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Oxidation reactions of carbaryl in aqueous solutions
Hydroxyl radical induced oxidation of carbaryl has been studied using steady state photolysis followed by high-resolution mass spectrometry (LC-Q-TOF-MS), pulse radiolysis, and theoretical (DFT) calculations. The reaction of ?OH with carbaryl resulted in a number of hydroxylated adduct radicals (?max - 330 nm and 390 nm; k2 - 1.2 1010 dm3 mol-1 s-1). The DFT calculations and results obtained from LC-Q-TOF-MS analysis shows the possible addition of ?OH at C1 (energetically most stable) and C7 positions of carbaryl leading to the generation of resonance stabilized hydroxycyclohexadienyl-type radicals as the immediate intermediates, which eventually converted into naphthol and a hydroxylated naphthols. LC-Q-TOF-MS results also revealed the formation of other hydroxylated derivatives and naphthoquinones that are most likely originated from the consecutive ?OH attack on the initially formed products. Naphthoquinones are found to undergo ring opening and the corresponding products are identified. The reaction of SO4?- with carbaryl, on the other hand, results the radical cation of parent molecule (?max - 320 nm and 390 nm) which exhibits reasonable stability in the pulse radiolysis timescale. Total organic carbon (TOC) analysis after H2O2/UV photolysis revealed that nearly 70% of the organic content is mineralized after 35 min of irradiation, which demonstrates the potential application of oxidative methods towards the degradation of carbaryl. 2021 Elsevier B.V. -
P type copper doped tin oxide thin films and p-n homojunction diodes based on them
P-type copper doped tin oxide (SnO2:Cu) thin films were prepared by chemical spray pyrolysis method on glass substrates for different doping concentrations. Their structural, optical, surface morphological, elemental and electrical studies were investigated. We fabricated two transparent homojunction diodes using optimized sample of SnO2:Cu which are p- SnO2:Cu/n-SnO2 and p-SnO2:Cu/n- SnO2:F.These diodes are reported for the first time by this method. 2021 Elsevier B.V. -
P-energy of generalized Petersen graphs
For a given graph G, its P-energy is the sum of the absolute values of the eigenvalues of the P-matrix of G. In this article, we explore the P-energy of generalized Petersen graphs G(p; k) for various vertex partitions such as independent, domatic, total domatic and k-ply domatic partitions and partition containing a perfect matching in G(p; k). Further, we present a python program to obtain the P-energy of G(p; k) for the vertex partitions under consideration and examine the relation between them. 2022 The authors. -
P-ROCK: A Sustainable Clustering Algorithm for Large Categorical Datasets
Data clustering is crucial when it comes to data processing and analytics. The new clustering method overcomes the challenge of evaluating and extracting data from big data. Numerical or categorical data can be grouped. Existing clustering methods favor numerical data clustering and ignore categorical data clustering. Until recently, the only way to cluster categorical data was to convert it to a numeric representation and then cluster it using current numeric clustering methods. However, these algorithms could not use the concept of categorical data for clustering. Following that, suggestions for expanding traditional categorical data processing methods were made. In addition to expansions, several new clustering methods and extensions have been proposed in recent years. ROCK is an adaptable and straightforward algorithm for calculating the similarity between data sets to cluster them. This paper aims to modify the algorithm by creating a parameterized version that takes specific algorithm parameters as input and outputs satisfactory cluster structures. The parameterized ROCK algorithm is the name given to the modified algorithm (P-ROCK). The proposed modification makes the original algorithm more flexible by using user-defined parameters. A detailed hypothesis was developed later validated with experimental results on real-world datasets using our proposed P-ROCK algorithm. A comparison with the original ROCK algorithm is also provided. Experiment results show that the proposed algorithm is on par with the original ROCK algorithm with an accuracy of 97.9%. The proposed P-ROCK algorithm has improved the runtime and is more flexible and scalable. 2023, Tech Science Press. All rights reserved. -
P(III)-Mediated Cascade C-N/C-S Bond Formation: A Protocol towards the Synthesis of N,S-Heterocycles and Spiro Compounds
A P(III)-mediated entry towards construction of C?N/C?S bond has been devised. The developed heterocyclization method was exercised for the synthesis of a diverse range of N,S-heterocycles and related spiro molecules. P(NMe2)3 revealed the maximum efficacies under the aerobic reaction conditions and a spectrum of bis-nucleophiles, and isothiocyanates were tolerated well to serve the access of manifold immense molecules. (Figure presented.). 2020 Wiley-VCH GmbH -
PA1 cells containing a truncated DNA polymerase ? protein are more sensitive to gamma radiation
