalore city. The study has shown that the learning and teaching through ICT improves the knowledge and learning skills of students. This indicates that existence of ICT is improving the educational efficiency among the management graduates in Bangalore city. 2019, Institute of Advanced Scientific Research, Inc. All rights reserved. -
Predictors of emotional and behavioral problems among Indian adolescents: A clinic-based study
Background: Emotional and behavioral problems place a heavy burden on the adolescents and their families. Many factors are known to influence adolescent mental health. The current study was designed to determine the predictors of emotional and behavioral problems among Indian adolescents. Methods: The parents of adolescents in the age group of 10 to 18 (N = 81) were recruited from the National Institute of Mental Health and Neuro Sciences, Bangalore, Karnataka, India. Alabama Parenting Questionnaire (Parent version), Strength and Difficulty Questionnaire (Parent version) and, the Parent Interview Schedule (PIS) were used to assess the parental practices, emotional and behavioral problems and abnormal psychosocial environment of the adolescents. The data were analyzed with stepwise multiple linear and Quantile regression to find out significant predictors of emotional and behavioral problems among adolescents. Results: Adolescent's age, parental involvement, and paternal age are the significant predictors of emotional problems. Parental mental disorder or deviance, gender, and inconsistent discipline are the significant predictors for conduct problems. Poor monitoring and supervision, paternal and maternal age are statistically significant predictors of prosocial skills among the adolescents. Inadequate or distorted intrafamilial communication and parental mental disorder are the significant predictors of total difficulties among the adolescents. Conclusion: The study validates the role of abnormal psychosocial environments and negative parenting practices as risk factors for emotional and behavioral problems among the adolescents. A comprehensive analysis which covers all possible variables related to adolescent mental health is mandatory for the health professionals before planning the intervention. 2018 Elsevier B.V. -
Determination of stress on turbine generator shaft due to subsynchronous resonance using finite element method
Power Capacitors plays a vital role in reactive power compensation. When the capacitors are connected to the transmission line, it improves the reactive power. Although the reactive power is improved, there is a possibility for sub synchronous resonance created by this capacitors in the transmission line which can impact the generator frequency. The sub synchronous resonance causes electro-mechanical stress in the generator shaft which ultimately leads to malfunction of the entire power generating unit. It is necessary to find out operating modes of the generator and turbine when the line is compensated with capacitors. Once the operating modes are clear, it is possible to damp the sub synchronous resonance. In this paper, three phase generator is coupled with a prime mover and capacitors are connected before the load. The stress on the turbine is analysed based on the torque of two rotating machines. Finite element method is used to estimate the stress in the turbine generator shaft system. 2006-2019 Asian Research Publishing Network (ARPN). -
Exact solution of non-coaxial rotating and non-linear convective flow of cual2 o3 h2 o hybrid nanofluids over an infinite vertical plate subjected to heat source and radiative heat
This paper investigates the non-linear convective flow due to non-coaxial rotation of vertical planar plate by utilizing three different liquids namely H2 O (water), Al2 O3 H2 O (nanofluid) and CuAl2 O3 H2 O (hybrid nanofluid). The impacts of Rosselands radiative heat and internal heat generation are also included in this study. The non-coaxial rotation of the plate crafts sine or cosine oscillations in its plane and the liquid at infinity. The density-temperature relation is studied which is nonlinear and causes a nonlinear convective heat transfer. The dynamic viscosity, thermal conductivity, density and specific heat of hybrid-nanofluids are assumed to vary with the volume fraction. These thermophysical properties of hybrid and nanofluids are determined by phenomenological laws and mixture theory. The simulation of the flow was carried out using the appropriate values of the empirical shape factor for five different particle shapes (i.e., sphere, hexahedron, tetrahedron, column and lamina). The LTM (Laplace Transform Technique) is employed to find the exact solutions. The flow, skin friction and thermal features are scrutinized with the discrepancy of governing parameters. The effective fluid properties and the Nusselt number are also calculated for sixteen different hybrid-nano-liquids. 2019 by American Scientific Publishers All rights reserved. -
Determinants of employee eco-initiatives in Indian hotel industry
