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Murraya koenigii extract blended nanocellulose-polyethylene glycol thin films for the sustainable synthesis of antibacterial food packaging
Non-biodegradable plastics are a worldwide problem that have a negative impact on all living things, including humans. Nanocellulose, an excellent biopolymer is known for their increasing uses in food, healthcare, cosmetics, and various other fields. Nanocellulose is readily biodegradable, bioderived, and useful for creating innovative bioplastics that are employed in the production of food packaging and wound dressing. Curry leaves (Murraya koenigii) belongs to the rutaceae family and has many health benefits. Synthesis of Murraya koenigii incorporated nanocellulose thin films, and its characterisation using FT-IR, and XRD is discussed in detail. The source of nanocellulose in this study is sugar cane bagasse, an easily available agricultural residue in Kerala. Also, a biocompatible plasticizer is utilised to produce antibacterial packaging for food. The synthesised nanocomposites showed non-toxicity against THP1-derived macrophage cells and significant antibacterial activity against gram positive and gram-negative bacteria suggesting the possible application as a viable alternative for food packaging materials. 2023 Elsevier B.V. -
Musculoskeletal Disorders and Psychological Well-being among Indian Nurses: A Narrative Review of Impacts and Interventions (2024)
Background: A prevalent occupational health issue that may have a detrimental effect on nurses' mental health and general well-being is musculoskeletal problems. This narrative review aimed to explore the social, economic, and personal implications of Musculoskeletal Disorder on nurses in India, and examine support, and intervention strategies available for them. Material & Methods: A comprehensive literature search was conducted in electronic databases, including PubMed, Scopus, and Google Scholar, using relevant keywords related to Musculoskeletal Disorder, mental health, nurses, social, personal, support, and intervention. The inclusion criteria were articles published in English and focused the nursing workforce in India. Results: A total of 15 articles were selected for review synthesis. According to the summary, nurses in India who suffer from musculoskeletal disorders deal with serious social and personal repercussions that impact their everyday life and general well-being. Musculoskeletal Disorder can lead to decreased social connections, reduced job satisfaction, and physical and emotional distress. However, limited interventions are available that address Musculoskeletal Disorder and the mental health of nurses in India. Conclusion: There is a significant effect of Musculoskeletal Disorder on the mental health, quality of life, and economic well-being of nurses in India. However, limited scientific research exists exploring the prevalence and psychosocial implications of Musculoskeletal Disorder in the Indian nursing population. Consequently, additional research is essential to comprehend the scope and ramifications of this occupational health concern. To create interventions and support systems that are effective in the unique cultural and occupational context of nursing in India, it is imperative to engage in interdisciplinary collaboration. 2024 The Author(s); Published by Rafsanjan University of Medical Sciences. -
Museum visit intervention in K-12 education: a scoping review
This scoping review aims to provide an overview of empirical studies on worldwide museum visit intervention in K-12 education. The study employed Mendeley citation software to identify the articles in the database. A metaanalysis PRISMA statement is used for reporting the items. Out of 135 possibly rich articles, the present study reviewed 18 studies that met the inclusion criteria and were subjected to descriptive and content analyses published between 2017 and 2021. Most of the studies are experimental and from primary school contexts. It is revealed that science is the subject matter context majority of the studies, but philosophy, disaster management, language, and environmental science are also represented. The content analysis resulted in the following learning and social outcomes. It states that social outcome is explored chiefly, followed by learning outcome. The findings indicate that museum visit intervention positively impacts students learning and social outcome. The review also identifies the need for further research on museum visit intervention in the Asia Pacific region. 2024, Institute of Advanced Engineering and Science. All rights reserved. -
Mutual Information Pre-processing Based Broken-stick Linear Regression Technique for Web User Behaviour Pattern Mining
