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Green synthesis of nanoparticles from biodegradable waste extracts and their applications: a critical review
The contemporary world is concerned only with non-biodegradable waste management which needs more sophisticated procedures as compared to biodegradable waste management. Biodegradable waste has the potential to become useful to society through a simple volarization technique. The researchers are behind sustainable nanotechnology pathways which are made possible by using biodegradable waste for the preparation of nanomaterials. This review emphasizes the potentialities of biodegradable waste produced as a viable alternative to create a sustainable economy that benefits all humans. Volarization results in the utilization of biowastes as well as provides safer and hazard-free green methods for the synthesis of nanoparticles. Starting from different sources to the application which includes therapeutics, food industry and water treatment. The review hovers over the pros and cons of biowaste-mediated nanoparticles and concludes with possible advances in the application. In the present scenario, the combination of green synthesis and biowaste can bring about a wide variety of applications in nanotechnology once the hurdles of bulk-scale industrial production are resolved. Given these points, the review is focused on the cost-effective synthesis of metal and metal oxide nanoparticles. 2022, The Author(s), under exclusive licence to Springer Nature Switzerland AG. -
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Green Synthesis of Nanoparticles Leading to the Biocontrol of Aedes Aegypti
Mosquitoes are the potential vectors of many diseases such as malaria, dengue, brain newlinefever, etc. There is a need to check the proliferation of the population of vector newlinemosquitoes to reduce vector-borne diseases by appropriate control methods. Nanotechnology, a promising field of research, opens up in the present decade and is expected to give major impulses to technical innovations. Over the past few decades, nanoparticles of noble metals such as silver exhibited significantly distinct physical, chemical and biological properties. Presently, there is a need for increased efforts to develop newer and more effective methods to control mosquito vectors. Due to different technical and operational reasons, the existing chemical and biological methods are not as effective as in the earlier period. Therefore, this study is designed to extract silver newlinenanoparticles from plant, fungal and bacterial species and assess their impact on the third and fourth-instar mosquito larvae and the adult mosquito (Aedes spp). The study has formulated a gel material that is composed of nanomaterials that exhibited promising properties to develop a nano gel product. The study is designed in a way to have an impact on the control of mosquito larvae using biologically synthesized nanoparticle formulations. Green synthesis is expected to show a higher yield of nano products that can be formulated in various forms to standardize the biocontrol of mosquito species. Bioinformatic studies revealed the good binding potential of the extracted bio compounds against the juvenile hormone binding proteins in A. aegypti. The study deduced meaningful outcomes that can benefit the environment by controlling the mosquito population and thereby reducing disease transmission in many developing countries. -
Green Synthesis of Reduced Graphene Nanostructure from Cinnamomum Camphora
A facile green synthesis for carbon nanoparticle production using Cinnamomum camphora (Camphor) is presented. Camphor upon carbonization and chemical oxidation leads to the formation of nano-carbon structures with lateral size 7.33nm to 4.14nm, respectively. The nanomaterial's stacking height is about 2.76nm and 3.10nm, leading to the formation of about 10 layers of carbon. The AFM analysis confirms that the graphene layer formed is wrinkled or folded. Developments of a layered structure with spheroids are observed on the sample's surface, confirming the graphitization of the amorphous carbon. The relative intensity of the defect to the graphite band is found to be 0.98 for the nanostructure indicating a lesser degree of defects. The C1s band of the nanostructure is deconvoluted to components at 284.7, 286.5, 287.3, and 289 eV, which are assigned to non-oxygenated ring carbon (sp2 carbon), C in C-O (bound to O either as epoxy or hydroxyl), C in C=O (of alcohols, phenols or ether), and C in C(O)O (carboxylic acid) respectively. The study reveals the formation of few-layer oxygenated carbon layers from the botanical hydrocarbon. 2020 by the authors. -
Green synthesis of reduced graphene oxide using Plectranthus amboinicus leaf extract and its supercapacitive performance
