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Procedural Justice, Perceived Organisational Support, and Organisational Citizenship Behaviour in Business School
Background/Purpose: The effectiveness of a Business School depends on the extra role behaviours or Organ-isational Citizenship Behaviour (OCB) of its committed academics. The social exchange theory postulates that employees tend to display OCB when they know how their organisation would treat them. As B-School academics' inclination towards OCB is less understood, this study examines the interaction between Procedural Justice (PJ), Perceived Organisational Support (POS) and Organisational Citizenship Behaviour (OCB) among B-School academics. Methods: A survey was carried out to collect data from B-School academics, 378 responses were collected from B-Schools from the state of Kerala, India. Data validity and reliability analyses, and direct and indirect effects of research variables were tested using Partial Least Square (PLS) path modelling. Results: The results indicate PJ positively influences POS as well as dimensions of the OCB for B-School academics. Contrary to previous OCB studies, this study finds that POS do not significantly relate to Courtesy. The findings also show that POS fully mediates PJ's relationship with Altruism, Conscientiousness and Civic Virtues of B-School academics. Conclusion: This research explains the dynamics of PJ and POS towards OCB in a B-School setting. The academic setting of this study provides more insight into the relationships and provides insights into enhancing the organisational citizenship behaviour of academics in enhancing educational outcomes. Further, it also adds to existing understanding of organisational behaviour theory. 2021 Elizabeth Dominic et al., published by Sciendo. -
Synthetic Approaches of Prelactone and Its Analogues: A Review
In this review we have discussed the synthetic approaches of prelactones and their epimers from 1997 to date. The presence of unique molecular architecture and its high biological importance enhanced the research activity over the last two decades. Most of the syntheses involve either a chiral auxiliary, chiral pool or catalytic enantioselective approaches as a key step. Overall this review highlights the contribution from different research groups in the total synthesis of various prelactones. 2021 Wiley-VCH GmbH -
Regulation of cryptocurrency: An Indian perspective
Cryptocurrency is a currency created and held electronically in the virtual world. In the absence of a proper legal framework, cryptocurrencies are unregulated in many countries, including India. This article attempts to delve into the concept of cryptocurrency and the issues and challenges they face. It also discusses the current legal and regulatory framework for cryptocurrencies in India and offer suggestions for their better regulation. 2021 Economic and Political Weekly. All rights reserved. -
Light-induced advanced oxidation processes as pfas remediation methods: A review
PFAS substances, which have been under investigation in recent years, are certainly some of the most critical emerging contaminants. Their presence in drinking water, correlated with diseases, is consistently being confirmed by scientific studies in the academic and health sectors. With the aim of developing new technologies to mitigate the water contamination problem, research activity based on advanced oxidation processes for PFAS dealkylation and subsequent mineralization is active. While UV radiation could be directly employed for decontamination, there are nevertheless considerable problems regarding its use, even from a large-scale perspective. In contrast, the use of cheap, robust, and green photocatalytic materials active under near UV-visible radiation shows interesting prospects. In this paper we take stock of the health problems related to PFAS, and then provide an update on strategies based on the use of photocatalysts and the latest findings regarding reaction mechanisms. Finally, we detail some brief considerations in relation to the economic aspects of possible solutions. 2021 by the authors. Licensee MDPI, Basel, Switzerland. -
A Journey toward the Syntheses of ?-Amino-?-hydroxybutyric Acid (GABOB) and Carnitine
In this review, we discuss the synthetic approaches to ?-amino-?-hydroxybutyric acid (GABOB) and carnitine from 1980 to date. The unique structure and biological importance of these molecules have created much interest in various synthetic approaches over the last four decades by organic chemists from across the world. Most of the syntheses are asymmetric methods that involved chiral pool, enantioselective synthesis, enzyme resolution, or a chiral auxiliary as a source of chirality, and the biological significance of the molecules was also discussed. The compiled synthetic methods may fill the existence gap, simplify the complexity involved in the synthesis, and allow the best synthetic route to be found by comparison of all the methods. However, this review also will be useful to prepare similar kind of scaffolds present in various complex natural products. 2021 American Chemical Society -
