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Conversion of alkynes into 1,2-diketones using HFIP as sacrificial hydrogen donor and DMSO as dihydroxylating agent
A metal-free and hypervalent iodine free conversion of internal alkynes into 1,2-diketo compounds has been described. The efficacy of the present protocol rely on the use of HFIP (1,1,1,3,3,3-Hexafluoro-2-propanol) as reducing agent of alkynes and DMSO as dihydroxylating agent of olefins to acquire the desired chemical transformations. The obtained 1,2-diketones were further transformed into useful derivatives. 2020 Elsevier Ltd -
Size Tuning, Phase Stabilization, and Anticancer Efficacy of Amorphous Selenium Nanoparticles: Effect of Ion-Pair Interaction, ?OH Functionalization, and Reuse of RTILs as Host Matrix
Se nanoparticles (NPs) of predominantly amorphous phase (?-Se) have been prepared in room-temperature ionic liquids (RTILs). The effects of ion-pair combination and ?OH functionalization of RTILs on the size and phase stability of Se NPs were investigated. The RTILs used were 1-ethyl-3-methyl imidazolium boron tetrafluoride ([EMIM][BF4]), 1-(2-hydroxyethyl)-3-methyl imidazolium boron tetrafluoride ([EOHMIM][BF4]), and 1-ethyl-3-methyl imidazolium methane sulfonate ([EMIM][MS]). The size of Se NPs@[EOHMIM][BF4] was found to be the smallest (?32 nm), followed by Se NPs@[EMIM][BF4] (?57 nm) and Se NPs@[EMIM][MS] (?60 nm), respectively. Interestingly, the stability studies revealed minimal size variations for Se NPs@[EMIM][MS], followed by Se NPs@[EOHMIM][BF4] and Se NPs@[EMIM][BF4], respectively. The observed trends could be correlated with the strength of interionic interactions in the respective RTILs, as well as their packing order (density). Importantly, the RTILs played the role of a solvent, a stabilizer, and an in situ source of reducing species. Pulse radiolysis study revealed imidazolium-originated radical species-driven formation of Se NPs. Further, anticancer efficacy studies demonstrated the role of NP size, wherein Se NPs@[EOHMIM][BF4] exhibited the highest cancer cell killing, followed by Se NPs@[EMIM][BF4] and Se NPs@[EMIM][MS]. Another significant highlight of this work is the reuse of the spent RTILs for the synthesis of the next batch of Se NPs. 2021 American Chemical Society -
Defect originated photoluminescence tuning of silica nanoparticles prepared by electron beam irradiation and their applications
Considering the imminent importance of Silica (SiO2) nanoparticles (NPs), a highly rapid and one-pot scalable approach is being reported for their preparation. Electron-beam was used to derive the formation of SiO2 NPs, while in situ functionalization was carried out by ?-Cyclodextrin (?-CD). XRD pattern of as prepared ?-CD functionalized SiO2 NPs (i.e., ?-CD@SiO2 NPs) revealed their amorphous nature, while imaging studies showed self-assembling of NPs into a porous structure. UVvisible absorption spectra showed multiple peaks at 233, 323, 390 and 455 nm, which signifies the presence of different kind of defects in the as prepared NPs. An interesting aspect of this work is tuning of the photoluminescent properties of NPs from blue to green by simply varying the absorbed dose. This could be attributed to the formation of a particular kind of defects at a proportionate absorbed dose. These defects act as emission centers (ECs) and were analysed through steady state and time-resolved emission studies. Notably, ?-CD played significant role in influencing the composition of the NPs, whilst enhancing their colloidal stability and quantum yield. The prospective applications of ?-CD@SiO2 NPs were explored in latent fingerprinting and thermosensing. 2020 Elsevier Ltd and Techna Group S.r.l. -
Electron beam mediated synthesis of photoluminescent organosilicon nanoparticles in TX-100 micellar medium and their prospective applications
The inherent advantages of Silicon have made it as one of the most sought-after elements in the field of nanoscience and nanotechnology. Herein, we report an electron-beam induced formation of blue light emitting organosilicon nanoparticles (OSiNPs) in the micellar medium of Triton X-100 (TX-100). The profound role of the micellar medium can be realized from the enhanced colloidal stability as well as photoluminescence (PL) quantum efficiency (from ~9% to ~55%) of as synthesized OSiNPs. Mechanistic investigations revealed the crucial role of hydroxyl radical ([rad]OH) in the formation of OSiNPs. XPS and FTIR studies indicated the presence of siloxane/silicone and silica (SiO2) like units as the major constituents in the NPs. XRD pattern showed the amorphous nature of the NPs, while TEM studies revealed their aggregation. The hydrodynamic size of the NPs was determined to be ~24 nm. Interestingly, the NPs