A rapid, efficient, green and eco-friendly approach for the preparation of reduced graphene oxide (rGO) using Plectranthus amboinicus (Indian borage) leaves extract (PAE) is explored in this study. The improvement in the reduction process was studied by varying the concentration of graphene oxide (GO), temperature and time duration. The physical and chemical properties of rGO are studied using Raman spectroscopy, Fourier transform infrared spectroscopy, X-ray diffraction (XRD) and field emission scanning electron microscope. The result obtained from XRD analysis confirms the removal of an oxygen-containing functional group of GO significantly by PAE. Raman analysis showed a higher ID/IG ratio for rGO (1.297) than GO (1.07), which indicates a higher level of disorder in the rGO with a decrease in the average size of the sp2 domain. From the electrochemical studies, a significant specific capacitance of 92.05Fg1 (5mVs1) is obtained from the cyclic voltammetry (CV) curves and 73.20Fg1 (0.1Ag1) from the galvanostatic chargedischarge (GCD) curve. 2021, Indian Academy of Sciences. -
Green synthesis of silver nanoparticles using calendula officinalis and its anti-bacterial studies /
Mapana Journal of Sciences, Vol.17, Issue 2, pp.11-17, ISSN No: 0975-3303. -
Green synthesis of zirconium phosphate by combustion method: photocatalytic application and microwave-assisted catalytic conversion of aldehyde to nitriles
Water pollution has increased swiftly, especially the dyes from industries that have disturbed aquatic eco-system. Photocatalytic degradation (PCD) is one of the attractive methods to eliminate dyes from industrial effluents. Zirconium phosphate (ZP) nanoparticles were synthesized by combustion method using zirconyl nitrate and phosphorous pentoxide as precursors. The obtained ZP was characterized by powder X-ray diffractogram, Fourier transform infrared, scanning electron microscopy, high-resolution transmission electron microscopy, Raman spectroscopy, photoluminescence spectroscopy, BrunauerEmmettTeller surface area. PCD was carried out using methylene blue as a model pollutant in aqueous medium in the presence of UV light irradiation with different concentrations of dye, catalyst and pH. Higher degradation efficiency was observed in basic medium. ZP is employed as a catalyst to form nitrides from aldehydes using different solvents with different aldehydes. Graphic abstract: [Figure not available: see fulltext.]. 2021, Indian Academy of Sciences. -
Green synthesis, characterization of silver nanoparticles using aqueous leaf extracts of Solanum melongena and in vitro evaluation of antibacterial, pesticidal and anticancer activity in human MDA-MB-231 breast cancer cell lines
The present study validated the green synthesis and characterization of AgNPs using the leaf extracts of Solanum melongena (SM-AgNPs). The efficiency of the phytocompounds in the leaf extract in reducing Ag+ to Ag0 ions was studied. The synthesized SM-AgNPs were characterized by spectroscopic methods and standard methods were adopted for the antioxidant activity, HPTLC, cytotoxicity and antimicrobial assays and pesticidal activity as well. The synthesised nanoparticle was measured to be 20.54 nm which was confirmed by the characterization. The total phenolic content was 5.98 0. GAE/g which indicated potent antioxidant activity. HPTLC profile showed thirteen peaks corresponding to the phenolic compounds with Rf values ranging from 0.05 to 0.95. The average particle size and zeta potential was 75.14 nm-19.8 mV respectively. Cytotoxicity assay of the synthesized AgNP's showed viability percentage of 50.23 at 100 mg/mL. Treatment of MDA-MB-231 cell lines with the SM-AgNPs induced early apoptosis in a greater number of cells. The synthesizedAgNPs were effective against the bacterial isolates Escherichia coli, Pseudomonas aeruginosa, Shigella flexneri, Proteus vulgaris, Klebsiella pneumoniae and Staphylococcus aureus. High mortality of Bemisiatabaci was observed in the100 g/mL of the SM-AgNPs treated concentrations. The study demonstrated the efficiency of SM-AgNPs against cancer cell lines, microbial isolates and insect pests. 2023 The Author(s) -
Green synthesized cobalt nanoparticles from Trianthema portulacastrum L. as a novel antimicrobials and antioxidants
Trianthema portulacastrum is a dietary and medicinal plant that has gained substantial importance due to its pharmacological properties. This plant was used for its various healing properties since the ancient period in ayurvedic system of medicine. The green synthesis technique is an eco-friendly as well as cost effective technique which can produce more biocompatible nanoparticles when compared with those fabricated by physio-chemical methods. Therefore, nanoparticles produced by green synthesis are credible alternatives to those which are produced by conventional synthesis techniques. This research mainly aims to produce nanoparticles with the methanolic leaf extract of T. portulacastrum. The optimized nanoparticles were further analyzed