Web usage behaviour mining is a substantial research problem to be resolved as it identifies different user's behaviour pattern by analysing web log files. But, accuracy of finding the usage behaviour of users frequently accessed web patterns was limited and also it requires more time. Mutual Information Pre-processing based Broken-Stick Linear Regression (MIP-BSLR) technique is proposed for refining the performance of web user behaviour pattern mining with higher accuracy. Initially, web log files from Apache web log dataset and NASA dataset are considered as input. Then, Mutual Information based Pre-processing (MI-P) method is applied to compute mutual dependence between the two web patterns. Based on the computed value, web access patterns which relevant are taken for further processing and irrelevant patterns are removed. After that, Broken-Stick Linear Regression analysis (BLRA) is performed in MIP-BSLR for Web User Behaviour analysis. By applying the BLRA, the frequently visited web patterns are identified. With the identification of frequently visited web patterns, MIP-BSLR technique exactly predicts the usage behaviour of web users, and also increases the performance of web usage behaviour mining. Experimental evaluation of MIP-BSLR method is conducted on factors such as pattern mining accuracy, false positives, time requirements and space requirements with respect to number of web patterns. Outcomes show that the proposed technique improves the pattern mining accuracy by 14%, and reduces the false positive rate by 52%, time requirement by 19% and space complexity by 21% using Apache web log dataset as compared to conventional methods. Similarly, the pattern mining accuracy of NASA dataset is increased by 16% with the reduction of false positive rate by 47%, time requirement by 20% and space complexity by 22% as compared to conventional methods. 2020. All Rights Reserved. -
My Motherhood, My Way: A Sociological Study of Contemporary Employed Mothers in Kolkata
Motherhood in India has been understood primarily by placing mothers in the domestic space. A mother is constructed as a protector and the complete caregiver of her children. But there have been significant changes in the status of Indian women recently. In the 21st century, with suitable qualifications and employment opportunities, women have the choice to be economically independent and career-driven, which has a profound impact on their roles and responsibilities as protectors and caregivers in the home. It is essential to study and document how women in this generation have started to redefine their roles and negotiate what a mothers duties are at home. This study aims to make a systematic inquiry to understand the issues and challenges faced by employed mothers in everyday life and how they balance their career and childcare activities. Researchers investigate this through a qualitative study on mothers employed in different types of professions in the city of Kolkata. Data was collected by conducting in-depth interviews of around twenty-nine urban, upper-middle class employed mothers from different professional backgrounds to have a set of diverse narratives about their experiences and struggles. The key findings of this study provide an insight into the challenges that mothers face and their balancing mechanisms. Such studies have the scope to motivate many employed mothers by presenting some cases of women who have succeeded in breaking the stereotypical ideas of motherhood and are redefining their stories in more humane terms. 2021. Journal of International Womens Studies. -
N-doped graphene quantum dots incorporated cobalt ferrite/graphitic carbon nitride ternary composite for electrochemical overall water splitting
Multicomponent electrocatalysts containing carbon supports play a crucial role in influencing the hydrogen and oxygen evolution reactions which enhance the total water splitting. Herein, we report a ternary composite with cobalt ferrite, graphitic carbon nitride, and N-doped graphene quantum dots prepared via hydrothermal technique. The purity of the samples is established by carrying out various characterization methods. The intrinsic characteristics of the obtained materials are investigated by employing electrocatalytic processes in an alkaline media toward hydrogen and oxygen evolution reactions. Cobalt ferrite/graphitic carbon nitride/N doped graphene quantum dots electrocatalyst demonstrates a very low overpotential towards hydrogen evolution reaction of 287 mV at a constant 10 mA cm?2 current density in 1.0 M KOH. Tafel slope and Rct values generated are 94 mV dec?1 and 0.86 cm2, respectively. Oxygen evolution reaction studies reveal an overpotential of 445 mV at 10 mA cm?2 with a Tafel slope of 69 mV dec?1. Finally, the cell potential needed for the cobalt ferrite/graphitic carbon nitride/N doped graphene quantum dots electrode to achieve 10 mA cm?2 in total water splitting is only 2.0 V while displaying long-term stability. 2022 Hydrogen Energy Publications LLC -
N-rGO/NiCo2O4 nanocomposite for high performance supercapacitor applications
Spinel structured transition metals oxide GO/NiCo2O4 nanocomposites and nitrogen doped N-rGO/NiCo2O4 nanocomposites were developed. Powder X-ray diffraction investigations confirmed the structure. The bonding vibrations of the produced nanocomposites were confirmed using infrared and Raman spectroscopy. EDX analysis was used to determine the composition and element weights of the nanocomposites. The electrochemical properties of the nanomaterials were measured using 1M KOH electrolyte. At 5mVs?1 scan rates, cyclic voltammetry revealed a specific capacitance (Csp) of 1078.2 Fg?1 for N-rGO/NiCo2O4. The bare and nanocomposites of NiCo2O4, GO/NiCo2O4, and N-rGO/NiCo2O4 specific capacitance, charge-discharge capability, and cyclic stability were investigated. Energy density and power density of the N-rGO/NiCo2O4 nanocomposite were estimated to be 20.4 Wh kg?1 and 1300W kg?1, respectively. N-rGO//N-rGO/NiCo2O4 asymmetric supercapacitor device with Ed of 14.9 Wh kg?1 and Pd of 3500W kg?1 was fabricated. 2023, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature. -