exhibited an excitation-wavelength-dependent PL behaviour, thereby indicating the presence of multiple emission centres (ECs). Detailed investigations based on steady-state as well as time-resolved PL measurements were conducted to analyse these ECs. In addition, pH and temperature-dependent studies were carried out to further substantiate these findings. Moreover, the experimental observations revealed their potential applications in the areas of thermosensing, fingerprinting and cell-imaging. Notably, the internalization of as prepared NPs within cells was evident from the bright fluorescence images obtained from the cytoplasmic region as compared to control cells. This observation also suggests the prospective application of these NPs for image guided drug delivery systems. 2021 Elsevier B.V. -
Leveraging Machine Learning: Advanced Algorithms for Soil Data Analysis and Feature Extraction in Arid and Semi-arid Regions with Expert Systems
India is culturally diverse nation at large. There are two words of symphony one is tradition and second one is inherited agriculture. India has long historical advantage having conventional agricultural practices and the scope for it to dive into day to day life as agriculturist. Happiness shrinks as people grow into modern world current trend of agriculture faces a monument challenge and needs immediate address to survive. Now withstanding with this phrase of human life on earth its necessary to give more importance to soil rather than the existence. Soil health is more paramount in this equation, as it directly influences crop growth and yield. Traditionally, analysing a few key soil properties has been the cornerstone of soil treatment practices. However, this approach often overlooks the complex interplay between various soil characteristics. To overcome the above hurdle present research incorporates the method of multivariate data analysis with selective advanced algorithms in machine learning to find suitability to predict best fit algorithm in real time data sets in arid and semi-arid zones of kolar district in Karnataka. The purpose is to draw the attention of stake holders to leveraging the new technology to deploying them into effective assessment in building expert system to incorporate in regular use on handy devices. This penetrates the results by two extremely good classifications algorithms Decision Tree and Gradient Boosting emerged as winner with 99% accuracy. In contrast, Passive Aggressive and Linear SVC produced below average of 36% accuracy. The ensemble algorithms of SMOTE on Random Forest and Stochastic Decent Gradient produced the acceptable accuracy of 83%. This input helped dynamically to build ready to use expert systems for farmers. The Author(s), under exclusive licence to Springer Nature Singapore Pte Ltd. 2024. -
Sixth-Generation (6G) Mobile Cloud Security and Privacy Risks for AI System Using High-Performance Computing Implementation
The exchange of information from one person to another is called communication. Telecommunication makes it possible with electronic devices and their tools. The scientist Alexander Graham Bell has invented the basic telephone in 1876 in the USA. Telephones now have the new format in the form of mobile phones, which are the primary media for communicating and transmitting data. We are using 5th-generation mobile network standards. Still, there are some requirements for the users that are believed to be solved in the 6th-generation mobile network standards. By 2030, all of the people would be using 6G. The computing model in the cloud is not dependent on either the location or any specific device that would provide the service. It is an on-demand computational service-oriented mechanism. Combining these two technologies as mobile cloud computing provides customized options with more flexible implementations. Artificial intelligence is being used in devices in many fields. AI can be used in mobile network services (MNS) to provide more reliable and customized services to the users, such as network operation monitoring, network operation management, fraud detection, and reduction in mobile transactions and security to the cyber devices. Combining cloud with AI in mobile network services in the 6th generation would improve human beings' lives, such as zero road accidents, advanced level special health care, and zero crime rates in society. However, the most vital needs for sixth-generation standards are the capability to manage large volumes of records and excessive-statistics-fee connectivity in step with gadgets. The sixth-generation mobile network is under development. This generation has many exciting features. Security is the central issue that needs to be sorted out using appropriate forensic mechanisms. There is a need to approach high-performance computing for improved services to the end-user. Considering three-dimensional research methodologies (technical dimension, organizational dimension, and applications hosted on the cloud) in a high-performance computing environment leads to two different cases such as real-time stream processing and remote desktop connection and performance test. By 'narrowing the targeted worldwide audience with a wide range of experiential opportunities,' this paper is aimed at delivering dynamic and varied resource allocation for reliable and justified on-demand services. 2022 Srinivasa Rao Gundu et al. -