Purpose: DNA polymerase ? (Pol?) acts in the base excision repair (BER) pathway. Mutations in DNA polymerase ? (Pol?) are associated with different cancers. A variant of Pol? with a 97 amino acid de-letion (Pol??), in heterozygous conditions with wild-type Pol?, was identified in sporadic ovarian tumor samples. This study aims to evaluate the gamma radiation sensitivity of Pol?? for possible target therapy in ovarian cancer treatment. Materials and Methods: Pol?? cDNA was cloned in a GFP vector and transfected in PA1 cells. Stable cells (PA1Pol??) were treated with60Co sourced gamma-ray (015 Gy) to investigate their radiation sensitivity. The affinity of Pol?? with DNA evaluated by DNA protein in silico docking experiments. Results: The result showed a statistically significant (p < 0.05) higher sensitivity towards radiation at different doses (015 Gy) and time-point (4872 hours) for PA1Pol?? cells in comparison with nor-mal PA1 cells. Ten Gy of gamma radiation was found to be the optimal dose. Significantly more PA-1Pol?? cells were killed at this dose than PA1 cells after 48 hours of treatment via an apoptotic pathway. The in silico docking experiments revealed that Pol?? has more substantial binding potential towards the dsDNA than wild-type Pol?, suggesting a possible failure of BER pathway that results in cell death. Conclusion: Our study showed that the PA1Pol?? cells were more susceptible than PA1 cells to gamma radiation. In the future, the potentiality of ionizing radiation to treat this type of cancer will be checked in animal models. 2022 The Korean Society for Radiation Oncology. -
Padmarajans enigmatic and enduring relationships
[No abstract available] -
Pain track analysis during gestation using machine learning techniques
During the gestation period women experience Braxton Hicks which is called the false labor, contractions during the second trimester. These contractions are not in regular intervals and also they are often unnoticed. The real labour or the true labour contractions develop late in the third trimester of the gestation usually beyond 36th week (excluding pre-term birth). Some women often fail to identify these pains in the third trimester of the gestation where an efficient facial recognition algorithm along with the support vector machine (SVM) helps them to identify these pains and take optimum care of themselves. The authors in this paper convey a mechanism to identify the pains effectively by creating a database of images pertaining to the pregnant women, her emotional states throughout the pregnancy. Using MATLAB the algorithm of decision tree is implemented and the values obtained from them help us analyze the pain type efficiently. 2021 Institute of Advanced Engineering and Science. All rights reserved. -
Paired Domination Integrity of Graphs
The concept of vulnerability in a communication network plays an important role when there is a disruption in the network. There exist several graph parameters that measure the vulnerability of a communication network. Domination integrity is one of the vulnerability parameters that measure the performance of a communication network. In this paper, we introduce the concept of paired domination integrity of a graph as a new measure of graph vulnerability. Let G = (V,E) be a simple, connected graph. A set of vertices in a graph G, say S, is a paired dominating set if the following two conditions are satisfied: (i) every vertex of G has a neighbor in S and (ii) the subgraph induced by S contains a perfect matching. The paired domination integrity of G, denoted by PDI(G), is defined as PDI(G) = min{|S| + m(G - S): S is a paired dominating set of G}, where m(G - S) is the order of the largest component in the induced subgraph of G - S. In this paper, we determine few bounds relating paired domination integrity with other graph parameters and the paired domination integrity of some classes of graphs. 2024 World Scientific Publishing Company. -
Palladium immobilized on guanidine functionalized magnetic nanoparticles: a highly effective and recoverable catalyst for ultrasound aided Suzuki-Miyaura cross-coupling reactions
We designed and prepared a palladium catalyst that can be magnetically recyclable by anchoring guanidine moiety on the surface of Fe3O4 nanoparticles, named Fe3O4@SiO2-TCT-Gua-Pd. It was established to be a potent catalyst for the Suzuki-Miyaura cross-coupling reaction (SMCR) in the EtOH/H2O system under ultrasonic conditions. FT-IR spectroscopy, field-emission scanning electron microscopy (FESEM), energy dispersive X-ray (EDX) microanalysis, vibration sample magnetometry (VSM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), and inductively coupled plasma atomic emission spectrometry (ICP-AES) analyses were used to characterize the structure of the Fe3O4@SiO2-TCT-Gua-Pd nanoctalyst. The Fe3O4@SiO2-TCT-Gua-Pd catalyst produced favorable coupled products with excellent yields and was harmonious with various aryl halides and aryl boronic acids. The stability, low palladium leaching, and heterogeneous nature of the nanocatalyst were confirmed by a hot-filtration test. The palladium nanocatalyst could be easily recovered by magnetic field separation and recycled at least 6 times in a row without noticeable loss in its catalytic activity. 2023 The Royal Society of Chemistry. -
