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N'-[(E)-Furan-2-Ylmethylidene]-4-Hydroxybenzohydrazide
Acta Crystallographica Section E, Vol-E70(o242), ISSN-1600-5368 -
Na+ doped CuO: A new paradigm electrode material for high performance supercapacitors
This study investigates the influence of sodium doping on the properties of cupric oxide (CuO) thin films synthesized via spray pyrolysis. Comprehensive characterization was conducted using X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDAX), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FESEM), Raman spectroscopy, Hall effect measurements, and electrochemical studies. All films exhibited p-type conductivity, with an optical band gap variation from 1.53 to 1.73 eV. XRD analysis confirmed the dominance of monoclinic CuO, with minor phases of Cu2O and Cu4O3. EDAX and XPS verified the incorporation of Cu, O, and Na elements. FESEM revealed a densely packed morphology with uniform particle distribution and rough surfaces in the electrically optimized film. The Raman spectra of doped samples showed increased intensity and sharpness, attributed to Na + ion-induced polarizability enhancement. Hall effect measurements indicated a tenfold decrease in carrier concentration and a more than tenfold increase in mobility upon sodium doping. Films doped with 4 at.% sodium exhibited the lowest resistivity. Additionally, Na doping enhanced the electrochemical performance of CuO. These findings demonstrate that sodium doping significantly enhances the electrical, optical and electrochemical properties of CuO thin films, making them suitable for applications in optoelectronic devices and supercapacitors. 2024 Elsevier Ltd and Techna Group S.r.l. -
Nano A-AL203 particles agglomerated by spray dying to produce free following powders suitable for /
Patent Number: 202141035836, Applicant: Gowtham Sanjai.
This invention discloses a method to produce free flowing plasma sprayable powders comprised of nano a-Alumina grains, suitable for injection into the high temperature plasma stream of an atmospheric plasma spray system. The plasma sprayable powder particles will be in the range of 30-90 microns, but the grains within the powder particles will only be about 50 nanometers. This micron sized powder, when flowing through the high temperature plasma will dissociate to release the nano grains, resulting in 12 to 15 microns thick coatings, deposited on the substrate per individual pass. -
Nano A-AL203 particles agglomerated by spray dying to produce free following powders suitable for /
Patent Number: 202141035836, Applicant: Gowtham Sanjai.
This invention discloses a method to produce free flowing plasma sprayable powders comprised of nano a-Alumina grains, suitable for injection into the high temperature plasma stream of an atmospheric plasma spray system. The plasma sprayable powder particles will be in the range of 30-90 microns, but the grains within the powder particles will only be about 50 nanometers. This micron sized powder, when flowing through the high temperature plasma will dissociate to release the nano grains, resulting in 12 to 15 microns thick coatings, deposited on the substrate per individual pass. -
Nano Zinc Oxide Particle Synthesis from Bio-Waste Selaginella willdenowii Leaf Extract: A Multi-Faceted Approach for Environmental and Biomedical Applications
Selaginella willdenowii, a commonly used greenhouse fern, was often used as a biowaste to synthesize zinc oxide nanoparticles (ZnO NPs) in an eco-friendly and cost-effective way. UV-Visible spectra studies were carried out to confirm the synthesis of S. willdenowii-mediated ZnO NPs (SW-ZnO NPs), and a peak at 367nm with a sharp band gap of 3.415eV was observed. The X-ray diffraction analysis indicated that the crystalline size of the synthesized SW-ZnO NPs was 11.971nm. The phytochemicals present in the extracts and the compounds involved in the reduction of metal to nanoparticles were determined by Fourier Transform Infrared analysis. Scanning electron microscopy was utilized to analyze the surface morphology and size of the obtained SW-ZnO NPs. The examination revealed that they exhibited a hexagonal shape, with an average size falling within the range of 17-23nm. Under ultra-violet light, reactive blue 220 and reactive yellow 145 dyes showed 78.06% and 60.14% degradation, showing potential photocatalytic degradation activity. The synthesized SW-ZnO NPs also exhibited antimicrobial activity against bacterial strains (Escherichia coli and Bacillus subtilis) and fungal cultures (Candida tropicalis and Candida albicans) showed cytotoxic activity against Hep-G2 cell lines. Our results suggest the green synthesized SW-ZnO NPs have potential photocatalytic, antimicrobial and cytotoxic potential. 2024 World Scientific Publishing Company. -