Quantum-inspired meta-heuristic approaches for a constrained portfolio optimization problem
Portfolio optimization has long been a challenging proposition and a widely studied topic in finance and management. It involves selecting and allocating the right assets according to the desired objectives. It has been found that this nonlinear constraint problem cannot be effectively solved using a traditional approach. This paper covers and compares quantum-inspired versions of four popular evolutionary techniques with three benchmark datasets. Genetic algorithm, differential evolution, particle swarm optimization, ant colony optimization, and their quantum-inspired incarnations are implemented, and the results are compared. Experiments have been carried out with more than 10 years of stock price data from NASDAQ, BSE, and Dow Jones. This work proposes several enhancements to allocate funds efficiently, such as improved crossover techniques and dynamic and adaptive selection of parameters. Furthermore, it is observed that the quantum-inspired techniques outperform the classical counterparts. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024. -
A brief review of portfolio optimization techniques
Portfolio optimization has always been a challenging proposition in finance and management. Portfolio optimization facilitates in selection of portfolios in a volatile market situation. In this paper, different classical, statistical and intelligent approaches employed for portfolio optimization and management are reviewed. A brief study is performed to understand why portfolio is important for any organization and how recent advances in machine learning and artificial intelligence can help portfolio managers to take right decisions regarding allotment of portfolios. A comparative study of different techniques, first of its kind, is presented in this paper. An effort is also made to compile classical, intelligent, and quantum-inspired techniques that can be employed in portfolio optimization. 2022, The Author(s), under exclusive licence to Springer Nature B.V. -
A method to secure FIR system using blockchain
In India, we can see that technology has touched in every aspect of our life. There exist technology in all the fields e.g. education, agricultural, business, government etc. and we can also understand how beneficial it is, as it saves the time, money and human power. In spite of being technologically advanced, the system lacks in security perspective. When we talk about today, India has moved to the era of digitalization after the launch of the campaign Digital India, the Indian Police Department has replaced the manual system with the centralized online process to register the complaint. The main objective of this paper is to provide a method to secure the FIR system using blockchain technology. This introduces to the essential principal of blockchain technology and its future in the police department of India. Blockchain technology will also explain to protect the FIR from the malfeasance. BEIESP. -
Interplay between personality and attitude towards emotions with creative self concept among young adults
Creative self-concept, intimately intertwined with the personality traits and plays a pivotal role in shaping individuals behavioral tendencies. Personality traits are largely responsible to influence how people perceive and navigate their creative abilities and self-expression. Moreover, attitudes towards emotions are another key facet of ones psychological landscape, impacting their inclination to perceive, process, and manage emotional experiences. Keeping this view, the present research attempts to explore the interconnectedness of creative self-concept, personality traits, and attitudes towards emotions among young adults, as well as focuses on exploring the predictors of creative self concept. For this purpose participants consisted of 200 young adults with a mean age of 21.20 years. Statistical outcomes revealed that creative self concept is a significant positive correlate of openness, conscientiousness, extraversion, agreeableness, attitude towards sadness, and attitude towards fear. Additionally, stepwise multiple regression analysis confirmed that openness (R2 = 27%), neuroticism (R2 = 2%) and attitude towards sadness (R2 = 2%) emerged as the significant predictors of creative self concept. Findings from the current research concludes that for young adults to have self-perception in the realm of creativity, personality traits and attitude towards emotions are significant contributing factors. By recognizing and employing these connections, individuals, educators, counselors, and practitioners can contribute to the cultivation of creativity and personal development. The Author(s) 2024. -
