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New Insights in the Bubble Wall of NGC 3324: Intertwined Substructures and a Bipolar Morphology Uncovered by JWST
We report the discovery of intertwined/entangled substructures toward the bubble wall of NGC 3324 below a physical scale of 4500 au, which is the sharp edge/ionization front/elongated structure traced at the interface between the H ii region and the molecular cloud. The sharp edge appears wavy in the Spitzer 3.6-8.0 ?m images (resolution ?2?). Star formation signatures have mostly been traced on one side of the ionization front, which lies on the molecular clouds boundary. The James Webb Space Telescopes (JWST) near- and mid-infrared images (resolution ?0.?070.?7) are employed to resolve the sharp edge, which has a curvature facing the exciting O-type stars. The elongated structures are associated with the 3.3 ?m polycyclic aromatic hydrocarbon (PAH) emission, the 4.05 ?m ionized emission, and the 4.693 ?m H2 emission. However, the PAH-emitting structures are depicted between the other two. The H2 emission reveals numerous intertwined substructures that are not prominently traced in the 3.3 ?m PAH emission. The separation between two substructures in the H2 emission is ?1.?1 or 2420 au. The intertwined substructures are traced in the spatial areas associated with the neutral to H2 transition zone, suggesting the origin of these structures by thin-shell instability. Furthermore, an arc-like feature traced in the Spitzer 3.6-8.0 ?m images is investigated as a bipolar H ii region (extent ?0.35 pc) at T d ?25-28 K using the JWST images. A massive-star candidate VPHAS-OB1 #03518 seems to be responsible for the bipolar H ii region. 2023. The Author(s). Published by the American Astronomical Society. -
New insights into surface functionalization and preparation methods of MWCNT based semiconductor photocatalysts
The manuscript primarily describes the influence of various synthesis strategies on the photocatalytic properties of MWCNT/TiO2 binary nanohybrids. The multiwalled carbon nanotube modified titania hybrids synthesized via two-step reaction involving the covalent functionalization with green and mild oxidizing agent like H2O2, followed by simple surfactant/template free hydrothermal synthesis exhibited the maximum photocatalytic efficiency. The Total Organic Carbon (TOC)analysis showed complete mineralization of the persistent Rhodamine B dye in about 8 h. These synthesized nanohybrids in varying MWCNT content were tested for their photocatalytic efficiency in the degradation of explosive effluents like 4-nitrophenol and picric acid. The UVVis diffuse reflectance spectroscopy (UVVis DRS), X-ray photoelectron spectroscopy (XPS), BrunauerEmmettTeller Surface area analysis (BET), Fourier transform infrared spectroscopy (FT-IR), Transmission electron microscopy (TEM)and Raman spectra analysis evidently revealed the effective synergistic interaction between the MWCNT and titania at the interface that has contributed to the significant enhancement of photocatalytic performance. 2019 Elsevier Ltd and Techna Group S.r.l. -
New Paradigm of Marketing-Financial Integration Modelling for Business Performance: An IMC Model
When it comes to the provision of financial services, the integrated marketing communication (IMC) process is crucial in the creation and maintenance of client-provider bonds. This research presents a literature assessment on the theoretical basis for using marketing communication tools in the provision of financial services. This research is an attempt to bolster the little theoretical literature on the effectiveness of marketing communication techniques in the provision of financial services. Financial service providers use marketing communication as a channel for two-way exchanges with their clientele, with the ultimate goal of maximising the benefits their customers bring to the company. When it comes to providing financial services, an organisations success hinges on its ability to effectively manage its relationships with both current and potential consumers. As a result, it is important for practical reasons to be guided by well-defined marketing communications goals to identify the extent of usage and within the constraints of available resources. In this regard, businesses are free to establish specific communications objectives in accordance with their unique situations to direct the implementation of their IMC plan. This study aims to find out an impact of financial integration with IMC on business performance. This study is descriptive in nature. Primary data is collected with the help of questionnaire. The study finds that the financial integration in the IMC model has a statistically significant impact on business success. The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. 2024. -
New results on orthogonal component graphs of vector spaces over Zp
A new concept known as the orthogonal component graph associated with a finite-dimensional vector space over a finite field has been recently added as another class of algebraic graphs. In these types of graphs, the vertices will be all the possible non-zero linear combinations of orthogonal basis vectors, and any two vertices will be adjacent if the corresponding vectors are orthogonal. In this paper, we discuss the various colorings and structural properties of orthogonal component graphs. 2024 Azarbaijan Shahid Madani University. -
New results on upper domatic number of graphs