Nano ZnO@PEG catalyzed one-pot green synthesis of pyrano[2,3-d] pyrimidines in ethanol via one-pot multicomponent approach
A facile one-pot multicomponent protocol for the synthesis of bio-active Pyrano[2,3-d]pyrimidine derivatives by a one- step condensation reaction of substituted aldehyde, malononitrile/methyl cyanoacetate, barbituric acid has been demonstrated using nano ZnO@PEG as a catalyst at room temperature. The present approach offers several advantages, such as shorter reaction time, higher yields, and environmental friendliness. Easy isolation of products, absence of column chromatographic purification, use of commercially available low-cost starting materials and reusability of the catalyst make the methodology viable in organic synthesis. 2020 Elsevier Ltd. All rights reserved. Selection and peer-review under responsibility of the scientific committee of the Second International Symposium ''Functional Nanomaterials in Industrial Applications: Academy - Industry Meet''. -
Nano- from nature to nurture: A comprehensive review on facets, trends, perspectives and sustainability of nanotechnology in the food sector
Nanotechnology has underpinned vital progress in current research and has immensely promoted the food production chain. This review projected the critical intervention of nano-based technologies like modern advancements of nano-based biosensors in detecting mycotoxins, microbial contaminations, antibiotics, pesticides, food additives, and dyes. It also highlighted the starring roles of nanotechnology in terms of active, intelligent food packaging and food safety. These approaches have certainly intensified the strength of food processing technology and improved food quality and maintenance standards during shelf life. Apart from these trending facets, this review throw light on the utilisation of food waste for the biogenic synthesis of nanoparticles and the application of nano-based materials for the recycling process in food production units to ensure a complete cleaner technology. However, monitoring the chronic exposure of food contact nanomaterials should be critically evaluated to ensure food safety. Nanotechnology embraced an influential role in the food sector by providing effective avenues for energy conservation, sustainability, and cues to improve the capital funds well. 2021 Elsevier Ltd -
Nano-architectured polypyrrole based magnetic nanocatalyst for the N- arylation of imidazoles and fused imidazoles
A new magnetically recoverable polypyrrole supported copper based nanocatalyst was synthesized, characterized with various analytical techniques like Fourier-transform infrared spectroscopy (FTIR), Field Emission Scanning Electron Microscopy (FESEM), Energy Dispersive X-ray analysis (EDX), High Resolution Transmission Electron Microscopy (HRTEM), Thermogravimetric analysis (TGA), Vibrating Sample Magnetometry (VSM), and Inductively coupled plasma atomic emission spectroscopy (ICP-AES) analysis. The loading of copper on the surface of the catalyst was found to be 4.23 wt%. The application of the synthesized nanocatalyst was checked for the N-arylation of imidazoles. Excellent catalytic performance was obtained with easy recoverability and reusability upto six cycles. The current green protocol makes it environmentally beneficial for scale-up industries. 2025 Elsevier B.V. -
Nano-technological interventions in crop productiona review
Agricultural industry is facing huge crisis due to fast changing climate, decreased soil fertility, macro and micronutrient insufficiency, misuse of chemical fertilizers and pesticides, and heavy metal presence in soil. With exponential increase in world's population, food consumption has increased significantly. Maintaining the production to consumption ratio is a significant challenge due to shortage caused by various issues faced by agricultural industry even withthe improved agricultural practices. Recent scientific evidence suggests that nanotechnology can positively impact the agriculture sector by reducing the harmful effects of farming operations on human health and nature, as well as improving food productivity and security. Farmers are combining improved agricultural practices like usage of fertilizers, pesticides etc. with nano-based materials to improve the efficiency and productivity of crops. Nano technology is also playing a significant role improving