2,2,6,6-Tetramethylpiperidinyloxyl (TEMPO) Radical Mediated Electro-Oxidation Reactions: A Review
Over the last few decades, the interest in green and sustainable chemistry has led to the development of different synthetic methodologies which utilize clean reagents. In that direction, the electro-oxidation reactions are considered as one of the most interesting and promising methods. This is predominantly due to their environmentally benign nature, as oxidation can be achieved without the need for commonly used oxidizing agents. 2,2,6,6-Tetramethylpiperidinyloxyl radical commonly known as TEMPO is a stable aminoxyl radical utilized for the oxidation of various classes of alcohols to carbonyl compounds by using cyclic voltammetry. The present review focuses on the various electrochemical reactions utilizing TEMPO as a mediator such as the oxidative conversion of alcohols, carbohydrates, amines, sulphur-containing compounds, and alkenes in both laboratory as well as industrial scales and covers literature from 1950 till present date. The properties, reactivity, and yield percentages of these reactions would provide a basis for better electrocatalyst design in future studies involving TEMPO and its derivatives as mediators. 2021 Wiley-VCH GmbH -
Factors affecting luxury brand consumption and its impact on consumer purchase intentions: An India fashion luxury goods sector perspective
This study identifies and analyses the psychographic and demographic factors that influence luxury brand purchase intention in the Indian context. It discusses the existing knowledge pertaining to luxury brand consumption and a conceptual framework is developed based on the review of literature. India's favorable demographic profile, the growing middle class, high disposable income and young population, has helped the Indian luxury market witness a tremendous growth. The research identifies what drives the luxury brand purchase intention for the Indian consumers amidst this growth and analyses how it differs based on demographic variables such as age, gender and income. Based on the model thus created, the research seeks to segment the Indian luxury fashion brand consumers according to the significant demographic and psychographic variables thus identified. A questionnaire on a Likert scale was administered to 250 respondents of different age, income and gender groups within the city of Bangalore. The data was then analyzed using correlation, regression, cluster and frequency analysis in SPSS. The functionality is the major value factors effecting purchase intention of Indian luxury fashion consumer. The other identified value factors are correlated to self and others directedness. Age and income also have a significant influence of purchase intention. It was also found that purchase intention varies between different age and income groups. Finally, it was found that Indian consumers can be segmented as Superficial Luxury seekers, Luxury-Indulgers, Luxury-Avoiders, Attention and approval seekers. 2021 Ecological Society of India. All rights reserved. -
Fluorescein Based Fluorescence Sensors for the Selective Sensing of Various Analytes
Fluorescein molecules are extensively used to develop fluorescent probes for various analytes due to their excellent photophysical properties and the spirocyclic structure. The main structural modification of fluorescein occurs at the carboxyl group where different groups can be easily introduced to produce the spirolactam structure which is non-fluorescent. The spirolactam ring opening accounts for the fluorescence and the dual sensing of analytes using fluorescent sensors is still a topic of high interest. There is an increase in the number of dual sensors developed in the past five years and quite a good number of fluorescein derivatives were also reported based on reversible mechanisms. This review analyses environmentally and biologically important cations such as Cu2+, Hg2+, Fe3+, Pd2+, Zn2+, Cd2+, and Mg2+; anions (F?, OCl?) and small molecules (thiols, CO and H2S). Structural modifications, binding mechanisms, different strategies and a comparative study for selected cations, anions and molecules are outlined in the article. 2021, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature. -
Study of the personal factors influencing voluntary turnover amongst women
