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Interrogating Populist Tendencies within the Left Rhetoric in Kerala
After the disintegration of the Soviet Union, there has been an increasing shift from class-based politics to politics based on mobilising "people" within the left-wing political praxis and rhetoric. Such tendencies are visible even within the left rhetoric in Kerala. In the particular context of Kerala, this process is enmeshed with sub-nationalist sentiments and concerns around vikasanam (development). It is possible that this tendency can metamorphose into different directions, depending on the tactical priorities of the left in Kerala. 2022 Economic and Political Weekly. All rights reserved. -
Review on lightweight cryptography techniques and steganography techniques for IoT environment
In the modern world, technology has connected to our day-to-day life in different forms. The Internet of Things (IoT) has become an innovative criterion for mass implementations and a part of daily life. However, this rapid growth leads the huge traffic and security problems. There are several challenges arise while deploying IoT. The most common challenges are privacy and security during data transmission. To address these issues, various lightweight cryptography and steganography techniques were introduced. These techniques help secure the data over the IoT. The hybrid of cryptography and steganography mechanisms provides enhanced security to confidential messages. Any messages can be secured by cryptography or by embedding the messages into any media files including text, audio, image, and video using steganography. Hence, this article has provided a detailed review of efficient, lightweight security solutions based on cryptography and steganography and their function over IoT applications. The objective of the paper is to study and analyze various Lightweight cryptography techniques and Steganography techniques for IoT. A few works of literature were reviewed in addition to their merits and limitations. Furthermore, the common problems in the reviewed techniques are explained in the discussion section with their parametric comparison. Finally, the future scope to improve IoT security solutions based on lightweight cryptography and steganography is mentioned in the conclusion part. The Author(s) under exclusive licence to The Society for Reliability Engineering, Quality and Operations Management (SREQOM), India and The Division of Operation and Maintenance, Lulea University of Technology, Sweden 2024. -
Factors affecting luxury brand consumption and its impact on consumer purchase intentions: An India fashion luxury goods sector perspective
This study identifies and analyses the psychographic and demographic factors that influence luxury brand purchase intention in the Indian context. It discusses the existing knowledge pertaining to luxury brand consumption and a conceptual framework is developed based on the review of literature. India's favorable demographic profile, the growing middle class, high disposable income and young population, has helped the Indian luxury market witness a tremendous growth. The research identifies what drives the luxury brand purchase intention for the Indian consumers amidst this growth and analyses how it differs based on demographic variables such as age, gender and income. Based on the model thus created, the research seeks to segment the Indian luxury fashion brand consumers according to the significant demographic and psychographic variables thus identified. A questionnaire on a Likert scale was administered to 250 respondents of different age, income and gender groups within the city of Bangalore. The data was then analyzed using correlation, regression, cluster and frequency analysis in SPSS. The functionality is the major value factors effecting purchase intention of Indian luxury fashion consumer. The other identified value factors are correlated to self and others directedness. Age and income also have a significant influence of purchase intention. It was also found that purchase intention varies between different age and income groups. Finally, it was found that Indian consumers can be segmented as Superficial Luxury seekers, Luxury-Indulgers, Luxury-Avoiders, Attention and approval seekers. 2021 Ecological Society of India. All rights reserved. -
Comparison of streams delineated using various SRTM, ASTER and Cartosat DEM
Results from the study on the comparison of the stream network delineated from Shuttle Radar Topography Mission (SRTM) DEM, Advanced Space borne Thermal Emission and Reflection Radiometer (ASTER) DEM and Cartosat DEM with the stream network extracted from Toposheets concluded that SRTM DEM of 30m resolution was correlated well with the stream network extracted from SOI toposheets compared to ASTER and Cartosat DEM. It is recommended to utilise SRTM open access DEM of 30m resolution from research work carried out over the study area. 2021 Ecological Society of India. All rights reserved. -
Wastewater treatment using chitosan and its derivatives: A mini review on latest developments