animal health products, food packaging materials, and nanosensors for detecting pathogens, toxins, and heavy metals in soil among others. The nanobased materials have improved the productivity twice with half the resources being utilized. Nanoparticles that are currently in use include titanium dioxide, zinc oxide, silicon oxide, magnesium oxide, gold, and silver used for increasing soil fertility and plant growth. Crop growth, yield, and productivity are improved by controlled release nanofertilizers. In this review we elaborate on the recent developments in the agricultural sector by the usage of nanomaterial based composites which has significantly improved the agricultural sector especially how nanoparticles play an important role in plant growth and soil fertility, in controlling plant diseases by the use of nanopesticides, nanoinsecticides, nanofertilizers, Nanoherbicides, nanobionics, nanobiosensors. The review also highlights the mechanism of migration of nanoparticles in plants and most importantly the effects of nanoparticles in causing plant and soil toxicity. 2023, Prof. H.S. Srivastava Foundation for Science and Society. -
Nanoarchitectures as photoanodes
This chapter looks into providing detailed information on the state-of-the-art and recent trends on materials and nanoarchitectures for improved photoanode device. It provides a roadmap for researchers toward optimization of photoanodes using advanced material engineering. The chapter casts some light on the performance of various photoanode materials and nanostructures, such as TiO2, ZnO, SnO2, Nb2O5, Al2O3, ZrO2, CeO2, SrTiO3, Zn2SnO4, and carbon in dye-sensitized solar cells (DSSCs). Plasmonic photoanodes are an emerging field in DSSC spanning a wide range of materials where the paramount challenge is coming up with effective strategies to incorporate suitable plasmonic structures into nanocrystalline and nanostructured electrodes. Optical excitation of the dye is the basis of DSSC operation, where an electron is excited from the dye molecule into the conduction band of a wideband metal oxide. 2020 JohnWiley & Sons Inc. All rights reserved. -
Nanobiosensors for COVID-19
Coronavirus Disease (COVID-19) is an internationally recognized public health emergency. The disease, which has an incredibly high propagation rate, was discovered at the end of December 2019 in Wuhan, Hubei Province, China. The virus that causes COVID-19 is referred to as severe acute respiratory illness. Real-time reverse transcriptase (RT)-PCR assay is the primary diagnostic practice as a reference method for accurate diagnosis of this disease. There is a need for strong technology to detect and monitor public health. Early notification on signs and symptoms of the disorder is important and may be managed up to a few extents. To analyze the early signs and side effects of COVID-19 explicit techniques were applied. Sensors have been used as one of the methods for detection. These sensors are cost effective. These sensors will combine with a systematic device. It is utilized to detect the chemical compound and combined with a biological component. It is detected through physiochemical detector. Nanomaterials represent a robust tool against COVID-19 since they will be designed to act directly toward the infection, increase the effectiveness of standard antiviral drugs, or maybe to trigger the response of the patient. In this paper, we investigate how nanotechnology has been used in the improvement of nanosensor and the latest things of these nanosensors for different infections. The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. 2023. -
Nanobiosensors: A Promising Tool for the Determination of Pathogenic Bacteria
Pathogenic bacterial detection is a significant concern for the well-being of all human beings. These tiny microbes are capable of causing numerous diseases, which can be nipped in the bud through proper monitoring and controlling at the early stages itself. Some common pathogenic bacteria include Mycobacterium tuberculosis, Bacillus anthracis, Streptococcus pneumoniae, Escherichia coli, Salmonella spp., etc. These microbes contaminate air, food, and water through different modes of transmission. The classical methods used for the identification of these bacteria are time-killing and backbreaking. Rapid pathogenic bacteria determination became possible through the intervention of biosensors. Biosensors are further modified with nanoparticles to build nanobiosensors that are tenfold efficient in bacterial detection. The optical and electrochemical nanobiosensors provide hassle-free detection of pathogenic bacteria, and pointof- care detection is also possible. This book chapter aims to give a brief idea about nanobiosensors starting from the principle to the advantages and disadvantages of bacterial detection. Relevant works of literature on different methods to detect bacteria, types of nanobiosensors, and their efficacy in pathogenic bacterial detection portray the current stand and the need for more innovations in the area of nanobiosensors. The Editor(s) (if applicable) and The Author(s), under exclusive licence to Springer Nature Singapore Pte Ltd. 2022. -