In a country where the economic and social independence of a woman is dependent on the way households are structured and organised, the rise in their education and decline in their workforce participation rate is an indication of their paradoxical situation. In this study we evaluate the direct effect of the factors in the personal domain of women on her career break decision. The data from 402 Indian women was analysed using Exploratory Factor Analysis and Confirmatory Factor Analysis, which was then followed by Structural Equation Modelling to check the conceptual model developed through literature review. In present study support personal predictors to turnover intention outcome model, confirming the influence of role conflict, role expectation, role perception, stress, financial soundness, role overload and guilt. Role perception and expectation of women were most significant factors influencing turnover intention of women, implying that the most important change needed is for a change in their own mindset and those around them to arrest their exit from the workforce. 2021 Ecological Society of India. All rights reserved. -
A novel survey for young substellar objects with the W-band filter III: Searching for very low-mass brown dwarfs in Serpens South and Serpens Core
We present CFHT photometry and IRTF spectroscopy of low-mass candidate members of Serpens South and Serpens Core (?430 pc, ?0.5 Myr), identified using a novel combination of photometric filters, known as the W-band method. We report SC182952+011618, SS182959-020335, and SS183032-021028 as young, low-mass Serpens candidate members, with spectral types in the range M7-M8, M5-L0, and M5-M6.5, respectively. Best-fitting effective temperatures and luminosities imply masses of < 0.12M? for all three candidate cluster members. We also present Hubble Space Telescope imaging data (F127M, F139M, and F850LP) for six targets in Serpens South. We report the discovery of the binary system SS183044-020918AB. The binary components are separated by ?45 AU, with spectral types of M7-M8 and M8-M9, and masses of 0.08-0.1 and 0.05-0.07 M. We discuss the effects of high dust attenuation on the reliability of our analysis, as well as the presence of reddened background stars in our photometric sample. 2021 The Author(s). -
Randomized Trials of Psychotherapeutic Treatment for Psychogenic Seizures: Scoping Review
Background: Psychotherapy improves seizure frequency and psychosocial aspects in psychogenic nonepileptic seizures (PNES). Although randomized controlled trials (RCTs) on different psychotherapies have been conducted for almost two decades now, no review has exclusively assessed RCTs of different psychotherapies. Methods: The objective was to review RCTs of psychotherapy for PNES, to understand the impact of different psychotherapies. Eligibility criteria included full-text articles, English articles, published between years 2000 and 2020, randomized trials of psychotherapy, and the adult population. Databases included PubMed, ProQuest, Google Scholar, ScienceDirect, EBSCO, PsycINFO, Cochrane, and a random google search was conducted. Rayyan software was used to include articles that met our eligibility criteria. The search was carried out independently by two researchers Results: Based on the eligibility criteria, seven studies were found. Amongst them, cognitive behavioral therapy (CBT) was the most researched and seemed more effective when paired with standard medical care (SMC) or sertraline. Comparisons of CBT and brief psychodynamic therapy did not reveal significant differences. Other psychotherapies included motivational interview+psychotherapy, which significantly reduced seizure frequency and improved psychosocial functioning. Paradoxical intention therapy also reduced PNES symptoms; however, it has not been researched in the last 15 years. Group psychoeducation seems to have an impact only on psychosocial functioning and not on seizure frequency. Conclusion: CBT paired with SMC or sertraline and MI along with psychotherapy yields the most effective results for PNES in reducing seizure frequency and improving psychosocial functioning. 2021 Indian Psychiatric Society - South Zonal Branch. -
The Renaissance of Electro-Organic Synthesis for the Difunctionalization of Alkenes and Alkynes: A Sustainable Approach
Electro-organic reactions are now considered as one of the most efficient and environmentally benign methodologies to synthesize highly functionalized motifs like difunctionalized unsaturated compounds from readily available substrates. Excellent regioselectivity, functional group tolerance and broad range of substrates are the main advantages of electrochemical difunctionalization reactions. Alkenes and alkynes readily accept radical or ionic derivatives which makes it vital precursors for the electrochemical synthesis of industrially relevant and biologically active molecules through difunctionalization. This review aims to provide the readers an excellent coverage of the different electrochemical difunctionalization of alkenes and alkynes such as 1,2-homodifunctionalization, 1,2-heterodifunctionalization, rearrangement, ipso-migration, cyclization and dehydrogenative annulation reactions. 2021 Wiley-VCH GmbH -
