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Na+ doped CuO: A new paradigm electrode material for high performance supercapacitors
This study investigates the influence of sodium doping on the properties of cupric oxide (CuO) thin films synthesized via spray pyrolysis. Comprehensive characterization was conducted using X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDAX), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FESEM), Raman spectroscopy, Hall effect measurements, and electrochemical studies. All films exhibited p-type conductivity, with an optical band gap variation from 1.53 to 1.73 eV. XRD analysis confirmed the dominance of monoclinic CuO, with minor phases of Cu2O and Cu4O3. EDAX and XPS verified the incorporation of Cu, O, and Na elements. FESEM revealed a densely packed morphology with uniform particle distribution and rough surfaces in the electrically optimized film. The Raman spectra of doped samples showed increased intensity and sharpness, attributed to Na + ion-induced polarizability enhancement. Hall effect measurements indicated a tenfold decrease in carrier concentration and a more than tenfold increase in mobility upon sodium doping. Films doped with 4 at.% sodium exhibited the lowest resistivity. Additionally, Na doping enhanced the electrochemical performance of CuO. These findings demonstrate that sodium doping significantly enhances the electrical, optical and electrochemical properties of CuO thin films, making them suitable for applications in optoelectronic devices and supercapacitors. 2024 Elsevier Ltd and Techna Group S.r.l. -
Study of the structural, optical, electrical and electrochemical properties of copper oxide thin films synthesized by spray pyrolysis
In our present study we focus on characterizing copper oxide (CuO) thin films synthesized at various substrate temperatures and to assess the electrochemical performance of the optimized sample. The spray pyrolysis method was used to fabricate CuO thin film samples, with the substrate temperatures ranging from 250 to 400C. The coatings underwent characterization through different analytical techniques, including X-ray diffraction, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, field emission scanning electron microscopy, Raman spectroscopy, and Hall effect measurements. All the thin film samples were confirmed to have a monoclinic phase. The presence of Cu=O was confirmed by Raman spectroscopy. All the samples exhibited P type conductivity except the one synthesized at 400C. Galvanostatic chargedischarge studies revealed a pseudocapacitive nature for the optimized sample synthesized at 350C. The symmetrical charging and discharging curves imply excellent material reversibility, indicating long-term cyclic stability. The Nyquist plot exhibited a semicircle at high frequencies, representing the materials intrinsic resistance and a linear behavior at low frequencies, depicting the ion transfer resistance. The electrode demonstrated favorable electrochemical properties and potential use of the material in supercapacitor applications. 2024, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature. -
Effect of Substrate Temperature on Properties of Copper Oxide Thin Films Coated by Spray Pyrolysis
Copper oxide shows a wide range of optical as well as electrical characteristics depending upon the preparation parameters. This wide range turning capability makes it a preferable candidate for effective use in various application fields like optical filters, light energy harvesting, gas sensing and semiconducting device fabrication. Spray pyrolysis technique with manual spray system was used to deposit a thin layer of copper oxide on glass substrates at temperatures of 300oC, 350o C, and 400o C. X-ray diffraction analysis shows that all the thin films obtained have monoclinic phase. A change of grain size from 15 nm to 25 nm was observedas the substrate temperature was varied from 300oC to 400o C.The Hall coefficient analysis confirms p-type conductivity in films obtained at 300o C and 350oC and N type conductivity with high resistivity for film coated at 400o C. Optical band gap increases from 1.75 to 2.17 eV with the increase in substrate temperature due to energy band tailing. 2023, Books and Journals Private Ltd.. All rights reserved. -
Yoga Posture Recognition Using Image Processing