Nanocarbon assisted green hydrogen production: Development and recent trends
The increasing consumption of energy and consequent fast depletion of fossil fuels and associated environmental challenges necessitate transformative innovations in the field of energy conversion. Owing to its exceptional energy density and zero emissions during combustion, Hydrogen is hailed as a promising source of clean and renewable energy that can replace fossil fuels in future energy conversion systems. Since Hydrogen is not readily available in the atmosphere, a variety of pathways have been followed for the evolution of Hydrogen from water and organic materials, which requires the involvement of catalysts to accelerate the reactions. Currently, noble metals and their alloys represent state-of-the-art materials for HER (Hydrogen Evolution Reaction), and the scarcity and high expense of such materials impose significant constraints on their widespread implementation in hydrogen production. In this context, nanocarbons and their composites for HER are worth exploring owing to their abundance, cost-effectiveness, eco-friendliness, exceptionally large surface-to-volume ratio, and excellent electrical and charge transfer properties. Here, three leading hydrogen production methods - biological, electrochemical, and photo-driven- are analyzed based on their characteristics, effectiveness, and limitations w.r.t. different nanocarbon materials. 2023 Hydrogen Energy Publications LLC -
Nanocomposites in Combating Antimicrobial Resistance
Extensive and improper usage of antibiotics has resulted in the outbreak of multidrugresistant microorganisms and increasing antimicrobial resistance (AMR), which has become a significant threat to global health and health care. Resistant microorganisms adapt various resistance mechanisms like modifying the structure of antibiotics, altering the target, inhibiting the internalization of antibiotics, ejection of antibiotics from bacterial cells, etc. By lowering or completely disabling the efficacy of antibiotics, AMR may become a primary cause of mortality if left unattended. Developing effective antiresistance strategies to combat AMR is an urgent need of time. Nanomaterials have great potential to inactivate pathogens, and their mechanism of antimicrobial activity is different from antibiotics. With these unique mechanisms of antimicrobial action, nanomaterials are less prone to develop AMR. Developing nanocomposites can provide synergistic effects to improve the properties and strengthen the antimicrobial capability of individual nanomaterials. In this chapter, contemporary developments in the application of antimicrobial composites such as carbon nanocomposites, metallic nanocomposites, nonmetallic nanocomposites, metalloid nanocomposites, polymer nanocomposites, ceramic nanocomposites, and their hybrid forms to prevent the evolution of AMR will be discussed. The current research direction, prospects, and possible strategies to explore nanocomposites as potent antimicrobial agents to conquer AMR will be highlighted. The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. 2024. -
Nanoencapsulation of Ru(p-cymene) Complex Bearing Ginger-based Natural Product into Liposomal Nanoformulation to Improve Its Cellular Uptake and Antiproliferative Activity
The organometallic compounds are prospective candidates in the row of developing metallochemotherapeutics with the aim of overcoming the limitations of platinum drugs. In order to explore the anticancer properties of organometallic compounds with the natural medicines, two Ru(II)-p-cymene complexes containing the natural products, viz., 6-gingerol (6G) and benzylated-6-gingerdione (B-6GD) have been synthesized and characterized well. The phenolic group of the Ru(6G) complex facilitates its higher cell-free antioxidant activity than its analogue complex. Also, the same complex shows higher cytotoxicity toward A549 lung and HeLa-S3 cervical cancer cells than the Ru(B-6GD) complex but lower cytotoxicity