Usage data for predicting user trends and behavioral analysis in E-commerce applications
Reviewing and buying the right goods from online websites is growing day by day in todays fast internet environment. Numerous goods in the same label are available to consumers. It is thus a difficult job for consumers to pick up the correct commodity at a decent price under different market conditions. Therefore, it is important for owners of online shopping websites to better understand their customers needs and offer better services. For these reasons, the access log documented a vast amount of data related to user interactions with the websites. This access log therefore plays a key role in predicting user access trends and in recommending the best product to consumers. This research work therefore focuses on one such methodology for evaluating the pattern and behavioral analysis of users in e-commerce websites. Copyright 2021, IGI Global. -
Recent advances in carbon nanotubes-based biocatalysts and their applications
Enzymes have been incorporated into a wide variety of fields and industries as they catalyze many biochemical and chemical reactions. The immobilization of enzymes on carbon nanotubes (CNTs) for generating nano biocatalysts with high stability and reusability is gaining great attention among researchers. Functionalized CNTs act as excellent support for effective enzyme immobilization. Depending on the application, the enzymes can be tailored using the various surface functionalization techniques on the CNTs to extricate the desirable characteristics. Aiming at the preparation of efficient, stable, and recyclable nanobiocatalysts, this review provides an overview of the methods developed to immobilize the various enzymes. Various applications of carbon nanotube-based biocatalysts in water purification, bioremediation, biosensors, and biofuel cells have been comprehensively reviewed. 2021 Elsevier B.V. -
GalNAc-siRNA conjugates: Prospective tools on the frontier of anti-viral therapeutics
The growing use of short-interfering RNA (siRNA)-based therapeutics for viral diseases reflects the most recent innovations in anti-viral vaccines and drugs. These drugs play crucial roles in the fight against many hitherto incurable diseases, the causes, pathophysiologies, and molecular processes of which remain unknown. Targeted liver drug delivery systems are in clinical trials. The receptor-mediated endocytosis approach involving the abundant asialoglycoprotein receptors (ASGPRs) on the surfaces of liver cells show great promise. We here review N-acetylgalactosamine (GalNAc)-siRNA conjugates that treat viral diseases such as hepatitis B infection, but we also mention that novel, native conjugate-based, targeted siRNA anti-viral drugs may also cure several life-threatening diseases such as hemorrhagic cystitis, multifocal leukoencephalopathy, and severe acute respiratory syndrome caused by coronaviruses and human herpes virus. 2021 Elsevier Ltd -
A review on extraction and separation of cellulose fibers from agro wastes
Over the past few decades, there was significant increase in research concerning resources that have certain desirable characteristics like renewability, ease of availability, economic value, excellent mechanicalthermal properties, biocompatibility and biodegradability. Cellulose is one such resource that possesses these characteristics and yet various sources that constitute ample quantities of lignocellulose are discarded, as their peculiarities and applications were not widely known to the population. Agro wastes, which are generated every year at a tremendous rate, are viewed as a promising substrate for the commercial extraction of cellulose. Hence in this review, an appropriate utilization of these agricultural by-products, with respect to extraction of cellulose is discussed, so as to ameliorate their applications in an aim to diminish the disposal rate of essential commodities. 2021 World Research Association. All rights reserved. -
Is robotics education and training gender dependent? A suggestive robotics syllabus for teacher training