For a graph G = (V, E), a partition ? = {V1, V2,..., Vk} of the vertex set V is an upper domatic partition if Vi dominates Vj or Vj dominates Vi or both for every Vi, Vj ? ?, whenever i 6= j. The upper domatic number D(G) is the maximum order of an upper domatic partition of G. We study the properties of upper domatic number and propose an upper bound in terms of clique number. Further, we discuss the upper domatic number of certain graph classes including unicyclic graphs and power graphs of paths and cycles. 2020 Azarbaijan Shahid Madani University -
Newly designed single-stage dual leg DC-DC/AC buck-boost converter for grid connected solar system
This paper proposes a novel single-stage buck-boost inverter based on dual leg. Modulation techniques, working principle, guidelines for components design, and guidelines are discussed and presented. A theoretical concept is initially tested in Simulink platform and practically verified with a test bench model. A practical model is developed to verify the simulation model and tested different modes of operation are analyzed. The main advantages of the proposed work are as follows: The number of passive components is less, switching frequency components are not high so leakage current is very less, and voltage control in a wide range is achieved without using a DC link capacitor. High efficiency can be achieved due to multi-stage operation. This proposed work is suitable for high/low voltage PV-based energy conversion. Electromagnetic interference is also reduced due to continuous input current. 2023 John Wiley & Sons Ltd. -
Next generation employability andcareer sustainability inthehospitality industry 5.0
Purpose: With an industry 5.0 revolution taking place in the hospitality industry, a shift from manual to cognitive labor is anticipated, characterized by greater sustainability, resilience and a human-centric approach. In this regard, hospitality educators' ability and willingness to teach novel topics such as automation at work, upskilling of employees, man-machine interaction and service robots have become more important than ever. This study aims to interpret the perspectives of hospitality educators about bridging the gap in the employability skills of (next-gen) hospitality graduates and the concerns relating to career sustainability in times of transition. Design/methodology/approach: A case study method was used given the novelty of the topic in a developing country like India. A qualitative survey with open-ended questions, is employed to understand the viewpoints of Indian hospitality educators, including those with more than 15years of teaching experience. In-depth interviews were conducted with 23 hospitality educators to reach the theoretical saturation point. MAXQDA software was used to analyze the qualitative data collected in the study. Findings: The findings reveal the challenges and motivations of hospitality educators in adapting to frequently changing business environments. In doing so, it sheds light on the methods employed to create a generation of hospitality graduates aligned with the changing dynamics of the industry. Originality/value: The paper presents the viewpoints of hospitality educators in India in relation to a futuristic approach to next-gen employability and career sustainability. Whilst numerous studies have focused on the role of robots and artificial intelligence in replacing the human component of the service environment, the concept of people working alongside advanced technologies is fairly new and needs to be fully explored. 2023, Emerald Publishing Limited. -
Next-Generation Connectivity in A Heterogenous Railway World
Global System for Mobile communication - Railway (GSM-R) is widely used for operational communications between train and signaler. However, there is a need to define a successor that addresses: obsolescence, radio spectrum demand and the enabling of a range of emerging digital applications such as radio-based signaling and Automatic Train Control (ATC). Therefore, the International Union of Railways (UIC) started the initiative to develop the Future Railway Mobile Communication System (FRMCS). This article describes an Adaptable Communication System (ACS) that is being developed jointly by industry and railway operators as a possible successor covering all types of railways and all aspects of the FRMCS. A pragmatic approach is suggested that considers diverse railway settings and makes use of various radio access technologies. Countries, geographical regions and infrastructure managers differ concerning available radio technologies, but use of a suitable ACS could pave the way towards innovation in the railway sector. For this adaptive concept we discuss several network models and enhancements including satellite communications (SatCom), Software-Defined Networking (SDN) integration and antenna systems that support multiple bearers in one. For SatCom a software defined radio (SDR) prototype using random access is presented that is able to fulfill the requirements of ETCS. We found that SDN can be used for dynamically changing the access technology for critical and non-critical railway use cases. Furthermore, we present an antenna prototype that can be used for 5G, GSM, WLAN and LTE in parallel which saves limited mounting surface on the train. 1979-2012 IEEE. -
Nexus Between Credit Conditions, Financial Literacy, and Loan Accessibility Among Indian MSMEs