N-tier modelling of robust key management for secure data aggregation in wireless sensor network
Security problems in Wireless Sensor Network (WSN) have been researched from more than a decade. There are various security approaches being evolving towards resisting various forms of attack using different methodologies. After reviewing the existing security approaches, it can be concluded that such security approaches are highly attack-specific and doesnt address various associated issues in WSN. It is essential for security approach to be computationally lightweight. Therefore, this paper presents a novel analytical modelling that is based on n-tier approach with a target to generate an optimized secret key that could ensure higher degree of security during the process of data aggregation in WSN. The study outcome shows that proposed system is computationally lightweight with good performance on reduced delay and reduced energy consumption. It also exhibits enhanced response time and good data delivery performance to balance the need of security and data forwarding performance in WSN. 2019 Institute of Advanced Engineering and Science. -
N?-[(1E)-1-(2-Fluorophenyl)ethylidene]pyridine-3-carbohydrazide
The title compound, C14H12FN3O, adopts an E conformation with respect to the azomethine double bond whereas the N and methyl C atoms are in a Z conformation with respect to the same bond. The ketonic O and azomethine N atoms are cis to each other. The non-planar molecule [the dihedral angle between the benzene rings is 7.44(11)] exists in an amido form with a C=O bond length of 1.221(2) In the crystal, a bifurcated N - H(O,N) hydrogen bond is formed between the amide H atom and the keto O and imine N atoms of an adjacent molecule, leading to the formation of chains propagating along the b-axis direction. Through a 180 rotation of the fluorophenyl ring, the F atom is disordered over two sites with an occupancy ratio of 0.632(4):0.368(4). Sreeja et al. 2014. -
N?-[(E)-1-(2-fluorophenyl)ethylidene]pyridine-4-carbohydrazide
The title compound, C14H12FN3O, adopts an E conformation with respect to the azomethine bond. The pyridyl and fluorobenzene rings make dihedral angles of 38.58(6) and 41.61(5) respectively with the central C(=O)N2CC unit, resulting in a non-planar molecule. The intermolecular interactions comprise two classical N - H?O and N - H?N hydrogen bonds and four non-classical C - H?O and C - H?F hydrogen bonds. These interactions are augmented by a weak ?-? interaction between the benzene and pyridyl rings of neighbouring molecules, with a centroid-centroid distance of 3.9226(10) This leads to a three-dimensional supramolecular assembly in the crystal system. The F atom is disordered over two sites in a 0.559(3): 0.441(3) ratio, through a 180 rotation of the fluorobenzene ring. 2014 CrossMark. -
N?-[(E)-2-Fluorobenzylidene]benzohydrazide
The asymmetric unit of the title compound, C14H 11FN2O, contains two independent molecules, both of which adopt the E conformation with respect to the azomethine C=N bond. The molecules are non-planar, with dihedral angles of 26.92 (12) and 11.36 (11) between the benzene and phenyl rings. In the crystal, molecules are linked through N-H?O=C and N-H?N hydrogen bonds into chains along [101]. C-H?O contacts link these chains into layers parallel to (001). The three-dimensional crystal packing is stabilized by ?-? interactions, the shortest separation between the centroids of benzene rings being 3.884 (1) -
N?-[(E)-Furan-2-ylmethylidene]-4-hydroxybenzohydrazide
The title compound, C12H10N2O3, exists in the E conformation. The five-membered ring and the phenyl rings form dihedral angles of 36.73 (10) and 12.22 (10), respectively, with the central C(=O)N2C unit. The crystal packing is dominated by strong N - H?O and O - H?N hydrogen bonds. Together with weaker C - H?O interactions, these establish a three-dimensional supramolecular network. -
N'-[(1E)-1-(2-Fluorophenyl)Ethylidene]Pyridine-3-Carbohydrazide /
Acta Crystallographica Section E, Vol-E70(o115), ISSN-1600-5368 -
N'-[(E)-1-(2-Fluorophenyl)ethylidene]pyridine-4-carbohydrazide
Acta Crystallographica Section E, Vol-E70, ISSN-1600-5368 -
N'-[(E)-Furan-2-Ylmethylidene]-4-Hydroxybenzohydrazide
Acta Crystallographica Section E, Vol-E70(o242), ISSN-1600-5368 -
Na+ doped CuO: A new paradigm electrode material for high performance supercapacitors
This study investigates the influence of sodium doping on the properties of cupric oxide (CuO) thin films synthesized via spray pyrolysis. Comprehensive characterization was conducted using X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDAX), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FESEM), Raman spectroscopy, Hall effect measurements, and electrochemical studies. All films exhibited p-type conductivity, with an optical band gap variation from 1.53 to 1.73 eV. XRD analysis confirmed the dominance of monoclinic CuO, with minor phases of Cu2O and Cu4O3. EDAX and XPS verified the incorporation of Cu, O, and Na elements. FESEM revealed a densely packed morphology with uniform particle distribution and rough surfaces in the electrically optimized film. The Raman spectra of doped samples showed increased intensity and sharpness, attributed to Na + ion-induced polarizability enhancement. Hall effect measurements indicated a tenfold decrease in carrier concentration and a more than tenfold increase in mobility upon sodium doping. Films doped with 4 at.% sodium exhibited the lowest resistivity. Additionally, Na doping enhanced the electrochemical performance of CuO. These findings demonstrate that sodium doping significantly enhances the electrical, optical and electrochemical properties of CuO thin films, making them suitable for applications in optoelectronic devices and supercapacitors. 2024 Elsevier Ltd and Techna Group S.r.l. -