Results of a questionnaire survey completed by 402 respondents who were all employees of hotels that have adopted eco-friendly practices showed that eco-initiatives are significantly and positively correlated to conservatism, commitment to the cause of the environment, and monetary rewards and recognition; significantly and negatively correlated to self-transcendence and environmental training; and bear no significant relationship with environmental communication and self-enhancement. Future research should consider the role of guests in promoting employee eco-initiatives. Copyright 2019 Inderscience Enterprises Ltd. -
The quantum key distribution, attenuation and data loss over foggy, misty and humid environment
The quantum encryption is a method of key transfer in cryptography by using quantum entanglement of photons. The real power of quantum entanglement is instantaneous communication that is non interceptable. The advantage of quantum encryption method is, it can be incorporated with conventional encryption methods safely. The quantum cryptography can replace conventional key exchange mechanism with the polarized photons using channels like optic fiber cables. Quantum cryptographic can also provide far and secure data communication. The present day experiments clearly proved that the quantum cryptography can be implemented through medium like optic fiber cable or air. But the distance of transmission through the air is limited by rule of line of sight propagation. The quantum key distribution will have uses in different types of communication between distant parts of earth. So this paper discussing various aspects of Quantum key distribution and successfully calculated polarized photon loss during transmission of Quantum cryptography link, while using in various type of atmospheric conditions like Mist Fog Haze. Also successfully calculated probability of single polarized photon missing by successfully utilizing the Light transmission characteristics and power measurements in various Atmospheric conditions. 2019, Institute of Advanced Scientific Research, Inc.. All rights reserved. -
Insights on bar quenching from a multiwavelength analysis: The case of Messier 95
The physical processes related to the eect of bars in the quenching of star formation in the region between the nuclear/central subkiloparsec region and the ends of the bar (bar region) of spiral galaxies is not fully understood. It is hypothesized that the bar can either stabilize the gas against collapse, inhibiting star formation, or eciently consume all the available gas, leaving no fuel for further star formation.We present a multiwavelength study using the archival data of an early-type barred spiral galaxy, Messier 95, which shows signatures of suppressed star formation in the bar region. Using optical, ultraviolet (UV), infrared, CO, and HI imaging data we study the pattern of star formation progression and stellar/gas distribution, and try to provide insights into the process responsible for the observed pattern. The FUV NUV pixel colour map reveals a cavity devoid of UV flux in the bar region that matches the length of the bar, which is 4.2 kpc. The central nuclear region of the galaxy shows a blue colour clump and along the major axis of the stellar bar the colour progressively becomes redder. Based on a comparison to single stellar population models, we show that the region of galaxy along the major axis of the bar, unlike the region outside the bar, is comprised of stellar populations with ages 350 Myr; there is a star-forming clump in the centre of younger ages of 150 Myr. Interestingly the bar region is also devoid of neutral and molecular hydrogen but has an abundant molecular hydrogen present at the nuclear region of the galaxy. Our results are consistent with a picture in which the stellar bar in Messier 95 is redistributing the gas by funnelling gas inflows to nuclear region, thus making the bar region devoid of fuel for star formation. ESO 2019. -
Rainbow neighbourhood number of graphs
In this paper, we introduce the notion of the rainbow neighbourhood and a related graph parameter namely the rainbow neighbourhood number and report on preliminary results thereof. The closed neighbourhood N [v] of a vertex v ? V (G) which contains at least one coloured vertex of each colour in the chromatic colouring of a graph is called a rainbow neighbourhood. The number of rainbow neighbourhoods in a graph G is called the rainbow neighbourhood number of G, denoted by r?(G). We also introduce the concepts of an expanded line graph of a graph G and a v-clique of v ? V (G). With the help of these new concepts, we also establish a necessary and sufficient condition for the existence of a rainbow neighbourhood in the line graph of a graph G. 2019 Johan Kokand Sudev Naduvath and Muhammad Kamran Jamil. -
Enhanced technique for detection and prevention of phishing on websites