Palliative care in duchenne muscular dystrophy: A study on parents' understanding
Introduction: Duchene muscular dystrophy (DMD) is a neuromuscular disease of childhood, which has clear progression. The international standardized care guidelines for DMD suggest that palliative care is essential for the affected children. Objective: To explore the parent's understanding of palliative care services available for children with DMD and the challenges faced by them in utilizing the same. Methods: A cross-sectional qualitative exploratory study was conducted among six families of boys diagnosed with DMD. A semi-structured interview guide with prompts was used to conduct in-depth interviews which lasted for an average of 1 h. Thematic analysis was done to identify the pattern or themes. Results: The major themes identified were 'palliative care, living with DMD, awareness about palliative care services and challenges.' Awareness about palliative care services is the dominant theme identified as influencing rest of the experiences narrated by the parents of children with DMD. Discussion: Integration of palliative care services from an early stage of the illness can help the child to make transition from one stage to another stage of the illness. To ensure the utilization of the available palliative care services, there is a need to create awareness about it among the general public. Conclusion: Introducing the concept of palliation of symptoms and ensuring quality of life of the child with DMD by accessing the available services can aid the parents to reach out for help for their child. 2021 Wolters Kluwer Medknow Publications. All rights reserved. -
Pan-generation investigation of sustainability factors in conjunction with personality aspects influencing consumer's perception towards sustainable marketing
Sustainability has become the goal of governments and organizations worldwide since the 2030 agenda of the United Nations was declared. The large number of products has emerged in the market that claims to be green and sustainable or promise to serve a social cause. Even though numerous studies that claim consumers are increasingly conscious of their choices and consumption behaviour there has been a marked gap between this awareness and the actual behaviour exhibited. In a quest to comprehend the curious gap between the attitude and behaviour of consumers, several studies have endeavored to find a plausible explanation. Marketing specialists have come up with several strategies in order to make sustainable marketing a success but inexplicably still fail to do so. This study proposes a conceptual framework that comprehensively explains the impact of external and internal drivers for a consumer's perception of products that claim to be sustainable in nature, which may eventually explain the attitude-behaviour gap. This has been constructed using well-established consumer behaviour and personality theories. Sample size was calculated using proportion to population method and was derived as 270. Judgment and convenience sampling were used to collect the data through a structured questionnaire. The study uncovered that age influences the attitudes of consumers and both Gen X (cohort born between 1965-79) and Y (cohort born between 1980-96) bear positive attitudes towards sustainable marketing. Pricing had a major influence as well, buyers who ranked high on the 'Conventional' and 'Realistic' interests of the RIASEC personality model had a more positive perception. 2021 Ecological Society of India. All rights reserved. -
PANCHAYAT SYSTEM IN KARNATAKA: DEMOCRACY, REPRESENTATION AND POLITICAL PARTIES; [SISTEMA PANCHAYAT EM KARNATAKA: DEMOCRACIA, REPRESENTAO E PARTIDOS POLICOS]
As far as the Indian sub-continent is concerned local governance/panchayat has an elaborate history. The rural population have for long practiced this system of governing themselves through their representatives. The mode of working and the powers vested in the local bodies, have not been uniform throughout. The federation conferred constitutional status to the local governance bodies in 1993 and this system has progressed in an interesting way. Karnataka, a southern State in India has been ahead of time in enacting legislations dealing with local governance. Even before the amendment inserting provisions to the Constitution of India was passed, Karnataka had and was implementing extravagant laws pertaining to panchayats. Since democracy and decentralisation are closely associated with the panchayats, the idea of representation has a key role to play. The concerns with respect to involvement and influence of political parties in the local body elections are an important aspect as well. This paper ventures out to understand the panchayat system in Karnataka, pre and post the Constitutional amendment. The paper intends to throw light on the essence of the legislations relating to panchayats in Karnataka and understand the idea of democracy, representational factor and the concept of elections on a non-party basis. The researchers have keenly pondered upon the implementation of apolitical elections in Karnataka, the flaws in the proposed phenomenon. The paper also aims to look into hurdles in the way of