toward A2058 metastatic melanoma cancer cells. Both complexes are shown to easily accumulate in melanoma cancer cells, and their degree of cytotoxicity in the same cells is found to be positively correlated with cell uptake. The cytotoxicity of complexes arises from their intracellular activity, mainly due to the induction of singlet oxygen production in cancer cells. The subcellular fractionation study shows that mitochondria and ER-Golgi membranes might be their predominant targets. Also, the mechanistic investigation revealed that Ru(B-6GD) induces caspase-dependent non-apoptotic cell death whereas Ru(6G) can induce caspase-independent non-apoptotic cell death. Furthermore, both complexes are found to moderately alter the adhesion properties of cancer cells, which is beneficial for antimetastatic treatment. Despite the potential pharmacological activity, Ru(6G) is encapsulated into polymer-supported liposomes to reduce its toxicity and further improve its anticancer potency. The ?-conjugated yne-ene chain of polydiacetylene aids in the development of a stable nanoformulation, which achieved a slow release of the complex. Most importantly, the cancer cell uptake of the liposome-encapsulated Ru(6G) complex is 20 times enhanced and the total ROS formation in cancer cells is significantly increased compared to the non-encapsulated complex. However, the nanoformulation does not alter the antimetastatic potency of the encapsulated complex. 2022 American Chemical Society. All rights reserved. -
Nanofluid flow past a vertical plate with nanoparticle aggregation kinematics, thermal slip and significant buoyancy force effects using modified Buongiorno model
The flow of ethylene glycol-based titania nanoliquid passing through a vertical plate induced by significant buoyancy forces (nonlinear convection) is analyzed with quadratic thermal radiation and considering the aggregation kinematics of the nanoparticles. The nanoliquid is modeled accounting for thermo-migration, Brownian motion, and the effectual thermophysical properties. The realistic zero mass flux and thermal slip conditions are considered on the surface of the plate. In addition, the mechanisms of exponential space-related heat source (ESHS) and thermal-based heat source (THS) are incorporated. The finite-difference technique-based bvp5c routine is used to obtain the numerical solution of thenonlinear system of equations. The effects of the parameters are examined on the dimensionless profiles of velocity, temperature, heat transport rate, the volume fraction of nanoparticles, and streamlines. It was found that the aggregation of nanoparticles significantly advances the temperature field while the velocity field is reduced. The ESHS and THS modulations improve the thickness of the thermal boundary layer. The quadratic thermal convection aspect improves the velocity of nanoliquid. Furthermore, the effects of quadratic thermal radiation assist the growth of the thermal boundary layer. The present results are relevant to various thermal systems including flat plate solar collectors, heat exchangers, and nuclear reactors. 2021 Informa UK Limited, trading as Taylor & Francis Group. -
Nanofluid flowing over a rotating disk that is stretching and permeable: An unsteady model
The model presented in this paper deals with the investigation of the unsteady laminar flow past a stretchable disk. The nanofluids Al2O3/H2O and Cu/H2O are considered for the analysis where the thermal characteristics and flow behavior of these nanofluids are compared. In addition, the system is subjected to the suction force that has significant impacts on velocity of the nanofluid flow. Further, the nanoparticle solid volume fraction is another important parameter that is discussed which has a prominent role on both profiles of the nanofluid. Furthermore, the investigated mathematical model is framed using PDEs that are transformed to ODEs using suitable transformations. The system of equations obtained in this regard is solved by employing the RKF-45 numerical method where the results are obtained in the form of graphs. Various nanofluids flow parameters arise in the study and the impact of all these parameters has been analyzed and interpreted. Some of the major outcomes are that the higher values of nanoparticle solid volume fraction enhance the temperature while it decreases velocity of the flow. The comparison of flow of the two nanofluids concluded that aluminawater nanofluid has a better velocity while the copperwater nanofluid has a better thermal conductivity. World Scientific Publishing Company. -