We examine the interplay among commercial bank loan terms, financial literacy, and formal loan accessibility for micro, small and medium enterprises (MSMEs). Despite recent strides in integrating MSMEs into commercial bank portfolios via micro-lending initiatives, persistent challenges hinder their access to formal credit. Drawing from empirical data and existing literature, this study explores the nuanced impacts of loan terms and financial literacy on SMEs ability to secure formal loans. Addressing gaps in prior research, we concurrently analyse borrower characteristics and credit regulations influence on formal loan accessibility. The Author(s), under exclusive license to Springer Nature Switzerland AG 2024. -
Nexus between Entrepreneurial Education, Entrepreneurial Mindset, and Entrepreneurial Passion on Entrepreneurial Intentions: Mediating Role of Self-efficacy
This study examines the complex dynamics of factors affecting self-efficacy (SE) and entrepreneurial intentions (EIs) among engineering students in India. It investigates the mediating role of SE in the relationships between entrepreneurial education (EE), entrepreneurial mindset (EM), entrepreneurial passion (EP), and EIs. The research reveals that SE remains stable across various personal characteristics, highlighting it as a robust individual trait less influenced by external factors. Gender significantly impacts EIs, underscoring its pivotal role in shaping entrepreneurial intentions, while other personal characteristics show limited influence. Passion and mindset appear to be consistent across demographics, suggesting they are intrinsic qualities. SE serves as a mediator in the connections between entrepreneurial mindset, passion, and intentions, elucidating its pivotal role in the entrepreneurial process. EE indirectly affects EIs and SE through other factors in the research model. Entrepreneurial passion directly influences both EIs and SE, emphasizing its role as a driving force for entrepreneurship. An entrepreneurial mindset doesn't directly affect intentions but significantly influences SE, indicating its importance in shaping self-efficacy, which in turn influences intentions. The findings can guide the development of educational programs and initiatives designed to promote entrepreneurship among engineering students in India while considering the impact of self-efficacy and gender-related factors. 2024, Iquz Galaxy Publisher. All rights reserved. -
Nexus Between Interest Rate Risk and Economic Value of Equity of Banks
This analytical study looks to provide recommendations to the banking sector on different policies and regulations by examining certain aspects of the Basel III accord, which was designed to manage specific operational, capital and market risks of banks. A review of extant literature reveals that only a few papers have been written on simulation-based approaches, using basis and re-pricing risks. We look to connect this as a source while attempting to define and measure the impact of interest rate risk (IRR) on the economic value of equity (EVE) of banks. We propose to use the driverdriven method, wherein interest rate shocks are derived through prime lending rate (PLR) for the period of 20162019 in the context of India. Monte Carlo Simulation and OLS regression was performed to predict the IRR; Granger causality was used to examine the cause and effect relationship; the impulse response function (IRF) was used for sensitivity analysis; and the vector error correction model (VECM) technique was used for co-integrating relationships. Notably, the EVE movement caused due to shocks in interest rates had to be traced as it envisages probable EVE losses. Importantly, our study is among the first few to show the relationship between IRR and EVE of banks, especially after the deregulation of Indian banking sector. 2021 International Management Institute, New Delhi. -
Nexus between ownership structure and firm performance - Evidence from Indian service sector
Shareholding pattern of an organization determines the management control and decision making climate. Empirical researches have proved relationship among the type of shareholdings, managerial efficiency and stock returns in manufacturing sectors. This study investigates the relationship between the organizational shareholding pattern and financial performance of select services sector companies taking sample from listed financial services and Information technology firms from CNX500 Index for a period of five years. The study emphasizes on the significance of categorical distinctions among ownership and evaluating its influence on firm performance for investment decisions. Both accounting and market based approach of Firm performance has been considered using Tobin Q ratio and Return on Capital Employed as proxy. The results show that there is Insider owners dominance in services sector. A higher percentage of aggregate promoter and promoters group holdings are documented in services sector. The study also documents a positive and significant relationship between the firm performance as measured by market model and the percentage of shares held by promoters and Institutional bodies. In contrast, there is negative and insignificant influence of promoters holdings on the firm performance. However, Institutional shareholdings have a positive and significant influence. Dominant insiders ownership enhances management efficiency through excessive control for wealth maximization. IAEME Publication. -
Nexus Between Tax Buoyancy and Economic Growth Evidence from India1