these local bodies and propose suggestions to get over the same. Purpose: To Analyze the panchayat system in Karnataka, both before and after the 1993 constitutional amendment. Examine the essence of Karnataka's panchayat-related legislation. Explore the concepts of democracy, representation, and non-party elections in the context of panchayats. Evaluate the implementation of non-partisan elections in Karnataka and identify potential flaws. Analyze the challenges faced by panchayats and propose solutions. Theoretical Reference: Mainly Doctrinal research methodology. Relies on primary sources like the Indian Constitution, relevant statutes relating to panchayaths, and relevant data. Draws on secondary sources like articles and research papers. Method: Analyzes relevant legal documents and scholarly works. Analytical Method of Study Comparative Studies in relation to various factors pertaining to the research between the three levels of Panchayat (Gram Panchayat, Taluk Panchayat and Zilla Panchayat) Results and Conclusion: Non-partisan elections in Karnataka are largely theoretical; political parties influence local elections. Political interference hinders effective panchayat functioning. The paper likely proposes recommendations for strengthening panchayats and minimizing political influence. Implications of Research: Provides insights into the challenges and potential of decentralized governance in India. Informs policymakers and stakeholders about improving panchayat effectiveness. May contribute to debates on non-partisan elections and local democracy. Originality/Value: The study offers a focused analysis of Karnataka's panchayat system within a specific theoretical framework. Its findings on the limitations of non-partisan elections could be valuable for other regions considering similar approaches. 2024 ANPAD - Associacao Nacional de Pos-Graduacao e Pesquisa em Administracao. All rights reserved. -
PANDEMIC-INDUCED CRISES IN TOURISM AND HOSPITALITY AN INDIAN CONTEXT
This paper aims to examine the pandemic-induced crises psychological and physical distress experienced by the employees during the Covid19 pandemic and the implications on job loss and job characteristics from all domains of the hospitality industry in India. The study is designed to explore the pandemic-induced tourism crisis along with emotional, mental, and physical effects. An in-depth qualitative exploration was used and a tool comprising of data sets include representatives from aviation, resorts and hotel segments, tour operators, and travel agents. The researchers used a semi-structured questionnaire that had two sections and explored industry concerns, HR strategies, and employee distress through a multi-stage process involving coding and content analysis. The study analyzed the pandemic-induced crises at the micro and macro levels and grouped them under three essential dimensions such as; organizational and industry concerns, organizational HR policies, and employees psychological distress. The subthemes under these dimensions can contribute to scale validation. The subthemes grouped under the three major dimensions have come out as a theoretical model of how the pandemic has affected professionals at these three levels. The findings as items can be validated through descriptive research in quantitative terms forming the future scope. The study analyzed the perceptions of professionals in the tourism and hospitality business amid the pandemic and concludes that a proactive HR policy can minimize employees psychological distress. 2022 Editura Universitatii din Oradea. All rights reserved. -
Pandemic, theatre and performance: Democratizing the subalterns through the Theatre of the Oppressed
The presented work analyses Theatre of the Oppressed (TO) methods impacting the pandemic. It follows the WHO timeline, when the COVID-19 pandemic had cast a dark shadow, making sustenance difficult for the marginalized section of Indian society. TO methods, though reflected, adapted and accommodated exhaustively in Indian applied theatre over the last four decades, offered a fresh, collective, democratic space during the pandemic. Forum theatre (FT) and legislative theatre (LT) praxis rendered a platform for activism, awareness and emancipation of the subalterns during the pandemic. Thus, TO renewed psycho-social dialogue and critical, creative, experimental space during this time. The applicability of such methods facilitating social change is gauged using Boals spect-actorship and Freires conscientization. The article looks forward to the TO signposts to serve as nodal points for further scholarly discussion and study on democratizing the disenfranchised population through FT and LT during the pandemic. 2023 Intellect Ltd Article. English language. All Rights Reserved. -
Panel data analysis of Indian textile exports in the post quota period /
Trade And Development Review, Vol. 11, Issue 1-2, pp.1-27. -
PANI/Bi2O3 polymeric nanocomposite for the reduction of 4-nitrophenol