Yoga is an ancient Indian practice that focuses on maintaining balance through various techniques like asanas and meditation. Traditional Indian yoga involves physical postures, regulated breathing, meditation, and relaxation techniques. The practice, rooted in physical, mental, and spiritual disciplines, offers numerous benefits. In this paper, we present an approach for classifying four prominent yoga poses: Goddess Pose (Utkata Konasana), Tree Pose(Vrksasana), Dead Body Pose (Savasana), and Downward Dog Pose (Adho Mukha Svanasana) using image processing techniques. The proposed methodology leverages sophisticated feature extraction techniques that analyse the posture's shape to help capture the details of the posture like the centroid, eccentricity, convex hull, etc. The subsequent classification process employs Support Vector Machines (SVM) enabling accurate categorization based on the extracted features. This blend of traditional wisdom and modern technology offers a promising tool for automating posture recognition, benefiting yoga practitioners and instructors, and can be extended to other real-life scenarios like odd posture detection. 2024 IEEE. -
Detection of Disease in Mango Trees Using Color Features of Leaves
The goal has been to detect disease in mango trees. This paper compares different approaches to extract color features and check the accuracy and applicability for mango trees. The paper proposes variations which helped in increasing the accuracy of features extracted for mango trees: firstly, a customized method of splitting leaf into layers while doing K-means clustering, and secondly, segmenting the region of interest to blocks to help in applying statistical functions more accurately over a region. 2020, Springer Nature Singapore Pte Ltd. -
Pseudo Color Region Features for Plant Disease Detection
This study reports a novel pseudo color region features for a computer vision system for the identification of diseases in Tomato Plants. The HSV based algorithm identifies eccentric and non- eccentric dots, spots, patches and region of different pseudo colors. Proposed method uses region properties and creates an enhanced and effective feature vector for plant disease detection. The features are more intuitive for humans to understand and help in tuning the underlying Artificial Intelligence Model better. The algorithm uses a scalable data structure to store regions counts using a hash function. It has wide application in the Computer Vision domain. 2020 IEEE. -
Development and Analysis of Current Collectors for Proton Exchange Membrane Fuel Cells
Hydrogen fuel cells are gaining popularity in power-consuming devices due to their zero-emission characteristics. However, ohmic resistance, which arises from the resistance to electron flow through the electrodes and external circuit, can cause reduced efficiency and voltage drops in a fuel cell. This research aims to develop current collector plates for proton exchange membrane fuel cells with optimal design, high electrical conductivity, and thermal conductivity to mitigate ohmic resistance. Six different designs and five different materials-copper, brass, aluminum, stainless steel 316, and stainless steel 304 were considered for this purpose. The study involved experimental electrical conductivity and fuel cell performance tests to identify the best material and design for the current collector. Results indicated that brass and copper exhibited the least resistivity and favorable material characteristics. Consequently, all six current collector plate designs were developed using brass and copper with various machining and finishing processes. Performance testing on a fuel cell test station revealed that brass current collector plate design 5, featuring open ratios, demonstrated superior performance. Ultimately, the optimum design and material selection of the current collector plates have led to the development of fuel cells with reduced ohmic resistance and improved overall performance. 2024, Politechnika Lubelska. All rights reserved. -
Novel Applications of Graphene and its Derivatives: A Short Review
Graphene, a layered allotropic form of graphitic carbon, has fascinated the scientific world since its discovery. Its unique structural, physical, chemical, mechanical, and electrical properties find application in many areas. Because of its large surface area and its apt electrical property, it is used in electromagnetic interference shielding. With excellent carrier mobility, it is used for sensing purposes. Mechanical strength and elastic properties coupled with its lightweight make graphene a promising material as a supercapacitor. The 2-dimensional structural properties of the graphene layers can be used for the purification treatment of water and gas. The number of research in graphene applications is increasing every day, showing the importance and excellency of graphene properties. This short review provides a comprehensive understanding of graphene's properties and progress in electromagnetic interference shielding, sensors, water treatment, energy production, storage, and conversion applications such as supercapacitors, fuel cells, solar cells and electrocatalysts. 2023 Bentham Science Publishers. -
The role of switching cost in the e-service recovery framework among banking customers
