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Effect of Copper and Cobalt Metal Complex Redox Mediator Based Xanthan Gum Gel Electrolyte Materials on Performance of Dye Sensitized Solar Cells
In this study, we report the first application of (4-(tert-butyl) benzyl or 4-methyl benzyl)-substituted 2-(pyridin-2-yl)-1H-benzo[d]-imidazole coordinated copper and cobalt redox shuttles Cu [((tbb) pbi)2]+1/+2, Cu [(mbpbi)2]+1/+2, Co [((tbb) pbi)3]+2/+3 and Co [(mbpbi)3]+2/+3 based xanthan gum gel electrolytes (XGE-1, XGE-2, XGE-3 and XGE-4) in fabrication of Dye sensitized solar cells. Interestingly, XGE-1 and XGE-2 obtained higher efficiency of 4.08 and 3.04 % under 1sun illumination. Specifically, highly donor moiety 4-(tert-butyl)benzyl)-substituted (on N?H position) 2-(pyridin-2-yl)-1H-benzo[d]-imidazole ligands coordinated, Cu [((tbb) pbi)2]+1/+2 gel electrolyte achieved best performance due to its appropriate redox potential of 0.80 V versus Normal Hydrogen Electrode. This high performance also confirmed with the interfacial studies of the devices. As per the computational results, the copper redox mediators conquered lower reorganization energy and free energy about (0.11-0.20 & 0.180.27 eV) due to the effect of ligands structure. Overall, Cu [((tbb) pbi)2]+1/+2 act as redox shuttle for highly proficient DSSCs. 2022 Wiley-VCH GmbH. -
Effect of Coriolis force on Rayleigh-Bard convection with internal heat generation
The objective of this paper is to analyze the influence of the Coriolis force and internal heat source on Rayleigh-Bard convection in a Boussinesquian fluid of depth d. A linear theory which is oriented towards the normal mode analysis technique is used for this mono-diffusive convection in order to find the criteria for the onset of Rayleigh-Bard convection. The eigenvalue of the said problem was obtained by the use of the Galerkin method in the cases of rigid-rigid, rigid-free, and free-free velocity boundary combinations considering the isothermal and adiabatic temperature boundaries that determine the stability of the system. The effects of various parameters, Taylor number and the internal Rayleigh number are put under consideration only for stationary convection. Treating Taylor number as a critical parameter, shown that it plays a major role in stabilization of the system in case of any particular infinitesimal disturbance. The destabilization of the system has been possible with rotation by treating internal Rayleigh numbers as a critical parameter since the increase in values of the internal Rayleigh number advances the onset of convection. Oscillatory convection seems highly improbable as the scaled frequency of oscillation remains less than 0 for all combinations of Prandtl number, internal Rayleigh number, and Taylor number. 2019, Accent Social and Welfare Society. All rights reserved. -
Effect of corporate restructuring on shareholder's value in the information technology sector /
International Review of Research in Emerging Markets and the Global Economy, Vol.1, Issue 1, pp.182-188, ISSN No: 2311-3200. -
Effect of Coupled Microstructural Characteristics of Catalyst Layer on High Temperature: Proton Exchange Membrane Fuel Cell Performance
The widespread adoption of High Temperature-Proton Exchange Membrane Fuel Cells (HT-PEMFC) in commercial applications is limited by their performance and durability compared to conventional energy sources. A key factor affecting these cells is the sluggish oxygen reduction reaction (ORR) at the cathode catalyst layer (CL). Optimizing the structural parameters of the cathode CL can enhance cell performance and longevity. Current research on these parameters is mostly descriptive, lacking numerical evidence to quantify their impact. This study develops a three-dimensional, non-isothermal HT-PEMFC numerical model to investigate the sensitivities of coupled structural parameters of the cathode CL, including Pt loading, CL thickness, and Pt particle diameter, at three levels. The orthogonal/Taguchi approach quantitatively assesses the impact of these parameters. The study reveals that Pt loading significantly affects cell voltage and cathode overpotential, while Pt diameter influences the homogeneity of overpotential distribution. The dominant impact of a single parameter decreases at higher current densities, necessitating careful analysis of trade-offs between different structural characteristics to maximize performance. These findings offer valuable insights for future experimental studies to enhance cell performance through adjustments to cathode catalyst characteristics. 2024 The Electrochemical Society (ECS). Published on behalf of ECS by IOP Publishing Limited. All rights, including for text and data mining, AI training, and similar technologies, are reserved. -
Effect of COVID-19 on ETF and index efficiency: evidence from an entropy-based analysis