Nitro-aromatics pollute the aquatic environment and reach human beings via drinking water. 4-Nitrophenol (4-NP) is the most common pollutant among them and can be reduced to non-toxic 4-aminophenol in the presence of sodium borohydride (NaBH4). Polyaniline/bismuth oxide (PANI/Bi2O3) nanocomposite is synthesized from aniline and Bi2O3 by chemical oxidative polymerization. The composition and structural properties of PANI/Bi2O3 composite are identified by various characterization methods like X-ray powder diffraction, fourier transform infrared spectroscopy, thermogravimetric analysis , and zeta potential analysis. The synthesized PANI/Bi2O3 shows high catalytic efficiency towards the reduction of 4-NP in the presence of NaBH4 under optimized reaction conditions. The numerous active sites on the composite and the presence of PANI/Bi2O3 interface are the reasons for the reduction of 4-NP to 4-aminophenol. A complete degradation is achieved in 15min with 0.1g of the composite. This nanocomposite shows good stability for five cycles without losing efficiency. PANI/Bi2O3 possesses a high reduction capacity and can be used to reduce other nitro organic pollutants in water. The aim of the study is to study the effective catalytic reduction of 4-NP using PANI/Bi2O3. Graphical abstract: [Figure not available: see fulltext.] 2022, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature. -
Parallel queue scheduling in Dynamic Cloud environment using Backfilling algorithm
Cloud Computing reshapes the entire computing paradigm. In general, cloud computing means outsourcing available services and data storage in centralized scenario. In cloud computing task allocation is a major problem because multiple numbers of tasks are allocated to multiple numbers of processors for simultaneous processing. From the given list, tasks are queued according to the ascending order based on their duration. This paper is designed to solve the Task Scheduling problem, by using our proposed effective new approach of Backfilling algorithm. Depending upon the task duration, tasks are split into multiple threads for processing. Multiple thread tasks are processed in the basic concept of "gang scheduling" technique. Here we implement new backfilling algorithm concept to minimize the idle processing time of the processors. The existing Simple Backfilling Algorithm (SBA) is used to minimize the ideal time processing. Whereas comparatively Dynamic Cloud Scheduling using Backfilling Algorithm (DCBA) is designed to reduce the ideal time processing than SBA to carry out the process of both LQueue and SQueue simultaneously. At the outset, DCBA reduces the average waiting time. As mentioned the algorithm which is specified in the previous line that contains three level which represent the working speed of the algorithm. The first and second level of DCBA algorithm is comparatively similar to the performance of SBA algorithm. The maximum better performance was given in a queue size (q=1.5) by DCBA algorithm as compare to SBA algorithm. The existing type (Gang Scheduling) consist of two approaches namely Adaptive First Come First Serve (AFCFS) and Largest Job First Served (LJFS) that focus on non-parallel jobs with deadline. When compare to existing gang scheduling algorithm and SBA algorithm the average waiting time of DCBA has slight improvement in the loader level of the key. As the separation of the queue like LQ and SQ the waiting time and average waiting time is reduced comparatively. 2018, Intelligent Network and Systems Society. -
Parallelization of frequent itemset mining methods with fp-tree: An experiment with prepost+ algorithm
Parallel processing has turn to be a common programming practice because of its efficiency and thus becomes an interesting field for researchers. With the introduction of multi-core processors as well as general purpose graphics processing units, parallel programming has become affordable. This leads to the parallelization of many of the complex data processing algorithms including algorithms in data mining. In this paper, a study on parallel PrePost+ is presented. PrePost+ is an efficient frequent itemset mining algorithm. The algorithm has been modified as a parallel algorithm and the obtained result is compared with the result of sequential PrePost+ algorithm. 2021, Zarka Private University. All rights reserved. -
Paramagnetic mononuclear oxovanadium(IV) complex as oxidation catalyst
2-Thiophenecarbanicotinic hydrazone is added with equimolar mixture of vanadyl acetyl acetonate in methanol to obtain oxovanadium(IV) complex of 2-thiophenecarbanicotinic hydrazone. Oxovanadium(IV) complex of 2-thiophenecarbanicotinic hydrazone is acted as an effective catalyst in the process. The catalytic reactions were carried under room temperature. The products generated were benzil and furil. The influence of solvent, oxidant and quantity of catalyst has been investigated. Oxovanadium(IV) complex of 2-thiophenecarba-nicotinic hydrazone proves significantly higher catalytic activity towards oxidation of secondary alcohols to ketones. The catalyst was proved to be very effective due to its recovery by simple filteration after completion of the reaction. It was reused several times which suggests that there is no change in the catalytic efficiency. Oxovanadium(IV) complex of 2-thiophenecarbanicotinic hydrazone did not show any leaching during the reaction, confirmed the heterogeneous nature. 2018 Chemical Publishing Co. All Rights Reserved.