Purpose: The emergence of tech-driven initiatives in retail banking has created a vast spectrum of system-related service failures; hence, e-service recovery quality is of prime importance to banks to ensure e-service recovery satisfaction. However, e-service satisfaction is dependent on the ease of moving from one service provider to the other; thus, switching costs assume great significance. This study aims to probe the moderating role of switching cost on e-service recovery satisfaction by exploring e-service recovery quality antecedents. Design/methodology/approach: A measurement model is suggested in the contextual settings of the Indian banking scenario and is estimated using structural equation modeling. Responses from 399 e-banking customers, who had experienced a service failure, were sought using a five-point Likert scale. Findings: The result affirms that recovery expectation is the most significant predictor of e-service recovery satisfaction, and that switching cost moderates the relation between e-service recovery quality and e-service recovery satisfaction. Practical implications: The study highlights the high relevance of switching costs in the e-banking context and emphasizes investment in marketing strategies and campaigns to do away with switching intentions. It also highlights the relevance of recovery expectations as an antecedent of e-service recovery quality and thus stresses the need to satisfactorily address the same in the e-service recovery process. Originality/value: This study contributes to the e-service recovery satisfaction literature in the banking context by empirically validating the moderating role of switching cost. It also identifies the critical antecedents of banking e-service recovery quality. 2021, Emerald Publishing Limited. -
Visible light photodegradation of organic dyes using electrochemically synthesized MoO3/ZnO
In this study, flake-like MoO3-ZnO composite was prepared using a simple and robust electrochemical setup. The composite was characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, elemental analysis, X-ray photoelectron spectroscopy, thermogravimetric analysis, photoluminescence, zeta potential analysis, and electrochemical impedance study. The modified ZnO shows a remarkable catalytic activity towards the photodegradation of three potentially hazardous dyes, malachite green, crystal violet, and methylene blue. More than 95% of both malachite green and crystal violet degraded within 140 min under visible light irradiation. Scavenger studies reveal that OH radicals produced by the photo-separated charges on MoO3-ZnO are responsible for the degradation of all three dyes. The photoactive charge carriers show less recombination rate as evidenced by the photoluminescence spectrum due to the interparticle charge migration process. This work suggests a new versatile procedure for the synthesis of MoO3-ZnO composites and establishes its photocatalytic efficacy under visible light with three common pollutant dyes found in wastewater. Graphical Abstract: [Figure not available: see fulltext.] 2021, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature. -
Destination image and perceived meaningfulness for visitor loyalty: A strategic positioning of Indian destinations
The purpose of this study is to empirically test and validate a multi-dimensional structure of In-loco Destination Image and perceived meaningfulness using an integrated model of visitor loyalty. The model was tested using data collected from responses of foreign tourists visiting India (n = 246). The results identified six dimensions of In-loco Destination Image: Amenities, Attractions, Leisure, Culture, Support Systems, and Hospitality. In addition, the investigation observes that of the identified dimensions of perceived meaningfulness, the spiritual and societal dimensions contribute more to perceived meaningfulness than the physical well-being aspect. Further, the exploration estimated the theoretical framework developed using structural equation modelling and established the mediating role of perceived meaningfulness in developing visitor loyalty from In-loco Destination Image. The studys observations helped identify three positioning approaches, namely objective, subjective, and combined, offering suggestions to destination marketers to effectively reposition Indian destinations. 2022 Informa UK Limited, trading as Taylor & Francis Group. -
Electrochemical synthesis, photodegradation and antibacterial properties of PEG capped zinc oxide nanoparticles