We examine the informational efficiency of domestic equity ETFs vis-a-vis their underlying market indices during the COVID-19 pandemic. To do so, we employ a multiscale entropy-based methodology. Our findings indicate that the informational efficiency of all ETFs as well as the indices fall sharply during the COVID induced market crash in February-March 2020. Having said so, we find disproportionate deterioration in market efficiency of ETFs and indices pertaining to USA and Canada as compared to those of China, Hong Kong and Taiwan. Interestingly, ETFs and indices pertaining to certain developed markets were found to be less efficient than their emerging market counterparts even during the pre-covid timeline. Lastly, there is a discernible difference between the efficiency of ETFs vis-a-vis their underlying indices. These findings should nudge investors to exercise caution while dealing with ETFs, for domestic ETFs do not exactly mimic the dynamics of their underlying indices. 2021, Academy of Economics and Finance. -
Effect of different base isolation techniques in multistoried rc regular and irregular building
Base confinement system for a structure is acquainted to decouple the building structure from possible movement incited by the movement of the seismic tremor, keeping the building superstructures from retaining the quake vitality. Base isolator increases the regular time period of the general structure and diminishes its shear increasing speed reaction to the seismic movement. In this explanatory examination, a ten-storey reinforced concrete (RC) building with lead elastic bearing, high damping elastic bearing and triple-contact pendulum framework bearing is acquainted with the structures, and correlation is made between fixed base and the base-secluded structures. Demonstrating and investigation are conveyed utilizing ETABS 2015 v15.2.2. The investigation examination is performed to check the ampleness of the working against the lateral displacement, inter-storey drift, story shear and story acceleration. It is found from the investigation that reaction of working to lateral load diminishes, while modular period is expanded in both X and Y bearings. Furthermore, it was reasoned that triple grating pendulum bearing is increasingly compelling in examination of different direction utilized in this investigation. Springer Nature Singapore Pte Ltd 2021. -
Effect of different impact velocities on mechano-luminescence of natural calcite for mechanical sensors
This paper studies the mechanoluminescence (ML) behavior of natural calcite under varying impact velocities to assess its potential use in passive mechanical sensing. Calcite samples obtained from Byrnihat, Meghalaya (2603?03.8?N 9152?11.0?E), were analyzed using X?ray diffraction, field emission scanning electron microscopy, energy-dispersive X?ray spectroscopy, and Fourier-transform infrared spectroscopy. The analysis confirms the formation of the nanocrystalline hexagonal phase with minor impurities that affect its luminescent properties. When subjected to the mechanical impact, the calcite consistently produces asharp ML peak around 17?ms, regardless of the impact speed. The emitted light intensity shows alinear dependence on the impact velocity, suggesting areliable correlation between the mechanical input and optical response. The emission decay follows afirst-order exponential pattern, supporting its usefulness for identifying short-duration force events. Aplot of time against the logarithm of intensity displays aclear negative slope, supporting this kinetic model. These research findings highlight the potential of natural calcite as areliable and environmentally friendly material for mechanical sensor applications. The Author(s), under exclusive licence to Springer Nature Switzerland AG 2025. -
Effect of digital financial literacy on digital consumer protection: Mediating role of financial self-efficacy and financial confidence
The digital consumer is gaining importance in the current digital age and there is a need to adapt to the changing context. When discussing digital consumer protection, it's critical to gauge the degree of digital financial literacy. This study explores the mediating role of financial self-efficacy and financial confidence between digital financial literacy and digital consumer protection. The study was conducted in the Indian context, and the target population was users of digital platforms for financial activities in the age group of 20 to above 60. It was found that digital financial literacy significantly impacts digital consumer protection, financial self-efficacy, and financial confidence. However, only Financial self-efficacy and digital financial literacy impact digital consumer protection. It shows that financial self-efficacy mediates the relationship between digital financial literacy and digital consumer protection. This study will benefit the users of digital platforms and assist government/ non-government agencies in designing digital consumer protection programs. 2024, IGI Global. All rights reserved. -
Effect of Doping Concentration on the Luminescence Properties of MoO3: Tb3+ Nanobelts