Phishing is a kind of assault where cyber criminals trap individuals to gain access to someone's private data like credit card details, passwords, account details, etc. The false e-mails look shockingly genuine and even the Web pages where clients are requested to enter their data may look legitimate. Forgery of a website is a sort of online assault where the phishing person builds a duplicate of a true authorized site, with the objective of misguiding a client by fishing out data that could be utilized to dupe or instigate different assaults upon the victim. In this paper, a new technique is developed using the combination of CORS, Public Repository technique and Heuristic functions. This technique allows only authorized Domain to replicate the original website. Copyright 2019 American Scientific Publishers All rights reserved. -
An intelligent inventive system for personalised webpage recommendation based on ontology semantics
Owing to the information diversity in the web and its dynamically changing contents, extraction of relevant information from the web is a huge challenge. With the World Wide Web transforming into a more organised semantic web, the incorporation of semantic techniques to retrieve relevant information is highly necessary. In this paper, a dynamic ontology alignment technique for recommending relevant webpages is proposed. The strategy focuses on knowledge tree construction by computing the semantic similarity between the query terms as well as the ontological entities. Furthermore, the semantic similarity is again computed between nodes of the constructed knowledge tree and URLs in the URL repository to recommend relevant webpages. The dynamic ontology alignment by computing their respective semantic similarity constitutes Ontology Semantics. Personalisation is achieved by prioritisation of webpages by content-based analysis of the users web usage data. An overall accuracy of 87.73% is achieved by the proposed approach. Copyright 2019 Inderscience Enterprises Ltd. -
Influence of Surfactant on the Phase Transformation of Bi 2 O 3 and its Photocatalytic Activity
Bismuth oxide with its unique narrow bandgap has gained significant attention in the field of photocatalysis. A new and efficient method to synthesise bismuth oxide with tuneable properties is proposed herein. A surfactant assisted modified sol-gel method is used to synthesise bismuth oxide with excellent photocatalytic activity for the degradation of Rhodamine B dye. Three different surfactants, namely polyethylene glycol-400, sodium lauryl sulfate, and cetyltrimethylammonium bromide (CTAB) have been used. The fabricated bismuth oxide nanoparticles were characterised by X-ray diffraction, IR, scanning electron microscopy, and UV-diffuse reflectance spectroscopy analysis. Evolution of both the ? and ? crystalline phases of bismuth oxide was observed. The bandgap of the synthesised bismuth oxides ranges from 2.03 to 2.37 eV. The CTAB assisted synthesised bismuth oxide with a bandgap of 2.19 eV showed the highest photocatalytic activity of 93.6 % under visible light for the degradation of Rhodamine B. This bismuth oxide based catalyst opens a new avenue for efficient photocatalysis for environmental remediation. 2019 CSIRO. -
Understanding the antecedents of service decisions: An integration of service promiscuity and customer citizenship behaviour
Promiscuity being casual and unrestrained towards any kind of service, the purpose of this article is to contribute to service literature by investigating the influence of customer citizenship behaviour and service promiscuity in the decision-making process in the context of public house services. This paper empirically draws a historic sum-up on the roots of service promiscuity towards the decision-making process. A questionnaire was administered to 1,509 pub customers using retrospective experience sampling technique. The proposed hypotheses were tested using structural equation modelling. Results from this research yielded novel insights into the dual antecedents extending to customer decision making process through customer citizenship behaviour and service promiscuity. The findings have implications for the ongoing argumentation on the practicality of customer promiscuity, thereby broadening the theoretical understanding of 'why customers' decision-making process establishes such an efficacious effect in the service environment? Further, these new and interesting results enlighten the insights of consumer behaviour and more importantly contribute substantially to the existing knowledge of service marketing literature. The results provide managers with specific decision-making process variables and substantial service strategies. 2019 Inderscience Enterprises Ltd. -
Biowaste derived graphene quantum dots interlaced with SnO2 nanoparticles-a dynamic disinfection agent against: Pseudomonas aeruginosa