Effluents and contaminants released from the industries are needed to be treated before releasing them to water bodies. Most common effluents from these industrial wastes are organic compounds, dyes and heavy metals. Heavy metals and their associated anions, as well as organic material, have been separated from wastewaters in industries using a variety of methods. Adsorption is an effective method for water treatment as they are less energy consuming and cost effective. Biopolymers such as chitosan, cellulose, keratin are used for the process of adsorption as they are present abundantly and recyclable. Chitosan is a deacetylated product of chitin. Chitosan and its derivatives are extremely essential due to their abundant availability, low cost, environmental friendliness, and biodegradability and can be widely applied in wastewater treatment.-NH2 and-OH groups are present in chitosan and provide chitosan an opportunity to make physical and chemical modifications. Modifications of chitosan into hydrogels and nanocomposites provide wider applications in wastewater treatment. 2022, Horticulture and Forestry Society from Transylvania. All rights reserved. -
A Short Review on Recent Applications of Chitosan Biopolymer in Gene and Drug Delivery
The battle of the human race with genetic disorders was prevailing from the time immemorial. Revolutions and modernizations in science and technology have clearly improved our understanding regarding the molecular basis of genetic disorders thereby aiding in designing new therapeutic interventions in their treatment and prevention. With the advent and development of gene therapy in the last few decades, promising windows were opened for treatment and prevention of genetic disorders and cancer. Despite of its remarkable significance in medicine, the common practice of using viral vectors as gene delivery agents has created controversies and concerns among the scientific community. This made the research focus on biobased polymers as alternative non-viral vector systems for gene and drug delivery for treating genetic disorders and cancer. Chitosan is a cationic polymer that can be easily tailored to serve as gene and drug delivery due to their biocompatibility and biodegradability. Their structural integrity and stability have made them widely used for various applications in the biomedical field. Chitosan and its derivatives have gained more attention as vectors for gene delivery and cancer therapy in the past decade. The amenability of structural modification, non-toxicity and high biodegradability of chitosan derivatives can make them prospective carriers for controlled drug delivery in future. 2022 Chemical Publishing Co.. All rights reserved. -
Mapping the literature on school bullying in India: A scoping review
School bullying has been identified as a major issue among students throughout the world. With around 260 million school students, the largest student population in the world, it becomes essential to investigate this issue in the Indian context. The present work uses the Arksey and O'Malley (2005) framework for scoping review to examine the nature of research on school bullying in India and identify research gaps to be addressed by future research. The review maps the concepts examined, research approaches used, sample characteristics, data collection methods, researcher characteristics, and nature of publications in relation to bullying. Seven databases - JSTOR, PsycNET, Cochrane Reviews, ERIC, MEDLINE, Web of Science, and Cochrane Central Register for Controlled Trials - were searched for sources containing the terms bullying and India published in English and between the years 2015 and 2022. Thirty-eight sources selected for the review suggest that existing research in India on school bullying is limited compared to the West and yet provides a guiding light to future researchers. The findings from this review highlight research gaps in the existing literature and outline areas for further exploration. 2024 Elsevier Ltd -
Hardware in loop network simulators - An insight overview
Network simulation is a method of using software or a tool which can be used to mimic the network conditions that exist in pre-defined places. This kind of simulation allows the developers, designers, researchers and the network planners to intelligently plan, design, develop and test their applications or research work in changing network conditions. With varying network conditions either because of wireless nature or because of user mobility, it is very difficult to simulate the exact network conditions with the existing network simulators. These network simulators are flexible, re-usable and reliable. But they have a limitation of not being able to replicate the actual network conditions in the laboratories. This calls for a system in the loop or hardware in the loop concept to be extended to the network simulators. The idea of system in the loop is not new. In this paper, an overview with the fundamental understanding of the hardware-in-loop concept for network simulators, their applications and a review of the existing hardware-in-loop network simulators with their advantages and disadvantages is presented. 2024 World Scientific Publishing Company. -
The FPTC act, 2020 a blinkered vision
In the name of empowering farmers, the Farmers' Produce Trade and Commerce (Promotion and Facilitation) Act, 2020 has displayed a blinkered vision of an integrated supply chain-by undermining the importance of Agricultural Produce Market Committee markets in a competitive and inclusive agri-food market system. By overlooking many important aspects, the law has taken a quantum leap in the wrong direction. 2021 Economic and Political Weekly. All rights reserved. -
A review on synthetic approaches towards kavalactones
Kavalactones are classes of ?-pyrone and 5,6-dihydropyrone derivatives showing various biological activities, and numerous approaches have been reported for the preparation of these molecules. In this review, we discuss the different synthetic approaches towards these naturally occurring lactones, in both racemic and enantiomerically pure forms, that have been reported in the literature to date. It is hoped that this review will assist researchers in the development of additional and efficient synthetic routes towards kavalactones. 1 Introduction 2 Synthetic Approaches for the Preparation of Kavalactones 3 Conclusion. 2021. Thieme. -