The development of rare-earth-doped oxide nanomaterials has garnered significant interest due to their potential applications in display and biomedical imaging technologies. Among them, MoO3, with its favourable optical properties, emerges as a promising host material for nanophosphors. In this work, the hydrothermal method was employed to synthesise MoO3: Tb3+ nanobelts by varying the terbium concentration. Structural, optical, morphological and photoluminescence characteristics were systematically examined. FESEM and TEM revealed nanobelt morphology. XPS verified the successful incorporation of Tb3+ ions. A thorough study of the photoluminescence mechanism, including concentration quenching and lifetime measurements, was carried out, as these aspects are still not well studied for this material. Under 260 nm excitation, blue-green emission was observed with optimal photoluminescence intensity at 2 mol% Tb3+ doping. The optimised sample was annealed at 500C for 12 h, resulting in greenish-white emission. Emission colour coordinates were determined using the CIE chromaticity diagram, and a dipoledipole interaction mechanism with a critical distance of 17 was identified as the cause of quenching. The average photoluminescence lifetime of the annealed sample was ~1.1 ?s. These results demonstrate the potential of MoO3: Tb3+ nanobelts as efficient phosphor materials for next-generation display and bioimaging applications. 2025 John Wiley & Sons Ltd. -
Effect of Doping in Aluminium Nitride (AlN) Nanomaterials: A Review
Piezoelectric materials can generate electrical charges when subjected to mechanical pressure through the piezoelectric effect. In addition to generating electricity from environmental vibrations, they are also used as nano energy generators for micro electro mechanical systems (MEMS). Aluminum Nitride (AlN) with a doping element exhibits unique physical and chemical properties. It is used to manufacture many electromechanical devices. They are ideal candidates for many applications, including MEMS resonators and microwave filters, due to their large piezoelectric coefficient and low resistance. A number of material properties led to its selection, including high thermal conductivity, good mechanical strength, high resistance, corrosion resistance, and the largest piezoelectric coefficient. A piezoelectric coefficient d33 characterizes the piezoelectric response of AlN thin films. By doping this material, a wide range of applications have been explored. The Electrochemical Society -
Effect of Ethnocentrism and Attitude Towards Foreign Brands in Purchase Decision
Ethnocentrism refers to the intense preference for domestic products or a moral obligation to buy domestic products. With an extraordinary amount and variety of foreign goods and services now being made available to the Indian market, the level of competition faced by domestic companies has tremendously increased. This forms the need for domestic marketers to understand how the ethnocentrism and attitude of consumers towards foreign brands influence their purchase decision. In order to appeal to the Indian market better, many companies have started using patriotic advertising to evoke patriotic and nationalistic emotions among consumers. One such industry that utilizes such patriotic strategies is the automobile industry. The main objective of the study is to understand the effect that ethnocentrism and attitude towards foreign brands have on consumers purchase of automobiles. To measure the same, a survey consisting of a self-administered questionnaire with a sample size of 108 was conducted. For data analysis purpose, exploratory factor analysis, CART technique and regression analysis have been used in the study. CART technique has been used to develop a model keeping ethnocentrism and attitude as the base. The results of the study show that attitude has turned out to be dominant over ethnocentrism and has a significant role to play in persuading consumers to buy cars of an Indian or a foreign brand. The findings also show that ethnocentrism influences attitude which in turn influences purchase decision. The implications of the study suggest that domestic marketers should imply patriotic advertising in their marketing initiatives and also recommend them to highlight the Made in India tag. The study also suggests foreign marketers operating in the Indian market to focus less on the country-of-origin and focus more on the technicalities of the product because attitude towards foreign brands is a major contributor towards the purchase decision. 2020 Management Development Institute. -
Effect of ethnocentrism and attitude towards foreign brands in purchase decision /
Vision, Vol.24, Issue 3, pp. 1-10 -
Effect of face sheet on the flexural and tensile characteristics in GLARE laminates
The present study is carried out to study Glass Fibre Reinforced Aluminium Laminate (GLARE) structures and to evaluate their flexural and tensile properties. The GLARE specimens were fabricated using hand layup with vacuum bag moulding process wherein the aluminium sheets and E-Glass fibre woven mats of fixed thickness are bonded together by application of epoxy resins. Three different thicknesses of aluminium alloy (0.2 mm, 0.3 mm and 0.4 mm) Al-2024 T3 are used for the purpose of the study. The aluminium sheets are stacked together by application of epoxy resin between the sheets and are cured under a compression moulding machine under constant pressure. The overall thickness of the specimen is maintained constant for 2 mm. The samples were subjected to a three-point bending and tensile test as per ASTM D790 and ASTM D3039 standards, respectively, to evaluate their mechanical properties. The results indicate that the tensile strength of the composites is maximum for the specimen with aluminium 2024 T3 face sheet with a minimum thickness of 0.2 mm; however, with the increase in the thickness, the tensile strength is found to be decreasing. 2021 Engineers Australia. -