Nanomaterial - Based Electrochemical Sensor for Monitoring Potential Biomakers of Chronic Disorders
Detecting various biomarkers in the health industry and the biomedical sector has been newlinesignificant due to their crucial role in diagnosing, assessing, exposing, and treating disorders. This work reports electrochemical sensors for detecting biomarkers using different modifications (2D materials and nanomaterials) on carbon fiber paper electrode-based (CFPE) sensors. Adopting these modifications on the CFPE electrode greatly intensified the oxidation and reduction of peak current values. The physio-chemical characterizations of the designed electrodes were examined employing Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), Electron Diffraction X-ray (EDX), X-Rayv Photoelectron spectroscopy (XPS), Fourier Transform Infrared Spectroscopy (FTIR), and Raman Spectroscopy. Cyclic voltammetry (CV) and differential pulse voltammetry (DPV) newlineassisted in optimizing the electrochemical properties via Nyquist plots, sensing performance, scan rate effect, and pH effect. Both electro-activity studies and Nyquist plots confirmed the enhancement in the electroanalytical performance of the fabricated electrodes. Real sample newlinestudies were successfully analyzed using developed electrodes, producing good recovery newlinepercentages. Overall, all the works conducted have been established to be facile and selective, with novelty in the fabrication of ultrasensitive voltammetric-based sensors to quantify different biomarkers. -
Nanomaterial- Based Electrochemical Sensors for Vitamins and Hormones
Women and adolescent girls around the globe have fallen prey to, or rather have become vulnerable to, infections and poor health conditions due to the deficiencies caused by their deprivation of vitamins and proteins along with hormonal imbalance resulting in a snowballing effect causing declining well-being among women. The methods currently available in assessing vital hormones and vitamins are time-consuming and expensive, thereby making them inaccessible to economically weaker sections of society. The work carried out so far in determining and quantifying these biomolecules has mostly employed immunosensing techniques on screen-printed electrodes. Glassy carbon electrodes or carbon paste electrodes modified with metal nanoparticles, graphene, and various polymerized films are also being used for the sensing of these biomolecules. In this chapter, the authors navigate a path through, and give a concise outlook on, various nanomaterial-based electrodes and their comparative efficiency for electrochemical sensing of vitamins and hormones. 2023 selection and editorial matter, Anitha Varghese and Gurumurthy Hegde; individual chapters, the contributors. -
Nanomaterials as novel elicitors of pharmacologically active plant specialized metabolites in cell and organ cultures: current status and future outlooks
Specialized plant metabolites, such as phenolics, terpenes, terpenoids, nitrogen-containing compounds, and sulfur-containing compounds, are commercially valuable owing to their wide array of applications in the medical, pharmacological, cosmetic, agriculture, and food industries. Procuring valuable specialized metabolites from wild or cultivated plants is desirable; however, the concentrations and quality of secondary compounds vary between samples. Therefore, plant cells and organ cultures have been selected as viable alternatives for producing specialized metabolites. Elicitation is a strategy used to enhance the accumulation of specialized compounds in cell and organ cultures. Different biotic substances, including signaling chemicals such as salicylic acid and methyl jasmonate, elements of plant cell walls (cellulose and pectin), polysaccharides from microbes (chitin and glucan), and abiotic substances such as inorganic salts, heavy metals, UV radiation, and high salinity, have been successfully tested and used as elicitors for the hyperaccumulation of bioactive substances in cell and organ cultures. Recently, metals, metal oxide nanoparticles, and carbon-based nanomaterials have been used as unique elicitors to boost the synthesis of bioactive compounds in cell and organ cultures. The applications and usage of nanoparticles as elicitors in plant cell and organ cultures are summarized in this review. The mechanism of elicitation, toxicity, benefits, and drawbacks of using nanoparticles in plant cell and organ cultures are discussed. Graphical abstract: (Figure presented.) The Author(s), under exclusive licence to Springer Nature B.V. 2023.