This paper examines the trends in fiscal revenue collections and the relationship between tax buoyancy and economic growth. In recent years, the responsiveness of revenue growth in relation to economic growth is a growing concern as we witness staggered tax revenue growth with the convergence of percentage contribution of direct taxes to the aggregate revenue with indirect taxes. Using the Log OLS model, for the period between 2000-2018 the variability in tax revenue due to the change in economic growth as measured by GDP was verified. We confirm the test results using M-estimation Robust Log-OLS. We critically appraise the policy interventions and administrative initiatives taken up to improve the buoyancy rate and suggest ways to enhance the voluntary tax compliance rate in the country. The studys findings show a significant relationship between tax revenue and economic growth, but it does not necessarily improve the tax buoyancy rate. Indian Institute of Finance. -
Nexus Between The Carbon Dioxide Emission And Economic Growth: Evidence From India
Increase in economic activities contributes to the economic growth of a country. It is evident that emerging economies have recorded higher economic growth and significant increase in coal consumption, energy consumption and electricity consumption. On the other hand, the emission of greenhouse gases (GHG) generating consequences in the atmosphere. In this context, this study tries to analyse the association between GDP per capita, FDI, population, trade openness and CO2 emissions per capita in India. The study is based on secondary data, which has been collected from the World Bank database. The time period under consideration is from 1960 to 2017. Augmented Dickey Fuller test has been used to test the unit root. VAR lag order criteria have been used for lag selection of the model. Since the variables are integrated at I (1) and I (0), the ARDL model has been used for the purpose of analysis. Furthermore, for checking the stability of the model, the CUSUM test has been used. The results show that in the long run, GDP per capita and FDI has a positive impact on CO2 emission whereas, in the short run coal consumption, FDI, GDP per capita and trade openness appears to have a significant and positive impact towards CO2 emission. 2020 - Kalpana Corporation -
Nexus Between The Carbon Dioxide Emission And Economic Growth: Evidence From India
Increase in economic activities contributes to the economic growth of a country. It is evident that emerging economies have recorded higher economic growth and significant increase in coal consumption, energy consumption and electricity consumption. On the other hand, the emission of greenhouse gases (GHG) generating consequences in the atmosphere. In this context, this study tries to analyse the association between GDP per capita, FDI, population, trade openness and CO2 emissions per capita in India. The study is based on secondary data, which has been collected from the World Bank database. The time period under consideration is from 1960 to 2017. Augmented Dickey Fuller test has been used to test the unit root. VAR lag order criteria have been used for lag selection of the model. Since the variables are integrated at I (1) and I (0), the ARDL model has been used for the purpose of analysis. Furthermore, for checking the stability of the model, the CUSUM test has been used. The results show that in the long run, GDP per capita and FDI has a positive impact on C02 emission whereas, in the short run coal consumption, FDI, GDP per capita and trade openness appears to have a significant and positive impact towards C02 emission. 2020 Kalpana Corporation. All Rights Reserved. -
Nexus of Monetary Policy and Productivity in an Emerging Economy: Supply-Side Transmission Evidence from India
Monetary policy and its transmissions have been debated by various schools of thought. The purpose of this paper is to empirically tests whether monetary policy has supply side effect influencing Indian economys total factor productivity. This study uses ARDL model to ascertain the long run relationship between monetary policy proxies and total factor productivity (TFP). Cointegration tests reveal that total factor productivity has a relationship with all of the monetary policy proxies. The ARDL results reveal a negative relationship between TFP and some monetary policy proxies in the short run, but a positive effect in the long run. These results showcase the possible supply side transmission of monetary policy in India, which can help in determining an optimal policy so as to augment TFP, an important driver of economic growth. The study only focusses on the Indian economy and spillover effects of other Asian economies on Indias TFP can also be examined. The Author(s), under exclusive licence to The Indian Econometric Society 2024. -
Ni-Co MOF Flowers/ZnO NRs Mediated Electrochemical Sensor for Rapid and Ultrasensitive Detection of Neotame in Food Samples