The effect of surfactant and dopant on the properties of zinc oxide nanoparticles were studied by preparing polyethylene glycol (PEG) capped ZnO and tungsten doped PEG capped ZnO nanoparticles via the electrochemical method. These nanoparticles were characterized using X-Ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Ultraviolet Diffuse Reflection Spectroscopy (UV-DRS), Scanning Electron Microscopy (SEM) and Electron Dispersive Analysis of X Rays (EDAX). The photocatalytic degradation of malachite green dye using these nanoparticles was studied under visible light. The effects of various reaction parameters like dye concentration, catalyst concentration, pH and time were studied to optimize the photodegradation reaction. Reusability of these nanoparticles was studied and no significant change was observed in the degradation efficiency of PEG capped ZnO till the fourth cycle, while there was a gradual decrease in the degradation efficiency of tungsten doped PEG capped ZnO. Langmuir- Hinshelwood kinetic model well describes the photodegradation capacity and the degradation of malachite green follows pseudo-first order kinetics.Photocatalytic studies reveal that PEG capping increases the degradation properties of ZnO while tungsten doping decreases the extent of PEG capping and has a detrimental effect on the degradation properties of ZnO. The prepared nanoparticles exhibit significant antibacterial properties against gram-positive Bacillus cereus and gram-negative Escherichia coli bacterial strains by agar well diffusion method. 2018 Elsevier B.V. -
Unveiling the Necropolitics of Oil on Migrant Bodies in Deepak Unnikrishnans Birds
Oil played a significant role in fuelling the sociopolitical and economic development of Middle Eastern nations, attracting mass migration from South Asian nations. The article draws a nexus between the energy dynamics and labour exploitation within these petroleum-rich nations. It undertakes a close reading of the text Birds from Deepak Unnikrishnans novel Temporary People as it depicts the lives of migrant labourers who navigate an exploitative petro-capitalist system. The fictional text employs a narrative strategy juxtaposing elements of magic and realism, opening up a space for multilayered marginalised voices. The article engages with energy theories and interweaves Mbembes theory on necropolitics to grasp oils sovereign influence in delineating the boundaries between life and death in migrant lives. The surplus energy generated through fossil fuel extraction contributes to notions of boundless growth, coupled with technical and economic progress, which conceals the intensive manual labour underpinning these petrocultures. The magical property alluded to oil and the spectral absence of labour in the socio-cultural imagination co-constructs an exploitative and dehumanising labour regime for migrants. The migrant body is kept alive, and their existence is contingent upon the instrumental value of their labouring body, which constructs them as easily disposable and expendable as they are positioned outside the formal boundaries of citizenship. 2024 South Asian University. -
The Champions Boat League A Race to Commercialise Festival Cultures
[No abstract available] -
Language and identity formations of second-generation migrants in Deepak Unnikrishnan's temporary people
Decades of migration to the Gulf nations have led to the existence of second-generation migrants who were born and raised in migrant lands. The chapter uses the novel Temporary People (2017) by Deepak Unnikrishnan as a primary text to explore the role language plays in second-generation migrant identity formations and the assimilation process. The national language, Arabic, is situated in the specific socio-political context, a site where ideologies and power relations are reproduced. By identifying a gap in the language education policy, it reveals how migrant's inability to communicate in the Arabic language has complex implications on their identities and notions of belongingness. The chapter explores language's power to naturalize norms and hierarchical structures within society that can hinder the assimilation process and highlights the migrant-citizen divide. It shows how notions of temporariness and Othering in migrants are inherent within the language politics of the land. The chapter reaffirms language-identity relations and points to revaluating migrant language policies. 2023, IGI Global. All rights reserved. -
Modelling and analysis of split parallel hybrid electric vehicle based on 14 degrees of freedom
The paper studies the scope, performs the modelling and validation for conversion of any Convetional Vehicle to a Split Parallel Hybrid Electric Vehicle. The introduction of a smart Energy Management System for sucha setup is also evaluated. The EMS enables load sharing between the IC Engine and the Traction motor based on the gradient of the road. The gradient analysis is performed using the GPS based road gradient database. For the accurate modelling and the dynamic analysis of the designed model the performance of the vehicles Degrees of Freedom (DoF) for the variation in steering angle is analyzed. 14 DoF parameters are considered and the designed vehicle is subjected to variation in steer angle followed by the analysis on the response of the DoF parameters. BEIESP. -