Knowledge or Personality: An Empirical Analysis of Behavioural Finance and Investor Cognitive Biases
This research attempts to analyze to what extent knowledge and tactics or enduring personality traits predict investor behaviour and cognitive biases in portfolio investment. This study is based on exploring a wide-ranging dataset: responses to a questionnaire survey together with transactional data of the same individual customers of an Indian stock company. From the questionnaire survey, the authors estimate measures of domain-general personality traits, such as the big five, as compared to the knowledge, financial literacy, competency, and attitude specific to investor equity trading. The results show the dominance of knowledge and tactics measures over personality-related measures when predicting nine different dependent variables of investment performance, investor cognitive biases, and portfolio investment activity. This research concludes with the discussion of the findings and with insights into theory and managerial implications. Copyright 2022, IGI Global. -
Metaheuristic Machine Learning Algorithms for Liver Disease Prediction
In machine learning, optimizing solutions is critical for improving performance. This study explores the use of metaheuristic algorithms to enhance key processes such as hyperparameter tuning, feature selection, and model optimization. Specifically, we integrate the Artificial Bee Colony (ABC) algorithm with Random Forest and Decision Tree models to improve the accuracy and efficiency of disease prediction. Machine learning has the potential to uncover complex patterns in medical data, offering transformative capabilities in disease diagnosis. However, selecting the optimal algorithm for model optimization presents a significant challenge. In this work, we employ Random Forest, Decision Tree models, and the ABC algorithmbased on the foraging behaviours of honeybeesto predict liver disease using a dataset from Indian medical records. Our experiments demonstrate that the Random Forest model achieves an accuracy of 85.12%, the Decision Tree model 76.89%, and the ABC algorithm 80.45%. These findings underscore the promise of metaheuristic approaches in machine learning, with the ABC algorithm proving to be a valuable tool in improving predictive accuracy. In conclusion, the integration of machine learning models with metaheuristic techniques, such as the ABC algorithm, represents a significant advancement in disease prediction, driving progress in data-driven healthcare. 2024, Iquz Galaxy Publisher. All rights reserved. -
Taste of your Hometown: Evoking Nostalgia through the Diner Space in Midnight Diner
Restaurant spaces are seen as a space that intersects between the personal and the cultural. This paper looks at a Japanese TV series, Midnight Diner, an adaptation of a Manga by Yaro Abe, where a tiny, not-so-popular restaurant in one of the back lanes in Tokyo serves food from midnight to 7 a.m. This show makes several meaningful connections between food, memory, and space as the customers come with specific food cravings, and the Master (the owner-chef of the Diner) is happy to customize. The diner space transcends the traditional meaning of a diner that not only serves food to satiate hunger but is an experience that evokes nostalgia for their home and their loved ones. The wistfulness in the lives of the customers for their home, people, and home-cooked food finds a release in the diner. The space of the diner acquires different meanings, as do the dishes the customer relishes. Thus, the paper explores the diner space as a symbolic space where each episode introduces a new character, a new story, and the past they deal with while the food is prepared and consumed on screen. The taste, smell, texture, and ingredients of the food in this diner stimulate the senses, and this space acquires emotional meaning for everyone stepping in. 2023, University of Malaya. All rights reserved. -
Volatility in Indian stock markets during COVID-19: An analysis of equity investment strategies