A Journey toward the Syntheses of ?-Amino-?-hydroxybutyric Acid (GABOB) and Carnitine
In this review, we discuss the synthetic approaches to ?-amino-?-hydroxybutyric acid (GABOB) and carnitine from 1980 to date. The unique structure and biological importance of these molecules have created much interest in various synthetic approaches over the last four decades by organic chemists from across the world. Most of the syntheses are asymmetric methods that involved chiral pool, enantioselective synthesis, enzyme resolution, or a chiral auxiliary as a source of chirality, and the biological significance of the molecules was also discussed. The compiled synthetic methods may fill the existence gap, simplify the complexity involved in the synthesis, and allow the best synthetic route to be found by comparison of all the methods. However, this review also will be useful to prepare similar kind of scaffolds present in various complex natural products. 2021 American Chemical Society -
Synthetic Approaches to Diospongins: A Two Decade Journey
Tetrahydropyran units having multiple stereogenic centers serve as excellent building blocks for various active pharmaceutical ingredients (APIs). In particular, the presence of the unique molecular architecture of the trisubstituted tetrahydropyran (THP) unit in diospongins enhances their biological activity due to multiple stereogenic centers and has attracted attention from the synthetic community over the last two decades. In this review, we discuss synthetic approaches to chiral and racemic forms of diospongins during the period 2006 2020 in chronological order. 2022 by the authors. -
Synthetic Approaches of Prelactone and Its Analogues: A Review
In this review we have discussed the synthetic approaches of prelactones and their epimers from 1997 to date. The presence of unique molecular architecture and its high biological importance enhanced the research activity over the last two decades. Most of the syntheses involve either a chiral auxiliary, chiral pool or catalytic enantioselective approaches as a key step. Overall this review highlights the contribution from different research groups in the total synthesis of various prelactones. 2021 Wiley-VCH GmbH -
Synthetic approaches toward butenolide-containing natural products
The butenolide scaffold is ubiquitous in many natural products and pharmaceutical active ingredients. These candidates appeal to organic chemists for the synthesis of products with various biological activities. This review delineates the efforts made in the total synthesis of natural products based on the butenolide core unit such as umbelactones, akolactones, ansepcinolide, lissoclinolide, fugomycin, and muricadienin. Many of the reported syntheses involve chiral pool, enzyme resolution, and chiral auxiliary, or enantioselective approaches as a key step. Overall, this review highlights the synthetic methods involved in the preparation of butenolide-containing molecules and aims to increase the profile of such scaffolds to the synthetic community. 2022 Wiley Periodicals LLC. -
Recent Trends in the Synthesis and Mechanistic Implications of Phenanthridines
Phenanthridine derivatives are one of the most intensively studied families of biologically active compounds. There has been considerable scientific interest in the turn of this century in the synthesis of these N-containing heterocycles as they are prevalent in many alkaloids and also possess striking biological activities including antibacterial, antifungal, antitumor activities. In this regard, a number of synthetic approaches toward the construction of phenanthridine moieties with various substituents, and to increase their yield have been developed by the synthetic organic community. Even though many researchers have developed various innovative methods for the synthesis of phenanthridine derivatives for the past few years, still there is substantial scope for the discovery of novel synthetic methods. In this review, the latest developments in the diverse synthetic strategies of phenanthridine derivatives in the presence and absence of metals were described. The present review also enlightens the use of different reagents, the diversity of the substrates identified, and the plausible mechanisms unravelled towards the construction of these biologically relevant scaffolds. (Figure presented.). 2021 Wiley-VCH GmbH -
Social media influencers: literature review, trends and research agenda
Purpose: This study aims to provide a holistic review of social media influencers (SMIs) research based on a unique approach of bibliometric analysis and content analysis between 2011 and 2020. The review examines the main influential aspects, themes and research streams to identify research directions for the future. Design/methodology/approach: The sample selection and data collection were done from the Scopus database. The sample dataset was refined based on the inclusion and exclusion criteria to determine the final dataset of 183 articles. The dataset was exported in the BibTeX format and then imported into the BiblioShiny app for bibliometric analysis. The content analysis was done following the theory-context-methodology framework. Findings: The several findings of this study include (1) Co-word analysis of most used keywords; (2) Longitudinal thematic evolution; (3) The focus of the research papers as per the theory-context-methodology review protocol are persuasion knowledge model, fashion and beauty industries, Instagram and content analysis, respectively; and (4) The network analysis of the research studies is known as the co-citation analysis and depicts the intellectual structure in the domain. This analysis resulted in four clusters of the research streams from the literature and two emergent themes (Chen etal., 2010) Originality/value: In general, the previous reviews in the area are either domain, method or theory-based. Thus, this study aims to complement and extend the existing literature by presenting the overall picture of the SMI research with the help of a unique combined approach and further highlighting the trends and future research directions based on the findings of this study. 2023, Emerald Publishing Limited. -