Fuzzy based Controller for Bi-Directional Power Flow Regulation for Integration of Electric Vehicles to PV based DC Micro-Grid
Utilization of Electric Vehicle as an auxiliary power source to a DC micro-grid for active power regulation is examined here. This paper focus on development of a Fuzzy based controller capable of regulating the bi-directional active power flow between a 10 kW DC Micro-grid and an Electric Vehicle. The system enables to balance the load on grid by performing peak shaving during peak hours and valley filling during off-peak hours. The load curve of Bangalore city for a typical day was taken as the reference and was used to implement the power flow control. The DC grid was designed for a 10 kW PV based micro-grid. The integrated DC micro-grid was simulated on MATLAB/Simulink platform and the obtained characteristics demonstrate that the power flow from grid to vehicle and vehicle to grid during the peak and off-peak periods respectively. The auxiliary battery pack was stressed only to 10.7 % of its 1C-rating leaving scopes for higher level power transmission possible between the systems. 2019 IEEE. -
Taylor series method in TDOA approach for indoor positioning system
Localisation technologies have always remained in the limelight of positioning-science as researchers have ever shown keen interest to know the exact positions of things. Ultrasonic sensors are mainly used for localisation of mobile robots since they provide high accuracy. This paper presents Taylor Series Method in Time Difference of Arrival approach using ultrasonic sensors.Signals are send from the sensors periodically. The time difference of arrival of signals from the ultrasonic sensors is used by the receiver unit to estimate the location of the mobile unit. The equations formed by using Time Difference of Approach are solved using Taylor Series Method. Taylor Series Method provides a more accurate result since they give less error compared to other methods and they ignore the measurement errors. 2019 Insitute of Advanced Engineeering and Science. All rights reserved. -
IoT Based Water Management Using HC-12 and Django
Water is one of the important needs for a human being. Life on Earth is possible due to the presence of water on its surface. Even though 71% of Earth's surface is covered with water, the availability of water in certain areas is very less. So, the people in these areas must reserve water for ensuring a steady availability. These problems can be rectified with the help of Internet of Things (IOT). IOT is a global infrastructure with certain standards and communication protocols by which virtual and physical things can interact and exchange data by connecting to each other. In this paper, we propose a system for monitoring the availability of water, based on the water level in the storage system. Water level is measured with the help of a waterproof ultrasonic sensor and when the level reaches a threshold value, a notification is sent to the user or to the vendor to take the necessary action. The live feed data is sent to a relational database for storing and analyzing the data to predict when the water will run out, and to make sure that the water storage system gets refilled before that point of time. After processing the raw data from the sensors, the system can generate a fusion chart that can show or indicate the amount of water inside each storage system. With this, the user can have an idea of how much water is left in each of the storage system. The main aim of the proposed system is to showcase the functionalities and uses of different sensors and modules used in an IOT based system with the application of Wireless Sensor Network (WSN). In this present scenario, the world is filled with data both relevant and irrelevant, wherein the data for predicting a water crisis is less. So, through the proposed system we are generating a dataset for the prediction of a water crisis in an organization or a community. 2019 IEEE. -
Environmental sensors: Safeguarding the ecosystem by monitoring sanitary pad disposal
This chapter focuses on the applications of environmental sensors in general and their role in identifying and addressing the issues related to the improper disposal of sanitary pads, which is a growing concern. It also gives an overview of the pollutants associated with it, and the role that environmental sensors can play in mitigating this problem. By harnessing the power of advanced sensing technologies, we can gain a better understanding of the environmental impact of sanitary pad disposal and work towards sustainable solutions. This chapter aims to provide valuable insights and guidance for researchers and practitioners working to create a cleaner and healthier environment and generate self-awareness for individuals in safeguarding ecosystem. 2024, IGI Global. All rights reserved.