The aim of the paper is to evaluate the impact of novel COVID-19 on the returns and volatility of Indian stock markets with special reference to equity investment strategies of the Bombay Stock Exchange. For the purpose of evaluating the impact, the study has applied GARCH. The research has considered a time frame from March 2015 to January 2021. Prior to implementing GARCH model, pre-estimation tests (i.e., augmented Dickey-Fuller and ARCH-Lagrange multiplier) were conducted. Outcomes clearly indicate that the returns during the crisis for all the strategy indices have been negative, which means that the COVID-19 outbreak resulted in massive losses. Additionally, 'during crisis' period showed an increase in volatility for all the strategy indices depicting that the pandemic has a long-lasting effect and will take time to fade off. This research will help the investors in the investment decision process by giving them insights about the different strategies. 2021. -
Usability Evaluation and Classification of mHealth Applications for Type 2 Diabetes Mellitus Using MARS and ID3 Algorithm
The rapid growth of mHealth applications for Type 2 Diabetes Mellitus (T2DM) patients self-management has motivated the evaluation of these applications from both the usability and user point of view. The objective of this study was to identify mHealth applications that focus on T2DM from the Android store and rate them from the usability perspective using the MARS tool. Additionally, a classification of these mHealth applications was conducted using the ID3 algorithm to identify the most preferred application. The usability of the applications was assessed by two experts using MARS. A total of 11 mHealth applications were identified from the initial search, which fulfilled our inclusion criteria. The usability of the applications was rated using the MARS scale, from 1 (inadequate) to 5 (excellent). The Functionality (3.23) and Aesthetics (3.22) attributes had the highest score, whereas Information (3.1) had the lowest score. Among the 11 applications, mySugr had the highest average MARS score for both Application Quality (4.1/5) as well as Application Subjective Quality (4.5/5). Moreover, from the classification conducted using the ID3 algorithm, it was observed that 6 out of 11 mHealth applications were preferred for the self-management of T2DM. 2022 by the authors. Licensee MDPI, Basel, Switzerland. -
Multi-Criteria Usability Evaluation of mHealth Applications on Type 2 Diabetes Mellitus Using Two Hybrid MCDM Models: CODAS-FAHP and MOORA-FAHP
People use mHealth applications to help manage and keep track of their health conditions more effectively. With the increase of mHealth applications, it has become more difficult to choose the best applications that are user-friendly and provide user satisfaction. The best techniques for any decision-making challenge are multi-criteria decision-making (MCDM) methodologies. However, traditional MCDM methods cannot provide accurate results in complex situations. Currently, researchers are focusing on the use of hybrid MCDM methods to provide accurate decisions for complex problems. Thus, the authors in this paper proposed two hybrid MCDM methods, CODAS-FAHP and MOORA-FAHP, to assess the usability of the five most familiar mHealth applications that focus on type 2 diabetes mellitus (T2DM), based on ten criteria. The fuzzy Analytic Hierarchy Process (FAHP) is applied for efficient weight estimation by removing the vagueness and ambiguity of expert judgment. The CODAS and MOORA MCDM methods are used to rank the mHealth applications, depending on the usability parameter, and to select the best application. The resulting analysis shows that the ranking from both hybrid models is sufficiently consistent. To assess the proposed frameworks stability and validity, a sensitivity analysis was performed. It showed that the result is consistent with the proposed hybrid model. 2022 by the authors. Licensee MDPI, Basel, Switzerland. -
Antecedents and Trajectories of the Child and Adolescent Mental Health Crisis: Assimilating Empirically Guided Pathways for Stakeholders
Importance: Amid and following the COVID-19 pandemic, there has been a growing focus on understanding the underlying etiology of the mental health crisis in children and youth. However, there remains a dearth of empirically driven literature to comprehensively explore these issues. This narrative review delves into current mental health challenges among children and youth, examining perspectives from both pre-pandemic and pandemic periods. Observations: Research highlights reveal concerning statistics, such as 1 in 5 children experience mental health disorders. The pandemic exacerbated these issues, introducing stressors such as job losses and heightened anticipatory anxiety. Race relations have emerged as a significant public