Application of robotics is rapidly increasing in all fields of life. Though robotics education became popular in the 21st century, its teaching and training has not gained much importance across the world, especially in developing and low-income countries. There are various reasons for its neglect and one of them could be gender-science stereotypes. Research studies are yet to explore the reasons for its slow emergence. The present study explores the need and training for educational robotics considering the role of students, teachers, teacher-educators and parents, determining whether it is gender-dependent or not. The study also proposes to come up with a syllabus for robotics training. The study employs exploratory, sequential, qualitative-quantitative mixed-method research design and applies purposive sampling techniques. Researchers conducted semi-structured interviews, including five science teacher-educators, five science teachers, and five trainee teachers majoring in sciences to understand the need, scope and benefits of robotics education. They recruited 100 high school students, 50 teacher-educators, and 100 parents to test whether their interest in robotics is gender-dependent through Chi-square analysis. The study revealed the need for robotics education under four themes and seven subthemes. It has been found that the interest of students and parents and the readiness of teacher-educators for robotics education is gender-dependent. The study came up with a suggestive syllabus for robotics training. It recommends that future researchers should focus on the implementation of robotics teaching for teacher and school education. 2021 Authors. -
Doping and Surface Modification of Carbon Quantum Dots for Enhanced Functionalities and Related Applications
Carbon quantum dots (CQDs) are a unique class of 0D nanomaterials, featured by a graphitic core and shell layers saturated with hydrogen atoms and functional groups. CQDs are prepared through top-down and bottom-up strategies from natural and synthetic precursors. CQDs can be modified through chemical (e.g., surface functionalization/passivation, doping, etc.) and physical (e.g., coreshell architecture, composite material blending, etc.) strategies to control their properties. This review highlights the effect of such modifications on the photophysical properties of CQDs, such as photoluminescence (PL), absorbance, and relaxivity. The dependence of PL upon the size, orientation at the edges, surface and edge functionalization, doping, excitation wavelength, concentration, pH, aggregate formation, etc., are summarized along with the supporting theoretical evidence available in the literature. Also, this review outlines the recent advancements, and future prospective of optical (e.g., sensing, bioimaging, and fluorescent ink) and catalytic applications (e.g., photocatalysis and electrocatalysis) of CQDs enhanced through physical and chemical modifications of their structure and composition. 2021 Wiley-VCH GmbH -
A survey of the studies on Gallai and anti-Gallai graphs
The Gallai graph and the anti-Gallai graph of a graph G are edge disjoint spanning subgraphs of the line graph L(G). The vertices in the Gallai graph are adjacent if two of the end vertices of the corresponding edges in G coincide and the other two end vertices are nonadjacent in G. The anti-Gallai graph of G is the complement of its Gallai graph in L(G). Attributed to Gallai (1967), the study of these graphs got prominence with the work of Sun (1991) and Le (1996). This is a survey of the studies conducted so far on Gallai and anti-Gallai of graphs and their associated properties. 2021 Azarbaijan Shahid Madani University. -
Opportunistic mycoses in COVID-19 patients/survivors: Epidemic inside a pandemic
Being considered minor vexations, fungal infections hinder the life of about 15% of the world population superficially, with rare threats to life in case of invasive sepsis. A significant rise in the intrusive mycoses due to machiavellian fungal species is observed over the years due to increased pathology and fatality in people battling life-threatening diseases. Individuals undergoing therapy with immune suppressive drugs plus recovering from viral infections have shown to develop fungal sepsis as secondary infections while recovering or after. Currently, the whole world is fighting against the fright of Coronavirus disease (COVID-19), and corticosteroids being the primitive therapeutic to combat the COVID-19 inflammation, leads to an immune-compromised state, thereby allowing the not so harmful fungi to violate the immune barrier and flourish in the host. A wide range of fungal co-infection is observed in the survivors and patients of COVID-19. Fungal species of Candida, Aspergillus and Mucorales, are burdening the lives of COVID-19 patients/survivors in the form of Yellow/Green, White and Black fungus. This is the first article of its kind to assemble note on fungal infections seen in the current human health scenario till date and provides a strong message to the clinicians, researchers and physicians around the world non-pathological fungus should not be dismissed as contaminants, they can quell immunocompromised hosts. 2021