for anti-fungal, anti-bacterial and antioxidant properties. Disk diffusion assay was used for the determination of the antimicrobial property and on the other hand, DPPH radical scavenging assay as well as hydrogen peroxide scavenging activity proved the antioxidant property of the formulation. The study revealed that Escherichia coli (gram negative strain) shows greater zone of inhibition when compared with Bacillus subtilis (gram positive bacteria). The nanoparticles have also been reported to show significant anti-fungal activity against the strains of Aspergillus niger and Fusarium oxysporum which proves its desirability for its further use against both bacterial as well as fungal infections. The novel formulation can be explored dually as antimicrobial and antioxidant agent. 2023 Taylor & Francis Group, LLC. -
Green Synthesized Fluorescent Nano-Carbon derived from Indigofera Tinctora (L.) leaf extract for sensing of Pb2+ ions
Plant-based synthesis of nanomaterials is a more reliable method since it is easy, quick, and environmentally friendly, and it does not require any specific conditions, unlike other methods. For the first time, we report the sensing of metal ions using a fluorescent nano-carbon material via a plant-based synthesis from the medicinal plant, Indigofera Tinctora (L.) (IBLH). This nanomaterial from the leaf extract of IBLH was synthesized by hydrothermal assisted green synthesis method. The as-synthesized sample was characterized by various spectroscopic techniques for confirming the formation of nano-carbon material. Optical studies revealed that IBLH was influential in determining toxic heavy metal ions (Pb2+). Detection of Pb2+ was observed from a range of 1 Molar to as low as 1Nano-Molar using IBLH as the probe. Stern-Volmer plot exhibits the progressive detection of the metal ion, proving that the IBLH nano-carbon material is capable of progressive sensing of various heavy metal ions. The Electrochemical Society -
Green Synthesized ZnO Nanoparticles as Biodiesel Blends and their Effect on the Performance and Emission of Greenhouse Gases
Pollution and global warming are a few of the many reasons for environmental problems, due to industrial wastes and greenhouse gases, hence there are efforts to bring down such emissions to reduce pollution and combat global warming. In the present study, zinc oxide nanoparticles are green synthesized using cow dung as fuel, through combustion. Synthesized material was characterized by FTIR, XRD, UV, and FESEM. The as-prepared ZnO-GS NPs were employed as a transesterification catalyst for the preparation of biodiesel from discarded cooking oil. The biodiesel obtained is termed D-COME (discarded cooking oil methyl ester), which is blended with 20% commercial diesel (B20). Additionally, this blend, i.e., B20, is further blended with varying amounts of as-prepared ZnO-GS NPs, in order to ascertain its effects on the quality of emissions of various greenhouse gases such as hydrocarbons, COx, NOx. Moreover, the brake thermal efficiency (BTHE) and brake specific fuel consumption (BSFC) were studied for their blends. The blend (B20) with 30 mg of ZnO-GS, i.e., B20-30, displays the best performance and reduced emissions. Comparative studies revealed that the ZnO-GS NPs are as efficient as the ZnO-C NPs, indicating that the green synthetic approach employed does not affect the efficiency of the ZnO NPs. 2022 by the authors. Licensee MDPI, Basel, Switzerland. -
Green-synthesized nanoparticles and their therapeutic applications: A review
Antibiotic-resistant microorganisms are a rising issue when it comes to human health. Microbial pathogens that cause harmful infections are quickly becoming resistant to the antimicrobial action of traditional antibiotics. Nanotechnology, an innovative sector being an indispensable part of healthcare and research, has in-depth and extensive applications. Nano-compounds have been promising antimicrobial agents, anti-cancerous mediators, vehicles for drug delivery, formulations for functional foods, identification of pathogens, food and drug packaging industry, and many more. However, the chemical synthesis of nanoparticles (NPs) has certain drawbacks such as causing toxicity and other adverse effects. For more than a decade, the use of NPs that are conjugated or green-synthesized has gained popularity due to the two-fold action of metallic NPs mixed with biological sources. In contrast, NPs synthesized using plant or microbial extracts, conjugated with biologically active components, appear to be a safe alternative approach as they are environmentally friendly and cost-effective. Such environmentally safe techniques are referred to as "green nanotechnology"or "clean technology"and are feasible alternatives to chemical methods. Furthermore, NPs conjugated with natural biomolecules have improved bioavailability and have minimal side effects, as they are smaller in size and have higher permeability in addition to being reducing and stabilizing agents possessing excellent antioxidant activity. NPs serve as potential antimicrobial agents due to their affinity towards sulphur-rich amino acids, adhere to microbial cell walls by means of electrostatic attraction, and disrupt the cytoplasmic membrane along with the nucleic acid of microbes. They possess anticancer activity owing to oxidative stress, damage to cellular DNA, and lipid peroxidation. The green-synthesized NPs are thus a promising and safe alternative for healthcare therapeutic applications. 2023 the author(s), published by De Gruyter. -