health concern, with biases impacting students, particularly affecting Asian, black, and multiracial individuals. Substance use trends indicate a rise in overdose deaths, particularly among adolescents, with cannabis use linked to adverse outcomes. Increased screen time and income disparities further compound mental health challenges. Conclusions and Relevance: Proposed public health mitigation strategies include improving access to evidence-based treatments, implementing legislative measures for early identification and treatment of developmental disorders, and enhancing suicide prevention efforts. School-based interventions and vocational-technical education are crucial, alongside initiatives targeting sleep hygiene, social media usage, nutrition, and physical activity. Educating health care professionals about both physical and mental health is essential to address workforce burnout and effectively manage clinical complexities. 2024 Physicians Postgraduate Press, Inc. -
Framework to analyze customer's feedback in smartphone industry using opinion mining
In the present age, cellular phones are the largest selling products in the world. Big Data Analytics is a method used for examining large and varied data, which we know as big data. Big data analytics is very useful for understanding the world of cellphone business. It is important to understand the requirements, demands, and opinions of the customer. Opinion Mining is getting more important than ever before, for performing analysis and forecasting customer behavior and preferences. This study proposes a framework about the key features of cellphones based on which, customers buy them and rate them accordingly. This research work also provides balanced and well researched reasons as to why few companies enjoy dominance in the market, while others do not make as much of an impact. 2018 Institute of Advanced Engineering and Science. All rights reserved. -
Framework to analyze customer's feedback in smartphone industry using opinion mining
In the present age cellular phones are the largest selling products in the world. Big Data Analytics is a method used for examining large and varied data, which we know as big data. Big data analytics is very useful for understanding the world of cellphone business. It is important to understand the requirements, demands, and opinions of the customer. Opinion Mining is getting more important than ever before, for performing analysis and forecasting customer behavior and preferences. This study proposes a framework about the key features of cellphones based on which, customers buy them and rate them accordingly. This research work also provides balanced and well researched reasons as to why few companies enjoy dominance in the market, while others do not make as much of an impact 2018 Institute of Advanced Engineering and Science. All rights resented. -
Assessment of ML techniques and suitability to predict the compressive strength of high-performance concrete (HPC)
Using industrial soil waste or secondary materials for making cement and concrete has encouraged the construction industry because it uses fewer natural resources. High-performance concrete (HPC) is recognized for its exceptional strength and sturdiness compared to conventional concrete. Accurate prediction of the compressive concentration of HPC is vital for optimizing the concrete mix design and ensuring structural integrity. Machine learning (ML) techniques have shown promise in predicting concrete properties, including compressive strength. This research focuses on various ML techniques for their suitability in predicting the compressive dilution of HPC. In this research, the Extended Deep Neural Network (EDNN) technique is used to analyze the strengths, limitations, and performance of different ML algorithms and identify the most effective methods for this specific prediction task. However, there is a problem with accuracy. Therefore, our research approach is the EDNN-centred strength characteristics prediction of HPC. In the suggested approach, data is initially acquired. Afterward, the data is pre-processed through normalization and removing missing data. Thus, the data are fed into the EDNN algorithm, which forecasts the strength characteristics of the particular mixed input designs. With the Multi-Objective Jellyfish Optimization (MOJO) technique, the value of weight is initialized in the EDNN. The activation function is the Gaussian radial function. In the experimental analysis, the implementation of the suggested EDNN is evaluated to the performance of the prevailing algorithms. When compared to current research methodologies, the proposed method performs better in this regard. The Author(s), under exclusive licence to Springer Nature Switzerland AG 2024.