Effect of fiber types, shape, aspect ratio and volume fraction on properties of geopolymer concrete A review
Researchers have emphasized on sustainable construction with utilization of industrial wastes or byproducts in production of concrete. Geopolymer concrete is one of the popular construction materials which has shown promising results and potential to substitute conventional energy intensive materials such as Portland cement concrete. Further, the use of fibers has shown potential to overcome various deficiencies of geopolymer concrete. However, there are limited studies which explore the benefits of fiber reinforced geopolymer concrete and its applications. The development of fiber reinforced geopolymer concrete is relatively new construction material and has to be experimentally validated in order to increase its usage in the construction industry. As a result, this review paper is an attempt to discuss the effect of shape, type, aspect ratio and volume fraction of fibers on strength and durability properties of geopolymer concrete. From this detailed review it can be concluded that fiber reinforced geopolymer concrete enhances ductile behavior, tensile strength, toughness & energy absorption capacities. 2022 -
Effect of food insecurity on the cognitive problems among elderly in India
Background: Food Insecurity (FI) is a crucial social determinant of health, independent of other socioeconomic factors, as inadequate food resources create a threat to physical and mental health especially among older person. The present study explores the associations between FI and cognitive ability among the aged population in India. Methods: To measure the cognitive functioning we have used two proxies, word recall and computational problem. Descriptive analysis and multivariable logistic regression was used to understand the prevalence of word recall and computational problem by food security and some selected sociodemographic parameters. All the results were reported at 95% confidence interval. Results: We have used the data from the first wave of longitudinal ageing study of India (LASI), with a sample of 31,464 older persons 60 years and above. The study identified that 17 and 5% of the older population in India experiencing computational and word recall problem, respectively. It was found that respondents from food secure households were 14% less likely to have word recall problems [AOR:0.86, 95% CI:0.310.98], and 55% likely to have computational problems [AOR:0.45, 95% CI:0.290.70]. We also found poor cognitive functioning among those experiencing disability, severe ADL, and IADL. Further, factors such as age, education, marital status, working status, health related factors were the major contributors to the cognitive functioning in older adults. Conclusion: This study suggest that food insecurity is associated with a lower level of cognition among the elderly in India, which highlight the need of food policy and interventional strategies to address food insecurity, especially among the individuals belonging to lower wealth quintiles. Furthermore, increasing the coverage of food distribution may also help to decrease the burden of disease for the at most risk population. Also, there is a need for specific programs and policies that improve the availability of nutritious food among elderly. 2021, The Author(s). -
Effect of functionalization on the energy storage performance of super capacitors derived from wood charcoal
The electrochemical performance of wood charcoal is investigated with respect to the disorders in the system after subjecting to oxidation and exfoliation conditions. The Cyclic voltammetry and galvanostatic charge discharge curves indicate an improvement in the electrochemical behavior, resulting in a marginal increase in the specific capacitance values at higher exfoliation temperatures. The improvement is predominantly due to the change in the structural disorder in the system accompanied by the incorporation of oxygen functional groups which act as electrochemical active species. The exfoliation of wood charcoal at 160 and 200C yield a specific capacitance of 6.23 and 12.24 F/g at a current density of 0.01 A/g. The ESR values representing the overall resistance of the system are observed to be 6.07 ? for 200C as opposed to 10.41 ? of the bare material, making the material more conducting. The drastic change in the structural morphology along with the optimal amount of oxygen functional groups can be the reason for this behavior. The acquired results offer useful information for investigating the possibilities of fabricating supercapacitors with wood charcoal by tuning the defects of the system. 2024 American Institute of Chemical Engineers. -