Nano Zinc Oxide Particle Synthesis from Bio-Waste Selaginella willdenowii Leaf Extract: A Multi-Faceted Approach for Environmental and Biomedical Applications
Selaginella willdenowii, a commonly used greenhouse fern, was often used as a biowaste to synthesize zinc oxide nanoparticles (ZnO NPs) in an eco-friendly and cost-effective way. UV-Visible spectra studies were carried out to confirm the synthesis of S. willdenowii-mediated ZnO NPs (SW-ZnO NPs), and a peak at 367nm with a sharp band gap of 3.415eV was observed. The X-ray diffraction analysis indicated that the crystalline size of the synthesized SW-ZnO NPs was 11.971nm. The phytochemicals present in the extracts and the compounds involved in the reduction of metal to nanoparticles were determined by Fourier Transform Infrared analysis. Scanning electron microscopy was utilized to analyze the surface morphology and size of the obtained SW-ZnO NPs. The examination revealed that they exhibited a hexagonal shape, with an average size falling within the range of 17-23nm. Under ultra-violet light, reactive blue 220 and reactive yellow 145 dyes showed 78.06% and 60.14% degradation, showing potential photocatalytic degradation activity. The synthesized SW-ZnO NPs also exhibited antimicrobial activity against bacterial strains (Escherichia coli and Bacillus subtilis) and fungal cultures (Candida tropicalis and Candida albicans) showed cytotoxic activity against Hep-G2 cell lines. Our results suggest the green synthesized SW-ZnO NPs have potential photocatalytic, antimicrobial and cytotoxic potential. 2024 World Scientific Publishing Company. -
Nano ZnO@PEG catalyzed one-pot green synthesis of pyrano[2,3-d] pyrimidines in ethanol via one-pot multicomponent approach
A facile one-pot multicomponent protocol for the synthesis of bio-active Pyrano[2,3-d]pyrimidine derivatives by a one- step condensation reaction of substituted aldehyde, malononitrile/methyl cyanoacetate, barbituric acid has been demonstrated using nano ZnO@PEG as a catalyst at room temperature. The present approach offers several advantages, such as shorter reaction time, higher yields, and environmental friendliness. Easy isolation of products, absence of column chromatographic purification, use of commercially available low-cost starting materials and reusability of the catalyst make the methodology viable in organic synthesis. 2020 Elsevier Ltd. All rights reserved. Selection and peer-review under responsibility of the scientific committee of the Second International Symposium ''Functional Nanomaterials in Industrial Applications: Academy - Industry Meet''. -
Nano- from nature to nurture: A comprehensive review on facets, trends, perspectives and sustainability of nanotechnology in the food sector
Nanotechnology has underpinned vital progress in current research and has immensely promoted the food production chain. This review projected the critical intervention of nano-based technologies like modern advancements of nano-based biosensors in detecting mycotoxins, microbial contaminations, antibiotics, pesticides, food additives, and dyes. It also highlighted the starring roles of nanotechnology in terms of active, intelligent food packaging and food safety. These approaches have certainly intensified the strength of food processing technology and improved food quality and maintenance standards during shelf life. Apart from these trending facets, this review throw light on the utilisation of food waste for the biogenic synthesis of nanoparticles and the application of nano-based materials for the recycling process in food production units to ensure a complete cleaner technology. However, monitoring the chronic exposure of food contact nanomaterials should be critically evaluated to ensure food safety. Nanotechnology embraced an influential role in the food sector by providing effective avenues for energy conservation, sustainability, and cues to improve the capital funds well. 2021 Elsevier Ltd -
Nano-architectured polypyrrole based magnetic nanocatalyst for the N- arylation of imidazoles and fused imidazoles
A new magnetically recoverable polypyrrole supported copper based nanocatalyst was synthesized, characterized with various analytical techniques like Fourier-transform infrared spectroscopy (FTIR), Field Emission Scanning Electron Microscopy (FESEM), Energy Dispersive X-ray analysis (EDX), High Resolution Transmission Electron Microscopy (HRTEM), Thermogravimetric analysis (TGA), Vibrating Sample Magnetometry (VSM), and Inductively coupled plasma atomic emission spectroscopy (ICP-AES) analysis. The loading of copper on the surface of the catalyst was found to be 4.23 wt%. The application of the synthesized nanocatalyst was checked for the N-arylation of imidazoles. Excellent catalytic performance was obtained with easy recoverability and reusability upto six cycles. The current green protocol makes it environmentally beneficial for scale-up industries. 2025 Elsevier B.V.