Green-Synthesized Sm3+-Doped ZnO Nanoparticles for Multifunctional Applications
The present study focuses on the green-mediated synthesis of pristine and Sm3+-doped ZnO nanoparticles using Syzygium cumini fruit extract. The prepared material was characterized by various characterization techniques. Photocatalytic degradation of a fast orange red (FOR) dye under UV light resulted in 88% degradation, with a minimal decrease (87.90%) observed even after five successive runs, indicating the stability and effectiveness of the catalyst. The enhancement in degradation efficiency is attributed to the incorporation of Sm3+ ions into the ZnO lattice. Utilizing the optimized Sm3+ (5 mol%)-doped ZnO nanoparticles, cyclic voltammetry (CV) and electrochemical impedance spectra (EIS) were performed on the prepared electrode, demonstrating the excellent CV properties; this enhancement is attributed to the modification of ZnO's redox chemistry and the alteration of charge transfer kinetics at the electrode-electrolyte interface due to the addition of Sm3+ into the ZnO structure. The antibacterial activity was performed against two pathogenic strains, i.e., Escherichia coli and Streptococcus aureus. The obtained results suggest that the prepared material holds great promise for catalytic, energy storage, antibacterial, and other multifunctional applications. 2024 Lavanya R. et al. -
Greener Assembly of Nano Catalysts and Sustainable Applications of Magnetically Retrievable and Plasmonic Nano Catalysts
Since ages, catalysts have played a pivotal role in accelerating the production and lowering the cost of a plethora of industrially important commodities. The latest in the scenario are nanocatalysts, which offer a wide array of advantages ranging from improved reaction rates to higher rates of recyclability. However, factors such as stability and support systems must be fine-tuned to achieve maximum efficiency. In accordance with the principle of sustainability, green synthesis methods have propelled the development of a range of nanocatalysts that can be applied in various domains, such as the food industry and biofuel production. Simultaneously, heterogeneous catalysis is gaining more attention globally, primarily due to the ease of recoverability of the nanocatalysts and in this context, magnetically retrievable nanocatalysts are indeed a boon for the green synthesis and sustainable production. Nanocomposites combining plasmonic and catalytic components with noble metal nanoparticles (Au and Ag) and doped semiconductor nanostructures have gained interest in recent years owing to their utility in multiple sectors by virtue of their ability to convert sunlight to chemical energy. The current review describes some methods for the synthesis of such nanocatalysts and their applications in diverse domains. Graphical Abstract: (Figure presented.) The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. -
Greenpreneurship pioneering solutions for climate change: An Indian perspective
In an era marked by pressing global climate challenges, the role of green entrepreneurship, or "greenpreneurship, " has gained paramount significance. The present chapter begins by elucidating the inherent connection between greenpreneurship and climate change, followed the contributions of the greenpreneurs appreciating their efforts to make a difference to the society. The chapter mentions certain skills and traits required by greenpreneurs to run their business. It states the challenges that the greenpreneurs face. The chapter then takes a dive into the realm of greenpreneurship from an Indian perspective. India, with its unique blend of environmental challenges and a burgeoning entrepreneurial ecosystem, presents an intriguing case study. The chapter illustrates how Indian greenpreneurs are contributing to a cleaner, greener future. It states the policies which the government has made to support greenpreneurs in the country. Finally, recommendations are given for existing greenpreneurs, budding entrepreneurs, the public, and the government to collectively drive green solutions. 2024, IGI Global. All rights reserved. -
Grey Wolf Optimization Guided Non-Local Means Denoising for Localizing and Extracting Bone Regions from X-Ray Images