Effect of functionalization on the energy storage performance of super capacitors derived from wood charcoal
The electrochemical performance of wood charcoal is investigated with respect to the disorders in the system after subjecting to oxidation and exfoliation conditions. The Cyclic voltammetry and galvanostatic charge discharge curves indicate an improvement in the electrochemical behavior, resulting in a marginal increase in the specific capacitance values at higher exfoliation temperatures. The improvement is predominantly due to the change in the structural disorder in the system accompanied by the incorporation of oxygen functional groups which act as electrochemical active species. The exfoliation of wood charcoal at 160 and 200C yield a specific capacitance of 6.23 and 12.24 F/g at a current density of 0.01 A/g. The ESR values representing the overall resistance of the system are observed to be 6.07 ? for 200C as opposed to 10.41 ? of the bare material, making the material more conducting. The drastic change in the structural morphology along with the optimal amount of oxygen functional groups can be the reason for this behavior. The acquired results offer useful information for investigating the possibilities of fabricating supercapacitors with wood charcoal by tuning the defects of the system. 2024 American Institute of Chemical Engineers. -
Effect of glass and coir fiber on geotechnical properties of clayey soil
The use of fibers for the improvement of weak subgrade soils is beneficial as it not only acts as reinforcement but also, increases drainage, provides better workability, inexpensive and required in exiguous quantity. Available studies on clay soil reinforced are limited to a particular type of fiber, any comparative study on two or more types of fibers on same soil, provides a useful information on understanding suitability of specific type of fiber. This study deals with experimental characterization of clay soil reinforced with glass and coir fibers. California Bearing Ratio (CBR) and Unconfined Compressive Strength (UCS) tests were performed on these fiber reinforced clay samples with different percentage of glass and coir fibers. The results of these unreinforced and reinforced soils are compared. 2019 SERSC. -
Effect of gravity modulation on linear, weakly-nonlinear and local-nonlinear stability analyses of stationary double-diffusive convection in a dielectric liquid
The paper deals with the study of effect of gravity modulation on double-diffusive convection in a dielectric liquid for the cases of rigid-rigid and free-free boundaries. Using a modified Venezian approach, expressions for the Rayleigh number and its correction are determined. FourierGalerkin expansion is employed for a weakly nonlinear stability analysis and this results in a fifth-order Lorenz system that retains the structure of the classical one in the limiting case. A local nonlinear stability analysis using the method of multiscales leads to the time-periodic GinzburgLandau equation from the time-periodic generalized Lorenz system and the numerical solution of this simpler equation helps in quantifying unsteady heat and mass transports. Influence of various non-dimensional parameters (Lewis number, solutal Rayleigh number, electrical Rayleigh number and Prandtl number), amplitude and frequency of gravity modulation on onset of convection and heat and mass transports is discussed. The study reveals that the influence of gravity modulation is to stabilize the system and enhance heat and mass transports. The results from free-free boundaries are qualitatively similar to that of rigid-rigid boundaries. Further, it is shown that in the case of free-free boundaries the heat and mass transports are less compared to those of rigid-rigid boundaries. 2020, Springer Nature B.V. -
Effect of Halloysite Nanotubes on Physico-Mechanical Properties of Silk/Basalt Fabric Reinforced Epoxy Composites
Natural fiber reinforced polymer composites have become more attractive due to their high specific strength, light weight and environmental concern. However, some limitations such as low modulus and poor moisture resistance were reported. This paper presents the role of halloysite nanotubes (HNTs) on physico-mechanical properties of bidirectional silk and basalt fiber reinforced epoxy (SF-BF/Ep) hybrid composites. Vacuum bagging and ultra-sonication method were used for the fabrication of hybrid composite slabs. The effect of HNT loadings (1.5, 3 and 4.5 wt. %) on physico-mechanical characteristics like density, hardness, flexural and impact properties of SF-BF/Ep composites were determined according to ASTM standards. Experimental results revealed that the incorporation of HNTs improves the mechanical properties. The impact strength of SF-BF/Ep is predominant at 3 wt. % HNT loading where the impact strength surges to 568.67 J/m, which may render HNT filled SF-BF/Ep desirable for various toughness-critical structural applications. The test results demonstrated that SF-BF/Ep-3HNT coded composites exhibited improved mechanical properties among the all composites. 2022 Trans Tech Publications Ltd, Switzerland.