Highly resilient antibacterial strains are a major cause of concern in the modern sewage treatment and sanitation industry. Hence, development of efficient, low-cost disinfectant agents is essential. In this study, synthesis of graphene quantum dots (GQDs) from expended sugarcane bagasse via surface functionalization and the subsequent production of GQD/SnO2 nanocomposites via a facile hydrothermal route is demonstrated for the first time. The synthesized nanostructures are found to be studded with various oxygen moieties and exhibit an excitation independent fluorescence behaviour implying the existence of quantum confinement effects. Nanoparticles obtained after the hydrothermal treatment are found to possess spherical morphology with an average particle size of 4.5 nm. Antibacterial activity of the synthesized product is tested against Pseudomonas aeruginosa using the disc diffusion assay and minimum inhibitory concentration assay. A marked rise in the antibacterial performance is seen in the nanocomposite compared to its carbonized and GQD counterparts. This can be attributed to the presence of surface defects and smaller uniform sized particles. These cost-effective nanostructures are photo stable for extended periods of storage and may find excellent utility in the sanitation and disinfectant industry. 2019 The Royal Society of Chemistry and the Centre National De la Recherche Scientifique. -
Online fake review identification based on decision rules
Posting of online reviews play a dominant role in sharing the customers opinion in social Medias. But the challenge is how to trust these reviews. Many researchers carried their work on sentimental analysis, predictions or forecasting but very few focused on fake reviews analysis. Fake reviews also change the mood of the people on their buying pattern. In the online shopping at a greater extent. In this paper, several conditions are applied on the reviews to identify fake reviews using support vector machines. Experimental results are validated using various accuracy measures and compared to state of the art methods to demonstrate the efficacy of the proposed method. 2019, World Academy of Research in Science and Engineering. All rights reserved. -
Effects of dark matter in star formation
The standard model for the formation of structure assumes that there existed small fluctuations in the early universe that grew due to gravitational instability. The origins of these fluctuations are as yet unclear. In this work we propose the role of dark matter in providing the seed for star formation in the early universe. Very recent observations also support the role of dark matter in the formation of these first stars. With this we set observable constraints on luminosities, temperatures, and lifetimes of these early stars with an admixture of dark matter. 2019, Springer Nature B.V. -
Collision avoidance using gazebo simulator
Autonomous cars will make its complete presence on roads in the future. A major feature of autonomous cars currently under research is collision avoidance on roads. Better collision avoidance systems could result in a decrease in number of accidents. Smart collision avoidance systems could handle the increasing amount of vehicles on roads. Collision avoidance system provides alert to the autonomous vehicles if an unavoidable collision is detected. When the collision is definite to happen, collision avoidance system takes action by its own without any driver input (by braking or steering or both). Collision avoidance system does the obstacle avoidance by gathering information about the environment with the help of sensors embedded in the system. The effectiveness of collision avoidance system depends upon the speed at which the system reacts from the gathered inputs. This paper uses the Gazebo simulation to design and implement collision avoidance. This paper also present a simple and effective obstacle avoidance algorithm for a simulated robot. Turtlebots Obstacle Avoider algorithm is attached to the robot in the simulator with the support of ROS(Robotic operating system) to implement collision avoidance. BEIESP. -
A study of airfoil flap deflection angle using cfd simulation techniques
This research aims with the advent of advancements in the evaluation of liquids and gases, Computational Fluid Dynamics technique has found widespread applications in various fields including aerodynamics. The wing is an important aerodynamic feature that has seen modifications in recent years to suffice the growing need for a greater maximum lift coefficient (CL). Existing designs make use of greater lift gadgets such as flaps and slats these are enhancers of the lift force and are at large used as attachments on the main wing body. This project investigates the 4 digit NACA 2412 airfoil improved using a 5 digit NACA 24012 Fowler flap. The two airfoils are set at particular angles to each other with an overlap and gap distance. Optimization of the flap deflection angle ?flap, the horizontal gap, and overlap between the flap and wing is simulated using CFD tools and the obtained coefficients of lift and drag experimentally validated to determine the optimum model configurations. It is noted that the coefficients of lift and drag increase to a certain point as the flap deflection angle increases. However, beyond a certain angle, CL drops. This new multi-element wing configuration will find its applications in low-speed aircraft used for general aviation and to reduce the need for longer runways. TJPRC Pvt. Ltd.