The key focus of the current study is implementation of an automated semantic segmentation model to localize and extract bone regions from digital X-ray images. Methods: The proposed segmentation framework uses a pre-processing stage which follows convolutional neural network (CNN) obtained segmentation stage to extract the bone region from X-ray images, mainly for diagnosing critical conditions such as osteoporosis. Since the presence of noise is critical in image analysis, the X-ray images are initially processed with a grey wolf optimization (GWO) guided non-local means (NLM) denoising. The segmentation stage uses a Multi-Res U-Net architecture with attention modules. Findings: The proposed methodology shows superior results while segmenting bone regions from real X-ray images. The experiments include an ablation study that substantiates the need for the proposed denoising approach. Several standard segmentation benchmarks such as precision, recall, Dice-score, specificity, Intersection over Union (IOU), and total accuracy have been used for a comprehensive study. The proposed architectural has good impact compared to the state-of-the-art bone segmentation models and is compared both quantitatively and qualitatively. Novelty: The denoising using GWO-NLM adaptively chose the denoising parameters based on the required conditions and can be reused in other medical image analysis domains with minimal finetuning. The design of the proposed CNN model also aims at better performance on the target datasets. 2023 Biomedical & Pharmacology Journal. -
Grey Wolf optimization-Elman neural network model for stock price prediction
Over the past two decades, assessing future price of stock market has been a very active area of research in financial world. Stock price always fluctuates due to many variables. Thus, an accurate prediction of stock price can be considered as a tough task. This study intends to design an efficient model for predicting future price of stock market using technical indicators derived from historical data and natural inspired algorithm. The model adopts Elman neural network (ENN) because of its ability to memorize the past information, which is suitable for solving stock problems. Trial and error-based method is widely used to determine the parameters of ENN. It is a time-consuming task. To address such an issue, this study employs Grey Wolf optimization (GWO) algorithm to optimize the parameters of ENN. Optimized ENN is utilized to predict the future price of stock data in 1day advance. To evaluate the prediction efficiency, proposed model is tested on NYSE and NASDAQ stock data. The efficacy of the proposed model is compared with other benchmark models such as FPA-ELM, PSO-MLP, PSOElman,CSO-ARMA and GA-LSTM to prove its superiority. Results demonstrated that the GWO-ENN model provides accurate prediction for 1day ahead prediction and outperforms the benchmark models taken for comparison. 2020, Springer-Verlag GmbH Germany, part of Springer Nature. -
Grip-on: The ergonomic walking stick /
Patent Number: 202241053663, Applicant: Joel Sebastian.
A high percentage of elderly users depend on walking slicks to get better support or assistance in maintaining a good posture while walking. An ergonomically well-designed walking stick can only provide good postural stability. For the past few decades in India, no significant changes or innovations have been made to the conventional walking stick. The study identified that majority of the users are facing difficulty in handling these conventional walking sticks. -
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Ground Truncated Broadband Slotted Circular Microstrip Antenna
In this growing era of wireless technology, large sized devices have become obsolete. In response to the increasing demand for miniaturization over the past decades, microstrip antennas have drawn attention due to its various features like light weight, low cost, small in size and its greater resistivity to shock and vibrations. These can also easily get conformed to any surface. These antennas are also capable of operating at high frequencies, providing large bandwidth and gain by using various techniques slots and truncation of shapes. This report describes the design, simulation, fabrication and measurement results of a microstrip fed Slotted Circular Microstrip Antenna for broadband applications. The antenna was designed for an operating frequency of 2.45 GHz on a double side printed FR4 substrate measuring 55 mm x 55 mm x 1.6 mm with ?r of 4.4. It measured a very large resonant band of 1.3 - 9.05 GHz at a return loss level as low as -36.5 dB at 7.98 GHz. A maximum gain of 2.46 dB was achieved at 2.33 GHz. The enhancement in bandwidth was achieved by truncation in ground and inclusion of thin circular slot. The HFSS version 18.2 software and VNA model Anritsu SA20E were used for simulation and measurement respectively. It is found that the simulation and measurement results agree. 2018 IEEE.