The Renaissance of Electro-Organic Synthesis for the Difunctionalization of Alkenes and Alkynes: A Sustainable Approach
Electro-organic reactions are now considered as one of the most efficient and environmentally benign methodologies to synthesize highly functionalized motifs like difunctionalized unsaturated compounds from readily available substrates. Excellent regioselectivity, functional group tolerance and broad range of substrates are the main advantages of electrochemical difunctionalization reactions. Alkenes and alkynes readily accept radical or ionic derivatives which makes it vital precursors for the electrochemical synthesis of industrially relevant and biologically active molecules through difunctionalization. This review aims to provide the readers an excellent coverage of the different electrochemical difunctionalization of alkenes and alkynes such as 1,2-homodifunctionalization, 1,2-heterodifunctionalization, rearrangement, ipso-migration, cyclization and dehydrogenative annulation reactions. 2021 Wiley-VCH GmbH -
Review - Electrochemical Strategies for Selective Fluorination of Organic Compounds
The conventional methods for carrying out fluorination of organic compounds are typically conducted using a pre-modified starting material, usually expensive and toxic reagents. In this regard, electrochemical fluorination has been recognized as a sustainable and scalable strategy. Electrofluorination has proven to be an environmentally benign, highly effective, and versatile platform for the synthesis of selective organofluorine compounds under mild conditions. This review provides an overview on the use of anodic electrochemical methods for vicinal difluorination, iodofluorination, fluoroalkynylation, fluorodecarboxylation, fluoro desulfurization, radiofluorination, and synthesis of fluorinated heterocycles. Modern advances in the field of electrochemical fluorination, such as ionic liquids mediated electrochemical fluorination, triethylammonium halides, mixed non-aqueous solvents, alkali-metal fluoride, and split-bipolar electrodes in the field of electrochemical fluorination are also discussed. 2021 The Electrochemical Society ("ECS"). Published on behalf of ECS by IOP Publishing Limited. -
Evidence-Based Interventions for Improved Psychosocial Outcomes in Harmful Alcohol Use: A Scoping Review
Background. Harmful alcohol use is defined as a drinking pattern that lasts at least one month or has occurred often during the preceding 12 months and that negatively impacts multiple facets of life. It has a high recurrence rate and a poor prognosis, despite the availability of cognitive-behavioral and psychosocial therapy. Emerging neuromodulation techniques for treating harmful alcohol use are gaining traction in the field of psychotherapy, but knowing their efficacy in terms of psychosocial outcomes necessitates an adjuvant approach. This scoping review aims to investigate the existing evidence on the effectiveness of various psychosocial interventions that improve quality of life (QoL) dimensions in conjunction with neurotherapies for individuals with harmful alcohol use. Methods. The review utilized a five-stage technique to search for research papers from 2000 to 2022. After screening and reviewing 41 full-text papers, 29 were found to meet the inclusion criteria. Conclusion. The articles highlighted the advantages of integrated therapeutic interventions such as motivation enhancement therapy, cognitive behavior therapy, neurotherapy, multimodal therapy, supportive therapy, and 12-step facilitation programs. However, limited studies have explored the effectiveness of combining neurotherapy with psychosocial interventions. Implications. Future research should focus on the efficacy of combining neurofeedback with psychosocial therapies to improve QoL for individuals with harmful alcohol use. 2024. Thakuria and Bennett. -
GalNAc-siRNA conjugates: Prospective tools on the frontier of anti-viral therapeutics
The growing use of short-interfering RNA (siRNA)-based therapeutics for viral diseases reflects the most recent innovations in anti-viral vaccines and drugs. These drugs play crucial roles in the fight against many hitherto incurable diseases, the causes, pathophysiologies, and molecular processes of which remain unknown. Targeted liver drug delivery systems are in clinical trials. The receptor-mediated endocytosis approach involving the abundant asialoglycoprotein receptors (ASGPRs) on the surfaces of liver cells show great promise. We here review N-acetylgalactosamine (GalNAc)-siRNA conjugates that treat viral diseases such as hepatitis B infection, but we also mention that novel, native conjugate-based, targeted siRNA anti-viral drugs may also cure several life-threatening diseases such as hemorrhagic cystitis, multifocal leukoencephalopathy, and severe acute respiratory syndrome caused by coronaviruses and human herpes virus. 2021 Elsevier Ltd