This study focuses on the bioreduction of waste-derived graphite rods into reduced graphene oxide(rGO), followed by the fabrication with Ni-Co metal-organic flowers and Zinc oxide nanorods(ZnO NRs) using Nafion, for sensitive detection of neotame. The Ni-Co metal-organic flowers and ZnO NRs were synthesized using solvothermal synthesis and Azadirachta indica leaf extract, respectively. Additionally, Nafion polymer enhances the stability and conductivity of the nanocomposite. The nanocomposite was characterized using UVvis, Fourier transform infrared spectorscopy, X-ray diffraction, Raman spectroscopy, Dynamic light scattering, X-ray photoelectron spectroscopy, Field-emission scanning electron microscopy, Energy-dispersive X-ray analsysis, Transmission electron microscopy, and Atomic force microscopy. The electrochemical studies were carried out using Electrochemical impedance spectroscopy and Cyclic voltammetry. The modified electrode (rGO/Nafion/Ni-Co MOF/ZnO NRs) demonstrated improved electrochemical activity (34.01 ?A) for neotame with an enhanced peak current at +0.73 V. The LOD and LOQ values were calculated and found to be 0.32 and 0.99 ?M with a recovery (%) ranging from 94.50 to 101.34%. The outcome of this study identifies the morphological and electrochemical factors as major contributors to the adsorption affinities and catalytical activities, with promising possibilities for the design of electrochemical sensing of artificial sweeteners. 2024 The Electrochemical Society (ECS). Published on behalf of ECS by IOP Publishing Limited. All rights, including for text and data mining, AI training, and similar technologies, are reserved. -
Nickel Telluride Quantum Dots as a Counter Electrode for an Efficient Dye-Sensitized Solar Cell
Transition-metal dichalcogenides (TMDs) have recently emerged as highly appealing and efficient options for electrodes in dye-sensitized solar cells (DSSCs), effectively substituting the scarce and expensive metal platinum (Pt). In this work, nickel telluride (NiTe2) quantum dots (QDs) were effectively used as a counter electrode for DSSCs by providing a sustainable alternative to the scarce platinum (Pt). The DSSC based on NiTe2 QDs shows a power conversion efficiency (?) of ?8.06%, which is comparatively better than exfoliated NiTe2 (? ? 6.58%). The density functional theory (DFT) was employed to comprehensively understand the underlying mechanisms involved in the charge transfer between the QDs and the electrolyte species. The outcomes demonstrated the benefits of creating diverse structural configurations designed to enhance interfacial transport, ensure an even distribution of active facets, and improve the electrocatalytic performance in the DSSC process.(Figure Presented). 2023 American Chemical Society. -
Nickel-Based Inks for Flexible Electronics - A Review on Recent Trends
Inkjet printing (IJP) is an efficient, simple, scalable and low-cost additive manufacturing technique for the deposition of functional materials on substrates used in flexible electronic devices, sensors, and light-emitting diodes to name a few. Nanoparticle ink, metal oxide decomposition (particle-free ink), polymer ink, and semiconductor ink are classifications of the inks used in IJP. Effective printing of the material is possible when the ink parameters (viscosity, particle size, surface tension) and its derived dimensionless quantities (Weber number, Reynolds' number, and Ohnesorge number) fall within a desirable range. The formation of the coffee-ring effect during the post-printing process is one of the major concerns, which affects the morphology and electrical conductivity of the printed pattern. In this review, a summary of recent developments of Ni-based inks in terms of formulation, sintering and properties is presented, along with the effect of combining Ni with other materials such as NiO, Ag, Cu, Zn, Fe, carbon, and rare earth metals on the film properties. The precursors and solvents used for the Ni ink preparation, along with the additives and surfactants, have been presented to understand their impact on the film's properties and develop a design to choose the ideal precursor-solvent pair. Finally, the challenges in formulating inks and the necessity to develop a model to optimize the choice of solvent/ precursor are presented. The model would improve the selection of additives and precursors and reduce material wastage and enhance performance with fewer defects. 2022 World Scientific Publishing Company. -
Nicotiana genus: a green and sustainable source for designing of nitrogen-rich efficient carbon nanocomposites for the hydrogenation of nitrophenol and non-enzymatic glucose sensing
Transition metals based nitrogen-doped carbon nanocomposites have been envisioned as a potential replacement for precious metal-based nanostructures to catalyze a variety of reactions. Herein, we report the synthesis of a group of nitrogen-doped carbon nanocomposites derived from the Nicotiana genus family plant, e.g. tobacco, a highly nicotine rich entity, and iron nitrate mixture followed by their exploitation for the reduction of 4-nitrophenol (4-NP) and non-enzymatic electrochemical glucose sensing. The controlled study suggests that the pyrolysis of tobacco results in ?7 at.% of nitrogen doping, an important heteroatom to enhance the catalytic efficiency of nanocomposites. The kinetics of the reduction of 4-NP follow a pseudo-first-order reaction. The time constant is found to increase with the Fe content in the composite owing to the formation of FeNx centers. The separation of a catalyst with the aid of a magnetic field offers a huge add-on to vouch for the recovery of these catalysts. Along with the display of appealing catalytic reduction, its application to non-enzymatic electrochemical glucose sensing is also demonstrated. Overall, the Nicotiana genus can be used as nitrogen-carbon precursors for designing of targeted N-doped carbon-based composites that could be exploited for various applications. 2021 Elsevier Ltd